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By S. Chander, A. Briceno

The effect of sample storage in argon and in air on the kinetics of oxidation of pyrite from a coal source was studied using accelerated-weathering tests that were performed in laboratory columns. Prior to the weathering tests, the samples were crushed, ground and stored for various periods of time in either argon or air. The test results showed a dramatic difference in the rate of oxidation of the aged samples. The interpretation of the differences was based on the hypothesis that the aging of pyrite led to the formation of surface coatings that changed with time. "Dry" oxidation produced surface coatings that had properties different from those produced by "wet" oxidation. The significance of these results to pyrite/reagent interactions during flotation and in evaluating the acid-mine-drainage potential of pyritic waste materials is discussed.

Jan 1, 1995

By Lei Zhang, P. Somasundara

The beneficiation of phosphate is complicated due to its sparingly soluble nature. The surface proper- ties of phosphate and associated minerals are determined, in addition to the ionic composition of the solution, by the dissolution of the lattice ions of the minerals and subsequent complexation, hydrolysis, adsorption, and precipitation of the dissolved species. These, in turn, are influenced by the pretreatment of the mineral. These complex interactions determine the interfacial properties of phosphate and associated minerals and thereby the efficiency of beneficiation processes such as flotation and flocculation. Under- standing of the chemistry involved in such systems is helpful to develop the optimum beneficiation schemes. It is shown that desired selectivity can be achieved by controlling the chemistry of the systems. More important, the need to conduct development tests under plant conditions is clearly demonstrated.

Jan 1, 1999

By B. K. Parekh, W. M. Goldberger

Sludge obtained during the production of magnesium (Mg) from molten MgCl2 by electrolysis contains entrapped magnesium particles. The sludge containing the magnesium particles is a friable, continuous matrix of frozen salts that may also contain some oxides and impurities. Due to the high reactivity of magnesium metal with water, a dry process was developed to recover magnesium metal from the sludge. The process utilizes mineral-processing unit operations. The steps include selective comminution, screening, attritioning and tabling. Recovery of the high-grade (>90%) metal was in the 70% range. The novel process was also successfully applied to a magnesium-alloy for the recovery of metal from the sludges.

Jan 1, 1997

By Thomas C. Wilder, Firoze E. Katrak

As part of a survey on the long range supply of gallium, a comprehensive review of the chemistry of commercial gallium extraction was undertaken Owing to its very small concentration in all commercial minerals, gallium can be produced economically only as a by-product of major extraction processes for other materials. A summary is presented for the chemistry of gallium extraction from many of these process streams included are several procedures for gallium recovery from bauxite, currently the most prevalent source Other processes described are from waste streams from the production of zinc, phosphorus from phosphates, aluminum from kaolin clays, and from coal ash, the largest potential resource A brief review of development of solvent extraction as a unit process for gallium recovery is also presented

Jan 1, 1983

By Danqing Xu, A. W. Khair

This paper presents an analysis of mechanism of secondary fragmentation and respirable dust generation due to regrinding. In continuous miners, the recovered coal and uncleaned coal from the previous cutting cycle have to be transported through the circumference of the cutting drum, subjecting the coal to regrinding. Such regrinding comminutes the coal material utilizing kinetic energy, thus creating a great amount of respirable dust. The mechanism of a single particle subjected to regrinding is analyzed. A mathematical model is developed to describe regrinding in field conditions. The important factors influencing the comminution process are discussed in detail. Utilizing three types of coal seams, laboratory experiments are being carried out with an Automated Rotary Coal Cutting Simulator (ARCCS) to quantitatively evaluate the effects of some particular parameters, such as cutting velocity, depth of sump and properties of coal material, on breakage and on the amount of respirable dust generated. An orthogonal fractional factorial experimental arrangement is used to optimize experimental design. Preliminary experimental results are presented.

Jan 1, 1991

By K. A. Natarajan, M. K. Yelloji Rao

The electrochemistry of sphalerite and chalcopyrite was investigated under both open-circuit and applied potential conditions. Emphasis was placed on the selective dissolution of sphalerite from a mixture of sphalerite-chalcopyrite flotation concentrates as a function of applied potential, acid concentration, pulp density, and time. Morphological studies using a scanning electron microscope (SEM) were also carried out with chemically leached, galvanically leached, and unleached surfaces of sphalerite and chalcopyrite. Selective dissoulution of sphalerite could be achieved if the mixed chalcopyrite-sphalerite concentrate slurry was maintained at a negative applied potential of -0.4V (SCE). Probable mechanisms involved in the selective dissolution of zinc are disscussed.

Jan 1, 1990

By G. F. Friel, J. C. Edwards, C. C. Hwang

In the implementation of a mine fire alarm and location strategy, the Interpretation of the fire signature Is Important. Smoke and CO are the two dominant fire signatures, and many mine fire detection systems utilize sensors which respond to smoke or CO through a diffusion mode or a mechanical pump mode. The fire signature may be modified during its transport along airways and at crosscuts. The modification occurs through dilution of the contaminants. In this Investigation, computer codes were employed to compute the effects of contaminant dilution on the contaminant signature when a straight flow passage has one dead-end crosscut. The model predicted the airflow within always and the entrainment of contaminants into the crosscut from the airway. One application of the model is to determine the most suitable location for CO detectors for early mine fire detection.

Jan 1, 1995

By William H. Schiffbauer

Research is being conducted toward making underground mining equipment autonomous. This will facilitate improvements in safety by relieving workers of dangerous tasks and will increase production by providing more accurate control with less down time.. A Bureau of Mines developed microcomputer network has enhanced this research by permitting a group of diverse computers to interact with a mining machine as well as with each other over a common data link. The network is composed of specially integrated off-the-shelf hardware and industry-standard operating system and programming languages. Using the network, researchers can conduct various experiments with the mining machine using a diverse group of intelligent sensors, computers, and microcontrollers. Descriptions of the mining machine, the mining machine control computer, control algorithms, -the microcomputer network architecture, and communication protocols are discussed.

Jan 1, 1989

By Fathi Habashi

LEACHING IS the process of extracting a soluble constituent from a solid by means of a solvent. In extractive metallurgy it is the process of dissolving a certain mineral (or minerals) from an ore or a concentrate, or dissolving certain constituents from metallurgical products such as calcines, mattes, scrap alloys, anodic slimes, etc. In this respect, either one of two purposes can be achieved: 1) Opening of ores, concentrates, or metallurgical products to recover the metal values. 2) Leaching easily soluble constituents (usually gangue minerals) in an ore or a concentrate in order to have it in a more concentrated form, e.g., the

Jan 1, 1970

By Samir Kumar Das

Presently Geographic Information System (GIs) is gaining wider acceptance id appreciation in various resource management surveys, generation of various thematic maps, various scientific investigations, environment assessment, disaster management, etc in India but they are general in nature. A huge number of Global Positioning System (GPS) based "Total Station" are playing good roles in India for accurate and quick surveying . The GPS based real time Mine Management and Truck Dispatching System for optimization of productivity is being installed in the Panchpatmali opencast bauxite mines of India. This paper dealt in depth on GIs and GPS and their present roles in the Indian mining scenario.

Jan 1, 2002

By J. M. Kruger

High-resolution ground-penetrating radar (GPR) was used to image the near-surface extent of two exposed Late Cretaceous kimberlites intruded into lower Permian limestone and dolomite host rocks in northeast Kansas. Six parallel GPR profiles identify the margin of the Randolph 1 kimberlite by the up-bending and termination of limestone reflectors. Five radially-intersecting GPR profiles identify the elliptical margin of the Randolph 2 kimberlite by the termination of dolomite reflectors near or below the kimberlite's mushroom-shaped cap. These results suggest GPR may augment magnetic methods for the delineation of kimberlites or other forceful intrusions in a layered host rock where thick, conductive soil or shale is not present at the surface.

Jan 1, 1997

By P. Coleman, J. C. Kerkering, S. Iverson

A fatal accident may result when a dozer is driven over a hidden void in a coal surge pile and the dozer falls into the void, burying and suffocating the dozer operator. This type of accident was analyzed by researchers from the Spokane Research Laboratory of the National Institute for Occupational Safely and Health using inexpensive fault-tree programs that had been developed, for use on a personal computer. Fault-tree analysis is a systematic safety-analysis tool that proceeds deductively from the occurrence of an accident event to the identification of the root causes of that event. The analysis identified basic and intermediate events that led to the burial of the dozer and graphically depicted the interrelationship between the basic events as well as the intermediate events leading up to the accident. A sensitivity analysis on assigned probabilities showed which events had the greatest influence on dozer burial in a coal surge pile. Operational guidelines and engineering controls are suggested to decrease the probability of a burial event.

Jan 1, 2002

By G. Karahalios

Industrial minerals always play an important part in the technological growth of a country. The extraction and trading of industrial minerals continues to expand, but the industry is now subject to stricter environmental guidelines. This paper presents the current status and growth potential of industrial mineral exploitation in the southeastern European region, i.e. Albania, Bosnia-Herzegovina, Bulgaria, Croatia, the Former Yugoslav Republic of Macedonia, Greece, Italy, Serbia and Montenegro, Slovenia and Turkey. Annual production figures per country are presented for 1992-1998. These figures are compared to each other, and, where applicable, they are compared to world production figures. The marketing of industrial minerals to Europe and other regions of the world and the effects of such trade on the local economies are also evaluated when such data are available.

Jan 1, 2000

By G. T. Adel

As a prerequisite to removing mineral matter from coal by any physical separation technique, the mineral and coal particles must be sufficiently liberated. In the case of the production of superclean (< 2% ash), low-sulfur products, the appropriate liberation size may be less than 10 µm. Unfortunately, much of the liberation data obtained at these fine sizes is only qualitative due to the lack of appropriate instrumentation. In the present work, computerized image analysis has been used to characterize several common eastern U.S. coals. In most cases, it has been found that micronizing of the coal is necessary in order to achieve sufficient liberation for deep cleaning. Liberation analyses of the products from the microbubble column flotation process have been used to distinguish problems in liberation from problems in selectivity, especially as they pertain to pyrite rejection.

Jan 1, 1989

By I. Iwasaki, X. Cheng

A series of batch flotation tests was performed on chalcopyrite-quartzite, on pyrrhotite-quartzite and on chalcopyrite-pyrrhotite-quartzite mixtures. Pulp potential measurements in the flotation tests with single sulfide minerals indicated that each sulfide mineral had its own optimal potential range for flotation. When these results were used to select the potential ranges for the separation of the two minerals from their mixture, their flotation responses changed, and the selectivity of separation was adversely affected. A possible mechanism involving surface alteration through galvanic interaction is discussed, and a method to improve the selectivity of flotation separation is proposed.

Jan 1, 1993

By R. W. Smith, M. C. Fuerstenau, G. X. Xang

Nonliving dried water hyacinth (Eichhornia crassipes (Mart.) Solms) roots were investigated for the biosorption of cadmium, lead and other heavy metal ions from aqueous solutions. Dried water hyacinth roots, when suspended in solution, strongly and rapidly sorb several different metal ions. Factorssuch as reaction time, pH, the initial concentration of metal ions, the presence of other metal ions and biomass concentration were investigated. The adsorption was shown to follow the generalized Langmuir adsorption equation. The relative affinity of the roots for lead is greater than that for cadmium. The batch sorption kinetics of the uptake of cadmium and lead can be described by an apparent first-order reversible reaction model. The roots could be regenerated after the metal ions were stripped. Successful desorption of Cd and Pb from the biomass by acidic CaCl2 solutions revealed that the metal uptake phenomenon is reversible, implying physical sorption of Cd and Pb.

Jan 1, 2000

By E. G. Williams

Underclays and shales are two natural resources associated with the coal measures. Underclays are widely used as the raw material for refractory, semi-refractory, and face bricks. Shales are useful for sewer pipe and lightweight aggregate. This study concentrates on the geologic controls over the properties of shales for use in the manufacture of lightweight aggregate, and the geologic controls over the properties of underclays for use in the manufacture of bloating ladle refractories. The industrial processes are similar in that both involve the trapping of a gas phase to cause bloating. They differ in that the bloating of lightweight aggregate occurs at lower temperatures (1000-1200°C) than ladle bricks (1350°-1470°C). Lightweight aggregate bloats during an initial rapid firing. Ladle bricks are manufactured by slow firing at 1100°C for up to 80 hours. Bloating occurs when these bricks are reheated to 1350°C . Bloating shales are those which expand twice or more times their original volume during fairly rapid firing. Commercial bloating is usually done by rotary kiln processing or sintering; in both cases the firing rate is much faster than the experimental rate (5/8°C/minute). Bloating results from the entrapment of gasses which are evolved during firing. The material must have adequate viscosity to trap gas bubbles throughout the temperature range of bloating. The finished product contains a high percentage of closed pores with a bulk density between 35-75 pounds per cubic foot. Expanded shale finds its most important use as a substitute for heavy concrete aggregate (crushed stone, sand and gravel) where low bulk density is desired property. The extent of bloating in lightweight aggregate is a function of the mineralogy and chemistry of the shale. Figure 1 shows a corner of the three phase diagram, kaolinite-quartz-(illite and chlorite). Several areas on the diagram are outlined which contain predominantly marine shales, fresh and brackish water shales, and underclays. Each sample was rapid fired and the resulting expansion was plotted on the phase diagram.

Jan 1, 1973

By J. Hilgers

Metal prices are often predicted by relying on time trend projections of various economic indicators or even the trend in price itself Thus, time is the underlying explanatory variable acting through at best, a limited selection of economic variables. The price prediction method described in this paper differs from this by analyzing hundreds of economic variables to develop a few principle components that automatically capture the fundamental changes in the economy and delete duplicate or irrelevant information. This leaves a few principle variables to describe a state-space representation of the economy which can then be used for prediction. Forecasts of the price of a metal are then made based on these principle variables.

Jan 1, 1995

By A. I. Makhin, S. M. Sablukov, V. K. Sobolev, V. A. Larchenko, V. S. Shchukin

The kimberlites of northern Europe are related with a large crustal block having a northwest-southeast orientation. Kimberlites penetrate the Archean formations of crystalline basement, Late Proterozoic rocks, which are overlapped by Middle Carboniferous and younger deposits. The kimberlites bodies include pipes, dikes and sills of Upper Devonian age. Within the region, rocks of two magmatic series form diamond-bearing kimberlites. Aluminum rocks form a new type of diamond-bearing rock that is not found in other diamond provinces. Kimberlites of this region are characterized by highly developed deuteric alterations, a low content of associate minerals, the presence of two diamond generations and an increased content of jewelry-grade diamonds.

Jan 1, 1997

By Stefan Zanon, Ty Faechner, Clayton V. Deutsch

Secondary data are important in geostatistical simulation of continuous variables. Geophysical data and geological trends are used for modeling porosity and permeability. Multiple mineral grades must often be modeled for mining applications. Sequential Gaussian simulation (SGS) is often used because of its relative simplicity and robustness. The two most common approaches to integrate secondary data in Gaussian simulation are with (1) locally varying mean, or (2) collocated cokriging. A significant problem with both of these techniques is variance inflation, that is, the variance of the resulting simulated values is too high because of an inappropriate decision of stationarity or an artifact of choosing a single secondary data in presence of many. We introduce a self-healing procedure for dynamic correction of this problem. The dynamic correction is different for the locally varying mean approach and for collocated cokriging since there are different reasons why each of these methods causes variance inflation. The reasons for variance inflation are discussed and the self-healing is applied to a number of data sets.

Jan 1, 2002