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By E. A. van Dijk

Dusts from steel-making processes contain substantial amounts of zinc. Such dusts are also a hazardous waste and dumping them becomes unacceptable from environmental point of view. Therefore processes that can recover zinc and possibly other metals from steel-making dusts are being investigated. The aim of this paper is a contribution to the more fundamental kinetic aspects of zinc reduction from silica free calcium ferrite slags. The effects of alumina, lime and magnesium oxide contents of the slag, the COICO, ratio and the effect of initial Fe2O3/CaO ratio were studied experimentally at 1400°C The results indicated that the reduction of zinc from molten slag was possibly a first order reaction. As expected higher COICO, ratios increased both the extent and the rate of reduction. It was also observed that a higher iron content of slag improved the reduction of zinc from calcium ferrite slags. This fact seems to support the proposed mechanism that zinc is partly reduced by ferrous iron to zinc vapour and that ferric iron is reduced by carbon monoxide. The reduction rate of zinc in these slags was decreased by increasing alumina content of the slag. Alumina decreased the calculated optical basicity of the slag showing the fact that reduction of zinc oxide was more favorable in more basic slags. Probably the formation of complex ions by alumina and zinc oxide such as ZnAl2O32+ lowers the activity of Zn2+ ions in the slag and hence render them more difficult to reduce.

Jan 1, 1999

By R. Mehta, M. Misra, X. Su

"The conventional methods to assess Acid Mine Drainage (AMD) potential of the waste rocks and tailings are based on wet chemistry and leachability tests. These methods are time consuming and expensive. There is a growing interest to develop alternate techniques to establish the reactivity of acid mine tailings and stability of treated waste forms. The Electrochemical Impedance Spectroscopy (EIS) is a reliable non-invasive technique which can be used for quick estimation of reactivity of the potential acid generating tailings. In this paper the utilization of the EIS technique for the estimation of reactivity of tailings is discussed. EIS can also be used to predict the long term stability of different stabilized waste forms.IntroductionMetal contaminated mine drainage is one of the most persistent environmental problems facing the mining and mineral processing industries today. Of all the mine drainage pollutants, acid mine drainage has become a substantial concern because of the potential long-term environmental implications and the accompanying liabilities. The main source of acid mine drainage is the tailings containing sulfide-ores which are generated during the ore processing. When these sulfide minerals, particularly pyrite and pyrrhotite, are exposed to oxygen and water they begin to oxidize. The initial chemical reactions produce acid and the acid dissolves heavy metals present in the tailings. Rainfall and snow-melt flush the toxic solutions from the waste sites into the downstream environment [1-2]. In addition to mining tailings, several Department of Energy (DOE) sites contain wastes which are contaminated with radionuclides and heavy metals."

Jan 1, 1999

By Kumar A, Mishra N. C

For each tonne of chromite ore mined in Sukinda, approximately ten tonnes of fine overburden material is generated. The overburden typically contains about 30 - 60 per cent Fe2O3, 0.3 - 1.1 per cent Ni, four to nine per cent Cr2O3 and 0.04 - 0.2 per cent cobalt and is being discarded leading to loss of valuable metals and creating environmental pollution. In order to take the advantage of presence of iron, nickel and chromium, the present studies advocate the utilisation of nickel lateritic chromite overburden for production of Ni bearing pig iron through blast furnace extracting maximum iron and nickel from the chromite overburden. The present paper deals mainly with the beneficiation of chromite overburden, sintering characteristics and thermodynamic studies. The beneficiation study shows that a beneficiated concentrate having Fe - 50 per cent and Ni -- 1.1 per cent can be achieved from chromite overburden having Fe - 30 per cent and Ni -- 0.7 per cent. Sintering studies have been carried out with bed height of 300 and 450 mm at a suction of 600 and 900 WG respectively. The results reveal that good quality sinter can be produced from chromite overburden concentrate with a basicity of about 1.0 and coke breeze consumption rate about 16 per cent. In all the experiments, Tumbler Index, Abrasion Index and Shatter Index was found to be in the range of 65 - 70, 4.5 - 5.5 and 85 - 90 respectively. The other parameters namely softening temperature, melt down temperature, reduction degradation test and relative reducibility have also been determined. A thermodynamic analysis has also been carried out to make a technological assessment of the process for the production of alloyed pig iron from chromite overburden in blast furnace which shows that it is possible to produce nickel bearing pig iron in blast furnace using the sinter up to 80 per cent. Techno-economic analysis reveals that this route will yield a substantial profit even after accounting for cost of beneficiation, extra coke, raw materials and extra slag produced.

Jan 1, 1999

By H. A. F. de Souza, Dana S. Mills, P. E. Burgener

"ICP-MS has moved from a laboratory curiosity to a functional analytical tool. This paper discusses how ICP-MS has been used to solve difficult analytical problems encountered when analyzing various mine materials. Comparisons between analytical techniques applied to the analysis of gold and the platinum group metals illustrate the advantages and problems of ICPMS when. applied to trace levels of some metals iri the presence of ore grade metals. Interferences and matrix effects are compared to ICP, AA and Neutron Activation. The necessity to select chemical extractions which are compatible with ICP-MS are also discussed.The ICP-MS techniques explained in the examples on Au and precious group elements (PGE) have validity in analytical problems encountered in testing of trace metals in the presence of major elements found in mine materials. Exploration and environmental testing are other areas that require the same analytical approach to quantify trace levels in the presence of major interfering elements normally associated with mining environments."

Jan 1, 1999

This paper describes a simple finite element (FE) modelling approach which leads to the computation of seismic energy release rate (ERR) and strain energy storage rate (ESR) which result from mining. The concept of critical strain energy is introduced as a means to help evaluate the strainburst potential in mine structures. A new, energy-based, burst potential index (BPI) is proposed. The use of ERR, ESR and BPI is demonstrated by a cut-and-fill stope case study. The merits of using such energy parameters in the interpretation and analysis of strainburst phenomena are discussed. While the study gives promising results, site-specific back analyses would be required to first calibrate the model and fit it with the local mine conditions, before it can be adopted as a routine design tool.

Jan 1, 1999

By Mokka Rao, Asdrubal Serrano

"A mathematical model is developed which describes the movement of the minerals present where the vertical and angular velocities are related with the different operative parameters involved in the process of separation of silica from iron ore, which permit maximise the capacity of the spirals to obtain major productivity. The process is realised in two steps, of the rough dressing and other cleaning. Through the results obtained for chemical analysis of the final products of each spiral and the equation of movement of particles, it is proved the applicatibility and efficiency of mathematical model to operating parameters of the spiral. Moreover, it is determined though the recuperation of the final products of quality in the use spiral HC 1870 and HG 8/7. INTRODUCTIONThere is prospetive of increasing the production the iron ore in agreement with the demand of siderurgical proyects united with the external demand of quality 40 million tons per year. The Ferrominera de Orinoco Company is experimenting two types of modem spirals, Humprey (HC 1870) and Reichart (HG 8/7) which have limited capacity. For this reason this investigation designed a mathematical model with which larger units can be designed for increasing the capacity of the spiral."

Jan 1, 1999

By Yufeng Yao, Robert P. Lowell

Abstract - Conductive heat flow anomalies associated with hydrothermal sulfide mounds on the seafloor have been studied. Sulfide mounds tend to focus conductive heat flow because sulfide minerals have a greater thermal conductivity than country rock. The topography of the mound above the seafloor, however, leads to a reduction of heat flow, particularly near the center of the mound. Because the focusing effect is constant, whereas the topographic effect decreases with distance away from the center, the focusing effect dominates toward the edges of the mound. The magnitude of these effects depends upon the conductivity contrast and the height/radius aspect ratio of the mound. Conductive heat flow anomalies at sulfide mounds also result from fluid circulation within the edifice. For the active and relict mounds at the TAG hydrothermal field, which have an aspect ratio of approximately 0.3 and a conductivity contrast of 3, the heat flux through the center of the mound should be roughly 70% of the background heat flux. The maximum effect of heat flow focusing is to increase the heat flux by about 30% above background. By comparing these effects with conductive heat flow data at TAG, we find that advective processes dominate conductive heat flow at both the active and relict mounds. Advective circulation can also give rise to much larger lateral and vertical temperature gradients than would result from conduction alone.

Jan 1, 1999

By G Kennewell

At 11 am Monday 8 September 1997, the successful detonation of the 5/9 Mass Blast at Pasminco - Elura was signified by the subsiding of æMt KevinÆ (a 15 m high earth fill mound). The blast was in response to earlier mine subsidence, which holed through to the surface affecting future stability of underground workings. The blast was a first for Elura which fires small tonnages regularly to avoid rapid oxidation of the ore. This paper discusses the strategy and the considerable planning that went into EluraÆs first blast of this magnitude in order to succeed first time round.

Jan 1, 1999

By L. B. Hales

Color video or digital cameras have been installed over flotation cells to monitor color, bubble size, froth movement, and other characteristics. These systems are designed so that the camera provides flotation performance information just as any other sensor might. Factorial tests have been run to monitor and measure the variation in froth characteristics as a function of flotation control settings. Ultimately, it is envisioned that froth image sensors can be used to monitor and control the flotation performance as effectively and for less cost than current analytical systems.

Jan 1, 1999

By J Meinhart, J Rodler, I Katolicky

The ever increasing number of vehicles is leading to slow-moving and even stationary traffic sitting longer in traffic jams over extensive city areas. This traffic situation causes a sharp increase in pollutant emissions from vehicles, and high levels of pollution usually result throughout the built-up area. Reducing the pollution level by using traffic routing measures to speed up the flow of traffic in the existing street network is only possible in exceptional cases.In many cases the only option for achieving a significant improvement in traffic conditions is to shift the traffic underground using a road tunnel or underpass. Such tunnel routes suck off the traffic from large sections of the city, thereby easing the overall traffic flow. Thus on the one hand it produces a sharp reduction in pollution levels in the area of the tunnel route, but on the other hand it can result in locally increased exhaust pollution levels from longer tunnel systems that require mechanical ventilation. The air extracted by the ventilation system is blown out into the atmosphere either directly through the tunnel portal, or via a venting tower. Pollution can therefore occur in the area surrounding such exhaust air outlets.Thus if a tunnel is planned in a city, then closer investigation is required of both aspects: the reduction in pollution in the area of the tunnel route thanks to relocating the traffic and easing congestion, and the increased short-range pollution around the tunnel portals (shafts).

Jan 1, 1999

By Clay McNail, Paul N. Worsey, John Schillie

"This paper is the result of undergraduate student research over the period of 2 semesters at UMR, which was focussed on developing a practical way to pneumatically stem horizontal boreholes, mostcommonly used underground. The majority of dry horizontal underground boreholes are pneumatically loaded with bulk ANFO. ANFO is preferred due to its low cost and the ease of pneumatic loading. However, stemming underground in the United States is a rare practice. In sharp contrast, stemming material (crushed stone or drill cuttings) is virtually always used in surface holes. The purpose of stemming is to increase blast efficiency by containing the explosive energy in the ground and to reduce environmental effects such as air-blast. The problem with stemming horizontal boreholes are; gravity cannot be used to load stemming material and the ANFO does not have a good interface due to problems with withdrawing the hose and the loading itself. This work follows on from Wilkins’ work on stemming angled boreholes."

Jan 1, 1999

By S. C. Grund

In secondary copper smelting as it is performed at Hüttenwerke Kayser plant in Lünen, tin-and lead-containing flue dusts are produced as intermediate products. These flue dusts are further processed in a hearth furnace. Followed by certain refining operations a saleable tin-lead-alloy is produced. Even though the hearth furnace technology has been in use for this purpose for a long time still its performance undergoes changes in search for optimum processing conditions regarding to the increasing complexity of the raw materials and tightening economical and ecological boundaries. The use of modern statistical tools for the calculation of accurate mass balances is demonstrated for the tin-lead hearth furnace. These reliable mass balances are the basis for any further modelling of the process with the aim of optimization. Incorporating metallurgical knowledge and experience as well as different mathematical modelling techniques, further studies are planned in which the recoveries of valuable and minor elements and their dependency from various process parameters are examined. The aim of this modelling is to optimize the recoveries of the valuable elements, to minimize the energy consumption and the processing costs and thus to keep the process competitive in a harsher economical and ecological surrounding. The modelling principles are transferable to other metallurgical operations and are especially suited for ill-defined pyrometallurgical processes.

Jan 1, 1999

By Nagy El-Kaddah, T. T. Natarajan

This paper describes a novel approach for modeling three-dimensional electromagnetically driven flow in inductively stirred systems, and its application to modeling electromagnetic and flow phenomena in sub-mold rotary stirring of billets. It is based on a new T-\jf potential formulation of electromagnetic field, which does not require the calculation of the field in free space. A finite element algorithm has been developed for solving the electromagnetic field and Navier-Stokes equations in the fluid flow domain. The computed results have shown that the electromagnetic force field generates a strong rotational flow within the vertical section covered by the stirrer, and a relatively strong secondary flow beyond the stirrer. It has also been shown that the rotational and secondary flows were driven primarily by the vorticity of the force field at the billet corners. The induced flow in the molten pool was found to be turbulent and the effective mixing region in the molten pool was about three times the length of the stirrer. The mathematical approach presented in this paper provides the theoretical framework for quantifying these effects for any given stirrer configuration and operating parameters.

Jan 1, 1999

By Knut H. Bech, Stein Tore Johansen

"The collision efficiency for small particles relative to 2D spherical bubbles in a developed turbulent flow field were calculated applying an adopted version of the CPD program FLUENT. The turbulence field was related to bubble size and fluid properties. The results were compared with analytical theory. The turbulence intensity was found to be the most important single parameter for collision efficiency. Effects of boundary layer thickness and particle diameter were discussed. IntroductionRemoval of inclusion particles from melted aluminium can be facilitated by means of a rotor system that supplies kinetic energy and gas bubbles to the floating metal. At the surface the inclusions adhere to the surface dross or slagg which is removed at regular intervals by the operators. When applying computational fluid dynamics (CFD) to model such a system, one experiences difficulties with the large range of turbulent length-scales encountered, from the large geometrical scales of the rotor and container, through the bubble size and down to the particle diameter. A mathematical model for the complete system will be both complex and require an extreme spatial resolution. Another way of dealing with the problem is to model the micro-scale phenomena separately and apply the results to create a model for the macroscopic system. In a previous work [12] we addressed these problems and developed a procedure for calculating turbulence enhanced flotation to bubbles. It was found that turbulence may have a profound effect on the collision rate of particles to idealized bubbles. In this study we recognize that only a fraction of the total turbulent kinetic energy generated by the rotor's work on the liquid metal may contribute to enhanced flotation. By using a model spectrum for the turbulence, the fraction of turbulent energy in eddies smaller than the bubble diameter is calculated. A twodimensional CFD model was then constructed to calculate the collision efficiency between particles and bubbles of various sizes."

Jan 1, 1999

By Ruben Alvarado

The need to increase business competitiveness while complying with environmental requirements represent the great challenge that the Caletones smelter has decided to face in a new development project with a compromising and willing alliance with its workers. To date, the project is at the feasibility stage, with start up scheduled for the middle of the year 2002. The processing capacity of the Teniente Converters will be increased to levels up to 2400 tpd of chalcopyrite-based concentrates containing 30% Cu, by means of more intensive use of oxygen and improved stabilization of the overall operation. Productivity increses in the converting of white metal and the pyrometallurgical treatment of slag are also planned. As a result of related strategies, the productivity of the supporting facilities, included the capacitiy of the sulfuric acid plants, will be increased. An intensive and well-designed labor-upgrading scheme will allow the transformation of every worker into an expert in his working areas, thus becoming an active driving force in technology development. Mechanization, appropiate infrastructure, and complete process control and instrumentation will give to the skilled and motivated personnel the necessary tools in order to attain the highest potential ever reached with the Teniente technology. The necessary investment for this project based on the adding facilities to the existing plant is only a third of that required to reach the same objective for a greenfield plant, thus yielding a very high return on investment.

Jan 1, 1999

By Stephen P. E. Redmond

A 15 km water supply tunnel is being constructed in Buenos Aires, Argentinata expand the capacity of the existing system. Two 4.3 meter diameter Earth Pressure Balance (EPB) tunneling machines operating at times from the same shaft on a congested work site and advancing through sedimentary deposits underlying this wonderful city pose interesting challenges. As of January 1999approximately 50% of the tunnel has been excavated. Combined machine production rates of 1026 m/month have been achieved. Presentations made in prior proceedings can be referenced for details of the overall Project scope and for details of the tendering process. The purpose of this paper is to compliment those presentations by addressing now the execution of the work.

Jan 1, 1999

By James R. Hein, Jane Reid, Robert W. Embley, Se-Won Chang, Randolph A. Koski

"Abstract - This is the first reported occurrence of an active hydrothermal field in an oceanic fracture zone setting. The hydrothermal field occurs in a pull-apart basin within the Blanco Fracture Zone (BFZ), which has four distinct mineral deposit types: (1) barite mounds and chimneys, (2) barite stockwork breccia, (3) silica-barite beds, and (4) silica, barite, and Fe-Mn oxyhydroxide in sediments. All deposit types contain minor amounts of sulfides. In barite stockwork, silica-barite beds, and mineralized sediment, Ba, Pb, Ag, S, Au, Zn, Cu, Hg, Tl, As, Mo, Sb, U, Cd, and Cu are enriched relative to unmineralized rocks and sediments of the BFZ. Fe and Mn are not enriched in the barite stockwork or silica-barite beds, but along with P, Co, and Mg are enriched in the mineralized sediments. Silver contents in deposits of the hydrothermal field range up to 86 ppm, gold to 0.7 ppm, zinc to 3.2%, copper to 0.8%, and barium to 22%.Mineralization occurred by diffuse, low to intermediate temperature (mostly <250°C) discharge of hydrothermal fluids through pillow lavas and ponds of mixed volcaniclastic and biosiliceous sediments. Bacterial mats were mineralized by silica, barite, and minor Fe hydroxides, or less commonly, by Mn oxyhydroxides. Pervasive mineralization of bacterial mats resulted in formation of silica- barite beds. Silica precipitated from hydrothermal fluids by conductive cooling and mixing with seawater. Sulfate, U, and rare earth elements (REEs) in barite were derived from seawater, whereas the REE content of hydrothermal silica deposits and mineralized sediments is associated with the aluminosilicate detrital fraction. Fe-, Zn-, Cu-, Pb-, and Hg-sulfide minerals, Ba in barite, and Eu in all mineralized deposits were derived from hydrothermal fluids. Manganese oxides and associated elements (Co, Sb, Mo, W, Cl, and Cu) and Fe oxides and associated elements (Be, B, P, and Mo) precipitated as the result of mixing of hydrothermal fluids with seawater."

Jan 1, 1999

Prediction of fragmentation by blasting is most commonly based on theassumption that a single distribution of pre-existing discontinuities is present within a blasted rock volume and that the underlying mechanism of failure is tensile failure. It is assumed that the tensile stress field created by a blast initiates and extends radial cracks around the blastholes. Interaction between radial cracks from different blastholes and the free surface creates rock fragments. In reality, fragmentation of the rock occurs due to two mechanisms.One is related to the compressive-shear failure of the rock (mainly rock matrix) close to the blastholes, while the second mechanism is the previously mentioned tensile failure of the rock mass. The secondmechanism of failure occurs in the form of extension of the larger cracks in the region beyond the crushed rock, and this type of fragmentation occurs after the crushing phase. In the case of hard rock or blasting where the extent of crushing is minimal, the currently used prediction methods give a reasonably good result. However, there are many blasting conditions where the amount of rock crushing is significant. In the case where fragmentation of the given rock volume occurs dueto two different mechanisms, modeling of the rock fragmentation with a single distribution function is not appropriate. To model the fragment size distribution generated by two different mechanisms, it is necessary to use a two-component fragment size distribution function and a scaling parameter that will determine the proportion of the fragmented volume created by each mechanism. The purpose of this paper is to present results of blast fragmentation modeling based on two mechanisms of failure. The two-component model (TCM) utilises experimentally determined parameters from small scale blasting and parameters of the Kuz-Ram model, for more accurate prediction of the complete rock fragment size distribution curve. The methodology is such that it is possible to predict complete fragment size distribution, including fines, of ROM product for a future mine, at the feasibility phase of mine design.

Jan 1, 1999

By D. D. Banerjee, S. K. Kawatra, T. C. Eisele

A high calcium fluidized-bed combustor ash was shown to be an effective binder for iron ore pellets at dosages of 1 % to 2% of the magnetite concentrate weight. Magnetite pellets that were between 1.1 and 12.7 mm (7/16 and 1/2 in.) in diameter were produced with dry crushing strengths greater than 22.3 N (5.0 lb-force) per pellet, which is comparable to the results produced using conventional bentonite binder. The effectiveness of fly-ash-based binders was considerably improved when calcium chloride was added as an accelerator. The addition of calcium chloride at a rate of 0.1 % to 0.2 % of the total powder weight increased the strength of the dried pellets by as much as 22 % compared to the strength of pellets made using fly-ash without accelerators.

Jan 1, 1999

By B. A. Ridolfi, S. M. Alvarez

The Moon Creek Reclamation Project provides a case study in the development of creative cleanup solutions for an abandoned lead and zinc mine and mill site located in northern Idaho. Innovative design features include construction of a 88,000cubic yard combined waste containment facility on soft in-situ tailings, water-balance cap, limestone gravel drains, a geocell mattress for stability, and a below-grade scour protection berm. The stream, including a wetlands buffer, will be relocated within an existing road alignment and rehabilitated to provide trout habitat. These elements allow for the integration of reclamation and stabilization measures into an effective site design.

Jan 1, 1999