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By G. Reuben Yourt

THIS paper is chiefly a description of the improvements in dust control chat have been brought about in the assay office grinding room at Wright-Hargreaves. The fume exhaust systems are briefly included because they also are important to the health of the employees. There are three chief factors which determine the efficiency of a dust control system: First, the amount of time and thought spent in designing it. Second, how close! y it is kept up to date with the growth of the plant-a system that is adequate for the number of machines operating when it is installed may fall short of fulfilling its purpose as the plant expands. Third, unless someone is held directly responsible, a system is likely to get out of repair and gradually lose its efficiency-this can easily be detected by regular dust surveys. In designing the present system at Wright-Hargreaves, the object kept in mind was to reduce the dust concentration of all operations to a safe limit, chat is, well under 300 particles per cubic centimecer of air. By doing this, a condition would be attained chat would make it possible to discontinue the use of respirators, which at best are not very comfortable and do not remove all of the hazardous fine-dust particles.

Jan 1, 1941

By H. Al-Kazzaz

The effects of laser power and joint gap on the welding quality of 2-mm butt joints of ZE41A-T5 sand castings were investigated using a continuous wave 4 kW Nd:YAG laser system and 1.6-mm EZ33A-T5 filler wire at a welding speed of 6 m/min and surface defocusing. The smooth weld profiles with the minor welding defects were obtained at a laser power of 4 kW and joint gap of 0.3-0.4 mm. The hardness values in the fusion zone are similar to those of the base metal but there is a drop in the heat-affected zone after a natural aging of 18 months.

Jan 1, 2006

By Franz Simon

Conventional fine gold electrolytes for barrel applications working electrolytically actually permit significant precious metal savings by corresponding optimizations but the most gold is still deposited on areas of the components where it is not absolutely essential for the desired bonding and soldering applications, i.e. in high current density areas. Therefore an electrolyte working electrolessly has been developed which inevitably leads to a much more uniform thickness distribution since in an electroless process there are no areas favoured by metal deposition and current distribution. The new electrolyte will be presented and its performance will be compared with conventional electrolytes as regards thickness distribution. The potential gold savings will be discussed.

Oct 1, 2003

By D. W. Smith, J. J. Koskinen, T. A. Enwald, M. E. Ball

"A full-scale demonstration unit of Tampella's LIFAC desulphurization process was tested at SaskPower's Poplar River Power Station Unit No. I. The test program included a series of parametric tests, followed by a 1500 hour operational evaluation. This paper summarizes the results of the test program, and SaskPower's economic evaluation which led to selection of the LlFAC process for SaskPower's 300 MW Shand power station. IntroductionOne of the major influences on the coal mining industry today is public and legislative response to acid rain. When sulphur-bearing fuels such as coal are burned, the sulphur oxidizes to sulphur dioxid e (S00 which, if uncontrolled, enters the atmosphere as one of the by-products of combustion. S02 then combines with water in the air to form an acid and acid rain results. Combustion also produces nitrogen oxides (N0J which can combine with water in the air forming nitrogen based acid , also contributing to acid rain.Acid rain has become a significant international concern. Newspapers have reported on dying forests, dead lakes and crumbling statues. Papers also include articles professing that the physical results of acid rain are vastly overstated. In the United States, a IO-year, Y2-billion dollar study called the National Acid Precipitation Assessment Program (NAPAP) was commissioned to evaluate the effects of acid rain. Even this extensive scientific study did not resolve the controversy. Despite disagreement over the quantitative effects of acid rain, there is no doubt that public concern over the issue is widespread and deeply felt.In response to this concern, legislators throughout the world have reacted with programs that restrict the emission s o f SO, and NO,. To industries involved in the supply and use of coal, the impact of these legislative programs has been extensive. United States power plants will be spending 10 billion dollars in the next decade for flue gas clean-up equipment. Even all this new equipment will not stem the tide of change to low sulphur coals and to “clean “natural gas. The following summarizes legislative actions taken for Canada and the United States."

Jan 1, 1993

By Eric Best

"In the past two to three years, all continuous mining machines at the Potash Corporation of Saskatchewan Mining Limited, Lanigan Division, have been changed over to a new cutting pattern using 1 -inch- and 1-3/l6-inch-diameter self-sharpening pencil bits. The bits are arranged in a cone-type pattern across the face on 2 1/2 -inch and 3-inch spacing. The result is that the ore is removed by chipping and flaking. Previously, rap-lock bits were used, with the pattern being several bits in single rows at wide spacings. The cutting action was grinding and breaking.Besides improved penetration rates and lower bit costs, there are many other advantages. The ore size is much smaller, resulting in less wear and tear on conveyors and other associated equipment. Feeder-breakers are no longer routinely set up at the head end of every extensible belt, as the banana-shaped chunks of ore that used to require breaking are no longer produced. Also, less dust is generated by the cutting heads and fewer stops are required for bit changes. Even the mill operation has been improved, as fewer fines are produced.Further improvements are still sought after, but, all in all, the new cutting pattern is considered to be a giant step forward from the old method."

Jan 1, 1981

By J. M. Beeckmans, S. G. Butcher, M. Goransson

"The counter-current fluidized cascade is a novel and potentially efficient pneumatic gravity separation device. Data are presented on over 150 runs of cleaning Alberta thermal coals, covering several size ranges. The coarser sizes of coal were processed in admixture with a fluidizing medium consisting of 0.5-by 0.1-mm hematite (or magnetite) and limestone particles. The partition curves for coal particles larger than about 3 mm, mixed with fluidizing medium, showed that the sharpness of separation achievable with the cascade approaches that of wet heavy medium processes, whereas with particles in the size range of 3 by 0.6 mm the sharpness of separation was comparable to that of a Baum jig. Useful cleaning was also achieved with particles smaller than 0.6 mm , Throughput rates of up to 11 tonnes per metre width of cascade per hour were achieved, with no indication of a deterioration in performance.IntroductionPneumatic coal beneficiation has steadily lost ground vis-a-vis hydraulic beneficiation during the past quarter century, primarily because of the sharper separations achievable with the latter methods. Nevertheless, there are certain inherent advantages of pneumatic separation methods which would give them an advantage in the market place were it possible to increase their efficiency to be technically competitive with those of hydraulic processes. These advantages are a dry product, resulting in a higher calorific value per ton, and avoidance of the problems associated with treatment and storage of process waste waters. Also, although it may be necessary to dry the raw coal prior to pneumatic processing, the dry rejects produced constitute an ideal fuel for a fluidized-bed combustor, which could provide heat both for drying the coal and for other purposes."

Jan 1, 1982

By Zygmunt Wegrzyk

Poland is rich in hard and brown coal reserves, which have become the most important, and steadily developing, primary source of energy. With 192.6 mill. t of hard coal production and 40 mill. t of exports in 1978, Poland is fourth and second in the world respectively. The paper discusses the various mining methods adopted in the country's history of mining. Particular emphasis is placed on longwails, their mechanization and equipment assembled in the form of fully mechanized face complexes suited for varied geological conditions. Measures to improve the recovery ratio of coal resources are dealt with. investment efforts undertaken in the coal industry are outlined. An account is given of the ever improving techno-economic results of coal mining. The country also exports a wide range of mining equipment and transfers its well-founded technical know-how to others. There are strong cooperative links with many foreign partners.

Jan 1, 1979

By G. R. Tostengard

"The paper identifies functional areas which frequently can yield significant productivity improvement. Emphasis is placed on the repair and maintenance, material supply and training functions. Successful approaches are discussed in some detail, and typical results which have been achieved are reviewed.IntroductionA challenge which at all times confronts the manager o f any mineral operation is the potential to improve his operation no matter how effective it might be a t the present time. The challenge has been present through my entire lifetime and I suspect a good many years prior to that and, I expect, will continue many year s and decades in the future. The competitive and economic situation in which we in the minerals industry find ourselves today makes the challenge eve n more important during the 1980s. In many cases it’s a question of survival, not simply pr of it improvement.There are, of course, many avenues to improving profitability; technological changes, new equipment and facilities, improved products, improved mine plans, etc. All of these are important and must be addressed by each manager. This paper focusses on just one avenue to improvement and that is ""improved management"", not so much of management at the boardroom level but of improved management o f the facilities and workforce as the y currently exist. Management implies control. There are three areas where control is often found lacking:1, Repair and maintenance of equipment and facilities;2. Material supply including procurement, inventory control and warehousing; and3. Training.These three areas are all complex and difficult to manage and they are all but ignored in the formal education which our industry's manager s normally receive. They are areas which can be improved with relatively small investments and therefore, they represent especially attractive improvement targets during the 80s when, for most of us, investment dollars are very difficult to come by."

Jan 1, 1983

By A. P. E. Dirige

The stability design of cemented backfills is normally conducted using conventional approaches. Analytical or numerical models, backed by trial-and-error methods, are the primary means used to describe or predict the support performance of backfills during mining. The stability of paste backfill free-standing faces is a major concern due to potential consequences to production, ore dilution and safety. Available analytical or mathematical models are developed based on assumptions of the failure modes that may occur when vertical fill faces are exposed during adjacent mining. Numerical modeling serves to provide an understanding of backfill strength and deformation behaviour. Such approaches offer inherent limitations and generally result in conservative designs. In this paper, centrifuge physical modeling was conducted not only for performance evaluation studies, including stability analysis, but to develop an understanding of the strength and deformation behaviour of paste backfill exposed faces when the adjacent ore zone is removed. The failure mode and mechanics of failure observed in the centrifuge model of a given prototype situation are discussed in detail. Centrifuge model results were compared to numerical modeling and it was concluded that a sliding block failure mechanism that resembles a circular slip appears to be the predominant failure mode.

Aug 1, 2013

By Andrew Bamber

The mining and beneficiation of minerals is the second largest end-use of electrical power on the planet, and comminution is by far the largest single contributor to this. Several jurisdictions, including British Columbia, have, in response to concerns about greenhouse gas emissions and climate change, adopted energy conservation legislation, including carbon taxes, carbon trading and conservation incentive schemes. Key to achieving conservation objectives is firstly an understanding of usage metrics across the various unit operations in the sector, and secondly an understanding of the conservation potential represented by available technologies and approaches in reducing end-use. This paper presents the results of a recent utility-funded study on energy use metrics and conservation potential at large open pit mines which are typical of the sector in BC.

Aug 1, 2013

By B. E. Jones

"The area of uranium deposition is situated within the Churchill Province on the western edge of the Wollaston Iithostructural domain where it underlies the eastern edge of the Helikian Athabasca Formation. The Collins Bay deposit is 6 miles north-northeast of the Rabbit Lake mine. Two principal zones of uranium mineralization are described.The ""A"" zone is a partly eroded, high-grade pod of metal oxide and arsenides sheathed by clay-like minerals. It trends north-northeast and lies under 25 to 40feet of water. Uranium mineralization is localized at or adjacent to the unconformity between the Athabasca Formation and the basement rocks. The basement comprises a granitoid Archean terrain overlain by paragneisses of the Aphebian Wollaston Group. ""A "" zone ore contains phyllosilicates, quartz, pitchblende, rammelsbergite, pararammelsbergite, carbonaceous material, galena, gersdorffite, niccolite, carbonate and a trace of sphalerite.The ""B "" zone lies 6,000 ft south of the ""A "", and subcrops under till cover. It is a partly eroded zone composed of metal oxide and arsenides which occur within variably altered Athabasca Formation. Minerals recognized are phyllosilicates, pitchblende, niccotite, gersdorffite, millerite, carbonaceous material, pyrrhotite, skutterudite and a trace of galena. The Athabasca Formation varies from 90 to 160ft thick. Granitoid gneisses of probable Archean age and paragneisses of the Wollaston Group underlie the deposit. An easterly dipping thrust fault transects its length.The deposit is typical of the ""unconformity-type"" uraniumnickel deposits of the Athabasca Basin. Observed features fit well with the ""diagenetic-hydrothermal"" model for such deposits, as envisioned by Hoeve and Sibbald (/978)."

Jan 1, 1980

By Robert A. Gault, T. Scott Ercit, Mehmet F. Taner

"Abstract -Vanadium mineralization occurs in oxide-rich horizons within the layered gabbro zones of the upper parts of the Bell River Complex, Matagami, Québec and the Lac Doré Complex, Chibougamau, Québec. The vanadium-rich horizons are well defined on the ground and in aeromagnetic surveys by their high magnetic susceptibility; consequently, magnetic susceptibility can be an indicator of vanadium mineralization. The main oxide minerals are ilmenite and titanian magnetite, containing 20% to 70% of volume and the ratio of titanian magnetite to ilmenite is relatively constant, ranging from about 1:1 to 2:1. Their sizes are less than 5 µm to greater than 1 mm to 2 mm, occurring as coarse- to medium-grained subhedral crystals intergrown with cumulate silicate minerals (plagioclase, pyroxene, etc.). Electron microprobe analyses indicate that the ilmenite grains are mineralogically and compositionally homogeneous and have low V contents (average 0.18% equivalent V2O5). In contrast, the titanian magnetite grains are inhomogeneous, consisting of trellisworks of ilmenite lamellae in Ti-poor, V-rich magnetite [less than 2 wt% TiO2, and 1.41% equiv. V2O5 (1.16% V2O3) for 20 analyses]. Thus, the magnetite is the principal ore mineral of vanadium; it hosts vanadium in the form of V3+, not V5+, as is commonly and erroneously reported. We have also devised a flowchart for the beneficiation of vanadium-titanium ores. Sommaire - La minéralisation de vanadium se trouve dans des horizons riches en minéraux oxydés de la partie supérieure des zones de gabbros lités des Complexes de la Rivière Bell, Matagami, Québec et du Lac Doré, Chibougamau, Québec. Des horizons riches en vanadium ont été bien définis sur le terrain et dans les levés aéromagnétiques par leur susceptibilité magnétique élevée; conséquemment, la susceptibilité magnétique est l’indicateur directe du contenu en vanadium. Les principaux minéraux oxydés sont l’ilménite et la magnétite titanifère, contenant 20% à 70% du volume et le rapport de magnétite titanifère à ilménite est relativement constant, allant d’environ 1:1 à 2:1. Leur dimension varie de 5 µm à plus grande que 1 mm à 2 mm, apparaissant sous forme de cristaux subidiomorphes, de grains grossiers à médiums, intercroissant avec la gangue silicatée (plagioclase, pyroxène, etc.) de la texture de cumulat. Les analyses à la microsonde électronique montrent que les grains d’ilménite sont minéralogiquement et chimiquement homogènes avec un faible contenu en V (moyenne 0.18% équiv. V2O5 ). Contrairement, les grains de magnétite titanifère sont hétérogènes, contenant des lamelles d’ilménite en "trellisworks"; ces grains sont pauvres en Ti et riches en V pour la portion magnétite de la magnétite titanifère [surtout contenant moins de 2 wt. % TiO2, et en moyenne 1.41% équiv. (1.16% V2O3) pour 20 analyses]. Ainsi, la magnétite est le principal minerai de vanadium; elle renferme du vanadium sous forme de V3+ et non de V5+, tel qu’il a été communément et à tort rapporté. Nous avons aussi défini un "flowchart" pour la bénéficiation des minerais de vanadium-titanium."

Jan 1, 1998

By Robert Voisey, Robert J. Spencer

"LynnGold's MacLellan Mine is located about 8 km south east of Lynn Lake immediately to the east of the Keewatin River (Fig. I). The property is accessible by an all-weather road, leading north from the provincial highway 391, which links with the Town of Leaf Rapids and the City of Thompson to the south.The ore body, as outlined in the original feasibility study, is expected to produce in excess of 9.3 x IQ6 gm of gold and silver over the next 5 years. However, the deposit is open to depth and exploration is continuing on and around the main zone and the many satellite deposits.The start of construction of the MacLellan Mine and mill was scheduled to phase in with the closure of the Fox copper-zinc mine located 48 km west of Lynn Lake. The majority of the employees from the Fox Operation were either employed at the MacLellan Mine or relocated to Sherrin's Ruttan Operation.GeologyThe MacLellan gold ore deposit is located on the northern section of the Lynn Lake Greenstone Belt known as the Rainbow Trend. This Trend is a 40 km gold bearing rock sequence extending both east and west from the MacLellan Mine. The southern section of these two east-west trending structures is known as the Johnson Shear, this is also gold bearing."

Jan 1, 1990

By D. B. Dreisinger, M. R. Tavakoli

Vanadium has been produced from a variety of sources. This metal is known to make aqueous solutions of complex speciation as a function of vanadium concentration and pH. Considering the method of leaching, the impurities in the PLS and the planned vanadium product, different extractants and flowsheets can be applied for solution purification. In this paper, purification of vanadium leaching solution using organophosphorus, solvating and amine extractants will be reviewed. This review will be focused on vanadium separation from iron, molybdenum and uranium which are often present in vanadium resources including primary ores, fly ashes and spent catalysts.

Jan 1, 2014

By G. R. C. Pacheco, D. M. Fonseca, R. Neuböck, G. E. Gonçalves, W. Moulin-Silva

Degradation by sulfur gases is an important lining wear mechanism in the copper industry. SO2/SO3 gases infiltrate into the pores of the basic refractory bricks, combine with their raw materials through expansive reactions and significantly modify the bricks’ structure. This study presents a comparison of the corrosion resistance against sulfur attack of different magnesia-based refractories using a simple, low-cost and quantitative method. Recipes containing sintered MgO grains showed lower resistance to corrosion by sulfur oxides compared to basic grades containing fused grains. Chromium corundum grades were used as a reference and showed very good resistance to this corrosion mechanism under the test conditions. The novel test provided relevant results that agree with what is commonly observed during operation and in previous post-mortem studies. This tool could be very useful in selecting refractory grades for the copper industry and predicting their performance. INTRODUCTION Oxidation of matte sulfides during copper production leads to the formation of sulfur oxides, which infiltrate into the pores of the refractory lining and react with the basic oxides below 1000°C to form magnesium and calcium sulfates. This reaction is accompanied by an expressive volume increase, consequent densification of the refractory microstructure and weakening of the brick bond (Malfliet et al., 2013). Thus, corrosion by SO2/SO3 is an important wear mechanism in the non-ferrous industry and the resistance to this compound should be considered when defining refractories for this application. Previous studies on this matter include expensive and complex testing methods involving pressurized SO2 gas cylinders in order to investigate the corrosion resistance of MgO-containing materials by sulfur oxides (Gerle & Podwórny et al., 2016; Fotoyi & Eric, 2011; Fotoyi, 2009; Podwórny & Piotrowski et al., 2008). The current study was based on a test developed by Pacheco & Fonseca (2018) to assess alkali infiltration and aims to provide an evaluation method of the corrosion resistance of refractories by SO2/SO3 in a simple and quantitative manner. This novel test is useful to compare the corrosion resistance of different refractory recipes and properly select the grades that should be employed in the non-ferrous industry. A case study is provided to illustrate the damage caused by sulfur oxides in refractory linings.

Jan 1, 2019

By Gordon E. Agar

"The effectiveness of two this compounds for copper sulphide depression in molybdenite flotation has been examined with batch bench scale tests.Both thioglycollate and trithiocarbonate proved to be good depressants producing results similar to those f or cyanide and hydrosulphide. Ferrocyanide was ineffective on the samplematerial tested.The depressing effect of thioglycollate was readily reversed by an addition of xanthate.IntroductionThe separation of molybdenite from copper sulphide minerals has been practised for a long time(1,2). The predominant scheme is to depress the copper sulphides while capitalizing on the ready floatability of molybdenite to effect the separation. There are many recipes for depressing the copper minerals(3), among them the addition of sodium cyanide, particularly if the copper is present primarily as chalcopyrite; some form of sulphide whether as sodium sulphide, sodium hydrosulphide or phosphorous pentasulphide when there is a mixture of copper sulphides such as bornite, chalcocite and chalcopyrite; potassium ferro cyanide may be used when chalcocite is the principal copper sulphide; peroxide or hypochlorite; as well as heating in the presence of lime. There are different mechanisms by which these reagent s depress the copper sulphides. Sodium cyanide and the sulphide-producing compounds apparently reduce the potential of the copper sulphides to the point where they ar e rendered unfloatable by xanthates . Another study(4) showed that after cyanide addition, chalcopyrite was rendered un floatabl e until the REDOX potential (measured with a gold electrode with a saturated calomel reference) had become more positive than -250 mY. If the chalcopyrite pulp was conditioned after the cyanide addition the REDOX potential increased slowly, whereas if air was introduced during the conditioning the potential r ose much more rapidly. The difference in time to reach the desired level of - 250 mV was as much as 20 minutes' 25 minutes being required when air was absent but less than 5 minutes when air was admitted . These observation s demonstrate some of the problems encountered when using cyanide to depress sulphides such as chalcopyrite . The system adjusts to counteract the depressing effect of the additive. To overcome this tendency it is necessary to either add an overdose at the beginning or to more or less continuously add the regulating reagent. In this study cyanide solution was added under automatic control to maintain a specified REDOX potential."

Jan 1, 1984

By N. Ahern, M. Barbanell

Mercury is often present in gold ores and can be released during processing. In view of health and environmental concerns related to mercury, the mining industry takes leadership in the responsible management of mercury. This paper reviews various aspects of mercury management, including an overview of mercury deportment in typical gold processing flowsheets; trends in mercury legislation impacting the international flow and management of mercury in the gold mining industry; and treatment, storage and disposal options for mercury and mercury containing materials.

Jan 1, 2014

By Roland Froidevaux

"The main object of ore reserve classification is to assess the reliability of an ore reserve estimate. Because traditional classification schemes fail to provide a means of calculating this reliability, the terms 'proven "" 'probable' and 'possible ' ore were introduced as an attempt to qualify it.Geostatistics, on its part, allows the quantification of the precision of any ore estimate and thus appears as an appropriate tool for ore reserve classification.However, the problem of fixing quantitative boundaries for ore classes remains. In order to be meaningful, ore class limits based on the degree of reliability should be customized to the commodity, and the type and size of the deposit. In addition, the precision of an ore estimate will be affected by the cut-off grade and the size of selective mining units.IntroductionPrimarily, ore reserve classification should be seen as a communication tool between the geologist and the mining engineer on one hand and the management and policy maker on the other. By classifying ore reserves, the geologist tries to answer the very fundamental question: ""What quantity of metal is there in the ground and how sure am I that it really exists?""The difficult y of quantifying the degree of reliability of reserves has led to the creation of a large suite of terms and definitions, with almost every mining company having its own set of definition standards. As lower-grade deposits are brought into production, the margin of tolerable error in estimates of the grade and tonnage is becoming much narrower. Consequently, the need for unequivocal definition of the reliability of ore reserves is increasingly acute. Most of the generally accepted systems of classification, however, describe the reliability of reserves in qualitative, rather than quantitative, terms."

Jan 1, 1982

By G. M. Ritcey, S. H. Lucas

"On the north shore of the St. Lawrence River, in Quebec, are located orebodies of low-grade titaniferous magnetite. The Quebec Mining Exploration Company (SOQUEM), who have an interest in the deposits, believed that beneficiation of the could generate sufficient revenue to defray the mining costs and the costs of transporting the ore to a steel production facility. A joint research project of SOQUEM and CANMET investigated alkaline roasting of a magnetic concentrate, followed by leaching of the calcine and separation and recovery of Cr and V by solvent extraction. Aluminum was recovered by precipitation.The present paper describes the roast-leach bench-scale and pilot-plant work leading to the development of the optimum conditions f or the integrated process.A plant flowsheet was developed for the treatment of 5 x 106 tons of magnetic concentrate per annum. Estimates of capital and operating costs were made.Based on a recovery of approximately 90% V, 85% Cr and 75% AI, the total hydrometallurgical plant fixed capital costs, including mining, concentration and shipping, are estimated at $1.021 x 109; the operating costs are estimated at $131.92/ton concentrate. Annual revenue from the Na2CrO4.H2O, V2O5 and A12O3 produced is calculated to be $421 x 106.IntroductionThe Quebec Mining Exploration Company (SOQUEM) acquired in 1968 an interest in four titaniferous magnetite orebodies located in Eastern Quebec. 85 miles north of Mingan on the north shore of the St. Lawrence River. The Mingan deposit, with an estimated tonnage of one billion tons, has a reported average grade of 43% Fe, 6.3% Ti , 1.60% Cr, 0.19% V and 6.1% Al with minor amounts of nickel. SOQUEM, on the basis of previous bench-scale data, believed that the recovery of chromium, vanadium and alumina by alkaline roasting would generate sufficient revenue to defray the mining costs and the costs of transporting the ore to a steel production facility on the coast. One of the approaches selected by SOQUEM for beneficiation of the ore consisted of a combination of magnetic concentration followed by alkaline roasting of the calcine."

Jan 1, 1980

By Hamid-Reza Manouchehri

Coarse particles flotation is controlled by detachment (particle hydrophobicity and flotation cell turbulence) For composite particles (the bubble may attach to good hydrophobic region, but the expansion of the three phase line of contact is limited. Hence, the equilibrium contact angle, characteristic of the hydrophobic region, may never be attained, and the force of attachment is decreased relative to that possible for homogenous hydrophobic surfaces.

May 1, 2013