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In China the hydrogeological type of solid mineral deposits can be divided into A. Mineral deposits with fissure water; B. Mineral deposits with pore water; and C. Mineral deposits with karst water. The hydrogeological conditions of mineral deposits with fissure water are relatively simple with the exception of a few cases. Mineral deposits with pore water are few but great amounts of ground water can be encountered in the mine accompanied by floating sand or slope failure during the exploitation. Mineral deposits with karst water are complex in their hydrogeological conditions. Enormous inrushes occur frequently in the mines of north China; Karst collapses are a serious matter in the mines of the south; Subterranean river and conduit systems are often encountered in the southwest. This paper will give full discussion on these features and put forward a way of combating and controlling the groundwater problem in accordance with type and feature.

Jan 1, 1988

The purpose of this work is to determine the equilibrium-state of the aqueous-solution which is produced by the leaching processes, including natural weathering of pyrite minerals. The latter can lead to acid-mine-drainage (AMD). The ferric iron species (Fe3+) resulting from bacteria-catalysed oxidation of ferrous iron (Fe2+), in the presence of water and air, is known to bring about steady-dissolution of minerals chalcopyrite (CuFeS2), sphalerite (ZnS), pyrite (FeS2), and so forth. Good-aeration, relatively high-porosity and sufficient bacterial activity tend to promote leaching in waste-rock-dumps. The composition of the aqueous-phase that accumulates in the pore-space (or in open-pits) is of practical interest as it would strongly influence the leaching of both sulfide and non-sulfide minerals. Since the reactions among the various ionic species occur relatively fast, the solution-phase may be regarded as approaching a state of virtual-equilibrium and it is possible to determine by computation the respective concentrations of the many dissolved species. For the Cu-Fe-H-O-S system, these species may include: H+, Fe2+, Fe3+, Cu2+, HSO4-, SO42-, OH-, CuSO4o, H2O, Fe(OH)+, Fe(OH)2+, Fe(OH)2+, Fe2(OH)24+, Fe(SO4)+, Fe(HSO4)+, Fe(HSO4)2+, and Fe(SO4)2-. The aqueous-system which may be constituted from appropriate mole-quantities of H2SO4, FeSO4, Fe2(SO4)3, and CuSO4 is in fact the result of various natural processes (reactions) and due respect must be accorded to the extents of these reactions. The present model computes the equilibrium molalities of the foregoing ionic and neutral aqueous species, using the iterative equilibrium constant method that ensures strict-adherence to charge-balance and elemental molar-balance constraints. The dissolving sulfide-minerals (FeS2, CuFeS2) consume Fe2(SO4)3, H2O, and O2 and yield FeSO4, H2SO4, and CuSO4 while the aqueous-phase tends to become progressively acidic (declining pH) reflecting the gradual increase in the extents of sulfide-dissolution reactions. The equilibrium-state of the solution-phase is computed for specific set of values for the extents of respective reactions. The temperature and pressure of the system are 25¦ C (298.15 K) and 101.325 kPa (1.0 atm), respectively. The mica-like minerals such as the biotite [H2K(Mg,Fe)3Al(SiO4)3] tend to consume much of the H2SO4(aq), with the extracted K+, Mg2+, Fe2+ and Al3+ ionic species accumulating in the solution. The precipitation of the jarosites (potassium, hydronium, or ammonium) contributes to the removal of ferric and ferrous species from the solution-phase. In the present work, the emphasis is on predicting the compositions of the aqueous- and condensed-phases with advancing time or increasing æextent of reactionÆ. The results of such calculations are compared to published data on raw AMD (acid-mine-drainage).

Jan 1, 2008

By G J. Sparrow, M J. Fisher-White

A mineral and chemical characterisation study was conducted on ilmenite-rich heavy mineral concentrates sourced from the western sector of the Eucla Basin in southern Australia. Test work involved using X-ray diffraction (XRD), scanning electron microscope (SEM) and electron microprobe-based characterisation methods. Results showed considerable variability in the degree of ilmenite alteration between deposits with TiO2 contents varying from 53 - 63 wt per cent TiO2. Notwithstanding variability between individual deposits, the samples all had [Ti]/[Ti+Fe] ratios >0.5 consistent with a mineral assemblage of hydrated ilmenite or the hydrated, Ti-rich alteration phase pseudorutile (Fe3+2-x Ti3O9-3x (OH)3x). Accessory phases consisted of rutile (primary and secondary), zircon, aluminosilicates, quartz, Fe oxyhydroxides and spinels. Results for the most altered material are broadly comparable with data for ilmenite concentrates from the eastern margin of the basin. The mineralogy of the western Eucla Basin concentrates and the minor element composition of the ilmenite grains suggest they could be upgraded to synthetic rutile by a modified Becher process.

Jan 1, 2008

Electrochemical investigations of the flotation of sulphide minerals are re- viewed. Flotation with thiol collectors is interpreted in terms of a "mixed poten- tial" model in which the process leading to hydrophobicity is the anodic oxidation of the collector at the mineral surface and this is driven by the cathodic reduc- tion of oxygen. Electrochemical studies have identified the products of anodic oxidation as chemisorbed collector, metal collector compounds, and dithiolates; the products formed in each situation depend on the collector used, the mineral under study, and the pretreatment of the mineral surface. Investigations on galena, pyrite, and chalcocite are discussed. Electrochemical and x-ray photoelectron spectroscopic studies have been used to determine the products of surface oxi- dation of sulphide minerals in order to elucidate the mechanism of collectorless flotation. The mixed potential mechanism allows consideration to be made of the ways in which flotation of sulphides with thiols can be inhibited. Examples of depressant action are presented. The relevance of electrochemical investi- gations to practical flotation is Discussed.

Jan 1, 1984

By Wright S, Jorgensen F. R A

The reaction between lead sulphate and a number of base metal sulphides (galena, sphal- erite, chalcopyrite and synthetic pyrrhotite was studied as a means of desulphurizing lead sulphate containing fumes and residues to levels acceptable as ISF feed. The reactants were mixed with 50% zinc oxide to act as a "basket" to contain the molten products of the reaction and pressed into small briquettes 20 mm in diam. Factors such as temperature, time and the composition of the atmosphere were investigated. Using the PbS/PbS04 system as an example it was shown that the reaction became rapid above 800¦C and that both sulphur dioxide and oxygen in the atmosphere were detrimental to achieving low sulphur in the product. In an inert atmosphere all the sulphides when roasted for 1 h at 1000¦C gave results corresponding to the elimination of more than 95% of the sulphur in the reactants. Leach plant residues were considered for use as the "basket" material. It was shown that the residual sulphide and sulphate components of the residues underwent similar reactions to those experienced by the pure systems.

Jan 1, 1987

By Warner R. E

Present capacity for molten iron production at Port Kembla is an average of 13 000 t/day from five blast furnaces. The most recently installed blast furnace, No.5, was commissioned in March 1972 with a design capacity of 4 500 t/day. For the first reline currently scheduled for 1977, plans are being finalized.for significant modifications and uprating of capacity. Achievement of the initial design capacity from No.5 blast furnace on a sustained basis was not realised until the third year of operation. Although the furnace is only 42% larger than No.4 blast furnace on an inner volume basis, the more stringent raw materials, operation and maintenance requirements of the larger furnace and more complex equipment have been found to be much more critical than anticipated in the planning stages. These problems have also been experienced by many other companies who have recently installed large new blast furnaces. Some of the principal problem areas are described together with measures taken to over- come the difficulties. The problem areas include the failure of'the shower cooled bosh, failure of the upper shaft brickwork, sludge

Jan 1, 1976

All companies and individuals who embark on a business venture incur costs. For the most part these costs can be conveniently categorised, firstly into capital and operating costs and then into the various elements of these major cost centres. Although the nature of expenditure naturally differs as between industries certain broad cost types are characteristic of all heavy industries. The capital costs of gaining access to an orebody, equipping a new mine, building a treatment plant and perhaps refining and smelting facilities are likened to capital expenditure by a manufacturer on new plant and equipment required for an expansion or new product innovation. Similarly the day to day costs of labour and materials employed in the running of a mining operation can be likened to similar costs in other heavy industry. There is another group of costs that are not so easily categorised. Most industries incur unavoidable costs that do not form part of the direct or capital costs of physical production. These costs include taxes and other payments to government and research expenditure. The mining industry has a particularly heavy burden of non-production costs and it is the objective here to highlight and analyse a few of them. These costs are exploration expenditure, infrastructure expenditure, royalties and income tax. This is not to suggest that these are the only major non-production costs that the mining industry needs to bear. The industry may incur significant costs for environment protection, land tenure maintenance and on liaising with Government on a wide variety of matters. It is for reasons of subject manageability that the list is confined to the four costs mentioned. For the mining industry, exploration and infrastructure expenditure, royalties and income tax have several distinguishing features. Firstly, they are generally proportionately large costs. Exploration and infrastructure expenditure for example, could well exceed mine development costs. Depending on how royalties are levied, they may be very high in relation to profits earned and many in fact exceed profits. Secondly, except for income tax, they are costs that are generally not payable by other industries. Exploration expenditure is in some respects comparable with industrial research and development. However, because mines are wasting assets exploration is necessary for survival, and it is likely to form a larger part of costs per dollar of profits or sales than R&D. It can therefore be said that exploration is of far more significance to the miner than R&D is to the typical industrial company. Furthermore, unlike exploration expenditure, R&D results are transportable and patents permitting, transferable. The infrastructure burden that miners must carry is unique to the industry. Whereas urbanised industry is not usually liable for the capital cost of power, water, transport, townships and community facilities, the miner must finance these projects himself. Neither the payment of royalties, nor of course, income tax are unique to the mining industry. Royalties are more properly described as a unique charge on some primary industries but however described, they are a charge that manufacturing and service industries do not have to pay. Whilst we all pay income tax, the mining industry's uniqueness derives from the special problem that the industry has in arriving at annual net income in view of the capital intensity of the industry, partly due to expenditure on infrastructure, the indefinite life of capital equipment and its unpredictable residual value, funds expended on exploration and long lead times associated with a mine development. The third distinguishing feature of these costs is that, with the possible exception of exploration expenditure, they are heavily influenced by the policies and actions of Government. As such the industry has a responsibility to promote the industry by emphasising its potential to improve national product including exports and by requesting that the Government provide for the industry in its long term planning and seek its co-operation to prevent the industry incurring inequitable penalties relative to other industries.Finally, exploration and infrastructure expenditure are significant because they are front-end charges on a project. When due allowance is given the time value of money and the deferment of income from a mining development to which they relate, exploration and infrastructure expenditure assume greater importance than the raw money expenditure suggests. For all these reasons, exploration and infrastructure expenditure, mining royalties and mining income tax are worthy of detailed study. This is the purpose of this paper. The objective is to examine the determinants that give rise to them and provide some thoughts on their impact on on-going and potential mining developments and, where relevant, to make some suggestions as to how they may be minimised.

Jan 1, 1977

By J C. Furness, F S. Cannon

Metal casting operations are a significant source of hazardous air pollutants. In particular, high production iron foundries emit significant quantities of volatile organic compounds (VOCs) during pouring, cooling and shakeout of iron castings made in green sand molds. End-of-the-pipeline capture and destruction methods to reduce VOC emissions add crippling costs to foundries. Alternately, the incorporation of advanced oxidants (AO) into metal casting green sand systems has been shown to reduce emissions from high production iron foundries in the US, and at the same time reduce operating costs. Cost savings are driven by the benefits of AO in clay recovery systems. Emissions reductions are the direct result of cascading AO-based reactions taking place in green sand molds. This sustainable greening of the metal casting process is a prototype for the development of other AO and non-AO process-based solutions for sustainable high temperature processing of materials. Fundamentals of AO technologies will be discussed along with the performance characteristics of AO processing systems in the metal casting industry and the breadth of other processing and remediation applications for which AO technologies have the potential to be successfully employed.

Jan 1, 2002

By P Hayes, B Zhao

A range of materials are treated in zinc fuming processes to recover metal values and produce benign slag waste products. The selection of the optimum process conditions in these various technologies can be greatly assisted by the use of a chemical thermodynamic model of the system. In this paper the effects of slag chemistry on the liquidus temperatures, subliquidus phase equilibria and thermodynamic properties are described by a FACT model of the ZnO-PbO-FeO-Fe2O3-CaO-SiO2 system. In addition new experimental data on the effect of Al2O3 on the liquidus are presented. The implications of these findings for plant practice are discussed.

Jan 1, 2000

By de Brodtkorb MK

Late Cenozoic ore deposits "Precious and base metal-rich" and " Sn-Ag-polymetallic"of Northern Puna are associated either with Middle Miocene dacitic volcanic-dome complexes or with Upper Miocene dacitic-andesitic volcanic centers. Ore mineralogies and their related volcanism are discussed. A strong link is observed between the Cenozoic Metallogenetic Province of Northern Puna and the Southern Bolivia Tin and Polymetallic provinces.

Jan 1, 1995

By S F. Simmons, A McOnie, J L. Mauk

Three cross sections, 200 m apart, display the distribution of indicator hydrothermal minerals across the Empire zone of the Golden Cross epithermal Au-Ag deposit, Waihi, New Zealand. These minerals are used to interpret the temperature and composition of hydrothermal fluids. The distribution of interstratified illite-montmorillonite and illite indicate that temperatures ranged from 140 to >220¦C, with temperatures above 220¦C predominating. The mineral assemblage of quartz-adularia-chlorite-illite-calcite-pyrite envelops the Empire vein system and stockwork, and reflects formation from an alkali chloride water whereas the mineral assemblage of replacement calcite-interstratified illite û montmorillonite-kaolinite forms a carapace and reflects formation from a CO2-rich steam-heated water. Alkali chloride waters appear responsible for the epithermal Au-Ag mineralisation.

Jan 1, 1995

By Lye GN

Rock mechanics investigations have shown that some major slopes in the Panguna pit would be stable at angles in excess of 500 providing near-surface instability could be controlled. Excavation of final batters at angles between 55¦ and 60¦ is now being carried out using D10 dozers with berms at 45 to 60 m centres. A trial slope with berms at 90 m centres is planned. Shotcreting of weak zones combined with crest reinforcement, with rock anchors and dowels, is used to provide protection against erosion and toppling of the crests. Overall slopes excavated in this way are of the order of 10¦ steeper than slopes obtained by blast and shovel excavation.

Jan 1, 1986

The major incentives for developing continuous processes for the production of formcoke are to achieve a wider range of coals which can be used, greater operating flexibility enabling the production of various coke qualities, and environmental improvements. The characteristics of a formcoke which must be considered when assessing its performance in the blast furnace are compressive strength, abrasion resistance, volatile matter, reac- tivity, porosity, density, size, shape, ash yield and sulphur content. Lurgi's development work in attempting to pro- duce a formcoke which meets the specified requirements has resulted in most current efforts being concentrated on the Bergbauforschung/Lurgi hot briquetting process. This process blends hot char produced from a non-caking coal with small quantities of caking coal in a special mixer in the plastic range of the caking coal. The material is subsequently briquetted hot, then subjected to a thermal after-treatment to produce a strong abrasion resistant formcoke. A 650 tonne per day plant for British Steel Corporation is now under construction. A study of the equipment requirements and the operating costs indicate that the economics of large scale formcoke plants compare favourably with those of conventional coke-making plants.

Jan 1, 1975

The Greenvale Joint Venturers, Metals Exploration Queensland Pty. Ltd. and Freeport Queensland Nickel Incorporated, use ten Herreshoff roasters, for the reduction of ground lateritic nickel and cobalt containing ores.Initially the roasting section of the plant limited production, due to high down time.The use of technology developed and adapted over a number of years has achieved significant increase in on line time and a minimization of costs.

Jan 1, 1985

This paper will be a discussion of the geological exploration and drilling carried out on the Mt Davy Block, Greymouth Coalfield. A brief summary of the geology of the Greymouth Coalfield will be given to put the Mt Davy Block into perspective.

Jan 1, 1979

By Mansor A. N

Results are reported for the computer simulation of heap leaching of mixed copper oxide and sulphide ores. They resemble those obtained from testwork in terms of a substantial peak in the copper concentration of the pregnant solution, an initial period when no copper emerges and a lengthy period towards the end when the copper concentration and the daily increment in copper recovery are low. The simulation can be used to forecast process results before any column or similar testwork is performed. Potential applications of the simulation to process design, operating strategy and optimisation are discussed. Three modes of operation are identified that correspond to different performance patterns and dependencies on ore and process variables. The relative merits of different operating strategies for approaching the ideal performance are being investigated. For process design and development purposes, the simulation may be used with a limited testwork programme to achieve significant savings in time and resources.

Jan 1, 1989

There are a number of methodologies which can be used for the preparation of environ- mental impact statements. Selection of a method depends upon the type of project and the environmental characteristics of the area where it is to be built. Most methods are satisfactory for assessing impacts on the physical environment but less so for the biological. Major problems may arise in deal ing with sociological issues because value judgements are involved. Several methods of approaching problems of this nature have been tried with some limited success.

Jan 1, 1976

By Paine GG

In coal mining each of the unit operations are interrelated with each preceding operation having an effect on subsequent operations. This presents difficulties for determining when the lowest overall costs for a particular mining system are achieved. Drilling and blasting is the first mining operation for production and is known to have an effect on the subsequent loading, hauling and crushing operations. Computer blasting models developed over the past 15 years can be used to describe the drilling and blasting operation. This paper describes the ICI Blasting Model "SABREX" in detail. Methods of using the model are discussed. This involves field measurements of geological structure, shallow refraction seismic surveys, laboratory measurements of rock properties and high speed photography of blasts. The predictions are compared with actual blast results for fragmentation sizing and muckpile profiles. Outputs from the model are described and these can be used for input to models of subsequent operations.

Jan 1, 1987

The paper describes a simulating method.for ground water contamination originating from industrial and mining activrty. The finite difference model simulates heat, mass and solute transport. The applied stochastical method for dispersion provides more accurate solution of mass transport modelling. This method gives a more realistic approach of chemical processes in an aquifer depending on temperature.

Jan 1, 1988

Chemicals derived from petroleum raw materials satisfy so much of our industrial needs today that it is good to pause and realise two things -ò the petroleum chemical industry is so new, and the use of chemicals is a very old one.Petroleum is such an'abundant and convenient source of raw material that in little more than 30 years it has become the major source of supplyfor chemical rdanuf ctiree This paperw~l'l 'disc'uss t1.e main 'r`easons' for this rapid development by considering the : sub jest -under tkzree headings ea. Source of Raw Materials.b. The Impact of Petroleum Chemicals on Plant Design and Processes. ce Scme of the Major Chemicals Used Today.

Jan 1, 1962