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By Li Qihou, Liu Zhihong, Liu Zhiyong, Yao Wei

Black copper sludge, which mainly contains copper, arsenic and a little antimony, bismuth, selenium, tellurium, is an important recyclable secondary resource. In this paper, selective removal of arsenic from black copper sludge by alkaline oxidative pressure leaching was studied. The influences of alkali concentration, leaching time, leaching temperature, oxygen pressure, liquid-solid ratio and other variables on the leaching rate of arsenic, copper and tellurium were investigated. The results were as follows: when the leaching process was conducted at initial alkali concentration of 1mol/L, liquid-solid ratio of 10, stirring rate of 500r/min, leaching temperature of 140°C for 5 h and oxygen pressure of 2.5MPa, the leaching rates of arsenic and tellurium were 85.43% and 59.7% respectively, and copper, antimony, bismuth were not leached. Hence, arsenic has been removed effectively from black copper sludge, while the valuable metals such as copper, antimony and bismuth remained in the residue that can be further recovered easily. INTRODUCTION Black copper sludge is a byproduct in the purification process of copper electrolyte. Arsenic, antimony and bismuth are major harmful impurities in copper electrolytic refining system. The accumulation of these impurities will cause adverse effects, such as the increase of electrolyte resistance and power consumption and deterioration of cathode copper quality (Wang, Liu, & Zhang, 2001). Hence, electrolyte purification is an essential part of the electrolysis process (Liang, Chen, & Guo, 2009). Electrolyte purification methods include electrowinning (Davenport, King, Schlesinger, & Biswas, 2002), solvent extraction (Navarro, Simpson, & Alguacil, 1999), ion exchange (Arroyo et al., 2017), coprecipitation (Wang et al., 2003, 2018; Xiao et al., 2007; Xiao, Cao, Mao, Shen, & Ren, 2014), activated carbon adsorption (Navarro & Alguacil, 2002), electrodialysis (Cifuentes et al., 2015), redox process (Zhou, Peng, Zheng, Ma, & Cui, 2011; Peng, Zheng, Zhou, & Chen, 2012; Zheng, Peng, Ke, & Chen, 2013), among which the electrowinning method is simple in operation and effective in impurities removal, making it the main process for current electrolyte purification. Some copper ions can react with harmful impurities to form complex black copper sludge by controlling the operation conditions of electrowinning process. Based on the estimated data provide by Davenport et al. (2002), an annual output of 400,000 tons cathode copper could produce 432-2168 tons of black copper sludge by electrowinning method. Black copper sludge contains 30~50% copper, 15~30% arsenic and a small amount of rare elements such as selenium and tellurium. Thus, recovery of valuable metals can bring huge economic interests. Moreover, arsenic in these sludges could cause significant environmental pollution. Therefore, effective removal of arsenic from these sludges is urgent and significant.

Jan 1, 2019

By Jean-Guy L. Gauthier

"With the Ontario Ministry of the Environment stipulating that the cumulative concentration of copper, lead, zinc and nickel in mine mill effluent must be no greater than 1.0 milligram per litre, it has become necessary for the mining industry of find some form of treatment for the removal of heavy metals from effluent waters.To comply with these guidelines, it became necessary for Mattabi Mines Ltd., which is situated 50 miles Northeast of Ignace in Northwestern Ontario, to develop a compact, cost effective and technically sound treatment process to remove heavy metals from their tailings overflow. A design committee consisting of mine metallurgists, environmental engineers, a Dutch research and development team and the equipment supplier engineering staff was set up to accomplish this.Using some new and innovative wastewater treatment equipment, the guidelines established by the Ontario Ministry of the Environment can now be met. The sludge produced from the precipitated heavy metals is sent directly to the concentrator, thus eliminating the danger of re-dissolution of the metals in a landfill site, while recovering some of the valuable metals that would otherwise be wasted in a sludge landfill."

Jan 1, 1980

By R. K. Singhal

"On the mining side the Canadian oil sands industry has become proficient in excavation and disposal of ore and overburden. Nearly twenty years of mining experience is now behind this industry. While local improvements to existing mining systems and practices will continue, it is believed that some further gains in productivity can be achieved by selectively introducing new ideas from other mining and non-mining industries. This type of technology transfer is vital for over-all cost-effective technology enhancement of oil sands mining operations.Discussed in this paper are the issues of mining equipment, equipment sizing, microprocessor and computer based technol¬ogy as applied to mine-wide data management, automation and remote control and a projection of likely mining systems in the year 2000!This paper reviews the ""state-of-the-art"" in selected surface mining systems and attempts to evaluate the forthcoming technology and its application."

Jan 1, 1989

By Gerhard Melcher, Hermann Hilbrans, Michael Gamroth

"IntroductionSeveral new smelting processes have been proposed and developed during the last 20 years. This has been true, in particular, for copper smelting technology. The important impulses for the advances in this field have been the recent demands regarding the environmental protection, energy saving and improved utilization of the metals contents of deposits, in particular that of complex raw materials.The methods developed more recently for pursuing these objectives have been outlined in several papers. In some of them the advantages and drawbacks of certain developments have been stressed. These documents are of great importance for assessing the different processes. The following paper tries to explain some details of the cyclone smelting process taking into consideration a few of these well-known presentations. The effectiveness of operation of the cyclone smelting process indicates that this process presents a significant achievement when compared with other conventional methods.The application of the CONTOP smelting cyclone range s beyond the field of copper metallurgy or the smelting of sulphide concentrates with the aid of oxygen. The research work carried out in the pilot plant of KHD Humboldt Wedag AG in Cologne-Porz also includes the recovery of the metal contents of intermediate products and processing of smelter residues which have to be converted in a disposable stat e, free of environmental pollution. This paper explains a few examples in this regard."

Jan 1, 1987

By F. N. Smith

Corrosion was observed on the aluminum pressure plates and dress-caps that hold the glazing in place on a curtain-walled building, The multi-storey building in question is situated in the downtown area of a busy Canadian city, For aesthetic reasons, the original design required the dress-caps (which have L-shaped cross-sections) to be externally clad with thin copper sheet. Since the aluminum was in direct contact with the copper trim, galvanic corrosion developed that resulted in damage to the aluminum components, Soluble corrosion products washing off the copper trim may also have contributed to the accelerated corrosion of the aluminum, The aluminum pressure plates and dress-caps are being systematically replaced with components made of fibre-reinforced plastic. The outsides of these new components will be clad with thin copper sheet in order to preserve the original appearance of the building.

Jan 1, 2005

By Z. Trojanová

The deformation behaviour of ternary magnesium alloys AJ (Mg-Al-Sr) and AX (Mg-Al-Ca) were investigated in tension as well as compression tests. The samples were deformed at temperatures between 20 and 300 °C and at an initial strain rate of the order 10-4 s 1. The flow stress decreases with increasing temperature. The macroscopic work hardening rate decreases with increasing flow stress and temperature. The stress and temperature dependence of the work hardening rate is a result of the hardening and softening processes. Stress relaxation experiments were performed in order to reveal features of the thermally activated dislocation motion. Internal and effective stress components of the applied stress were estimated. A decrease in the internal stress was observed at elevated temperatures, which indicates recovery process (-es). A more detailed analysis of the estimated values of the activation volume and activation energy helped to interpret the thermally activated processes during plastic deformation. It is concluded that the deformation behaviour of the alloys depends on the activity of non-basal slip that is strongly influenced by temperature.

Jan 1, 2007

By Phil Keele

"Manalta Coal Ltd. 's Vesta Mine will supply Alberta Power Limited's 740 MW Battle River Generating Station with 1 128 000 tonnes of sub-bituminous ""C"" coal in 1983. Mana/ta Coal Ltd. and Alberta Power Limited are in their seventh year of a 31-year coal supply agreement. With the exception of localized topographic highs where three coal seams are mined, the Vesta Mine is primarily a single-seam mining operation. Vesta's comprehensive programs of mine planning, preventative maintenance, reclamation, and employee relations make it an efficient and a well run operation. Introduction The Vesta Mine, located in east-central Alberta approximately 300 km northeast of Calgary, supplies sub-bituminous ""C"" coal to Alberta Power Limited's 740 MW Battle River Generating Station. The coal reserves and principal stripping equipment are owned by Alberta Power Limited. Manalta Coal Ltd. owns and operates the additional mining equipment and support facilities. Coal production is from a single pit, 3.5 km in length. Both single and multi-seam operations are encountered in the active pit. In 1983, production is anticipated to increase to I 128 000 tonnes from 906 000 tonnes in 1982. The additional tonnage will be achieved by operating 24 hours per day, 5 days per week. The following sections briefly highlight historical, geological and mining/reclamation aspects of the Vesta Mine. Figure I illustrates the location of the Vesta Mine in relation to the cities of Calgary and Edmonton. History Coal mining for domestic use began near the turn of the century in the Vesta Mine area. Initially, small underground room-and-pillar operations were dominant. As equipment technology advanced, surface strip mining replaced the underground methods."

Jan 1, 1985

By M. Beech-Jones

The increased emphasis on the efficient utilization of capital and mineral resources has led to several new advances in the science of mineral separation. One example of a recent development is the application of high-capacity high-intensity wet magnetic separators to fine hematit e recovery by a leading Canadian iron ore producer. The iron ore recovery feasibilit , flow-sheet development, circuit operation and metallurgical performance are reviewed.

Jan 1, 1979

By F. Weinberg

"The recent development of the continuous casting process for steel has required basic understanding in a number of areas in the metallurgcal sciences. In some areas, information is still lacking. The success of the application of basic knowledge and research to the process is evidenced by the fact that a large percentage of the steel now produced in the world is produced by continuous casting.A number of areas in which metallurgical science has contributed and is currently contributing to better design and control of the continuous casting process and leading to a better quality product will be considered. These include:(a) heat transfer studies of the entire casting process;(b) fluid flow in the tundish, strand and liquid metal stream;(c) solidification structure and segregation;(d) strength and ductility of steel at high temperatures related to bulging and cracking; and(e) problems related to horizontal casting developments.IntroductionThe continuous casting of steel is a relatively new technology in steelmaking. It is now used extensively throughout the industry. In Japan, for example, continuous casting accounts for approximately 40010 of steel production, and this value is expected to increase to over 50% in the near future . New steel plants are now designed to use continuous casting exclusively. This means the process must work well and be completely reliable, because all the steel produced must go through the caster.The development of the continuous casting process in a short period of time has required concerted research and development in many areas . I shall cite a number of examples of these developments and refer to work done in Canada when applicable. No attempt will be made to review all of the research in continuous casting, nor refer to all of the workers in the field.The developments in continuous casting are based in many cases on metallurgical science, as described below. The use of metallurgical science in these developments is qualitative, in that concepts and idea s are used, as opposed to quantitative values calculated from fundamental equations. In general, most metallurgical problems are too complicated to enable fundamental equations to be used without the introduction of uncertain approximations and boundary conditions in the calculations.Starting at the beginning of the steelmaking process, very extensive research and development has been carried out to produce liquid steel of the required composition and temperature. The replacement of open hearth furnaces with BOF furnaces reduced refining time from many hours to roughly 30 minutes for 250 tons of steel. Two BOF furnaces effectively enable a continuous flow of steel to be available in a plant, essential for the introduction of the continuous casting process. This area of research will not be considered here."

Jan 1, 1981

By C. Gaubert, G. Bourassa

"The construction or rebuild process in the anode baking furnaces has been modeled with the software Rockwell Arena, in order to minimize the process cost and risk. The case study was focused on the sectional rebuild (""on the fly"") that needs a high coordination of the material inventory, the on-site personnel and the construction/production schedule. Multiple entities and resources were allocated for the different part of the process (in-furnace process, prefabrication, materials transportation, etc.). Logic flow charts and VBA macros were used to simulate the space utilization (including cranes utilization) and interaction with production. MS-Excel output files can show user-friendly results."

Jan 1, 2006

By R. B. Kaunda

One fundamental requirement for surface and underground rock engineering is the ability to characterise the rock mass. An accurate characterisation of the rock mass allows rock engineers to optimize designs safely and economically. A number of classification systems have been developed in the past 50 years to help characterise rock masses such as RMR, Q system, Rmi, and several others. The challenge in developing rock characterisation schemes is often practicality, i.e. creating systems with relatively simple inputs for the everyday practitioner. A second challenge is the degree of subjectivity often inherent in commonly used classification systems. These challenges are especially exacerbated in weak rock or densely jointed rock masses. This paper introduces a new approach to characterise densely jointed rock mass using artificial neural networks and principal component analysis, based on principles commonly used in the geotechnical engineering of rock fills and waste rock dumps. Thirteen input parameters are dimensionally compressed using principal component analysis. Using a global database with more than 100 case histories, an artificial neural network is developed to conduct the rock mass characterisation. The advantage of this approach is less subjectivity as commonly used engineering (quantitative) terms are put to use. A further advantage is that given that the method is site-data dependent, it allows for ‘fine tuning’ of the model for a specific site.

Jan 1, 2015

By Scott K. Palm, Neil D. Pearson, Jr. Read

"Uncertainty is an important feature of many investments, but it is especially important for mineral properties. Mine properties often entail large investments and fixed commitments. Managers in the mining industry often view price uncertainty as undesirable, due to the possibility that the price of the mined commodity will fall to a level that prevents the firm from recovering its investment and fixed costs. This paper identifies pitfalls in conventional valuation methods and outlines a new approach to valuation based on option pricing theory and dynamic programming. In the process, it identifies generic strategies for organizing mine production in ways that allow the owner to benefit from the uncertainty in mineral prices. IntroductionRisk is pervasive in the mining industry. The operation and maintenance of a mine may involve high, and unavoidable, fixed costs. A mine owner can only begin to recover these fixed costs if the price of the mined commodity is greater than the incremental cost of production. But the prices of many minerals are extremely volatile. The price volatility of copper has been significantly higher than the price volatility of a typical stock, for example. A mine owner cannot be sure that the price of the mineral product will remain high long enough for the firm to recover its capital and fixed costs.Mine owners are able to minimize their losses during periods when the output price is below the incremental cost of production by temporarily closing operations. During these periods they incur only fixed costs. While shut-downs help minimize losses, the y do not help the firm recover its initial investment. If output prices remain low long enough, the fixed costs and original investment may never be recovered. High fixed costs, therefore, lead to substantial downside risk."

Jan 1, 1986

By Serena Biella

Gold has received a growing interest as a catalyst for the selective oxidation of organic molecules using oxygen under mild conditions1. In the liquid phase application small gold particles (2.5-7 nm) deposited over different solid supports can be used but, like many other noble metals, their catalytic activity depends upon the nature of the support and the preparation metod2-5. In particular, gold on carbon is the preferred catalyst for the oxidation of the alcoholic 2-7 and the aldehydic7-9 groups and one of the best preparation method is the immobilisation of colloidal particles2-5,8,9. Suggested application of gold catalysis in fine chemicals production, tested on laboratory scale preparations, is reported in table 110. In order to produce more efficient catalysts for the liquid phase oxidation and to derive new insights into the reaction mechanism, we have made a comparison among catalytic systems based on different metals. The first effort was to test the activity, if present, of naked metal particles and then to study the influence of various materials commonly used as a support.

Oct 1, 2003

By M. Tanaka, H. Narita, T. Fuchikami, K. Morisaku, K. Nagao, T. Yoshida, K. Kuroda

The effect of various N-substituents on the performance of amide-containing tertiary amine compounds in the extraction of Rh(III) from HCl solutions was investigated to optimize the structure of these compounds for industrial use. It was found that N-2-ethylhexyl-bis(N-di-2-ethylhexyl-ethylamide)amine and tris(N-di-2-ethylhexyl-ethylamide)amine, which have long, branched alkyl chains, were suitable for Rh extraction, because they were soluble in a practical diluent (80 vol% n-dodecane?20 vol% 2-ethylhexanol) and stable against highly concentrated HCl/Rh solutions, and showed high selectivity for Rh(III) over Pd(II) and Pt(IV).

Jan 1, 2014

By N. Depountis, Th. Rondoyanni, N. Sabtakakis, K. Kavoura, G. Tsiambaos

"Some typical landslide phenomena in Western Greece, in terms of the geological composition and structure of the affected materials, induced by heavy rainfalls are thoroughly studied and analyzed. The studied cases involved composite landslides on Flysch and Neogene weak rock materials that constitute the most critical landslide prone geological formations in Greece. The studied cases named Platanos, Platanitis and Karya include representative landslide sites as regards to the geological composition and structure of the displaced formations. Thus: (a) flysch formation includes different lithological units as shales, marls, siltstones, sandstones and conglomerates and is closely related to the Alpine orogenesis, suffering intense past tectonic movements and (b) the Plio-Pleistocene sediments include clayey marls, marlstones and siltstones. The investigated landslides , affecting mainly transportation routes, are closely related to heavy rainfalls induced by extreme meteorological events and are controlled by active fault tectonics. Long term movement monitoring using borehole inclinometers and surface benchmarks showed that landslides control was effective only when the proper stabilization measures were taken.INTRODUCTIONLandslides represent a major threat to human life, property, infrastructure and natural environment in most regions of the world. They are recognized by the scientific and politic authorities as having a major socio-economic impact and they represent a significant hazard for the population and the properties in particular locations. Landslide hazard expressed as the probability of occurrence within a reference time period and is a function of the spatial and temporal probability (Varnes, 1984; Guzzetti et al. 1999; Lee and Jones, 2004). The spatial probability of landslide initiation (susceptibility) is mainly related to static causal factors (slope inclination, material properties, etc.), while temporal probability is mainly related to dynamic causal factors such as rain input, increased groundwater levels and drainage, earthquakes, etc. (Van Westen et al. 2005)."

Jan 1, 2015

By Bish Chanda

In the minerals business, like any other commodity-based business, management faces the daily challenge of holding down costs while the real prices of products are continually falling on an inflation-adjusted basis. Since the marketplace sets the prices, often without any premium attached for product quality, being one of the lowest-cost producers is the most viable competitive strategy. Continuous improvement is the mantra that can make the difference in terms of long-term survival of a mining company. Yet, this message has not always been followed, especially during periods of prosperity ushered by high commodity prices. More often than not, the need for improvement is only triggered by a crisis. This may be caused by events such as the onset of a severe economic recession, a prolonged oversupply situation due to an optimistic expansion of capacity during the period of prosperity, or simply falling profits alerting management to bring costs under control. At that time, there would be a need to implement a new cost-saving program, bring in a consultant to find ways to reduce costs, or re-activate an old program that had been shelved for some time.

May 1, 2003

By Kevin S. Borthwick

The subject of this paper is a facility wide Distributed Control System (DCS) upgrade being completed at a large copper and molybdenum mine. This paper will discuss the innovative hardware and software technologies employed in the new control system. This paper will also describe the planning process, migration path and simulation techniques used to ensure the success of such a large and complex DCS upgrade.

May 1, 2008

By D. B. Dreisinger, A. A. Gunaratnam

A pressure oxidation (POX)-hot cure (HC)-lime boil (LB) process is used in industry to recover silver from refractory gold sulfide ores containing minerals such as pyrite and arsenopyrite. Pressure oxidation is used to oxidize minerals and liberate occluded gold particles. As such, iron goes into solution and under acidic and high temperature conditions often precipitates as basic iron sulfate (BFS). BFS consumes excess lime during neutralization prior to cyanidation. Therefore, a hot cure stage is required to re-dissolve BFS back into solution. BFS re-dissolution consumes acid and produces ferric sulfate. In the presence of silver, these conditions favor the slow formation of silver jarosite. Silver jarosite is refractory to cyanidation, and must be broken down prior to cyanidation. This is done in the lime boil to produce a cyanide-soluble silver hydroxide. A study was conducted to investigate parameters that affect the precipitates that form in each stage of the POX-HC-LB process.

Jan 1, 2017

The steam-filtration process for dewatering solids involves the application of slightly superheated steam to a filter cake during filtration. The mechanism by which the technique promotes water removal has been deduced from bench-scale experiments on coal and on granular iron ore concentrates. The mechanism, along with some of the applications and limitations of the process, is presented. Introduction I N the steam-filtration process, slightly super-heated steam is applied to the filter cake during filtration to remove more water than can be extracted by conventional filtration. Although this process was developed by Burton for coal filtration (1), it should have far wider applicability; certainly, it could be used to treat any mineral product, because only low-temperature steam is needed and most conventional filtration equipment can be easily adapted to it. As few restrictions apply to this process, however, it is important that its more obvious advantages and disadvantages be appreciated and, especially, that the criteria on which economic evaluations can be based are understood.

Jan 1, 1965

By P. Espinoza, I. Yutronic, J. Olivares

"Compañía Minera Doña Inés de Collahuasi's (CMDIC) Concentrator Plant is located at 4300 meters above sea level, approximately 2000 kms north from Santiago, Chile. The concentrator has three grinding lines. Each one, Lines 1 and 2, have one SAG mill at the primary grinding stage followed by a secondary grinding and classification stage consisting of one ball mill, two hydrocyclone batteries and a sump with two pumps. Line 3 has one SAG mill (Gearless Mill Drive), followed by a secondary grinding and classification consisting two ball mills, four hydrocyclone batteries and a sump with four pumps. Average throughput for these three lines is 150 Ktons per day. Peak values of 180 ktons per day have been achieved.Since late 2008 and throughout 2009 and 2010, Operations and Automation areas developed an optimization program for the grinding process, considering the implementation of Model Predictive Controllers (MPC) for the three SAG mills, and later, extending MPC to the secondary grinding and classification stages. The implementation of a MPC solution was based on stability considerations (high variability of the SAG process, high interaction between sump level control and classification efficiency, etc), requirements for an automated and consistent operation, the need to maximize throughput under timevarying scenarios and, in the long term, optimization of grinding process considering Specific Energy Consumption, among other parameters. MPC solutions had proven control robustness and strong optimizing capabilities in terms of helping in discovering new operational points and so achieving all of the aforementioned goals.On the first stage of the program, MPC implementation considered identification of dynamical process control models based mainly on historical data, in order to know the impact of a group of Manipulated Variables over Controlled Variables. Also, the impact of measured Disturbance Variables was modeled in order to take into account the high impact and interaction of these variables over the processes. At the end of this stage, 4 controllers were successfully operating for the 3 SAG mills and the secondary grinding and classification process. In response to challenges made by the working group, the second stage of the development of control applications in the grinding process required to achieve a design and implementation of a solution capable of governing the milling process, in addition to stabilization and optimization of both processes (SAG milling and secondary grinding), to integrate from a point of view of process control and automation. Therefore, in the second stage, MPC performance was continuously monitored and optimized through advanced tuning, inclusion of more process models (with proper step tests), redefinition of specific optimization criteria and adjustment to new process needs.Finally, successful MPC implementation at Collahuasi has proved that fast development and deployment of process control solutions is possible and allows immediate process stability, higher throughput, specific energy consumption reduction, and successful product size control, among many others."

Jan 1, 2012