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By Michael Zinigrad

The quality of metallic materials depends on their composition and structure and these are determined by various physico-chemical and technological factors. To effectively prepare materials with required composition, structure and properties it is necessary to carry out a research in two parallel directions: Comprehensive analysis of thermodynamics, kinetics and mechanisms of the processes taking place at the solid-liquid-gaseous phase interface during welding processes and development of mathematical models of the specific welding technologies. We have developed unique method of mathematical modeling of phase interaction at high temperatures. This method allows us to build models taking into account the thermodynamic characteristics of the processes, the influence of the initial composition and temperature on the equilibrium state of the reactions, the kinetics of heterogeneous processes, the influence of the temperature, composition, hydrodynamic and thermal factors on the velocity of the chemical and diffusion processes. The model can be implemented in the optimization of various technological processes in welding, surfacing, casting as well as in manufacturing of steels and non-ferrous alloys, materials refining, alloying with special additives, removing of non-metallic inclusions.

Jan 1, 2003

By V. Jovicic, J. Likar

The knowledge of the geological sequence and hydrological conditions in the area of portals was the basis for the design of the entry of the highway into tunnel Trojane. Mudstone, claystone and sandstone dominate the rock layering, which is tectonically reworked and contains structural anomalies. The complexity of the sequence makes it impossible to survey all the relevant features along the full 3km length of the tunnel. Sudden and frequent transitions between litological sequences impose potential instabilities and make the excavation of the tunnel particularly difficult. The initial survey established the zones of potential failures. These were monitored using topographic survey and inclinometers with an aim to make further geotechnical analyses more reliable and adjusted to the ground conditions. The analyses of the wall construction and the results of the monitoring showed that the design of the retaining wall was adequate. La connaissance de la séquence géologique et des conditions hydrologiques dans l'aire des portails a été la base pour la planification de l'entrée de l'autoroute dans le tunnel Trojane. Le schiste, l'argilite et le grès dominent la couche rocheuse qui est tectoniquement transformée et contient les anomalies structurales. A cause de la complexité de la séquence, il est impossible de revoir toutes les particularités le long des 3 kilomètres de la toute longueur du tunnel. Les transitions soudaines et fréquentes entre les séquences lithologiques imposent l'instabilité potentielle et font l'excavation du tunnel particulièrement difficile. La revue initiale a été établie sur les zones où il existe l'éboulement potential. Elles étaient contrôlées à l'aide de la revue topographique et de l'inclinomètre pour que les analyses géotechniques suivantes soient plus sûres et adaptées aux conditions du sol. Les analyses de la construction des murs et des résultats du contrôle ont montré que la planification du mur réteneur était correspondante. Der Autobahneingang in den Trojane Tunnel war projektiert auf Basis von der Kenntnis der geologischen und hydrogeologischen Bedingungen in dem Portalgebiet. Das Gebiet besteht aus dem Tonstein und dem Sandstein. Die Schichten sind tektonisch verformt und sind deswegen sehr heterogen. Die anfaenglichen Untersuchungen haben die Zonen von den potentiellen Bruechen definiert. Weitere geotechnische Analysen waren fitted an reale geologische Bedingungen durch das Monitoring der potentiellen Bruchzonen, welches aus den topographyschen Messungen und Inklinometerdaten entstand. Die Analyse des Wandbaues und die Resultate von dem Monitoring haben erwiesen, dass die Wandprojektierung entsprechend war.

Jan 1, 2003

By D. L. Kowal, P. J. Whittaker, M. A. Tuzun, N. O. Lotter

The area of flotation testing of drill-core is important in the business plan of most mining companies. Metallurgical information derived from this practice can be used to advantage in strategic decision-making. Sampling, flotation testing and subsequent Qem SCAN analysis of a mineral resource is one example of this approach. Anew resource, located in Sudbury, Ontario, is being assessed for the Sudbury Operations of Falconbridge Limited, which includes the Strathcona Mill. In this case, it was possible to improve the value of information from sampling and flotation testwork by using an improved, statistically-based test design, by sampling the resource by generic end-member ore type, and by integrating the Mineral Processing and Mineral Science disciplines into a Process Mineralogy team. In addition to producing standard metal grade and recovery information, this new approach provides more reproducible information from representative samples and flotation testing in a replicate format. Qem SCAN technology is used to produce a size by size mineral balance, including both modal percentages and liberation, from which flotation models for each ore type can be developed. As a result, a key understanding of the potential behaviour of a given ore type, if mined and then processed at the current mill operation, is gained at the 95%confidence level. The three ore types of this mineral resource were shown to have different flotation characteristics. Quantifying the mineralogy and liberation in each of the three ore types, has shown that this difference is due to changes in modal percentages of ferro-magnesium and magnesium silicate minerals such as pyroxene, talc and serpentine. Liberation across the three ore types is very similar and is therefore not responsible for variation in flotation performance.

Jan 1, 2003

By K. Adam

Improved environmental performance comprises one of the key objectives of the sustainable development in the mining industry. Within this framework, a research project was undertaken by TVX Hellas, a mixed sulphides producer in northern Greece, in order to develop and evaluate anaerobic wetlands as an alternative method for the treatment of acidic waters originating from old mine areas. The anaerobic treatment using organic substrates, aimed to neutralize the acidity of the mine drainage and remove the dissolved metals, such as Fe, Zn, Mn etc., in the form of insoluble compounds retained within the substrate. The effectiveness of this treatment method, as compared with the conventional neutralization techniques with alkaline additives, extensively used in the mining industry, was assessed based on environmental and economic indicators. The indicators applied included contaminant removal, land take per unit of contaminant removed, effluents quality, remediation of past environmental damage, energy and reagents consumption, capital and operating cost. Based on the above, the applicability of anaerobic wetlands for the treatment of acidic streams originating from old mined areas was concluded.

Jan 1, 2003

By A E. McElnea, M A. Martens

An 18-month project was undertaken to test the effectiveness of controlled daily tidal exchange augmented with hydrated lime treatment of surface waters as an approach for remediating a severe acid sulfate soil disturbance at East Trinity, Cairns, north Queensland. Actual acid sulfate soils were producing hazardous levels of acid and heavy metal contaminants and degrading approximately 720 of the 940 ha East Trinity property and the adjacent foreshores. A government-led research team established a series of research projects with the aim of characterising the site (soils, water, terrain) and testing the effect of the lime-assisted tidal exchange management strategy on soils, water, sediments and biota.

Jan 1, 2003

By P. M. Solozhenkin, V. P. Nebera, V. D. Skorohodov

"Aqueous dispersions of air specifically prepared on the basis of flotation reagent solution acquire active properties in relation to the solid surface and may be imply as a medium for flotation ores. Such aerated solutions were defined as Activated Aqueous Dispersions of Air (AADA) with 5-6:1 ratio and the procedure of mineral separation was defined as a flotation process under non-equilibrium conditions. These procedures differ from conventional flotation mainly in reagent interaction with minerals through their adsorption films on gas bubbles simultaneously forming flotation complexes. Gas-liquid mixture is kept till an adsorption layer of reagents close to the limit value is formed on the surface of bubbles. The theoretical basis of AADA is considered.The results of two-phase gas- liquid mixture (AADA) were studied. Two versions of AADA were considered. Electrical surface potential of the air bubbles with the surfactant film, untreated minerals particles in Coulomb attraction and flotation complex formation were analyzed. Special flotation machines were constructed for separation of mineral suspension in air dispersion, whose effectiveness was confirmed in flotation of apatite waste of Kovdor ore. FK-9 machine introduced on Kovdor iron ore combine for the recovery of apatite from current departures of factory. The froth product contained 7.2 % P2O5, with recovery of 44 % apatite, which was processed for getting melted phosphoric-magnesium fertilizers."

Jan 1, 2003

By V F. Kucherov, V A, V M. Kirienko

In the paper the problems of elaboration and building up the computer engineering system æSafety and stability of underground buildingsÆ as subsystems of the common automated computer system of geomechanical monitoring for deposits of mineral resources are considered. The theoretical bases and techniques of calculation of underground buildings stability are considered. The example of elaboration of such system for a Starobin deposit of potash salts (Belarus) is considered.

Jan 1, 2003

The JORC Code, which has been in existence as a Code incorporated in the listing rules of the Australian Stock Exchange and New Zealand Stock Exchange since 1989 and 1992 respectively, has been revised and will be re-released in 2003. This revision followed a call for submissions in December 2001, the publication of an exposure draft in late-2002 and an exposure period during which a large number of constructive comments were received. These comments were reviewed and a further exposure draft released as part of the current exposure draft of the ASX listing rules. It is anticipated that the final Code will be incorporated into the stock exchanges listing rules in late-2003. The 1999 JORC Code has been the standard on which other reporting Codes have been based, each of which has contained refinements. Three in particular, the Reporting Code from the United Kingdom/Ireland/Western Europe, the new Canadian Reporting standards and the SAMREC Code from South Africa, influenced JORC in the preparation of the 2003 JORC Code. Whilst there are differences between the 1999 Code and the 2003 Code, these changes are mainly in the guidelines. The Code definitions, which are largely in accord with agreed international definitions, remain substantially unchanged. The two main changes in the 2003 Code are the requirement for a Competent Person to be responsible for the documentation relating to the reporting of Exploration Results, and the introduction of æRecognised Overseas Professional OrganisationsÆ as overseas organisations to which Competent Persons may belong. Other changes include: clarification of the reporting of exploration targets or potential; the rearrangement of the diamond reporting clauses; the introduction of guidelines for the reporting of Industrial Minerals; modification of the coal clauses and recognition of the new Coal Guidelines; and the introduction of a guideline encouraging the discussion of relative accuracy and confidence in resource/reserve estimates. Other lesser changes to the Code are listed and discussed briefly. The release of the 2003 JORC Code maintains the standard set by JORC as a world leader in the development of mineral reporting Codes and their adoption by industry.

Jan 1, 2003

By A. Sissing

Paper written on project work carried out in partial fulfilment of M.Sc. (Chemical Engineering) degree Thermophilic bioleaching, conducted at temperatures in excess of 65°C, provides considerable benefit over mesophilic bioleaching, particularly through extending the extent of leaching of base metal minerals such as chalcopyrite. Thermophilic bioleaching is facilitated through a group of micro-organisms known as the Archae, well adapted to extreme environment. In order to maximize the space time utilization of the stirred tank reactor in the thermophilic bioleaching process, it is desirable to maximize the loading of the finely divided mineral phase present while not adversely affecting the microbial performance. In this paper, the effect of the loading of the solid particulate phase on the bioleaching performance of Sulfolobus metallicus was studied in a stirred tank reactor. Emphasis was placed on the effect of the concentration of the finely divided solid phase (35 ? 75 µm). A model system comprised of 3% (w/v) pyrite in the presence of varying quantities of quartzite in the range 0 to 24% (w/v) was used to obtain the different solids concentrations. The bioleaching experiments revealed similar bioleaching performance in the presence of 3 to 18% (w/v) total solids. Above 18% (w/v) total solids (15% quartzite loading), bioleaching was impaired progressively with increasing solids concentration. At the highest solids loading studied of 27% (w/v), bioleaching was still observed. In terms of mass transfer, oxygen transfer potential was not significantly influenced in the bioleaching process over the range of solids investigated.

Jan 1, 2003

By Mike O’Brien, Rob Croll

The Evolution of AngloGold -Incorporated in 1944 under the name of Vaal Reefs Exploration and Mining Company Limited -Name changed to AngloGold Limited in 1998 as the vehicle consolidating the gold interests of Anglo American Corporation -Diversification (geographic and orebody) through the sale of low-margin, deep level, short-life assets and the acquisition of higher margin, open-pit and shallow underground operations

Jan 1, 2003

By Y. Takasaki

For zinc hydrometallurgical extraction, reducing the electric power consumption of the electrowinning process is an important issue for energy savings. At the Zinc & Lead 2000 symposium, the authors suggested that by using the Pb-0.5%Ag-0.6%Ca alloy, the electrolysis energy can be decreased compared to the conventional Pb-0.9%Ag alloy. In this study, the corrosion behaviors of the Pb-Ag-Ca electrode in a sulfuric-acid electrolyte were investigated. Based on the results Or me Pb-0.5%Ag-0.6%Ca anode after 20 days of electrolysis, the bath voltage and the quantity of anode slime decreased compared to the Pb-I%Ag anode. Subsequently, beta-PbO2 on the electrode surface was detected by XRD and its peaks were sharper than the Pb-1 %Ag anode. Moreover, a dense beta-PbO2 layer on the 0.6%Ca a anode surface was observed. Therefore, it was suggested that the dense beta-PbO2 layer on the anode surface is one of the factors that leads to a lower bath voltage and decreasing quantity of anode slime.

Jan 1, 2003

By M. Nakamura, T. Akamatsu

Embankment dams are often constructed on soft rock foundations in Japan, so it is important to precisely predict deformation of the foundations due to fill placement at the design stage. In order to accurately evaluate the settlement and the strain of the rock foundation surface during construction, the influence of the scattering of the deformability of foundations on the deformation behaviour should be investigated. In this paper, a method of evaluating the settlement and the strain of the rock foundation surface during construction was studied with stochastic deformation analysis considering the scattering of the deformability of the dam foundation. Based on the analytical results, a dam foundation design using the deterministic method considering the scattering of its deformability was discussed. Da in Japan Uferdämme of auf weichen Felsfundamenten gebaut werden, ist es wichtig, die Verformung der Fundamente auf Grund der Platzierung der Aufschüttungen bereits in der Planungsphase genau vorherzusagen. Im Zusammenhang mit einer genauen Beurteilung der Senkung sowie der Belastung der Felsfundamentoberfläche während der Bauarbeiten sollte auch der Einfluss der Streuung der Verformbarkeit der Fundamente auf das Verformverhalten untersucht werden. In der vorliegenden Studie wurde die Bewertungsmethode zur der Senkung sowie der Belastung der Felsfundamentoberfläche während der Bauarbeiten mit Hilfe von Wahrscheinlichkeitsanalysen der Verformung unter besonderer Berücksichtigung der Streuung der Verformbarkeit der Dammfundamente untersucht. An Hand dieser analystischen Ergebnisse wurde das Design der Dammfundamente dann enthusiastisch mittels deterministischer Methoden hinsichtlich der Streuung der Verformbarkeit diskutiert. Comme les barrages en remblai sont souvent construits sur des fondations rocheuses tendres au Japon, il est essentiel de prévoir précisément les déformations des fondations causées par la mise en place du remblayage durant la phase de conception. Afin d’évaluer avec exactitude le tassement et la déformation de la surface du rocher de fondation durant la construction, l’effet de la dispersion de la déformabilité des fondations sur le comportement de déformation doit être étudié. Dans cette étude, l’auteur a étudié la méthode d’évaluation du tassement et de la déformation de la surface du rocher de fondation durant la construction en procédant à une analyse aléatoire/stochastique de la déformation et en prenant en considération la dispersion de la déformation des fondations du barrage. En se basant sur les résultats de l’analyse, la conception des fondations de barrage avec la méthode déterministe considérant la dispersion de sa déformabilité a été activement discutée.

Jan 1, 2003

By Ko-ichiro Ohno

It is recently recognized that the iron reduction and melting as well as the slag separation of a composite of granular iron ore and coal are completed in a very short period of about IO minutes when the composite is rapidly heated up to approximately 1673K. These phenomena are expected to be applied to a new iron-making process. The mechanism of iron ore reduction and iron-slag separation during rapid heating has not yet been revealed and the fundamental research has just started. Carburization of the reduced iron is regarded as one of the most important steps in this process. In the present work, the composite was prepared from four kinds of coal or graphite as a carbon source and electrolytic iron powder as a completely reduced iron ore. The temperature at which the liquid formation and iron carburization occurred was monitored. Direct observation of smelting reduction behavior was made by a confocal laser-scanning microscope combined with the infrared image-heating furnace to clarify the effect of molten ash on iron carburization. It was found that the meltdown temperature of composite became lower as the melting temperature of coal ash decreased. From the observed result, it was presumed that the liquid slag would act as an important media for the carbon transfer from coal to iron. The carburization mechanism during the smelting reduction was estimated as follows. When slag containing iron oxide melted down and contacted carbon, iron oxide in the slag was reduced and the formation of the metallic iron particle as well as the its carburization occurred simultaneously at the slag-carbon interface. Carburized iron particle was carried from slag- carbon to slag-iron interfaces due to the slag convection flow caused by the difference of the interfacial tension between the carbon-slag and iron-slag interfaces. Carburization of reduced iron could proceed with a repeat of the above-mentioned process.

Jan 1, 2003

By K. B. C. Brady, B. E. Scheetz, J. E. Cuddeback, T. W. Bergstresser, W. A. Telliard, S. C. Parsons, R. J. Hornberger

Two weathering procedures are being developed by the Acid Drainage Technology Initiative in cooperation with federal agencies(OSM and EPA). Objects are to: (1) standardize existing humidity cell and leaching column procedures; (2) improve test methods by maintaining a carbon dioxide enriched environment needed to optimize carbonate mineral dissolution, and quantifying particle size variables to evaluate reaction kinetics, and (3) provide flexibility in test method implementation consistent with EPA guidelines for Performance-Based Measurement Systems. Preliminary results indicate the CO2enriched leaching environments produce alkalinities that are similar to field observations and greater than the tests run under atmospheric PCO2. Leaching columns produce higher alkalinity than humidity cells.

Jan 1, 2003

By Thomas Mucho, Anthony Iannacchione

This marks the 100th year that the aggregate industry has been served by a national association. Of all the accomplishments this longstanding relationship has achieved, there is probably none greater than the progress made, in worker safety. Perhaps the best way to measure this success is to examine injury trends in the aggregate miner population. For example, in the first half of the 20th [ ] century, 16 quarry mining disasters (a "disaster" is an incident with five or more fatalities) claimed 157 miners between 1909 and 1952. The largest of these was the disaster at the Sandts Eddy Limestone Quarry near Allentown, Pa., on March 26, 1942, where 31 miners died of asphyxiation by fumes/explosion. Thankfully, no mining disasters have occurred in the aggregate industry since 1952. It is these kinds of information that help us characterize improvements in aggregate worker safety over the last 100 years.

Jan 1, 2003

By S. Kahraman

The correlations between the modulus ratio and penetration rate of rotary and percussive drills were statistically investigated using the raw data obtained from the experimental works of different researchers. An inverse power law was found between the modulus ratio and the penetration rate of rotary and diamond drills. The penetration rate of rotary drills and diamond drills decrease with an increasing modulus ratio. The penetration rates of percussive drills increase with an increasing modulus ratio. There are significant linear correlations between the penetration rates of percussive drills and the modulus ratio. In one of the cases of percussive drilling, a strong correlation between the penetration rate and the modulus ratio was found for the rocks having a porosity value lower 1.23 %. It can be concluded that the modulus ratio might be a representative measure of rock drilling efficiency. However, further study is necessary to check the validity of the derived equations for other rock types. The effect of porosity on the correlations between the modulus ratio and penetration rate needs to be further investigated.

Jan 1, 2003

By Mikula Adolf

Lead-tin solders are commonly used in electronic packaging due to their unique combination of electrical, chemical, physical, thermal and mechanical properties. Since it is known that lead and lead containing alloys cause great environmental concern and health hazards it is necessary to replace lead in solder materials. Besides the environmental concerns new technologies in electronic packaging require new and improved solders. In most cases the new solders will consist of temary or quarternary alloy systems, the main component will be tin or indium and the second element could be bismuth. silver, copper and gold and to improve certain properties a third element will be added. For a third element zinc, nickel, antimony and aluminum can be considered. This report will concentrate on solders containing zinc as an environmental safe. element.

Jan 1, 2003

By Günter Strappler, Max John

When tunneling through karstic terrain, diverse and complex karst structures are to be expected. By means of drilling ahead of the face using drill jumbos, these structures can be detected to such a degree that by applying proper support measures both open karst cavities and karst holes surrounded by boulders embedded in soft rock can be mastered without causing any break-outs. Support measures such as spiles ahead of excavation, sealing off cavities, back?lling with sand, etc. have to be planned schematically and adapted to the dimensions and formations of the karst structures on site. An essential requirement for a smooth excavation procedure is the availablility of all necessary tunneling equipment for excavation by drill and blast as well as for excavation of soil, with experienced tunnel engineers being in charge of any adaptions on site.

Jan 1, 2003

By S Miller, A Neale

As part of a long-term acid rock drainage (ARD) mitigation study, PT Freeport Indonesia has completed the construction of a highly instrumented, full-scale, experimental, overburden stockpile to further evaluate the behaviour of the waste rock system at Grasberg mine. A total of 24 lysimeters, 30 sets of thermistor strings and 48 oxygen-sampling ports were installed at select locations during stockpile construction. ARD flow rates and chemistry have been recorded since the start of overburden rock placement in April 2000. Measurements of in situ temperatures and oxygen concentrations quantify reaction rates and the oxygen pathways that control oxidation kinetics deep within the waste rock profile. Direct field observations show the significance of advective oxygen flow with respect to the onset of oxidation kinetics. Oxygen measurements show that the rubble zone that forms at the base of a waste rock bench provides a critical pathway for oxygen entry to the waste rock profile. Furthermore, rapid oxidation as evidenced by measured temperature increases deep within the panels of waste rock is observed to occur. The observations presented in this paper provide critical insight for understanding the mechanisms and behaviour of full-scale waste rock stockpiles with respect to ARD generation. The results of this program will assist in the future selection, testing and evaluation of appropriate mitigation measures with respect to surface and face treatments to reduce long-term ARD generation. This project is a work in progress, and at least another two-years will be required to fully understand site-specific ARD generation and ARD mitigation mechanisms. This paper will discuss various design and construction considerations, provide an overview of results achieved to date, and some preliminary interpretation of what is happening within the overburden stockpiles.

Jan 1, 2003

Cospidie (3CaO*2SiO2*CaFe2) is one of the most important compounds crystallized in mold flux films during casting in the continuous casting process of steel, The primary crystallization field of cuspidine has been experimentally developed in the CaO-SiO2-CaF2-SiF4 system. The cuspidine-NaF binary and cuspidine-CaF2-NaF ternary systems have been also experimentally determined to study effects of addition of NaF on the primary field of cuspidine. In order to discuss its thermodynamic stability the standard Gibbs energy of formation of cuspidine has been deterimed by an electromotive force methods using CaF2 as solid electrolyte and a transpiration method as follows: ^fG° (cuspidine) /kjmol-1 = 5198 + 0.825T (+12) (1313<T/K<1329): EMF method ^fG° (cuspidine) /kjmol-1 = 5178 + 0.813T (+8) (1221<T/K<1469): Transpiration method The chemical potential diagram and constituent activities for the CaO-SiO2-CaF2 System have been evaluated based on the obtained thermodynamic data.

Jan 1, 2003