Search Documents

By Wei Zhang, Jinhong Zhang

"The adsorption of ethyl xanthate on copper sulfides, i.e., chalcopyrite, chalcocite and bornite, has been studied in situ in aqueous solutions by applying an atomic force microscopy (AFM). AFM images show that xanthate, such as potassium ethyl xanthate (KEX), adsorbs strongly on chalcocite and bornite mainly in the form of insoluble metal xanthate, which binds strongly with the mineral surface without being removed by flushing with ethanol alcohol. This adsorption mechanism is totally different from the one obtained with chalcopyrite/xanthate system, during which oily dixanthogen is the main adsorption product on chalcopyrite surface. The findings obtained from the present AFM study suggest that an AFM image analysis is a powerful tool for the study of the collector’s adsorption on mineral surface and as well the development of novel collector for copper sulfide flotation.INTRODUCTIONIn mining industry, copper sulfide minerals, i.e., chalcopyrite, chalcocite and bornite, are usually separated selectively from non-valuable gangue by froth flotation, which treats the highest throughput and produces the maximum economic outcome of any surface chemistry process. In flotation, collectors are added into the pulp (mixture of water and fine-grained minerals) to selectively adsorb onto the target mineral and render its surface with high hydrophobicity, which is generally beneficial for a strong mineralbubble attachment and thus a high flotation recovery.The adsorption of collector on mineral surface, therefore, is vital for a successful flotation process and it has been studied by applying various surface analysis techniques, such as IR (Infrared Spectroscopy), CV (Cyclic Voltammetry) and XPS (X-ray Photoelectron Spectroscopy). (Poling, 1963; Allison et al., 1972; Mielczarski et al., 1984; Leppinen et al., 1989; Kartio et al., 1996) These studies have revealed a lot of information, such as the reaction, product and mechanism, of the adsorption of chemicals on mineral surface. It is also of great interest to directly get the image of adsorbed collectors on mineral surface changing with pulp chemistry, such as pH, redox potential, ionic strength and chemical’s dosage."

Jan 1, 2016

By B. Schulz, T. Leißner, R. G. Merker

"Ores enriched in critical rare earth elements (CREE) keep on being of particular interest. The CREE are Nd, Eu, Tb, Dy, including Y. In conjunction with beneficiation tests on Y-mineral bearing flotation tailings of complicated mineralogy, the Mineral Liberation Analyses (MLA) was used to work out processing characteristics fraction-wise in terms of modal mineralogy, mineral recovery, locking and liberation, and particle size.Size fractions from mechanical sieving (“real fractions”) as well as fractions created virtually by using filters on the MLA-data of the unsieved head material (“virtual fractions”) were investigated comparatively thereby. The ""virtual-sizing-approach"" features a much simpler sample preparation procedure and considerably lower cost if a fraction-wise investigation of a head sample is needed. It can be conveniently applied to intimately locked ores needing a fine grinding to a particle size distribution (PSD) range below 25 microns for instance. However, its practical use is sometimes disputed in terms of the reliability of the results. Results are shown for the main Y-bearing mineral xenotime and selected main gangue minerals of a low grade REE-ore.The influence of sample representativeness, sample preparation and particle counting statistics turned out to be of crucial importance. Given that all preconditions for reliable results are met, locking characteristics, modal mineralogy, and even PSD trends can be read from virtual fractions.The authors encourage processing engineers to use the virtual approach. They propose practical measures to improve the reliability of the MLA results, identify and tackle conflicting results, and mitigate evaluation problems that may arise."

Jan 1, 2016

By M. Fairman

The effect of welding speed on the microstructure of friction stir processed (FSPed) AZ31B-H24 magnesium alloy was studied using light microscopy, image analysis, and microhardness tests. The grain size of the magnesium alloy was observed to increase after FSP from about 3.5 µm in the base alloy to about 8 µm in the stir zone. The aspect ratio decreased from 1.60 to 1.55 towards the center of the stir zone. The changes in the grain size and shape caused the microhardness of the samples to drop significantly across the FSPed region from 75 HV in the base alloy to below 55 HV in the stir zone. Decreasing the welding speed increased the grain size due to a greater input of heat energy. The faster heating rate due to the lower welding speed caused a deeper penetration of the annealing effects of FSP. It was also observed that the annealing effects caused by FSP were less pronounced with increasing distance from the interface between the sample and pin tool shoulder. The Hall-Petch type relationship of the micro-indentation hardness as a function of the grain size was observed to hold true after FSP.

Jan 1, 2007

By A. Eslami, H. Tabatabaei, M. Kolandoozan, Z. Manafi, A. R. Shahverdi, M. Noaparast, M. Oliazadeh

Application of Acidithiobacillus ferrooxidans bacteria to flotation of Sarcheshmeh low-grade copper sulphide ore was studied. Sarcheshmeh low-grade ore contains pyrite, which causes some problems in the flotation of copper minerals. In this study, A. ferrooxidans was used to change the surface chemistry of pyrite and copper sulphide ores and consequently, their flotation behaviour. In the presence of A. ferrooxidans and xanthate as a collector, pyrite was depressed whereas chalcopyrite and other sulphide minerals were unaffected. In addition, the pulp pH remained unchanged. It was shown that the surface chemical properties of the bacteria can be manipulated successfully to achieve the desired effects in a flotation process. The results showed that the recovery of pyrite in the presence of the bio-depressant is 50% lower than when no bacteria were present. At the same time the recovery of chalcopyrite remained unchanged.

Jan 1, 2004

Concentrator Improvements -1990-1995Back to Basics ?pilot plant versus plant opportunities identified ?understand process fundamentals & baseline -1996-2000Point ?C?Projects ?strategy to improve global competitiveness ?structure implemented to generate & drive ideas ?capital investment for life of mine asset renewal - 2001-200?Six Sigma Methodologies ?emphasis on data, measurements & analyses ?dedicated, highly trained personnel on projects 1990-1995 Improvement Phase??Philosophy??back to basics?approach?understand what each piece equipment needed to do?understand reagents, control variables?confirm operating strategies ??probe, stabilize, institutionalize??test theories, confirm with lab and plant trials?process stability (equipment reliability, controls)?enhanced operator guidelines, operator training?focus on continuous improvement?optimize existing equipment capability?stop looking for ?magic?solutions 1990-1995 Improvement Phase??Technical?finer grind, same equipment?optimize media size/shape to grinding application?balanced available ball mill power to applications?lowered cyclone feed densities where possible?improved selectivity, same equipment?balanced available cells to applications?streamlined process (eliminate process steps)?added cleaning stages where required?understanding pulp/mineral surface chemistry?lowered flotation pulp densities 1990-1995 Improvement Phase??Effort?numerous studies to understand process?liberation and mineralogical characterization?pulp and mineral surface chemistry?flotation kinetics and entrainment?extensive internal and external manpower?Brunswick, Noranda Technology Centre?CanMet, AMTEL, MinnovEx, Lakefield Research, McGill University?small capital expenditure

May 1, 2002

By I. Osvath, I. Gombköto, G. Mucsi, Z. Molnár

"In the present research, a deposited brown coal fly ash was used as raw material for geopolymer. The reactivity of the fly ash was altered using mechanical activation, which is one of the promising methods to improve bulk and surface reactivity. The mechanical activation experiments were carried out in a high energy density mill using 5 m/s circumferential speed, and various residence times (1, 3, 5, 10, 15 and 60 min). The effect of mechanical activation on particle size distribution was measured by a laser particle size analyzer and structural changes using FT-IR. Geopolymer samples were prepared from mechanically activated fly ash with an alkali solution. The progress of geopolymerisation was monitored using an Isothermal Conduction Calorimeter. The heat flow curve obtained indicated that reactions were more prominent and started much earlier in the mechanically activated samples. This observation is further supported by the compressive strength results which also improved in geopolymers using mechanically activated fly ash. Based on the obtained results, it can be inferred that mechanical activation is a possible way to enhance the reactivity of fly ash and consequently properties of resulting geopolymers.INTRODUCTIONCoal fired power plants generate fly ash and slag in huge amount worldwide, about 780 million tons/year (Heidrich et al. 2013). Due to the relatively low utilization rate, enormous quantities of these wastes are landfilled in ponds. The fly ash is the finest grained particle fraction of the solid ash, which is transported with flue gas, and removed by electrostatic or bag filters. The fly ash has pozzolanic activity, it does not react with water, but in the presence of calcium hydroxide solution hardens and solidifies, producing a reaction product practically insoluble in water (Opoczky, 2001). The most important property of the fly ash regarding geopolymerization is its reactivity, which depends on the chemical and phase composition, the dispersity (specific surface area, particle size distribution), and the morphology of the fly ash particles, and determined by the physical properties and chemical composition of the fly ash. Geopolymers concerning their chemical structure are polysialates, where the sialate (silicon-oxoaluminate) network is built up from the bonds of Si-oxide and Al-oxide by sharing oxygen atoms (Davidovits, 1988)."

Jan 1, 2016

By Jonathan Peck, Jim Gray

"With the implementation of more advanced monitoring, control and locating systems in surface mines, there is an ever increasing need for their mine-wide integration toward achieving over-all optimization. AQUILA Mining Systems Ltd. is developing the basis for a comprehensive real-time monitoring, control and information system called the Total Mining System or TMS. This system is being designed to address both current and future needs of open pit mines toward improving productivity and minimizing costs, through better two-way information flow between each component in the operation. At a basic level, feedback from equipment and process monitoring will enable decision making to be based on quantitative, on-demand information, thus permitting proactive rather than reactive planning. Dynamic planning would be a valuable tool as market conditions fluctuate, equipment fleets age and variations in the grade, quality, geometry and hardness of the mined material all contribute to either changing production targets or levels of achievable performance. Such a capability could be implemented within the next two years.At a higher level, and within five years, autonomous operation and/or real-time supervisory control of mobile and stationary equipment in open pit mines will be achieved. A discussion is provided in regard to the development and implementation of an autonomous haultruck and blasthole drill, to demonstrate the need for such a system.This paper outlines a preliminary program for the design, development and implementation of this system, primarily in relation to high-level communications and its role in the future automation of open pit mobile equipment."

Jan 1, 1995

By G. A. Highcock

"Operations started at BCL in December 1973J and the smelter is currently in the seventh year of its fifth campaign. The next major shutdown is scheduled for 1995. During the current campaign, a number of major on-line refurbishments have been carried out without any significant disruption to production. These include the complete rebuild of both drying plant electrostatic precipitators, the installation of a new electrostatic precipitator at the flash furnace, the conversion to a distributed control system throughout the smelter, and the installation of a converter air blowing control system.IntroductionBCL Limited operates a nickel-copper mine in northeastern Botswana approximately 100 km southwest of Francistown. Surface operations for the production of high-grade nickel-copper matte at a design capacity of 42 000 metric tonnes per annum, were commissioned in December 1973. Detailed descriptions of the mine and surface facilities have been presented previously(1-3).Over the years, a number of major engineering modifications and metallurgical projects have been carried out to overcome operating difficulties. improve metal recoveries, increase production rates and provide a better working environment.One of the major results of these projects was an increase in the 19805 in flash furnace feed capacity from 70 t/h to 120 t/h of new concentrate with a nominal feed rate of 105 t/h being achieved.(4)Because of the ore characteristics, i.e. a high mass fraction of ore reporting to concentrate, BCL operates one of the highest capacity spray drying plants and flash smelting furnaces in the world(5).A schematic of the BCL smelter is shown in Figure 1. The smelter is now in the seventh year of its fifth campaign, with the next shutdown scheduled for mid-l99S. In this campaign, the following major projects were completed:"

Jan 1, 1995

By T. L. Lee, D. Y. Tan, J. Mi

Considerable progress has been made in studying the mechanism and effectiveness of using ultrasound waves to manipulate alloy solidification microstructure, However, uncertainties remain in both the underlying physics of how microstructure evolve under ultrasonic waves, and the best technological approach to control the final microstructure and properties. We used the ultrafast synchrotron X-ray phase contrast imaging facility housed at the Advanced Photon Source, Argonne National Laboratory, USA to study in-situ the highly transient and dynamic interactions between the liquid metal and ultrasonic waves/bubbles. The dynamics of ultrasonic bubbles in liquid metal and their interactions with the solidifying phases were captured in-situ for the first time. The experiments were complemented by the simulations of the acoustic pressure field, the pulsing of the bubbles and the associated forces acting onto the solidifying phases, providing more quantitative understanding for using ultrasound to control the growth of dendritic grains and to enhance grain multiplication effects for grain refinement.

Jan 1, 2014

By V. Itkin

"Three methods were tested for the beneficiation of aluminum scrap, generated by heavy medium separation of non-ferrous automobile scrap residue. These were: crushing in a shredder followed by screening; grinding in a ball miff followed by screening; and eddy current separation. The best results were obtained with the grinding-screening method. IntroductionThe usual method of aluminum alloy reclamation from non-ferrous automobile scrap residue consists of a two-step heavy medium separation to remove materials lighter than and heavier than aluminum. The resulting aluminum scrap still contains over 15% impurities such as stones and glass, heavy rubber, insulated copper wire , plastics and heavy metals entrapped by macerated aluminum piece s, composite fragments, etc.(2). Upon melting, these impurities create difficulties and yield a low ingot recovery-65% to 70%, hence small foundries avoid this material.There are a number of ways to improve the quality of aluminum scrap such as:(1 ) crushing of the scrap, which powders the brittle content , a major impurity component, followed by screening out of the dust(2) eddy current separation , which removes metals from the material flow, and(3) implement better methods for density separation.The eddy current separation and two variants of the comminution-screening technique were studied by Intermetco Ltd., Hamilton , Ontario."

Jan 1, 1986

By Bian Xue, Wu Wenyuan

In order to recycle the iron and rare earth from the Baotou tailings, a roasting method was developed involving the addition of C, Ca(OH)2, and NaOH, designed to both decompose the rare earth minerals and convert haematite into magnetite and allow its recovery. The effect of various parameters such as roasting temperature, roasting time, C addition, Ca(OH)2 addition, and NaOH addition on the reduction ratio of haematite (iron sesquioxide) and decomposition ratio of rare earth were investigated. The results showed that the reduction ratio of haematite and the decomposition ratio of rare earth could be as high as 85% and 95% respectively when the roasting temperature was 650°C, roasting time was 60 min, Ca(OH)2 addition was 4%, NaOH addition was 3%, and C addition was 1.5%.

Jan 1, 2014

By Robert B. Parsons

"This article is based on a paper presented by Jim Scott at the 1988 annual convention of the Prospectors and Developers Association of Canada. The paper suggests a number of factors that might be taken into account in negotiating royalty terms.IntroductionRoyal ties are a part of mining life in Canada. They are used by many kinds of individuals in many kind s of situations. Prospectors commonly take royalty interests back when they transfer claims to development companies. Mining companies disposing of undeveloped (or sometimes even developed) properties are often paid at least in part by royalties. Royalties are even used by institutional investors with no other connection with the resource industry.Such different royalty holders have different investment goals, different cash flow requirements, and different risk / return preferences. These differences have given rise to a number of different royalty types. These types range from the simplest cents-per-ton royalty (where the operator pays a royalty at a fixed rate per ton milled) to net smelter return or ""NSR"" royalties (where the royalty is based on a percentage of the operator's NSR) all the way to net profit interest or ""NPI"" royalties (where the royalty is based on the operator's bottom-line net profit),The fundamental difference between the many royalty types is in the risk / return relationship. The cents-per-ton royalty, for example, is relatively risk-free. Of the many economic factors which affect a mine, the only one which will affect the royalty holder is the amount of ore physically milled. On the other hand, the potential for significant gains under a cents-per-ton royalty is also very limited. The royalty holder will not share in any increases in the market price of the end product or any cost reductions achieved by the producer."

Jan 1, 1989

By N. Katsikaros, R. Agius, B. Adaszynski

"With stricter limits globally being imposed on cyanide discharge levels in plant tailings, having a reliable and well designed cyanide detoxification circuit is critical for any operation. The INCO SO2/Air method is most commonly used for cyanide detoxification where sulfur dioxide and oxygen combine to oxidize cyanide to the much less toxic cyanate. This paper discusses the steps involved with the development, from laboratory through to design, of a robust cyanide detoxification circuit. The goal is to produce a cyanide detox circuit that reliably meets discharge target with the lowest operating and capital cost.Design begins in the laboratory where continuous tests simulate full scale operation of a detoxification circuit. Detailed design relies on several design parameters, based on theory and experience, to ensure the reactor can satisfy requirements of the cyanide destruction reaction. Selection of the correct reagents and their supply to the reactor is important to an operable process with minimal operator workload. The operability of the system relies on correct process control strategies to maintain optimal reagent addition and chemical conditions in the reactor. These design factors are critical to providing a robust plant that will consistently meet cyanide discharge levels, ensuring uninterrupted production and plant profitability."

Jan 1, 2014

By R. Bonifaz, R. Subiabre

The Chagres Smelter, part of the Anglo American plc group, situated 80 Km north of Santiago in Chile, completed a series of operational improvement in 2005 resulting in an optimum capacity in its operational units. At present the Chagres Smelter has developed an operational strategy which seeks to reduce bottle-necks in the production process. In this way we have managed to lower operational cost, decrease energy consumption and maximize the capacity of the Acid, Oxygen, and Smelting, Converting, Refining and Casting units. A constant review of international benchmarks together with continuous staff improvement and the latest smelter technology have combined to place Chagres among the finest smelting works in the world. In response to environmental challenges, we have studied various options for investment that will yield a suitably profitable business to benefit both Anglo American and Chile. The most relevant technical indicators are: energy consumption=6,3 GJ/ton fine copper (1st in the world), intensity of smelting rate in Flash Smelting unit of 6,900 ton of copper concentrate/m2 of furnace area (1st in the world) and to be one of the top five smelters in achieving the lowest direct cash cost .

Jan 1, 2007

By A. M. Brown, P. V. Straznicky

Dimpling as a means of flush countersinking rivets is an old process predominantly used in secondary structures. The introduction of GLARE as an aerospace material has renewed interest in dimpling and its possible application in primary structures. The dimpling process is able to prevent the creation of a machined knife-edge in the thin aluminum plies of the GLARE sheets. In addition, dimpling eliminates the need to use reduced height rivets, such as the NAS 1097 rivet style. This investigation expands on an earlier study into dimpling of GLARE by Rans and Straznicky. In order to tailor the dimpling process to GLARE, FEM simulations were developed. After verification, a study was performed to find the best parameters for dimpling GLARE3-2/l. Coupon fatigue tests were carried out and the dimpled joints demonstrated increased fatigue lives over the conventional machine countersunk joints. Future wide panel fatigue tests are planned to confirm the usefulness of dimpling thin GLARE laminates.

Jan 1, 2006

By T. C. WEBB

In New Brunswick, significant potash deposits are intimately associated with rocks of the Lower Carboniferous Windsor Group. To date, two deposits high in sylvinite, up to 20 m thick, have been confirmed at depths between 490 and 1,035 m below surface near Plumweseep and Salt Springs. These areas are currently under development by the Potash Company of America and the Denison-Potacan Potash Company respectively. A third area, near Lower Millstream, is also known to contain potash-bearing evaporites and is now being explored by BP Exploration Canada Ltd. All three areas are situated in the western half of the Moncion Subbasin and are within 25 km of Sussex. Numerous similarities in stratigraphy, thickness, mineralogy and structure suggest that deposition of evaporites throughout much of southern New Brunswick was contemporaneous and extended over a considerable area. Future opportunities for potash exploration in the province thus seem excellent. A number of large unexplored areas remain in the Moncion and Cumberland Subbasins and in parts

Jan 1, 1984

By A. A. Bakke

"The Fort Knox gold deposit is hosted within the Fort Knox Pluton, a Cretaceous multiphase granitic body that intrudes the Fairbanks schist. Gold occurs along the margins of stockwork veins and veinlets, quartz-filled shear zones, and along fractures within the granite. The mineralization is generally sulphide-poor and closely associated with trace amounts of bismuth, tellurium and to a lesser extent with molybdenum and tungsten. At present, proven/probable reserve estimates, based on a cutoff grade of 0.39 g/t Au, are 158.3 million tonnes grading 0.83 g/t Au.The Fairbanks schist comprises the bulk of the country rock. The dominant lithologies present include muscovite-quartz schist and micaceous quartzite. Immediately north and south of the main orebody, mixed metamorphic lithologies of the Cleary sequence, a subunit of the Fairbanks schist, have been mapped. Development of local zones of weakness, most likely due to a broad regional warping event, resulted in brittle-ductile deformation and activation of a northwest-southeast shear couple between contrasting lithologies.The Fort Knox Pluton consists of at least three phases based primarily on textural differences. Intrusion of a fine-grained granite was followed by a medium-grained porphyritic granite. The youngest intrusive phase is a coarse-grained, seriate porphyritic granite, the Vogt Stock. The Vogt Stock forms an elongate dome with the axis in the east-west direction. Structures displayed in the overlying units, believed to be the result of doming, include tension fiSSUres and longitudinal fractures.Premineralization fractures, the result of the magmatic doming, provided conduits for initial stockwork quartz vein development and quartz enrichment in shear zones. Weak development of vein-controlled phyl/ic, potassic, albitic, and argillic alteration styles are present. Evidence of a late thermal event resulting in a low-temperature alteration assemblage of calcite + zeolite (stilbite) + chalcedony + clay occupies breccia zones, joint surfaces, and fractures within the granite."

Jan 1, 1995

By A. Scheltema Beduin, M. Kalisch, E. Floch, R. J. Dijkhuis, H. J. Oterdoom

In metallurgical copper production, the traditional aim is to increase recovery of copper to the maximum. SMS Siemag (SMS) has supplied numerous furnaces for this application. New targets are to make sure end of line products are as safe as possible with respect to health and environment, and to maximize raw material utilization. This means a for example a minimization of leachable metals in slag, so it can be safely used as a construction material, and either a targeted concentration or fixation of volatile compounds, such as arsenic. Currently, 2 process routes are generally applied for slag cleaning. The first is grinding followed by flotation, and the second is slag cleaning in an (electrical) furnace. Popularity of both options has fluctuated over the years, and currently the milling-flotation seems to be the more popular option. In this article some of the advantages and disadvantages of both methods are described, and especially how long term environmental policies could have an impact on the decision which process route to choose. Finally, this article will describe some of the developments SMS is working on in pyrometallurgical slag cleaning that could influence the direction for the design of the copper plant of the future.

Jan 1, 2014

By F. Parada

During copper smelting and converting processes, slag generated is pyrometallurgically cleaned and then disposed, containing around 1 % of this metal. However, important amount of molybdenum initially contained in concentrates also goes to the slag phase. Research on molybdenum recovery from water granulated slags using acid leaching at low temperatures was conducted to find an efficient way for molybdenum extraction with lower magnetite in the slag. However because of the high fayalite content high acid consumption was found. Molybdenum can be recovered from solution using ionic exchange resins, but high silica content interferes with extraction. Some studies addressed to minimize silica extraction as well as alternatives of selective silica precipitation in order to develop a technically feasible process.

Jan 1, 2007

By Y. Miyabayashi, K. Nishikawa, H. Nagai

JX Nippon Mining & Metals Group recovers valuable metals from end-of-life electronic products in an economical and environmentally-benign way, based on technologies that have been acquired in mining, smelting, and refining operations over time. End-of-life electronic products contain halogens and hydrocarbons. When such materials are treated in the copper smelting process, corrosion of equipment and discoloration of sulfuric acid occur. As a countermeasure to these problems, we have developed pretreatment processes that include an incinerator, exhaust gas washing towers, and a defluorination facility. By implementing these improvements, we have been able to treat a large volume of end-of-life electronic products efficiently in the copper smelting process.

Jan 1, 2014