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By F. McIntosh Galbraith

EMPLOYING geophysics to find ore was for a long time considered by the Canadian mining fraternity to be a performance of dubious value: in a category somewhere between the practice of sorcery, and using a divining rod to locate underground water. With increasing knowledge, however, and with constantly improving instruments, a solid speaking acquaintance with this adolescent science is becoming an integral part of the mining geologist's stock in trade. And quite properly so: for, in the established mining districts, the ore deposits which could be easily found, by ordinary prospecting methods, have already been located. There remain; however, in almost all of the principal mining camps, areas which are covered to varying depths by glacial debris; and it is here that the obvious opportunities exist for the successful application of geophysical methods. Geophysical results must always be considered in the closest possible relation to the local geology; and, in reality, the 'doodle-bugs' are simply additional tools for the geologist (in the same category with a plane table or a microscope). The Sudbury Basin is a shining example of precisely this state of affairs. Detailed geological mapping has not significantly altered the position of the outer norite contact as placed on Dr. Coleman's original map of the district. What detailed examination has done, of course, has been to reveal the accuracy with which the contact can be placed in different parts of the district, and to show up, in consequence, areas in which further work might reasonably be expected to disclose hitherto unknown or unsuspected ore. Viewed in this light, the proportion of the norite contact which is covered by substantial quantities of overburden is astonishingly large.

Jan 1, 1939

By Michael Fuller

Roadmap ? Examples of Partnership from UBC ?? Event Sponsorship ?? Recruitment & Connections ?? Opportunities ? National Recruitment Survey Results ? Conclusion with Key Points Event Sponsorship ? Annual Canadian Mining Games competition ?? 160 senior mining engineering students, from 10 universities ? Field Trips ?? 2nd year: Open pit ? Highland Valley Copper ?? 3rd year: Underground ? Myra Falls, Quinsam Coal ?? 4th year: Self-organized ? Chile, China, Poland, Brazil

May 1, 2008

By Gunther F. Leichtle, James A. Finch, Colin A. Hardie, Cesar O. Gomez

"The recycling of wastepaper has become an important and common process worldwide. Techniques similar to those used in the mineral processing industry are used to produce high quality recycled fibers for use in newsprint. The mineral processing group at McGill University in conjunction with the Pulp and Paper industry (Mechanical and Chemi-mechanical Wood Pulp Network) has adapted one of these techniques, column flotation, for the purpose of deinking wastepaper. This article describes the typical process of recycling wastepaper from a mineral processing point of view. It also presents results from McGill University's flotation column test work at a Quebec wastepaper recycling facility.IntroductionThe recycling of wastepaper has become an important and common process worldwide, including Canada which is now the world's largest importer of wastepaper (CPPA, 1996). Much of the current drive to increase the utilization rate of recovered paper is a reaction to the solid-waste disposal problem that faces many Canadian and U.S. municipalities. The real problem in the disposal of solid waste is not the absolute amount of garbage that must be disposed of each year but this amount in relation to available disposal capacity.Environmental restrictions on the creation of new landfill sites and incinerators (the two main options for disposal of municipal solid waste) have tightened the demand/supply balance in the solid waste disposal market. This shrinking availability of waste disposal sites in the face of increasing population with greater disposal requirements defines the Developed World's solid waste crisis. Not only are there fewer disposal sites available, but the costs of using them is skyrocketing. These factors have increased government regulations mandating recycled paper content in newsprint. Conservation and environmental issues make the current drive for wastepaper recycling a real issue and business opportunity.A key to the success of producing quality recycled fibers from wastepaper is the deinking technology. The production of tissue papers, paper towels and newsprint requires regenerated fibers which are substantially free of ink particles. Of the various options available, mineral processing techniques can offer the most economical, environmentally acceptable and versatile strategies (Yoon, 1993). Today, it is recognized that flotation is one of the most effective processes for removing ink particles in the production of a high quality product. In a collaborative program with the Pulp and Paper industry, the mineral processing group at McGill University has adapted column flotation technology for this purpose. This article will describe the typical process of deinking from a mineral processing point of view (Part A). It will also present some results from McGill University's flotation column test work at a nearby paper recycling facility (Part 8)."

Jan 1, 1998

By M. Loan

The Zinifex's Hobart Smelter uses the paragoethite process to remove dissolved Fe(III) from concentrated zinc leach liquors. This produces a residue consisting primarily of 6-line ferrihydrite (a hydrated Fe(III) oxyhydroxide), several insoluble components derived from the calcined zinc concentrate neutralization agent and other precipitated phases, such as jarosite and silica. The precipitation of 6-line ferrihydrite in the paragoethite process was studied using a laboratory-scale continuous crystallizer, and the conditions were selected to limit high levels of dissolved silica and jarosite. This approach allowed the reactor pH and the rate of precipitation to be correlated with residue solid-liquid separation, particle size, morphology, residual zinc and sulfate concentrations, and phase formation (e.g., goethite, jarosite, schwertmannite, and 2- and 6-line ferrihydrite). These studies delineated the mechanism of 6-line ferrihydrite precipitation in the kinetically controlled paragoethite process, and its inter-relationship with goethite and jarosite precipitation under conditions where 6-line ferrihydrite is favoured. Unexpectedly, the generation of a more crystalline goethite precipitate with larger "primary" particle size did not produce a residue of improved properties, as bulk aggregates dictate the physical properties of the residue and not the crystallinity. Furthermore, it is difficult to precipitate 2-line ferrihydrite or schwertmannite under existing paragoethite process conditions.

Jan 1, 2006

By V. Itkin

"Three methods were tested for the beneficiation of aluminum scrap, generated by heavy medium separation of non-ferrous automobile scrap residue. These were: crushing in a shredder followed by screening; grinding in a ball miff followed by screening; and eddy current separation. The best results were obtained with the grinding-screening method. IntroductionThe usual method of aluminum alloy reclamation from non-ferrous automobile scrap residue consists of a two-step heavy medium separation to remove materials lighter than and heavier than aluminum. The resulting aluminum scrap still contains over 15% impurities such as stones and glass, heavy rubber, insulated copper wire , plastics and heavy metals entrapped by macerated aluminum piece s, composite fragments, etc.(2). Upon melting, these impurities create difficulties and yield a low ingot recovery-65% to 70%, hence small foundries avoid this material.There are a number of ways to improve the quality of aluminum scrap such as:(1 ) crushing of the scrap, which powders the brittle content , a major impurity component, followed by screening out of the dust(2) eddy current separation , which removes metals from the material flow, and(3) implement better methods for density separation.The eddy current separation and two variants of the comminution-screening technique were studied by Intermetco Ltd., Hamilton , Ontario."

Jan 1, 1986

By Y. O. Fortier

"ForewordTHE Arctic Archipelago and northern Greenland contain an orogenic region that is as much as 300 miles wide and over 1,400 miles long. It occupies much of what was formerly classified with the Arctic Plains and grouped with other plains and lowlands of Canada as one main geological division. It is proposed that this folded region be designated the Innuitian Region and be recognized as one of the main geological divisions of Canada.Canada's main geological divisions (see Geological Survey of Canada, 1947) have been considered as consisting of a central shield, largely surrounded by plains that separate it from eastern and western mountains. The plains include the Interior Plains, the St. Lawrence Lowlands, the Arctic Plains or Low-lands, and the Hudson Bay Lowland, which is in the central part of the Shield. Plains and mountains are, strictly speaking, physiographic terms, but because mountains are generally folded regions and plains are generally made of undisturbed strata, such terms are useful vehicles to express the fundamental make-up of the land. Nevertheless, it is preferable to use the terms Appalachian and Cordilleran 'Regions' rather than 'Mountains', as those geological divisions are not exclusively made of mountains.Because of the lack of more definite information, the 'Arctic Plains' have included, in the past, regions with plateaux two to four thousand feet above the nearby sea, mountain ranges reaching approximately 10,000 feet above sea level, and regions of folded strata."

Jan 1, 1955

By K. Tada

A surface of a magnesium slab (hereinafter, referred to as Mg slab) or magnesium alloy slab (hereinafter, referred to as Mg alloy slab) becomes black with the use of conventional manufacturing methods. The methods also involve a danger that an explosion of the molten magnesium occurs through contact with cooling water. Thus, it has been impossible to produce a slab having a smooth surface. In the present method, a molten magnesium alloy is supplied into a mold, which is sheltered from the surroundings, from a pool in tundish, which is shielded from the surroundings. AZ31B slab formed in the mold is drawn horizontally out to the outside from an outlet of the mold by revolving of the pinch rolls. A cooling water is jetted at an acute angle onto the slab on the outer side of the mold outlet. Further, an inert gas is sprayed at the inner side of the mold outlet in order to seal in a gap between a free surface of the molten magnesium alloy and a sheltered board surrounding an upper surface of the mold. As a result, oxygen and droplets of the cooling water are prevented from running back to the mold side through the gap. AZ31B slab has a smooth surface condition and high quality without a gas porosity, a segregation or the like. Further, the slab has a size of a width of 100 to 120 mm, a thickness of 5 to 20 mm and a span of 10 m or more.

Jan 1, 2006

By A. Dave Mackintosh

Historical closure data has provided a description of the stress distribution patterns occurring around mine openings and enabled the development of a time ? distance plot predicting the location of the stress peak and its migration away from mine openings with time. Data collected from active mining areas during the 1970?s and 1980?s indicated the peak appeared to stabilize approximately 135m (450 ft.) from openings after four years. The region of high load and accompanying poor ground conditions in which the peak was centred was spread over approximately 45m (150 ft.) to 60m (200 ft.). Recent data from new development headings cut adjacent to 25 year old extraction areas suggests load transfer takes place over a much greater distance and time frame than predicted.

May 1, 2001

By J. K. Van Beek

The Deep Underground Science and Engineering Laboratory (DUSEL) is a scientific facility that will be placed in the deeper reaches of the Homestake mine, Lead, SD. Our team of geologists and engineers is carrying out the first scientific project awarded to the site ? Towards a Transparent Earth. Taking advantage of the thousands of open exploratory and sand-line holes, we are installing the beginnings of a seismic observatory. Each installed station consists of a 3-D accelerometer package and a 1 nanoradian 2-D tilt meter. In order to allow for a variety of monitoring and characterization studies, the array instruments are sensitive over the frequency bandwidth of 0.2 - 1 KHz. Three, three component accelerometer stations are currently installed ? in a 140 m deep bore beneath the slurry pump house, and in 12 m deep bores on the 2000-foot level, 800 and 400 m from the Ross shaft. There is a tilt-meter installed at each 2000 level station. These installations are in 150 mm diameter sand-holes. From the currently installed tilt sensors we are investigating solid earth deformation as a response to tidal potential. The accelerometers are being used to locate and characterize events associated with mine dewatering and rehabilitation.

May 1, 2009

By René Dufour

Jusqu?à son acquisition par MM René Dufour et Alain Robin en 1994, les claims miniers et les droits de surface de la propriété étaient détenus depuis 1953 par la société Québec Columbium, une filiale de la socité américaine Kennecott Copper qui y a réalisé d?importants travaux miniers. En 1995 la compagnie NIOCAN inc. fut incorporée; ses actions furent inscrites à la bourse de Montréal en 1997, et à la bourse de Toronto en décembre 1999. Jusqu?à maintenant, NIOCAN a investi plus de 7 millions de dollars dans le développement de sa propriété minière de niobium située à quelques 40 kilomètres au nord-ouest de Montréal. Le haut rendement économique des deux gisements principaux que compte exploiter la compagnie, le S-60 et le HWM-2, a été établie par des études de faisabilité effectuées par le consortium Met-Chem/SNC-Lavalin. La mission que s?est donnée NIOCAN inc. consiste à mettre en production ses deux gisements et à devenir ainsi productrice de ferroniobium dans les plus brefs délais. Figure 2 Le projet est présentement à un stade avancé d?obtention du certificat d?autorisation du ministère de l?Environnement. À plus long terme, la compagnie compte aussi exploiter les sous-produits de ses gisements (apatite, forsterite, magnétite, calcaire et terres rares).

May 1, 2003

By Jan E. Nesset, L. Paul Staples

"High Gradient Magnetic Separation (HGMS) technology, although developed over 2 decades ago, has not been widely applied to the separation of sulphide minerals. Under conditions of strong magnetic field gradients, weakly magnetic minerals such as chalcopyrite (CuFeS2) and marmatite (Zn(Fe)S, sphalerite with iron in solid solution) behave paramagnetically and can be effectively separated from diamagnetic minerals such as galena (PbS). The application of this technology to the separation of Cu-Pb and Zn-Pb bearing streams in the treatment of fine grained complex sulphides may in some cases be more effective than separation by flotation. A 2 TPH Sala HGMS pilot plant was operated at Brunswick for a nine month period, ending in March 1995. The testing demonstrated the mechanical reliability of the technology, the consistency of operating results and the scale up from laboratory testing. HGMS is seen as a complimentary technology to flotation, best suited to performing those separations of galena (and other diamagnetics) which flotation does not do as well.IntroductionBackgroundSince the turn of the century, the magnetic character or magnetic susceptibilities of minerals have been determined with increasing precision and accuracy. Figure 1 illustrates specific magnetic susceptibilities of some common minerals. As long as susceptibility ranges do not overlap, separation is possible.In 1937, the principle of using a magnetizable matrix material in a magnetic field to increase both magnetic flux density gradients and number of capture sites for susceptible minerals was first applied (Frantz). It was not until the 1970's, however, that the genuine development of wet high gradient magnetic separation began with the introduction of very fine matrix materials to the magnetized volume of large solenoid magnets. Today, dozens of HGMS units purify, filter and separate minerals, primarily for the removal of iron stained minerals from clays used in the paper coating and china clay industries and for the recovery of fine titanium and iron oxides in the iron ore industry. Only the Garpenburg mill in Sweden is currently applying a continuous HGMS machine to separate complex sulphide minerals; upgrading a lead concentrate since 1988."

Jan 1, 1996

By Hervé Toubon, Matthieu Davrinche, Jim Corman, Mamane Bello Boubacar Kinassa, Pierre Amadieu

Orano Mining maintains a significant level of Innovation and Development Research for its sites in Canada, Niger, Kazakhstan, Mongolia, and France. This effort is formalized within the six major thematic programs below, which include more than one hundred affiliated R&D projects:  Geological understanding, tools and methods for exploration  ISR technology (geology, modeling, mining development tools)  Mining technology (SABRE)  Ore treatment and processing (in particular via our Centre for Innovation for extractive metallurgy, CIME)  Environment (radiochemistry, modeling, tools and methods for remediation)  Digital Mine (sensors, transmission, database, and data modeling) This paper describes the main actions of these six programs, their stakes, and their progress. There is no single path leading to innovation but fostering an innovative context and a structured project approach are essential ingredients to successful development and industrial deployment. As a result, Orano Mining has, over the years, developed a disciplined methodology for R&D portfolio and project management. This methodology, presented here, targets a reduction in time to implementation while valuing both the expertise and the work in project mode.

Jan 1, 2020

By Mike Power

Geophysical techniques have played a pivotal role in northern kimberlite exploration since the initial discovery at Point Lake in 1991. In the Slave Craton and surrounding regions, there are definite contrasts in physical properties between kimberlite intrusions and surrounding bedrock. Kimberlite commonly displays higher magnetic susceptibility, distinctive remnant magnetism, low electrical resistivity and lower density than surrounding rocks. In addition, the distinctive geometry of kimberlite pipes is reflected in geophysical responses which further facilitates target discrimination. There has been an evolution in geophysical exploration strategies over the past 12 years. Helicopter total magnetic field and electromagnetic (HEM) surveys have proven to the most cost-effective means of conducting first pass investigations in prospective areas. During the early 1990's, total magnetic field and frequency domain electromagnetic surveys were virtually the sole techniques employed during follow-up surveys. Inevitably, the initially high rates of kimberlite discovery declined in the areas surrounding the original finds. Marginal magnetic and EM anomalies were all that remained to be tested and this spurred interest in the improvement of existing interpretation algorithms and in the application of additional complementary techniques to reduce the exploration risk. Gravity has become a popular third survey following the deployment of the Falcon (TM) airborne gravity gradiometer system by BHP Billiton in 1999 and improvements in ground techniques. Ground penetrating radar (GPR) has proven to be particularly useful in delineating kimberlite pipes following drill discovery and in exploring for kimberlite dykes in settings where indicator mineral trains indicate such targets are likely. Seismic methods have been tested for both reconnaissance and delineation but remain underemployed. Given the high cost of drilling in the North and the proven success of geophysical techniques in reducing exploration risk, it is likely that an increasingly diverse range of geophysical techniques and innovative interpretation techniques will continue to be applied in kimberlite exploration.

May 1, 2003

By Richardson A. H.

"IntroductionSafety and training in the mineral industry will always be issues that are hotly debated and discussed.The nature of the mining industry, where people and equipment work in close quarters deep below the earth's surface, attracts a great deal of public attention and concern, especially in the areas of safety and related training activities. This concern has been carried over into the mineral processingsector which is, of course, a vital part of the mining industry.It is therefore imperative that mining people closely examine the policies, procedures and programs presently in place to determine if they meet the needs of the industry and its employees. Everyone stands to benefit: the companies, employees and the mineral industry as an important segment of the Canadian economy.Phrases such as ""Safety First"", ""Safety is Number One"", have a role to play in industrial safety programs but in reality are a shallow approach to the magnitude of the challenge. An industry must produce its products in a cost-effective way, with good employee relations. None of these objectives can be successfully achieved unless accompanied by good safety performance. Accidents both on and off the job result in very poor efficiency, high costs and poor employee relations.This chapter, Safety and Training, outlines those major areas that the author believes are necessary components for an industrial safety, health and training program, but are not all inclusive. More will surely be added as additional problem areas requiring attention are identified. The major sections discussed are: Development and Implementation of a Safety Program; Occupational Health; Training; and Audit Procedures.The author has drawn on his experience as both a mill superintendent, mine manager and superintendent of safety, health and training. The approach developed at loco Metals Manitoba Division is frequently used in this paper with examples and excerpts to better illustrate the subject, but does not represent the full scope of programs in place in the Division."

Jan 1, 1989

By G. Viramontes-Gamboa

Approximately 70% of world copper reserves consist of the mineral chalcopyrite, and much international effort has focused on its study. Ultimate objectives include the development of environmentally friendly alternatives to smelting, and technologies to treat low-grade ores, for which concentration and smelting are economically unviable. Unfortunately, chalcopyrite leaching is inefficient in H2S04-Fe2(S04)3-FeS04 solutions, which is considered to be the most desirable oxidizing medium for leaching of copper sulfides, since the chemistry is well known, corrosion of industrial equipment is negligible, subsequent copper recovery by SXlEW is well established, and environmental impact is minimal. The main reason for this inefficiency is the self-passivation of chalcopyrite. We have devoted considerable effort in the understanding of this phenomenon, and have developed a predictive electrochemical methodology capable of establishing a priori the precise range of potentials within which chalcopyrite leaches and where it is passivated. Since potential control is a critical parameter in chalcopyrite leaching, this experimental methodology can be very useful for establishing the best conditions to leach chalcopyrite. In this paper, the scientific foundations of this predictive experimental technique are presented, and its practical application is demonstrated by comparing its predictions with leaching experiments from the literature.

Jan 1, 2007

By K. Sawada

Along with the expanding demand of copper concentrate in Asian countries, custom-smelters have confronted with difficulties of low TC/RC. Now, Japanese Copper Industry have 2 options; investment in mine development and/or recycling of copper scraps. The strategy of global mining companies is analyzed, and implications for Japanese Copper Industry will be discussed from the viewpoint of sustainability of smelters in Japan.

Jan 1, 2014

By X. Cao, X. -G. Chen, K. Liu

As is well known, the standard Al-Cu 206 cast alloys have extremely low iron contents, usually less than 0.15 wt. %. Recently it is found that the iron contents of the 206 cast alloys can be extended up to 0.5 wt. % through the precise control of the iron-rich intermetallic phases. In the present work, the tensile fracture surfaces of the 206 cast alloys with various iron contents are systematically analyzed to understand the failure mechanisms. Results show that higher iron contents can reduce the tensile properties (especially the ductility) of the alloys mainly due to the increasing volume percent and size of the iron-rich intermetallics. Tensile failure mainly occurs at the iron-rich intermetallics/matrix interfaces for the platelet ß-Fe, but by the self-disassociation for the Chinese script a-Fe and Alm(FeMn). Cracking is easier to initiate and propagate along the longitudinal axis of the platelet intermetallics, but it can be deflected along the branches/arms of the Chinese script iron-rich phases, making the alloy more resistant to the propagation of the cracks, and thus the Chinese script iron-rich intermetallics are less harmful than platelet ß-Fe. In addition, it was also found that the Chinese script a-Fe has even a less damaging effect compared to the Chinese script Alm(FeMn) due to the relatively small size and compact morphology.

Jan 1, 2014

By Janne Karonen, Stephen Hughes, Mikael Jåfs, Jan Stål, Hannu Johto

End-of-life electrical and electronic scrap material attracts attention as a good opportunity for new value creation through efficient metal and energy recovery of such materials. On the other hand, the treatment of such wastes becomes important to avoid problems for society and environment. Treatment of such secondary raw materials faces multiple challenges due to their increasing complexity and evolving nature. Processing of these complex scrap materials together with recovery of a wide range of valuable metals with a combination of pyrometallurgy and hydrometallurgy using Outotec technology is discussed in this paper. One key consideration is environmental performance which needs attention when processing such complex secondary E-waste materials. Outotec has successful experience with commercial projects in the countries at the forefront of environmental and operational standards. INTRODUCTION Increasing attention has been drawn to the responsible processing of end of life Waste Electrical and Electronic Equipment (WEEE) as part of metals recycling, especially copper. It has been estimated that the amount of WEEE globally in 2016 was around the level of 46 Mtpa (Balde et al., 2017), representing a major disposal challenge but at the same time huge opportunity for resource recovery. The potential for increasing the recovery is high, because the official recycling rate of WEEE is in 2016 only 20% (Balde et al., 2017) and at the same time the estimated increase of the WEEE amount is between 3 and 5% per annum in the EU (Eurostat, 2019).

Jan 1, 2019

By M. D. Quinn

THE sand and gravel used for backfilling at the Hollinger mine is obtained from deposits in a low range of hills some three miles north of the mine, where the Company owns a number of claims. The material is transported to the mine by aerial tram. Shipments from these deposits to the Hollinger mine commenced in June, 1927, and since May, 1936, sand has been supplied also to the McIntyre mine. During 1942, Hollinger requirements were 1,700 tons per day, and 900 tons per day was delivered to McIntyre. For the past seven years production has averaged 900,000 tons annually, and total deliveries to the end of 1942 were 13,129,022 tons, of which 11,075,339 tons went to Hollinger and 2,053,683 tons to McIntyre. Some years ago, when the original pit was approaching exhaustion, new workings were opened on claims east and south of the tramway terminal. It soon became apparent that the sand varies considerably in character from place to place. The weight per cubic foot was found to range from 85 to 130 lb., and the water percolation rate from 2 to 50 inches per hour. As the mine requirement is a sand with percolation rate of 6 inches or better per hour, it was evident that in certain parts of the deposits the material was not suitable for use as backfill. As a consequence, it was decided to carry out a programme of systematic sampling of the claims in order to select the areas containing suitable material for back-fill and at the same time estimate the tonnage available.

Jan 1, 1944

By Chandrakala Kari, Divyang Shah, Lakshmi Kanth Reddy, Kaushik Vakil, Sanjay Sarkar, Bhavin Desai

Gases rich in sulfur dioxide generated as a by-product of smelting and converting operations of copper concentrate contain selenium apart from zinc, lead, copper, cadmium, bismuth, antimony, and arsenic. The gaseous stream is heat exchanged in waste heat boiler, dust collected in electrostatic precipitator followed by cleaning in reverse jet scrubber to remove fumes, halogens and fine dust before passing to DCDA Monsanto catalytic converter to produce commercial grade sulfuric acid. The gas cleaning section of the acid plant uses water to scrub the smelting gases. During scrubbing, precipitated solids, known as sludge, settles at the bottom of the reverse jet scrubber containing 30 to 40 wt% copper and selenium up to 40 wt% selenium. In the existing process, the sludge collected during scrubber cleaning process is directly recycled to the smelter for copper recovery. However, the selenium is expected to again vaporize due to high oxidation potential during smelting and converting, causing accumulation of selenium in sludge. In present investigation, a roasting process has been developed to recover the selenium from acid plant sludge before charging it to smelter for copper recovery. Selenium is associated with copper in acid plant sludge as copper selenide, as determined by X-ray diffraction and electron microscopy. Thermodynamic and thermo-gravimetry study revealed that the copper selenide phase present in the sludge was amenable to oxidation at 600°C forming oxides of copper and selenium (Cu-Se-O). However, the dissociation of selenium from the copper oxide was made possible by sulfatation using sulfur dioxide between 450°C to 600°C, resulting into the formation of CuSO4(s) and SeO2(g). Lab scale experiments were carried out in vertical tubular furnace to determine the optimum roasting conditions with respect to roasting time, temperature and molar ratio of O2:SO2. Using these optimum conditions, selenium up to 90 wt. % in the form of SeO2 vapors could be recovered from the acid plant sludge in a large scale commercial roaster. Roasted sludge free from selenium and containing oxides and sulfates of copper could now be recycled in the smelter for copper recovery. INTRODUCTION There is an increasing demand for minor metals due to their use in innovative technologies. Similarly, the increase in demand for selenium is expected due to disruption in sectors related to renewable energy and photovoltaic battery. Selenium is a chalcogen and a non-metal with black or red crystalline appearance. Selenium is used in the glass industry to decolorize glass and to make red-colored glasses and enamels. It is also used in solar cells and as a photographic toner. Selenium is used as a brasses in stainless steel to improve its machinability. Selenium sulfide is used in anti-dandruff shampoos. In spite of the toxicity of its compounds, selenium is also an essential trace element for humans and animals. Selenium occasionally occurs free in nature, but more often occurs as selenides of iron, lead, silver and copper. There is an urgent need for the development of new methods for selenium recovery from the existing resources. Commercially, selenium is obtained only from anode mud produced during electrolytic refinery of copper.

Jan 1, 2019