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"The ore currently being milled at Delnite is a high pyrrhotite ore with the gold intimately associated with the pyrrhotite. To get maximum recovery of the gold with the lowest reagent cost, it is necessary to keep the pH as low as possible In the laboratory the best results were obtained with a pH of 10 but in the plant it was found that a pH of 11 was the minimum practical pH. With the n1anual control it was difficult to maintain this figure.The Mines Branch had a conductivity probe (see Fig. 1), developed by Dr. G .G. Eichholz that they wished to try out in plant operation.On June 17, 1963, the probe with all necessary control equipment was installed in the regrind circuit (see Fig. 2) at Delnite Mines. Crushed quick lime is fed at this point but it is also necessary to feed hydrated li1ne at two other points in the cyanide circuit in order to maintain the pH close to 11. 0 throughout the circuit. Only the feeding of the quick lime at the regrind mill was controlled in this test.One thing that concerned me with the operation of the probe was whether the reading on the probe chart would correspond to the pH. A look at the graph accompanying this paper will show that except for very minor variations the graphs of the chart reading and the pH reading are parallel. The upper graph shows that the pH reading and the lime titrations also correspond and that the cyanide titrations appear to have little effect on the pH reading.Table 1 gives the results obtained for the two months before and after the instal1ation of automatic control as well as the two months of control. Unfortunately there was a decided change in ore just after the automatic controls were removed. There was much less pyrrhotitc in the ore than usual thus changing the need for lime and cyanide."

Jan 1, 1964

Unplanned open stope hanging wall dilution is a significant cost for many open stope mining operations. Significant advances in empirical and analytical approaches for estimating stope dilution have been made, however, many important factors are still either ignored or assessed in purely subjective terms. There are many hard to quantify factors that simultaneously influence opening stability and dilution. This creates a significant difficulty for determining the influence of a single variable, such as exposure time, on opening stability. Open stope exposure time has been found to be one of the important factors that influences overall stope stability and dilution. A study is currently being conducted to quantify many of the factors influencing open stope dilution. The assessment of a large comprehensive case history database of Hudson Bay Mining and Smelting Co. Ltd. (HBMS) operations forms the basis of this study. This paper presents the findings of a study on the influence of stope exposure time on open stope dilution. The study is based on applying existing empirical stope dilution prediction methods to the extensive HBMS database. Minimising stope mucking time has been recognised as a method to significantly reduce stope dilution. Factors which influence hanging wall dilution, such as drill and blasting methods as well as undercutting the hanging wall, have been applied to reduce the scatter in the database. Empirical design techniques based on rock classification attempt to relate opening stability to ?stand-up time?, however, these approaches have not frequently been applied to the mining industry. Data from a ?stand-up time? graph have been interpreted in terms of an equivalent average depth of hanging wall slough and compared to the HBMS database findings. To add to the existing HBMS database, several stope case histories have been taken from Geco mine. These cases include data from very large open stopes with long exposure times. Data from all three sources suggest that hanging wall slough increases between .14 and 0.3 metres per month for a rock mass Q? value between about 4 and 13.

May 1, 2003

By C. K. Baxter, A. Odeshi, M. Mohammadi, E. D. Cyr

"Metal additive manufacturing has been a revolutionary step in designing new complex shapes with faster and cleaner building capacity in comparison to subtractive manufacturing processes. The ability to print lightweight alloys such as aluminum has made metal 3D printing attractive to different industrial sector from aerospace to energy and bioengineering. Of particular interest in this study, are the mechanical and microstructural properties of AlSi10Mg-200°C alloys. In this project, samples were 3D-printed in horizontal direction using an EOS M290 machine by Direct Metal Laser Sintering (DMLS) technique. Uniaxial tensile tests and high strain-rate impact e tests were carried out to investigate the mechanical properties and to study the repeatability of the process. A constitutive model is developed to predict the results of the mechanical tests at varying strain rates to better understand the high strain-rate behaviour of these alloys. Using optical microscopy, features such as scan tracks and melt pools within the AlSi10Mg-200°C samples were observed, and the microstructure was observed to be homogenous. The previously listed tests were compared to the results obtained for similar cast alloy counterpart, i.e. A360.0.INTRODUCTION A relatively new way of manufacturing parts is on the increase as rapid prototyping becomes increasingly popular throughout the world. Additive manufacturing is a process which, given a 3D model, uses metallic material in powder form to build a part layer by layer until completion (Gu, Meiners, Wissenbach, & Poprawe, 2013). This way of rapid prototyping is very attractive in comparison to other possibilities because of its ability to accommodate complex design and geometries. Conventional manufacturing methods have limitations when it comes to complex geometries, but additive manufacturing allows for increased design flexibilities while maintaining a light and stable final product (Murr et al., 2012). It also allows for a reasonable cost, especially for small batch sizes that would otherwise be extremely expensive."

Jan 1, 2018

By R. Chen, K. Xia

In deep mining activities, blasting induced compressive stress wave would be reflected as tensile wave at a free surface around the openings, which would facilitate the tensile failure of the deep rock since it is much weaker in tension than in compression. It is thus critical to understand the dynamic tensile failure of rocks subjected to static tension for deep rock engineering applications. A modified split Hopkinson pressure bar (SHPB) system is adopted to load Brazilian disc (BD) samples statically, and then exert dynamic load to the sample through stress wave generated by impact. The pulse shaper technique is used to generate a slowly rising stress wave and thus to facilitate the stress equilibrium of samples during each test. Five groups of Laurentian granite (with tensile strength of 12.8 MPa) BD samples under the pretension stress of 0 MPa, 2 MPa, 4 MPa, 8 MPa, and 10 MPa are tested under different loading rates. The result shows that the dynamic tensile strength of the rock decreases with the increase of pre-tension stress, which is easy to understand because pre-tension stress weakens the rock sample. It is also observed that under the same pre-tension stress, the dynamic tensile strength increases with the loading rate, revealing the so-called rate dependency that is common for engineering materials. Furthermore, it is found that the loading rate sensitivity of the rock increases with the increase of pre-tension stress. A qualitative explanation for this phenomenon is that more microcracks are generated and activated under higher pretension stress, resulting in a more viscous material. Based on the results, an empirical equation is proposed to fit the data and explain the dynamic tensile behaviour of rock under pre-tension stress. A physical model is used to simulate the dependency of the dynamic tensile strength of rock on the pre-tension stress and the loading rate, which is shown to be in good agreement with the experimental results.

Jan 1, 2015

By Adam Jordens

Along with gravity separation and froth flotation, magnetic separation is one of the most common techniques for separating minerals. Minerals are separated by a magnetic force that is dependent on a combination of the applied magnetic field, the magnetic field gradient and the magnetic properties of the minerals themselves. Minerals may be classified as diamagnetic, paramagnetic or ferromagnetic based on the way they interact in a magnetic field. The magnetic susceptibility of a material may be determined by using a vibrating sample magnetometer to determine the magnetic moment of the material in an applied magnetic field and then converting this measured moment into the material?s magnetic susceptibility. In the case of rare earth minerals, magnetic separation is commonly used to remove ferromagnetic iron-bearing gangue minerals and to concentrate paramagnetic valuable minerals such as monazite and xenotime. These magnetic separation steps are frequently preceded by a gravity separation step as many iron oxides and rare earth minerals have specific gravities that are much larger than those of typical gangue minerals. By varying the magnetic field intensity it may be possible to use magnetic separation to selectively separate the paramagnetic and ferromagnetic minerals that report to the concentrate after gravity separation. Test work on a Canadian rare earth ore has shown that a gravity concentration step using a Knelson concentrator was able to selectively concentrate heavy magnetic minerals as evidenced by increased recoveries, relative to the Knelson tailings and fresh feed, after processing through a wet variable intensity magnetic separator. Mass pull to the Knelson concentrate was 4.5 % and the magnetic recovery of this concentrate, at 0.94 T, was approximately 40 % higher than the magnetic recovery from the Knelson tailings (70 % versus 30 %). The products of the wet high intensity magnetic separation were also analysed using a vibrating sample magnetometer to determine the magnetic susceptibilities of the various concentrate and tailings products.

Aug 1, 2013

By A. Monballiu, J. A. Martens, Y. W. Chiang, A. Van Audenaerde, R. M. Santos, T. Van Gerven, B. Meesschaert

In this work, bioleaching of non-sulphidic materials by applying chemoheterotrophic bacteria and fungi is studied. It was found that the tested fungus, Aspergillus niger, leached substantially more nickel from olivine than the tested bacterium, Bacillus mucilaginosus. A. niger also outperformed fungal species Humicola grisae and Penicillium chrysogenum in the leaching of olivine. Contrary to traditional acid leaching, the microorganisms leached nickel preferentially over magnesium and iron. On average, a selectivity factor of 2.2 was achieved for nickel compared to iron. This can potentially facilitate postprocessing of the leach liquor and reduce the cost. The impact of ultrasonic conditioning on bioleaching was also tested, and substantial increase in nickel extraction with A. niger was observed. This was credited to an increase in the fungal growth rate, the promotion of particle degradation, and the detachment of the stagnant biofilm around the particles. Furthermore, ultrasonic conditioning enhanced the selectivity of A. niger for nickel, resulting in a selectivity ratio for Ni/Fe equal to 3.5. The chemical resistance of the selected microorganisms to several heavy metal and metalloid (As(III,V), Cd, Cr(III,V), Ni, Pb, Zn) was evaluated. It was found that, with the exception of As(v) and Cd, A. niger has high tolerance to these components. Therefore, this biohydrometallurgical route can potentially be applied to non-sulphidic wastederived materials, such as industrial slags, ashes and sludges.

Jan 1, 2014

By Nelson Hogg

"THE NOR-ACME gold mine is located close to the north shore of Snow Lake, at 54°53' north latitude and 100°03' west longitude. It is about 75 air miles east of Flin Flon, and 36 miles by road from Wekusko at Mile 81 from The Pas on the Hudson Bay Railway.The claims which contain the Nor-Acme orebodies were staked in 1927 by C. R. Parres, who, with his sons, held the ground until 1938 when Nor-Acme Mines Limited was incorporated. In 194 l, on the recommendation of F. Ebbutt (1), this property was optioned by the Howe Sound Exploration Company, Ltd. A program of 50,000 feet of diamond drilling resulted in the outlining of two orebodies containing an estimated 5,000,000 tons with an average grade of 0.15 ounces per ton to a depth of 1,000 feet.A period of inactivity during the war years was followed by the construction of a mining plant capable of treating 2,000 tons of ore per day. Milling started in March 1949, and to the end of 1954 has resulted in the production of 383,793 ounces of gold and 32,906 ounces of silver from 3,331,403 tons of ore.General GeologyThe general geology of the Snow Lake area is described by J. M. Harrison (2), and will not be discussed here except insofar as it affects the Nor-Acme orebodies. The orebodies occur in rocks of Precambrian age that have been classified by Harrison as the Snow group, comprising meta-morphosed sediments interbedded with acid and basic volcanic rocks. The volcanic rocks include pyroclastic types which are unique in the region, a fact which led to their classification in the Snow group rather than the more widespread Missi group that generally occupies the same stratigraphic position above the Amisk group (Figure 1)."

Jan 1, 1949

By Halet. R. A.

"The Quesabe Mine, owned by Brunston Mines Limited, is a gold deposit in the south central part of Duprat Township, northwestern Quebec, about 10 miles northwest of Noranda.It is one of the few gold mines in Canada developed since World War II. The occurrence of gold in the Quesabe fault structure has been known for many years, but serious exploration did not begin until 1945. By 1949, 15,000 feet of diamond drilling had been completed and a shaft sunk to a depth of 635 feet, with lateral development on the 450 and 600 foot levels. In 1949 and 1950 a new shaft was sunk to 1,050 feet, new levels were established at 800 and 1,000 feet, and ore was mined and shipped to the Noranda smelter. After November 1950 the ore mined was treated in the company's own mill. The grade of ore was marginal under existing economic conditions, and production was suspended in April 1952. The mine produced about 100,000 tons of ore with an average grade of approximately 0.25 ounces of gold per ton.GeologyThe bedrock formations are all Precambrian, and the general geology of the area has been described by W. G. Robinson (1). The rocks in the vicinity of the mine are acidic and basic volcanics of the Keewatin series (andesite, rhyolite, agglomerates, tuffs) invaded by the Flavrian Lake granite stock, and by dykes and irregular masses of intrusive felsite, quartz porphyry, syenite-porphyry, diorite, and lamprophyre.The mine workings are in andesite and felsite, about 2,500 feet west of the western margin of the Flavrian Lake stock.The principal structural feature of the area, from an economic point of view, is the Quesabe fault. This steeply-dipping fault cuts all the rock formations of the area, and has been traced for about 11 miles along a strike of north 65 degrees east from Lake Arnoux in the northeast corner of Dasserat Township to Duprat Lake near the east boundary of Duprat Township."

Jan 1, 1949

By D. Eriksen

Zero Emission Gas power, ZEG, is a novel concept where a high temperature solid oxide fuel cell (SOFC) is integrated with a reforming reactor producing hydrogen from natural gas through Sorption Enhanced Steam Methane Reforming (SESMR). The SOFC is used as a high temperature heat source for regeneration of the CO2-absorbent. Moreover, by using part of the produced hydrogen as fuel for the SOFC, the waste heat of the process is considerably reduced. Thus, the process has a very high thermal efficiency and produces both electricity and hydrogen from natural gas. In addition, a stream of pure CO2 is produced in the regeneration step and can be deposited or used commercially. Initial cost estimates indicate a cost of electricity and a cost of hydrogen well below today's prices. A small (1kWel + 1kW H2) demonstration set-up is under construction and experimental results and related research will be presented. This set-up comprises one 2.5kWth H2 SESMR-reactor (about 0.85 Nm3/h H2) operating batchwise with dolomite as the CO2-sorbent. The reactor developed is designed like a parallel plate heat exchanger where the mixture of sorbent and reforming catalyst is packed between the heat exchanging plates. The demonstration set-up includes a 1kW SOFC operating in a continuous mode. The set¬up will therefore demonstrate continuous simultaneous hydrogen- and electricity production, but cannot demonstrate simultanuous electricity- and CO2-production. The set?up is well equipped for on-line monitoring of gas composition, flows and temperatures. This important part of the demonstration set-up is developed and provided by Christian Michelsen Research (CMR). A minor part of the project is the development of a continuous circulating fluidized bed SESMR-reactor system and in another related project the focus is on the development of more suitable sorbents. In these two projects co-operation with University of British Columbia and Lousianna State University, respectively, is highly appreciated.

Jan 1, 2005

By A. A. Nourbakhsha

The main application of refractories based on andalusite in ferrous metallurgy are in air heaters of blast furnaces, mobile mixers, and hot-metal transfer, pig iron ladle, steel-casting, and intermediate ladles. Three specific properties of andalusite are very interesting for the production of high-quality shaped and unshaped mullite refractories: being free of water, its crystal a remains stable without changing its density or volume after firing and therefore has no internal porosity .Graphite additives due to its great wetting ability play an important role in raising the property of refractory bodies. In order to improve properties of andalusite graphite bodies, oxidant agent for increasing in hot strength and oxidation resistance can not be avoided. In this research, firstly 8 pig iron ladles from ESC(esfahan Steel company) with different conditions selected and monitored during usage to determine of main factors affecting on corrosion of refractories. Results showed that tap to tap time, undischarged pig iron ,penetrated pig iron are the main ones.Literature studies showed that the graphite addition help to thermal shock resistance and liquid penetration(steel,pig iron) effect. In this research particle size distribution of aggregates containing andalusite and graphite determined by andreazen equation. Then different mixes with different percentage of graphite,Si, FeSi, SiC prepared by uniaxially pressing under 1500kgf/cm2 pressure by adding 4%wt novalak resin and 0.4%wt HMTA as hardner. Samples fired at 1100-1500oC under reduction atmosphere. According to specific standards density, porosity and CCS measured. Analytical tests such as XRD, SEM were carried out on sample selected from point of view of mechanical properties at different temperatures. Results showed that optimized amount of Si and Fe-Si for _-SiC formation in body is 4 and 6 %wt respectively at 1500OC. XRD and SEM analysis on sample with Fe-Si additives showed no destructive phase through the matrix, also SiC additives not only increase oxidation resistance but also no effect on thermo-mechanical properties.

Oct 1, 2011

By R. V. Typliski, G. J. Labarre

"Hudson Bay Mining and Smelting Co., Limited, Flin Flon, Manitoba, has developed a metallurgical wastewater treatment system employing two-stage lime neutralization, sludge recirculation and conventional mechanical thickening.Laboratory investigations, initiated in 1970, led to the construction of a pilot-scale minewater treatment plant, at Schist Lake Mine, in early 1971. This plant, treating 600 cubic metres /day of wastewater containing 30-60 mg/1 zinc. demonstrated metal extraction efficiencies of 99% under normal operating conditions.On the basis of this pilot work, a second pilot-scale treatment system was established in 1975 at the Flin Flon metallurgical plant to treat zinc refinery process waste water. Through numerous improvements, including automatic con¬trol equipment, the system has evolved to a full-scale operation capable of treating 800 cubic metres/day of wastewater containing 4-11 gm/1 zinc. Treated effluent contains 0.2-20 mg/1 zinc. The hydroxide sludge produced returns to the metallurgical process for the recovery of metals while clarified effluent discharges to waste.With the system, Hudson Bay Mining has achieved its original goal: the reduction of environmental contamination, while realizing a return from metal recovery.IntroductionWith the goal of reducing environmental contamination, Hudson Bay Mining and Smelting began laboratory testwork, during the late 1960's, into the methods and technology for neutralizing and removing heavy metals from acid mine drainage. Based on lime treatment, early tests showed much promise and culminated in the construction of a pilot-scale test plant at Schist Lake Mine in early 1971.This pilot system utilized technology developed in laboratory studies, and related to work then underway by state authorities in Pennsylvania coal mines. The basic operation consisted of a lime slurry tank, baffle reactor and a free-settling basin. Through three summers of operation, the Schist plant, capable of treating 600 cubic metres/day of minewater, produced a heavy-metal extraction of 99% under normal conditions. Although successful in proving the treatment chemistry, the plant displayed deficiencies in sludge densification and handling."

Jan 1, 1980

By K. J. Brouwer, J. P. Haile

"Construction of the first stage of the tailings disposal facility for the Montana Tunnels Project was completed in October 1986. The project is located 37 km south of Helena, Montana, and involves mining of42 million tons of weathered diatreme are at a rate or 13 500 tpd to produce a gold/silver dore, as well as lead and zinc concentrates. The tailings disposal facility for the project includes a fully drained tailings impoundment for storage of the tailings solids, and a process waterpond for storage of all decanted water prior to recyling to the mill. The over-all facility is designed to achieve the basic objectives ofminimizing seepage to the environment in the short- and longterm, and achieving a fully drained stable tailings mass suitable for immediate reclamation on completion of mining. Specific features of the design include a soil bentonite seal and drainage system within the tailings basin, a free draining embankment with a design flow-through capacity of 4000 US gpm and an ultimate height of 230 ft (70 m), and a soil bentonite lined make-up water pond with a capacity of 420 acre-feet (530 000 m'). The tailings will be discharged in a rotational sequence through multiple spigot offtakes to achieve a thin-layer low energy laminar flow. This 'sub-aerial' deposition results in higher stored densities and maximizes liquid-solid separation on the tailings beaches. The over-all design played a major role in the successful permitting of the project, and was significantly cheaper than a conventional wet disposal system, with overall unit costs for tailings disposal of less than US$0.36 per ton.This paper outlines the site characteristics and the tailings material properties and their influence on the design. Extensive use was made of naturally occurring free draining materials as well as bentonite modified soil liners within the tailings basin, embankment and retention ponds. General construction procedures for the various components are described, as well as on-going construction requirements utilizing materials from the open pit. Finally, the over-all costs and unit costs for tailings disposal are presented."

Jan 1, 1988

By D. Madsen, B. Salamondra, A. Moss, D. Etienne

"Raise mining at the Namew Lake Nickel Mine in Manitoba uses 3 m diameter bored raises driven at 45 to 50 degrees dip for stope access and drilling. These raises are developed within the orebody on 20 m centres to accommodate electric-hydraulic longhole jumbos and charging wagons. Critical elements of stope development include delineation of are contacts, control of deviation during raise development, optimal stope sequencing to permit a high extraction rate, drill anchorage installation, production drilling and blasting, and ground control. Procedures to deal with these elements are described, with emphasis on the geotechnical investigation for design of open stopes and pillars.Although mining with drilled raises does not have the flexibility to follow large variations in orebody dip, results to date indicate that it can be used successfully in the thicker ore zones. Thinner zones are currently mined using a modified Avoca method. Some flexibility to accommodate variations in orebody dip in thin are zones may be obtained by using alimack raise climbers to drive access raises, and carry longhole drills and charging equipment. Rock quality has been sufficiently good to maintain stable stope walls for full-height mining of primary stapes at 20 m strike length.IntroductionThe Namew nickel deposit is located 60 km south of Flin Flon, Manitoba. It is a moderately dipping (45 to 50 degrees) pipe-like ultramafic intrusion with a sulphide halo enrichment. The diluted recoverable ore reserves at January I, 1990 are 2.2 million tonnes grading 2.05% Ni and 0.7% Cu. The operation is a joint venture between Hudson Bay Mining and Smelting (60%) and Outokornpu Mines Ltd. of Toronto (40%). The mine is budgeted to produce 530 000 tonnes in 1990. The deposit was discovered in 1984 and mine development commenced in 1987.In the raise mining area, primary stopes will be filled with a high quality backfill consisting of cement and quarried limestone. Secondary stopes will be mined out between the primaries in the second pass of mining. The design extraction rate is 94% over all.The orebody above 120 level has an average mining width of 2.4 m, so is too narrow for raise mining. A modified form of Avoca stoping is used."

Jan 1, 1991

By G. M. Ritcey, S. H. Lucas

"On the north shore of the St. Lawrence River, in Quebec, are located orebodies of low-grade titaniferous magnetite. The Quebec Mining Exploration Company (SOQUEM), who have an interest in the deposits, believed that beneficiation of the could generate sufficient revenue to defray the mining costs and the costs of transporting the ore to a steel production facility. A joint research project of SOQUEM and CANMET investigated alkaline roasting of a magnetic concentrate, followed by leaching of the calcine and separation and recovery of Cr and V by solvent extraction. Aluminum was recovered by precipitation.The present paper describes the roast-leach bench-scale and pilot-plant work leading to the development of the optimum conditions f or the integrated process.A plant flowsheet was developed for the treatment of 5 x 106 tons of magnetic concentrate per annum. Estimates of capital and operating costs were made.Based on a recovery of approximately 90% V, 85% Cr and 75% AI, the total hydrometallurgical plant fixed capital costs, including mining, concentration and shipping, are estimated at $1.021 x 109; the operating costs are estimated at $131.92/ton concentrate. Annual revenue from the Na2CrO4.H2O, V2O5 and A12O3 produced is calculated to be $421 x 106.IntroductionThe Quebec Mining Exploration Company (SOQUEM) acquired in 1968 an interest in four titaniferous magnetite orebodies located in Eastern Quebec. 85 miles north of Mingan on the north shore of the St. Lawrence River. The Mingan deposit, with an estimated tonnage of one billion tons, has a reported average grade of 43% Fe, 6.3% Ti , 1.60% Cr, 0.19% V and 6.1% Al with minor amounts of nickel. SOQUEM, on the basis of previous bench-scale data, believed that the recovery of chromium, vanadium and alumina by alkaline roasting would generate sufficient revenue to defray the mining costs and the costs of transporting the ore to a steel production facility on the coast. One of the approaches selected by SOQUEM for beneficiation of the ore consisted of a combination of magnetic concentration followed by alkaline roasting of the calcine."

Jan 1, 1980

By F. Goodarzi

"The nature and distribution of the inorganic components and the concentration of certain environmentally sensitive elements, such as, As, Sb, B, Hr, Cd, CI, F, Mo, Pb, S, and Se, or elements detrimental to the utilization by industry such as B, Na, P and S are very important in determining coal quality. The concentration of elements in coal is controlled by the following factors: (1) frequency of occurrence of partings; (2) nature and habit of occurrence of minerals in coal; (3) environment of coal deposition; (4)rank; (5) geological setting; and (6) weathering.Selective mining of coal can reduce the input of undesirable elements such as As and S by eliminating the part of the seam which is enriched in these elements. IntroductionCoal is a sedimentary rock of plant origin and consists of two components: an inorganic component (minerals) which is formed by influx of clastic sediments into the coal-forming environment and also by activities of groundwater, and an organic component (macerals) which is formed from plant debris deposited in the original coal-forming environment. However, coal is a generic term with a broad range of utilization characteristics. A coal that is attractive for use in one market - such as generation of electricity (combustion) - may not necessarily be acceptable for use in another, such as for production of coke (Davis, 1978).The elements in coal are associated with both macerals and minerals. The elements associated with coal macerals, such as C, H and N are termed elements with organic affInities. The concentration of elements with organic affmities (including B, Br, CI, F, I, S, and Mg) often decrease with increasing ash content of coal (Nicholls, 1968; and Finkehnan,1982). FIgure 1 shows such a trend for chlorine. Some of these elements may also be incorporated in coal maceral as very fine mineral grains (Finkelman, 1982). The elements with organic affmities are often volatilized during combustion and carbonization of coal and emitted in the vapour phase. Emission of some of these elements (C, 0, Br, N and S) is of major environmental concern (Lim, 1979)."

Jan 1, 1994

By M. Saghaeian, R. Hejazi, Sheikhzadeh. V., A. Abazarpoor

"The morphology of iron ore concentrate particles is known to influence several properties of iron ore pellets, including drop number, compression strength, and reduction properties. This study aimed to determine why grinding methods and particle morphology influence green pellet properties. Particle morphology can be directly related to the grinding method: ball mill (BM) or high pressure grinding roll (HPGR). In this research, two iron ore concentrates, namely Gol-e-gohar and Ardakan, were ground by a BM and HPGR to produce a suitable Blaine value for pelletizing (nearly 1,900 cm2/g). Morphological features of particles were subsequently investigated by sieving and cyclone sizing for particle size distribution, the Brunauer-Emmett-Teller (BET) and Blaine methods for specific surface area (SSA) and scanning electron microscopy (SEM) for the evaluation of shape descriptors. It was concluded that HPGR resulted in generating a greater proportion of fine particles compared to ball milling. The BET results showed that the SSA of HPGR pellet feed was higher than that from the BM due to a greater proportion of cracks, indents and bulges and the creation of new fracture surfaces. SEM images processed by ImageJ software indicated that particles ground by the BM tended to be more rounded and less elongated than HPGR particles because of the breakage model of each method. To show the effect of morphology on the green pellet quality, green pelletizing was performed in a pilot pelletizing disc. The HPGR pellet feed had a higher drop number in comparison to the BM pellet feed, due to the angular and rough shape of the particles.INTRODUCTIONThe demand for fine or ultra-fine particles as feed material for ceramics, composite materials, and mineral processing is on the rise (Kotake, Kuboki, Kiya, & Kanda, 2011). The final concentrate of iron ore processing plants (filter cake) has a size range roughly between 0 and 300 µm, depending on the liberation of Fe containing particles (Meyer, 1980). In general, to produce a suitable pellet feed of appropriate quality, Blaine numbers of 1800–2000 cm2/g should be achieved (Van der meer, 2015)."

Jan 1, 2016

By R. H. McCorkell

"Sample drops were evaporated on Lexan disks on which fission tracks were etched and counted after neutron irradiation. [U] = 0.01 ppb could be measured. This method is rapid, cheap, simple and accurate when sufficient control and checking is possible, but several types of error were encountered in its use, the natures and sources of which were investigated but not always determined. The most troublesome were ""annealing"" processes which sometimes altered the fission tracks so that they were not fully revealed, or acquired varying appearances, after etching. Several different annealing processes seemed to exist and seemed to be produced by alteration of the Lexan surface by dissolved components in the solutions and, perhaps, by radiation and local heating during neutron irradiation. The appearances of the etched tracks varied with the natures of the droplet solutions even when annealing appeared to be absent, and for this reason, standards are best prepared by additions of known amounts of U to sample solutions. Contamination of sample droplets by U-containing dust from the air is best avoided by preparing the disks away from areas where other U-analysis is being carried out.IntroductionFission tracks are regions of radiation dam age produced in solids by the fission of atoms such as 235U. They can be enlarged to sizes visible through optical microscopes by etching surfaces through which they pass with solvents in which the solids are slightly soluble. A sample to be analyzed for U may be placed against a film of a solid of negligible uranium concentration (the track detector) and irradiated with thermal neutrons in a nuclear reactor to fission 235U. The track detector is then etched and the number of tracks per unit area, ?, which is proportional to the uranium concentration of the sample, c, and the neutron do se, n, is found by counting through a microscope. Uranium in solutions ha s been measured by evaporating drops on track detectors, irradiating, etching and determining the number of tracks per drop, T(2,3,4,5). Extensive test s of this method are reported here."

Jan 1, 1983

By P. J. van Staden

Several differences exist between the columns used for laboratory simulations of heap leaching and commercial heaps. Column walls support part of the weight of the ore and restrict the particle packing arrangements. Columns are typically of a diameter that is smaller than the dripper spacing to be used on the commercial heaps. The stacking practices that cause segregation and stratification on heaps are absent from columns. Intuitively, these physical differences would be expected to be the reasons behind the observed differences between column and heap leaching performance. But how can they be quantified, and what is the magnitude of the differences? Could some of these differences be built into column leaching experiments in order to better simulate commercial-scale heap leaching performance to ease the scale-up calculations from column leaching data? Alternatively, could heap construction practices be improved so that the ideal performance obtained in columns could be emulated on heaps? Data from a few heap leaching cases studies that permit direct comparisons between column and heap leaching performance is analysed, to reveal the extent of the differences in resistance to mass transfer. Discussion is provided on the implications for column and heap leaching practice, and for scale-up design procedures. INTRODUCTION Differences have been known to exist between leaching performance observed in laboratory columns and that of commercial-scale heaps. Both the heap leaching kinetics and finally achievable extent of extraction are generally found to be inferior in heaps compared to that achieved in columns. Heap leaching design engineers extrapolate the anticipated heap leaching performance by multiplying the time-axis of a column-leaching curve by a factor of about 2 and the extraction-axis by a factor of about 0.8, as explained by Jansen and Taylor (2002), Scheffel (2002), John (2011) and Scheffel, Guzmán, and Dreier (2016). The procedure is illustrated in Figure 1 by means of a hypothetical example. The solid line represents the leaching performance observed in a laboratory column, and the dashed line represents the anticipated leaching performance of a heap, extrapolated from the column leaching data using these empirical scale-up factors.

Jan 1, 2019

By R. G. L. McCready, Marco Zentilli

"Brogan coal containing mean averages of 6,93% w/w total sulphur (1.1% sulphate sulphur, 1.6% organic sulphur and 4.24% pyritic sulphur) and 16.34% mineral ash was used as the test coal in these studies.Shake-culture leaching studies on seven size fractions of the coal, ranging in size from 0.045 mm to 1.7 mm, showed that the rate of pyrite leaching was inversely proportional to the particle size. As the use of continuous stirred tank reactors would be uneconomical for the reclamation of waste coal, column leaching studies were initiated on coal sieved to >6.35 mm to < 12.7 mm, The leachate was monitored for all metal ions and the release of iron was used to monitor the rate of pyrite oxidation . Measurable amounts of Zn, Co, Ni, Mn, and V, all of which can replace iron in the pyrite crystal structure, were released during the initial stages of leaching. Further, high concentrations of AI, Ca and Sr and trace amounts of Sn, As. Se, B, Ca, Cr, Si, and Ti were detected in the column effluents.These studies suggest that bacterial leaching will remove the pyrite and qualitative amounts of environmentally undesirable trace metals from the coal if such a process is developed for waste coal reclamation.IntroductionIn 1947, Colmer and Hinkle showed that acid mine drainage was the result of an oxidative attack of the iron-mineral sulphides by Thiobacillus ferrooxidans to produce sulphuric acid . Ashmead (1955) proposed the use of these organisms to desulphurize coal , but the subsequent research effort was concentrated on the metabolism and physiology of these extreme acidophiles.A limited number of studies have been reported on the bacterial leaching of pyrite from coal (Silverman et al., 1963; Dugan, 1977). However, the bacterial oxidation of pyrite is a self-limiting first-order reaction, probably due to the precipitation of Fe(OH)J and elemental sulphur , which progressively inhibits intimate contact between the bacterial cells and the sulphide-mineral surface. Consequently, the best pyrite oxidation experiments with coal reported to date required five days to remove 97070 of the pyrite (Dugan &Apel , 1978) using mixed cultures of T. ferrooxidans and T. thiooxidans."

Jan 1, 1985

By H. Sakurai, M. Kato, F. Tanaka

The Mitsubishi Continuous Copper Smelting/Converting Process employs an electric furnace (CL- furnace) for settling the slag/matte mixture formed in the smelting furnace. The conditions in the CL- furnace change its settling efficiency, resulting in high variability of copper losses in slag. Modifications of the operation and maintenance procedures for the CL-furnace have significantly and sustainably reduced the copper losses in Gresik smelter to below 0.7%. A series of flow patterns evaluation in the CL-furnace demonstrated how the chemical reactions and settling conditions of the CL-furnace has been improved by the new operating procedures. Settling mechanisms for the matte droplets in the CL-furnace is also discussed using image analysis of solidified slag. INTRODUCTION The Mitsubishi Continuous Copper Smelting/Converting Process employs an electric furnace (CL- furnace) for settling the slag/matte mixture formed in the smelting furnace. Since the top-blowing in the S- furnace agitates the molten bath strongly, matte droplets are dispersed over the slag phase when melts flow out of the S-furnace. Thus, the CL-furnace has an important role to settle and recover matte droplets efficiently. Since many papers have ascribed major part of copper losses to matte droplets suspended in slag (Tanaka 2007; Genevski et al., 2008; Starodub et al., 2016), flow patterns of slag in the CL-furnace can affect greatly on the profitability of smelters which have adopted the Mitsubishi process. PROCESS DESCRIPTION Figure 1 illustrates the Mitsubishi process schematically. The Mitsubishi process is the only system for continuous production of blister copper from copper concentrates and consists of 3 furnaces connected by enclosed launders those ensure the minimum emission of fugitives. In a smelting furnace (S-furnace) copper concentrates are fed with flux, oxygen-enriched air to form a mixture of slag and matte which cascades down to a slag-cleaning furnace (CL-furnace). The CL-furnace settle matte droplets in the mixture on the crucible from which matte is siphoned to a converting furnace (C-furnace), while discharging the cleaned slag (CL-slag). The C-furnace converts matte to blister copper by the top-blowing of oxygen- enriched air.

Jan 1, 2019