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By M. F. Lopez, A. J. Mattus, S. B. Magid, D. B. Mobbs

"The use of Caro's acid as a replacement for hydrogen peroxide for the oxidation of vanadium prior to solvent extraction resulted in a 56% reduction in oxidant usage when compared on an equivalent hydrogen peroxide basis. Comparative oxidation tests, using two actual uranium mill raffinates, resulted in premature precipitation of an amorphous ferric vanadate when hydrogen peroxide was used to oxidize one of the raffinates containing a high iron to vanadium ratio. The use of Caro's acid eliminated the precipitation problem, thereby permitting the adjustment of the raffinate pH to a higher, more favourable level prior to solvent extraction.Potentiometric characterization of the raffinates revealed that vanadium is responsible for the inefficiency of hydrogen peroxide compared with Caro's acid, with the oxidation efficiency of iron being the same for both oxidants. A limiting potential between 720 and 740 mV was observed when using hydrogen peroxide, while, when using Care's acid, potentials approaching 1200 mV were achievable.A four-stage, countercurrent extraction performed on the oxidized raffinates did not reveal any operational problems. The extraction efficiency and the extraction coefficient were found to be higher when Caro's acid was used as the oxidant, as opposed to hydrogen peroxide.IntroductionMost vanadium is recovered as a by-product of some other process: leaching of Carnotite uranium ores, oil fly ash, phosphate rock or chromite processing. The major source of vanadium has been from uranium mills incorporating acid leaching of Carnotite ore s at elevated temperatures and pressures. The by-product recovery of vanadium from uranium ores of the Uravan Mineral Belt, located in the Colorado Plateau , is a common occurrence when vanadium recovery is economically viable."

Jan 1, 1983

By Z. Jing, C. Jun

High-purity Bi2O3 was prepared via extraction-preparation stripping method use BiCl3 leaching solution. Parameters such as oxalic acid concentration, phase ration, aging duration, feeding duration, were examined for their effect on the size and morphology of precipitate. The precipitate was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), particle size analysis, differential scanning calorimetry and thermal gravity analysis (DSC-TGA) and infrared spectroscopy analysis (FT-IR). Bi2O3 was characterized by elements analysis, particle size analysis and scanning electron microscopy (SEM). Bi2O3 product of 680 nm was obtained using 15 g/L oxalic acid, 1/1 phase ration, 0 min aging duration, 0 min feeding duration and calcinating at 500 °C for 2 h.

Mar 1, 2018

By David L. Bickel

Stress-relief techniques and instrumentation have been developed through many years of research in the Bureau of Mines and successfully used to determine the in situ state of stress in rock. This report describes the Bureau's three-component borehole deformation gauge and the drilling equipment and accessories used with it. Operation and calibration procedures for the deformation gauge are discussed in detail, along with site selection and overcoring procedures. Information and references included in this publication provide a guide to the Bureau's cover-coring method for determining rock stress.

Jan 1, 1985

By G. W. Garside

In order to render my descriptions more intelligible, I have compiled a general map of this section of Alaska, showing accurately the relative positions of the most important districts where valuable deposits of minerals have been discovered (page 819). Upon inspection of this map, it will be observed that the chief metalliferous belt in this mineral field is in close proximity to the mainland shore, the trend of which it follows for more than a hundred miles in a northwest and southeast course, while the mineral croppings on the adjoining islands are much shorter in extent, and more irregular with respect to their strike and continuity. This principal metalliferous zone, which I will call the main-land system of lodes, contains gold, silver and lead, besides traces of copper, zinc and iron, gold being found extensively in a free state and also associated with sulphur, and with many of the sulphides of iron, lead and other substances. On the line of this belt, as shown on the map, there are a number of distinct mineral districts. Beginning at the southerly extremity, they are named as follows: Sumdum, Snettishham, Grindstone Creek, Sheep Creek, Gold Creek, Lemon Creek, Montana Creek and Berners Bay districts, each deriving its name from the hay or creek on which it is situated. Harris mining district, as legally organized under the local customs, rules and regulations adopted by the miners of Juneau, embraces, within its exterior boundaries, Grindstone, Sheep, Gold and Lemon Creeks, and all of Douglas Island. The limits of this immense metalliferous horizon are becoming definitely known through the exposures made by prospectors. The belt, as now recognized, varies in width from one to several miles, the lateral measurement being greatest at Juneau in Harris district, where the famous Treadwell mine, with its slate foot-wall, marks the westerly boundary of the zone, while the eastern side of Silver Bow Basin, with a granite hanging-wall, defines its easterly border.

Jan 1, 1893

By Pedro Cunha Alves

A cada ano a demanda por aços limpos aumenta, tornando o controle de inclusões cada vez mais importante. Durante o refino secundário de aços, ocorrem a eliminação de impurezas, ajuste da composição química e ajuste da temperatura do aço líquido. A remoção de inclusões não-metálicas geralmente ocorre nessa etapa, sendo realizada pela escória. Neste trabalho, foi definido um planejamento de experimentos para que numa segunda etapa, os conhecimentos obtidos possam ser comparados e transferidos para a prática industrial. Inicialmente, foi feita uma revisão da literatura sobre experimentos realizados em fornos de laboratório com amostras de aços e escórias focados na remoção de inclusões. Depois de analisados diferentes arranjos experimentais propostos, alguns trabalhos selecionados foram analisados com respeito às inclusões e às escórias presentes. Finalmente, no planejamento proposto, definiu-se que os experimentos serão realizados em forno resistivo com passagem de argônio. As amostras serão fundidas em cadinhos de MgO na temperatura de 1600ºC e, após 90 minutos nesta temperatura, as mesmas serão resfriadas em água. Alguns parâmetros que poderão ser estudados são a população de inclusões, viscosidade efetiva da escória, teor de oxigênio total e composição de inclusões ao longo do tempo.

Oct 30, 2017

By N. A. Barcza

DC plasma-arc technology using a hollow graphite electrode (cathode) has been successfully implemented in the primary metallurgical industry in South Africa up to the 30 MW scale. Mintek has applied its expertise base, established over the past fifteen years, to testing the treatment of metallurgical wastes such as carbon- and stainless-steel plant dusts, lead- and zinc-containing slags, and residues from the base-metal industry. Favourable results have been achieved, and disposable products were produced. The evaluation of numerous wastes indicates that recovery of zinc as metal gives the best economic return from these sources. Direct recovery via a splash condenser or electrolytic zinc extraction from fume are the two preferred alternatives under review. In both instances dehalogenation is an important issue, but can be achieved by suitable treatment processes. The Enviroplas technology provides a flexible, commercially viable approach to the treatment of a wide variety of wastes. Mintek, together with its associate Pyromet CC, are installing a plasma- arc pilot-plant facility with both an ISP lead-splash condenser of about 5 t/d condensed zinc capacity and a combustion chamber to burn zinc vapour to zinc oxide. This will demonstrate the suitability of the Enviroplas technology for treating specific metallurgical wastes, so that customized industrial plants can be engineered based on large-scale testwork.

Jan 1, 1994

By J. W. Town

Recrystallization studies on chrome-bearing spinel materials were made by the Bureau of Mines to determine the effects of certain fluxing agents and cooling rates on the chromium-to-iron ratio of recrystallized spinel. Statistically designed and evaluated tests showed that the ratio of chromium to iron in naturally occurring chrome spinel could be increased from 1.5 to 1 to over 7 to 1 and that the ratio of chromium to iron in the chrome-spinel in a stain-less steel slag could be raised to over 18 to 1. Silica, magnesia, and lime had significant positive effects, while alumina had a significant negative effect. Cooling rates of 200 C per hour in a programmed spiral globar electric furnace were satisfactory for growing crystals of recoverable size.

Jan 1, 1967

By C. W. DeLong, L. L. Farnham, L. A. Stewart

This paper is one of a series covering mineral resources of the Nation . It describes briefly most of the known manganese deposits of eastern Arizona , which for the purpose of this report includes the counties of Navajo , Apache , Gila, Graham, Greenlee , Pinal , Pima , Santa Cruz , and Cochise . With few exceptions , these descriptions are the result of field examinations by the writers . Work on this paper was begun in May 1956 , and in the following 18 months 151 deposits were examined . The distribution of the deposits by counties is as follows : 1 in Navajo , and 1 in Apache , 37 in Gila , 4 in Graham, 13 in Greenlee , 25 in Pinal , 13 in Pima , 12 in Santa Cruz , and 45 in Cochise . In surveyed areas the locations of the deposits are described by section , township , and range and in unsurveyed areas , by approximate projections of these subdivisions . The township and range numbers refer to the Gila and Salt River base and meridian . The history, production, ownership , geologic setting , and mining methods used are discussed for most of the deposits that were visited . Probably , some occurrences have been overlooked , but all of the principal ones have been examined . Ore dressing studies were made of typical ores from several of the larger districts . The work was performed in the laboratory of the Bureau of Mines Tucson Metallurgy Research Laboratory . The results of these studies are given with the descriptions of the deposits from which the samples were taken .

Jan 1, 1961

By Yuezhen Zhou, Zewei Liu, Dachun Liu, Chongfang Yang, Wenlong Jiang, Fansong Liu

A novel process that the combination of vacuum decomposition and acid leaching was proposed. The influence of distillation times, diameter and thickness of the feeding material on the mass fraction of Molybdenum (Mo) and sulphur (S) in residual was investigated. The influence of leaching temperature, leaching time, concentration of hydrochloric acid solution, and ratio of liquid to solid on leaching rates of Mo and S in acid leaching process was also investigated. Due to the fact that SO2 emission happening in the long process of traditional molybdenum metallurgy could be avoided in this novel method, this combination process was environmentally-friendly. Molybdenum powder was obtained through handling molybdenite concentrate under the optimal condition parameters, and the mass fraction of Mo reached 98.29 wt%. So it's feasible to produce molybdenum powder from molybdenite concentrate by using this new method.

Mar 1, 2017

By K. A. Pauly

(Wilkes-Barre Meeting, June, 1911.) COMPRESSED air has been and is still very extensively used in connection with mining-operations, but its application in the past has been almost entirely confined to supplying power to underground machinery. Its introduction was due to the difficulty of taking care of the steam which is exhausted underground, rather than to any advantage in efficiency to be gained by its use. The ease with which electric power may be carried to the remotest parts of the mine and the high efficiency of the electric motor have long been appreciated by mine-operators, and electric power is now extensively used underground in the more recent developments, while many of the compressed-air engines in the older workings are being rapidly replaced by electric motors. Recently, however, it has been suggested to use compressed air for driving the large shaft-hoists, the air for the engines being supplied by electrically-driven compressors, and an installation of this character is being erected at Butte; Mont. It is the object of this paper to compare the compressed-air system of hoisting with the various electrical systems, from the stand-points of first-cost and cost of operation. However, before entering into a discussion of the various systems, it will be well to consider briefly the conditions affecting the choice of a system of hoisting in which electricity is the ultimate source of power. The power required by a mine-hoist is extremely intermittent and fluctuates between very wide limits, the all-day average consumption of power not exceeding from 5 to 15 per cent. of the maximum demand during hoisting. The cost of supplying power for such a fluctuating load is necessarily higher than that for supplying an equal amount of

Dec 1, 1911

By M. G. Zabetakis

Benzene and toluene are the first two members of an important homologous series whose general formula is CnH2n-6. The members of this series differ in composition from benzene by some integral multiple of CH2; they can all be prepared in the laboratory by the Wurtz-Fittig, Friedel-Crafts and Grignard syntheses. Because 'of the industrial importance of these-hydrocarbons, the limits of flammability of eight members of the series have been determined at 100° C.-(A temperature of 1000 C. was chosen because the determination of the upper limit of flammability of p-cymene requires an apparatus temperature. of at least 90° C. As elevated temperature data are available for other combustibles at 100° C. but not at 90° C., all data were taken at 100° C. in order to obtain comparable results.) Minimum ignition temperatures of these combustibles have been determined at laboratory-pressures.

Jan 1, 1951

By Rodrigo Cesar de Miranda

A importância de descrever o processo de beneficiamento por um modelo matemático tem sido apresentada por vários pesquisadores. O principal benefício é o controle e a otimização do processo dentro de uma situação industrial. O modelo seria capaz de prever determinada variável de controle do processo a partir de dados conhecidos. Assim, a simulação dinâmica representa um marco no campo da otimização de processos minerais. Essa tecnologia de simulação tem uma ampla aplicação no estudo de processos, o que permite a obtenção do seu conhecimento e domínio operacional. Além disso, possibilita melhores definições nas etapas de projeto, além de realizar uma análise de confiabilidade mais realista. O presente trabalho consiste em realizar uma análise de confiabilidade, através da simulação dinâmica, para entender como as paradas não-programadas influenciam a produção de uma planta de beneficiamento de ferro. Ainda, visa entender o desempenho fenomenológico dos equipamentos de acordo com a entrada de diferentes tipos de minérios e também como são suscetíveis a condições climáticas.

Aug 17, 2017

By B. W. Gandrud, G. D. Coe

"INTRODUCTION The Bureau of Mines, United States Department of the Interior, with the cooperation of the University of Alabama and coal producers of Alabama, is making a series of washability studies to obtain technically and commercially important data from the productive coal beds of the State. Based on the system followed in these studies, this report consists of screen-sizing and sink-and-float data on the America and Pratt beds at Gorgas, Ala.SAMPLING AT THE MINESAlthough operations were discontinued in 1929, the accessible openings of the old Gorgas mines of the Southeastern Fuel Co. made possible the taking of samples from the America bed at three openings and from the Pratt bed at two openings. A sample was taken from the America bed at the Klondyke opening; a second was taken about 1 rile south of the Klondyke at the Musgrove America opening, and a third sample was taken about 1-1/2 miles south of the Musgrove-America at the Cricket Lodge opening. A sample was taken from the Pratt bed at Musgrove-Pratt No. 1, which is about 3/4 mile east of Musgrove-America, and a second sample was taken at Musgrove-Pratt No. 2, which is about 3/4 mile west of Musgrove-America. The samples ranged in weight from 1/2 ton to 1 ton and were equivalent to approximately a 2-ton sample from each bed. Figure 1 shows sections of the beds at the places sampled.In addition to the samples for washability study, a seam sample for analysis was taken at each of the places sampled. So as to give a representative seam sample for each of the two beds, these samples were combined in the laboratory in proportion to the thickness of the bed at the places sampled."

Jul 1, 1939

By R. E. Thill

An ultrasonic, pulse-immersion apparatus and method are described for determining the effects of moisture on the dynamic elastic properties of rock. The method provides an alternative approach for assessing the moisture sensitivity of rocks. Ultrasonic wave velocities are continuously monitored in immersed rock samples as a function of water absorption and time up to saturation. Moisture effects on compressional wave velocity vary as a function of the type of rock and the time and amount of water absorption. Regression analyses are used to curve-fit plots of the data and to derive empirical expressions for compressional wave velocity as a function of water content for different categories of rock. Results indicate that compressional wave velocity can be used to predict both the moisture content and its effect on strength and deformational properties of rock. These results have potential for detecting or monitoring bad roof conditions in situations where the mine rock exhibits strength degradation with moisture absorption.

Jan 1, 1986

By N. Saracoglu, J. P. Golightly, R. H. Wallis, J. J. Brummer

"The McClean uranium deposits are in northern Saskatchewan, 11 km west-northwest of the Rabbit Lake mine. Their average grade is 1.8% UJ0 8 and they contain 6,350 tonnes of uranium oxide in seven pods of variable grade and mineral assemblage. They are hosted by both basal Athabasca Group and the regolith developed on the underlying crystalline basement. The major mineral facies are: sulphide, arsenide, 'bleached', and hematite, with the important uranium minerals being coffinite, uraninite and pitchblende.Abundances of carbon and sulphur isotopes are consistent with their derivation from pyritic graphite in basement gneisses. Isotopes of oxygen and hydrogen suggest mineralizing fluids were aqueous and at temperatures of about 200°C. Ar39/ Ar40 laser age determination of illite indicates mineralization began about 1300 m.y, ago and that significant hydrothermal alteration ceased about 1170 m.y. ago though Pb/U data suggest the deposits continued to evolve into the Mesozoic.The deposits are interpreted as the result of oxidizing ground water stripping uranium and other metals from either the Athabasca sandstone, especially the heavy mineral layers, or from the regolith, and precipitating these when encountering a warm reduced fluid emanating from the basement."

Jan 1, 1984

By Sathit Tandanand

This Bureau of Mines report describes the method of obtaining a strength index for rock drillability, particularly for percussion drills. The original Protodyakonov method has been slightly modified, essentially to eliminate uncertainties in the measurement of the volume of fines, and to avoid conjecture in selecting the representative value as the strength coefficient. A theoretical consideration of the relevant parameters in the method was extended from a comminution theory, and hence the meaningful value was obtained experimentally by plotting the ratio of the number of drops and the volume of fines against the number of drops. The minimum ratio of the number of drops to the volume of fines in the plot was selected as the coefficient of rock strength. The modified method of obtaining the strength coefficient preserves the original Protodyakonov test apparatus and the merit of simplicity of the test procedure. The modified coefficient of rock strength shows its usefulness in predicting penetration rates with greater reliability than other mechanical properties. Consequently, the drillability curves were drawn using the modified coefficient of rock strength as the parameter for penetration rate prediction in the field.

Jan 1, 1975

By Charles S. Allbright

This report describes hydrogenation of petroleum distillate fuels in bench scale equipment and the effects of hydrogenation on the storage stability and the composition of the fuels. Two distillate fuels were hydrogenated in laboratory equipment using a commercially available cobalt molybdate catalyst. Reactor temperatures were varied from 600° to 850° F and pressures from 100 to 600 psig. Product fuels were analyzed by ASTM, Bureau of Mines, mass, and infrared methods. Hydrogenation of a catalytically cracked fuel from Oklahoma crude oil significantly improved the storage stability, reducing insoluble gum formed during 9 months of storage at 110° F from 19.0 to 1.3 mg per 100 ml fuel, average. Conversion of the olefins to other hydrocarbon types varied with the temperature of hydrogenation--at 700° to 850° F the conversion was mainly to aromatics, at 650° F about 50:50 to saturates and aromatics, at 600° F principally to saturates. Processing a fuel composed of a mixture of virgin distillate and catalytically cracked stock, both from Illinois crude, at 700° F and 200 psig effected marked improvement in stability; the buildup of insoluble gum in storage was lowered from 18.3 to less than 1 mg per 100 ml fuel.

Jan 1, 1967

By Kenneth H. Johnston

For the past several years, Bureau of Mines petroleum engineers have arranged tours of selected waterflooding projects for the spring meetings of the Kansas-Oklahoma Waterflood Association. These tours are conducted to demonstrate unique operating methods and new field equipment and to provide additional opportunities for exchanging information. Each of these tours has been supplemented by a published report describing in detail the projects visited. This report has been prepared for distribution during the 1960 spring tour of four waterflooding projects in Greenwood County, Kans. (fig. 1). Three of the projects produce oil from the Bartlesville sand, and one produces from the Cattleman sand. The Bartlesville-sand floods have been in operation from 4 to 12 years and have produced about 3,910,000 barrels of waterflood oil from the injection of approximately 64,715,000 barrels of water, a cumulative water-injected to oil-produced ratio of 17 to 1. The Cattleman- sand flood, which has been operating for 3-1/2 years, has produced about 842,000 barrels of waterflood oil from the injection of approximately 9,305,000 barrels of water, a cumulative water-injected to oil-produced ratio of 11 to 1.

Jan 1, 1960

1.0 SCOPE AND REGULATIONS 1.1 This specification covers the minimum requirements for material handling and associated equipment including design and materials. 1.2 This specification requires compliance with all federal, state, local laws and regulations which may be applicable including the Occupational Safety and Health Act, Construction Safety Act as well as rules, regulations and standards of the Secretary of Labor.

Jan 1, 1979

By C. C. Jobes

Operating large face equipment, such as continuous mining machines, is one of the most basic and most dangerous elements of an underground coal mining operation. The operator usually performs cutting and tramming tasks in a restricted workspace with reduced visibility. During the execution of these tasks, operators often cannot see all of the locations needed to safely operate the continuous mining machine (CM ), which has sometimes resulted in accidents. In an effort to prevent these accidents, researchers at the National Institute for Occupational Safety and Health (NIOSH), Pittsburgh Research Laboratory, examined the continuous mining machine operator?s current information cues, or visual attention locations, so that risk of injury relative to the task, equipment and workplace environment can be evaluated in the future. The eventual goal is to develop interventions to enhance the information cues, and thereby increase the safety and health of machine operators. This paper details the operator interview process, determination of visual attention locations (VALs) and simulation of various mining scenarios.

Jan 1, 2011