An alkaline roast-leach process for treatment of titaniferous magnetite for recovery of chromium, vanadium & aluminum

"On the north shore of the St. Lawrence River, in Quebec, are located orebodies of low-grade titaniferous magnetite. The Quebec Mining Exploration Company (SOQUEM), who have an interest in the deposits, believed that beneficiation of the could generate sufficient revenue to defray the mining costs and the costs of transporting the ore to a steel production facility. A joint research project of SOQUEM and CANMET investigated alkaline roasting of a magnetic concentrate, followed by leaching of the calcine and separation and recovery of Cr and V by solvent extraction. Aluminum was recovered by precipitation.The present paper describes the roast-leach bench-scale and pilot-plant work leading to the development of the optimum conditions f or the integrated process.A plant flowsheet was developed for the treatment of 5 x 106 tons of magnetic concentrate per annum. Estimates of capital and operating costs were made.Based on a recovery of approximately 90% V, 85% Cr and 75% AI, the total hydrometallurgical plant fixed capital costs, including mining, concentration and shipping, are estimated at $1.021 x 109; the operating costs are estimated at $131.92/ton concentrate. Annual revenue from the Na2CrO4.H2O, V2O5 and A12O3 produced is calculated to be $421 x 106.IntroductionThe Quebec Mining Exploration Company (SOQUEM) acquired in 1968 an interest in four titaniferous magnetite orebodies located in Eastern Quebec. 85 miles north of Mingan on the north shore of the St. Lawrence River. The Mingan deposit, with an estimated tonnage of one billion tons, has a reported average grade of 43% Fe, 6.3% Ti , 1.60% Cr, 0.19% V and 6.1% Al with minor amounts of nickel. SOQUEM, on the basis of previous bench-scale data, believed that the recovery of chromium, vanadium and alumina by alkaline roasting would generate sufficient revenue to defray the mining costs and the costs of transporting the ore to a steel production facility on the coast. One of the approaches selected by SOQUEM for beneficiation of the ore consisted of a combination of magnetic concentration followed by alkaline roasting of the calcine."