Role of Surface Chemistry of Phosphate in Its Beneficiation

The beneficiation of phosphate is complicated due to its sparingly soluble nature. The surface proper- ties of phosphate and associated minerals are determined, in addition to the ionic composition of the solution, by the dissolution of the lattice ions of the minerals and subsequent complexation, hydrolysis, adsorption, and precipitation of the dissolved species. These, in turn, are influenced by the pretreatment of the mineral. These complex interactions determine the interfacial properties of phosphate and associated minerals and thereby the efficiency of beneficiation processes such as flotation and flocculation. Under- standing of the chemistry involved in such systems is helpful to develop the optimum beneficiation schemes. It is shown that desired selectivity can be achieved by controlling the chemistry of the systems. More important, the need to conduct development tests under plant conditions is clearly demonstrated.