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By John B. Goddard

Crystallization of ammonium paratungstate (APT) is frequently the last effective purification step in producing high-purity tungsten. However, crystallizer mother liquors are often several times higher in tungsten than predicted by the solubility of APT. The formation of heteropoly anions, particularly those containing phosphorus and silicon, is largely responsible. Solubility of tungsten in APT mother liquor can be linearly correlated with the concentration of these and other impurities. The problem can be overcome by direct treatment of the crystallizer feed solution with alum. By appropriate treatment, the aluminum hydroxide flocculates and is easily filtered, resulting in a purified low-aluminum crystallizer feed from which high APT yields can be attained.

Jan 1, 1984

By H. O. McDonald

The Bureau of Mines reviewed the chemical vapor deposition (CVD) literature of the group IVB, VB, and VIR elements. This review was utilized in the Bureau's research to provide erosion-, abrasion-, and corrosion-resistant coatings for valve components used in coal gasification units. This report attempts to bring together the many CVD references that have been published since 1966. Each of the group IVB, VB, and VLB metal coatings were reviewed, and some of their preparation methods, uses, and properties are given. A total of 160 references were found for the nine elements. Isotope separation, stronger steels, solar absorbers, alloys, superconductors, optical fibers, and coatings to increase the life of materials are some of the new uses for CVD.

Jan 1, 1979

By C. L. Molina

The U.S. Geological Survey (USGS), in cooperation with the Bureau of Land Management (BLM), Geological Survey of Wyoming, and U.S. Bureau of Mines (USBM), will produce an estimate of the amount of available coal in an area about 55 Ian (35 miles) south of Gillette, Wyo., where the Wyodak coal bed is 8-27 m (25-90 ft) thick. Available coal is coal that actually is accessible for development under current regulatory, land-use, and technologic conditions. Local coal-development considerations include roads, ranches, railroads, pipelines, power lines, wildlife and archaeological sites, alluvial valley floors, cemeteries, and the Hilight oil and gas field and gas plant. Some of these considerations would be mitigated so that surface mining may proceed; others presently preclude mining in their vicinity.

Jan 1, 1995

By H. Sevim

Three transportation systems in surface coal mines: 1-Truck Haulage, 2-Belt Conveying, and 3-Coarse-Coal Slurry Transportation are compared from the operations and cost point of Views. Computerized design and cost models were developed and cost data banks were compiled for each system. These models can be used to evaluate transportation systems and layouts that are practiced in most of the U.S. surface coal mines. A typical midwestern area strip mine was considered for illustration purposes. Sensitivity analysis on critical parameters such as production rate, transportation, distance, etc. was conducted and the outcomes are presented.

Jan 1, 1990

By Srisharan Shreedharan, Gang Huang, Hongqing Song, Sijing Cai, Pinnaduwa H. S. W. Kulatilake

"Subsidence prediction due to ore extraction and backfilling during open stoping operations for an underground iron mine in China is reported in this paper. Geologic complexities including faults and interfaces between different lithologies, and the stoping and backfilling sequence adopted from the mine plans are incorporated in building a 3-D discontinuum numerical model. The stoping was simulated in two vertically stacked horizontal layers (Fig. 6), with a total of 16 stopes. Large displacements of up to 50 cm were predicted by the model along the roof of the stopes, and a maximum surface subsidence of 22.5 cm was predicted by the model . Backfilling was found to control subsequent deformation and subsidence. The extraction of the upper orebody led to relatively higher deformations in extracting the lower orebody. Finally, the predicted subsidences at all locations along a subsidence profile on the surface are shown. INTRODUCTIONThe Luohe iron (pyrite) mine, located in Hefei city, Anhui, is an underground mine in China, being mined through the open stoping and backfilling method. The orebody lies at a depth of about 400 m and has an average thickness of 250 m (Magang Steel Company, 2012a). Discovered in the 1960s, the location has a reserve estimate of 300 million tonnes, which have been mined since 2007. The orebody has been divided by the mining company into an east and a west section to facilitate planning for ore extraction.Figure 1 shows the surface above the underground mine, which is seen to contain many human settlements including villages, pastures and other infrastructure. These locations are sensitive in that they need to be protected from potential adversities due to the underground mining, such as surface subsidence. While it may be near impossible to completely eliminate the subsidence due to ore extraction, operations such as backfilling have been adopted by the mine in an effort to substantially reduce it. Hence, this paper focuses on describing the stability of stopes in the mine and estimates future subsidence in a part of the mining region through numerical modeling."

Jan 1, 2016

By G J JAMESON

The flotation cell has undergone a number of changes since the process was first introduced in Broken Hill in the early years of this century. The development of the mechanical flotation cell is reviewed, followed by a discussion of more recent developments such as the flotation column, the air-sparged hydrocyclone, the Wemco-Leeds cell, the Bahr and Deister columns and the Jameson cell.

Jan 1, 1992

By Pingchao Ke, Zhihong Liu

"To overcome the problem that scoroditeis not stable in neutral and alkaline solutions, we proposed and investigated a synthesis method of scorodite coated in-situ with hydrated ferric oxide in the Fe(II)-As(V)-H2O system at the initial Fe(III)/As(V) molar ratios larger than 1.0.The synthesis was carried out at 90?,pH 1.5 under atmospheric pressure. During the synthesis, oxygen gas was conducted and bubbled into the system to oxidize Fe(II) ions into Fe(III)ions, and Na2CO3aqueous solution as neutralizing agent was added controllably into the system for keeping the pH constant at 1.5. In this study, three samples of scorodite were synthesized at the controlled initial Fe(II)/As(V) molar ratios of 1.0, 2.0 and 3.0, respectively. The characterizations of the samples by HRTEM, TEM/EDX, and chemical composition indicated that the particle surfaces of scorodite synthesized at the initial Fe(II)/As(V) molar ratio of 2.0 and 3.0 were coated in situ by a film of hydrated ferric oxide with the thickness of several nanometers, while the sample synthesized at the initial Fe(II)/As(V) molar ratio of 1.0 was uncoated scorodite. The TCLP and long-term leaching for the toxicity characteristic of the samples showed that scorodite coated in situ with hydrated ferric oxide was stable in a wide pH range from 3.0 to 10.0, with the arsenic concentrations in the leaching solutions less than 1.0mg/L. Nevertheless, uncoated scorodite was unstable under the conditions from weak acidity to alkalinity, with the arsenic concentrations in the leaching solutions larger than 5.0 mg/L.INTRODUCTIONArsenic pollution is a challenge for environment and health and has been an important issue for scientists (Hopkin, 1989).Arsenicis commonly associated with ores or concentrates of nonferrous metals, mainly as independent arsenic bearing minerals such as arsenopyrite (FeAsS), tennantite(Cu12As4S13), enargite (Cu3AsS4), cobaltite (CoAsS), and gersdorffite (NiAsS), realgar (As2S2), orpiment(As2S3), etc.(Matschullat, 2000; Mandal & Suzuki, 2002; Long & Peng, 2012). In the nonferrous metallurgical processes, arsenic is enriched mainly in such arsenic bearing materials as various flue dusts, residues, and anode slimes, which results in the accumulation of arsenic in the system owing to the circulation of those arsenic-bearing materials back to the system and the pollution to the environment (Harris, et al, 2003).In addition, the utilization of arsenic is limited and has been decreasing owing to its toxicity and carcinogenicity. Therefore, arsenic has to be removed from those arsenic-bearing materials and discarded safely (Dutrizac & Jambor, 1988; Monhemius & Swash, 1999; Drahota & Fillippi, 2009).In this case, how to immobilize arsenic has become a difficult problem which must be solved. Among the methods of immobilizing arsenic which have been proposed and investigated, immobilizing arsenic into a stable mineral to fix it, has been realized as a promising method and becomes a research focus(Dutrizac et al, 1987; Dutrizac & Jambor, 1988; Demopoulos et al, 1995; Fujita et al, 2008a; 2008b).Scorodite has been known as one of the best minerals for immobilizing arsenic, owing to its high stability under weak acidic condition, the arsenic content as high as 32wt%,and good crystallinity benefiting the separation of solid to liquid(Daivid et al, 1999; Zhu & Merkel, 2001). Scorodite can be synthesized from arsenic containing solutions under both hydrothermal and atmospheric conditions, and a lot of work has been done on the synthesis of scorodite and its leaching stability characterization (Filippou & Demopoulos, 1999; Gomez et al, 2011).Two plants for the immobilization of arsenic as scorodite have been putin to operation in Chile and Japan, respectively (Filippou & Demopoulos, 1999; Amir et al, 2016)."

Jan 1, 2017

By M. A. Girts

Wetlands can be constructed inexpensively on mined lands to treat small flows of acid mine water. Metals are removed from the water by the wetland vegetation and indigenous bacteria. Full-scale field tests initiated at over 20 mine sites during 1984 and 1985 indicate that water quality can be upgraded to meet discharge standards with relatively minor maintenance requirements. Iron concentrations of 25-85 mg/L in the influent water fall to less than 2 mg/L during flow through a small wetland. Manganese can also be removed, though somewhat less efficiently. At the discharge, pH is easily raised to 6 by flow over limestone.

Jan 1, 1986

By C. M. Lesher, R. R. Keays

"The komatnte-associated Fe-Ni-Cu sulphide mineralization at Kanihalda, Western Australia, is generally believed to be magmatic in origin, but a number of postmagmatic processes significantly modified the original distribution, structure, texture, mineralogy and chemistry of the ores. Two important types of mobilized magmatic sulphides are interpillow/interbreccia sulphides and hydrothermal vein-type sulphides. Interpillow and interbreccia sulphides occur interstitial to pillowed or volcaniclastic footwall metabasalts beneath or adjacent to the stratiform contact ore horizons. They are mineralogically and compositionally similar to massive ores (and are similarly depleted in PGE relative to the compositions of bulk samples of mined ores), but normally do not contain the distinctive chalco-phile ferrochromites characteristic of contact ores. They are interpreted as magmatic sulphides that have been mobilized from the overlying or adjacent massive sulphide layer during peak tectono-nietamorphism.Hydrothermal sulphide-quartz + albite veins also occur in the footwall metabasalt and contain unannealed deformation fabrics indicative of emplacement during retrograde metamorphism. The high Ni and Pd contents of these sulphides (7-13% Ni, up to 70 ppm Pd) indicate that the metals have been derived from the spatially associated komatiites and/or contact ores, consistent with the Pd depletion previously inferred for massive ores. Very low Ir contents and high Pd/Ir ratios of the vein-type sulphides confirm an aqueous transportation-deposition mechanism; hydrothermal transfer of PGE results in strong decoupling of Pd from Ir.There appears to be a complete continuum of sulphide mobilization at Kambalda ranging from whole-scale phy sical dislocation (fault offset ores) and selective mobilization (stringer sulphides) through nietamorphie replacement (interpillow/interbrec- cia sulphides) to jiydrothermal dissolution and redeposition (vein-type sulphides)."

Jan 1, 1984

By H. O. Hofman

The mining and metallurgical laboratory, as we understand the term in this country, is a place .in which mechanical and chemical working-tests are made on ores, fuels and furnacematerials. It is of quite recent origin. The first laboratory of this kind to be used in connection with teaching was put into operation in 1871 at the Massachusetts Institute of Techilo1ogy. † The idea had already existed in the mind of President W. B. Rogers when he wrote, in 1864, his pamphlet 'on " The Scope and Plan of the School of Industrial Science of the Massachusetts Institute of Technology;" but several years elapsed, and an extended visit to the mines and mills of Colorado, Utah, Nevada and California was required before this idea could take a form adapted to the purposes of original research as well as of instruction. The laboratory was given from the first into the charge of Prof. R. H. Richards, who, by improving its methods and enlarging its scope, has brought it to the position which it occupies to-day as the leading representative of its class. Private laboratories for making tests upon ores had previously existed here and there, especially on the Pacific coast, for silver and gold ores; but in the educational field the

Jan 1, 1896

By C. J. K. Purdy, H. E. Jamieson

"The comprehensive assessment of the environmental impacts of mining rare earth element (REE) deposits depends on a sound knowledge of the mobility of REEs in low-temperature aqueous environments. Temperature, pH and water chemistry are important factors controlling the aqueous mobility of REEs, while REEs are known to readily form complexes with both inorganic and organic ligands, and it has been shown that sorption and colloid formation may play an important part in dictating REE transport in the low temperature weathering environment. Ore and host rock mineralogy is also a key factor controlling the extent to which REEs are leached from mine waste. INTRODUCTIONThe aqueous mobility of rare earth elements (REEs) has commonly been explored in the past due to their potential application as tracers of geochemical processes in aqueous systems. REE mobility in low-temperature solutions has been shown to be dependent on the pH, temperature, ionic strength, and solution chemistry. For example, the aqueous transport of REEs can be modified by complexation with organic and inorganic ligands (Johannesson & Zhou, 1999; Klungness & Byrne, 2000; Luo & Byrne, 2004; Schijf & Byrne, 2004; Tang & Johannesson, 2010; Wood, 1990, 1993), or through sorption to suspended particles and colloids (Bau, 1999; Quinn, Byrne, & Schijf, 2004, 2006a, 2006b, 2007; Sholkovitz, 1995). Here we review the coordination chemistry, sorption behaviour and potential colloid association of REEs with respect to low temperature aquatic settings.RARE EARTH ELEMENT CHEMISTRYREEs include lanthanum to lutetium of Group IIIA in the periodic table. All share very similar chemical and physical properties. Often included in REE studies is another Group IIIA element, yttrium owing to its similar properties, and occasionally scandium, although its considerably smaller ionic radius makes for different properties and will not be discussed further here. The REEs are often subdivided into the light REEs (LREE), La to Sm, and the heavy REEs (HREE), Eu to Lu, which also usually include Y (hence are often referred to as YREE). The REE may be subdivided further into the LREEs, middle REEs (MREEs), and HREEs, in which case each classification includes La-Nd, Pm to Ho, and Er to Lu as well as Y, respectively, although definitions vary throughout the literature."

Jan 1, 2012

By Qing-Yun Huang, Xiao-Yi Zeng, Bing Xie, Hong-Yi Li, Jia-Rong Yan

"In order to utilize vanadium resource in vanadium-titanium magnetite ore efficiently, vanadium distribution ratio between hot metal and slag should be improved during BF process, meanwhile the precipitating of Ti(C,N) in slag must be minimized. Effects of temperature, Ti02 content in the slag and basicity on vanadium distribution between slag and hot metal were investigated by experiment and thermodynamic calculation. The results indicated that high temperature, low Ti02 content and high binary basicity of slag were beneficial to increase the vanadium distribution ratio. The effects of temperature and Ti02 content in slag on vanadium distribution were stronger than that of slag basicity.IntroductionVanadium is an important element that is widely used in industrial fields. Most of vanadium resource is hosted in vanadium bearing titanomagnetite [l]. Vanadium bearing titanomagnetite is thus one of the domainate raw materials to produce the vanadium products. In other words, the comprehensive utilization of vanadium bearing titanomagnetite is beneficial for vanadium resource utilization. Vanadium bearing titanomagnetite sources are abundant in Pan Xi of China [4]."

Jan 1, 2013

Using Dynamic Simulation Throughout a Process Plant's Life Cycle

Sep 13, 2010

By Aiming Z, Shenyi S, Xialei W

Zhangmatun Iron Mine is situated in the suburbs of Jinan city. Shandong, China. Because of surface environmental constraints, no suitable site can he selected to dispose of mill waste. The full mill tailings must be disposed of underground. This paper deals with the work conducted at Zhangmatun mine to develop a total tailings backfill system, taking advantage of a double- shaft blade mixer and an activating agitator to prepare backfill. Cement and ground slag are added to tailings for strength development. Two scopes have been filled and the pillars have been effectively mined out during the field trial. The application of innovative total tailings backfill technology is a new concept at the mine. Detailed planning has achieved a close integration of mining, milling and backfilling. Full mill tailings, with or without rock, are disposed of underground in a continuous process to fill, totally and systematically, the cavities formed by mining.

Jan 1, 1998

By D. C. Crowell

This publication presents the results of a laboratory investigation of displacement of gas by injection or imbibition of water into sandstone models under essentially isobaric conditions. A brief discussion of scaling requirements is included. The influence on residual gas saturation of independently varying the parameters of dimensional ratios of the porous media, rates and methods of flooding, surface tension, initial water saturation, and permeability is shown. Of these variables, increased initial water saturation and decreased surface tension reduced residual gas saturation significantly, whereas variations in flooding rate and dimensional ratios had no apparent effect. No correlation was evident between absolute permeability and residual gas saturation.

Jan 1, 1966

By Jr. Koch

As a means of investigating the distribution and variability of gold in ore from the Homestake mine, Lead, S. Dak., the Bureau of Mines performed a designed sampling experiment, and assay results were statistically interpreted. Fifty-six feet of diamond-drill core from five boreholes was sawed into l-inch-long cylinders, which were sampled randomly and were assayed. Analyses of variance of the assay results were used to compare and assess the different types of variation: within drill holes, among paired drill holes, among unpaired drill holes, and among furnace runs. The extreme variability in gold mineralization found is the natural variability on the smallest scale that can be detected by fire assay; most of the variability is associated with among-feet rather than within-feet sample intervals. Because of the extreme variability, one-half of the gold is in 3 percent of the samples.

Jan 1, 1967

By M. B. Sizgoric

Quantitative mineralogy is used in a study done on an Inco Metals Company nickel sulfide occurrence from 'the Thompson area in Northern Manitoba. The study included: a) determination of the variations in chemical composition of the ore minerals; b) determination of the liberation of the ore minerals for the various types of ore and for different feed grinds; c) assessment of the preliminary mill test results by comparing the mineral distribution in the different tailings. Preliminary mill test results had outlined three main problem areas: 1) unacceptabiy low grade concentrate with, 2) very high weight recovery and, 3) low pyrrhotite rejection resulting in a high sulfur concentrate. The mineralogical study readily explained these results by showing that: 1) between 20 and 40% of the nickel in the feeds and 55 and 75% of the nickel lost in the tailings is associated with pyrrhotite. This accounts in part for the low grade of the concentrates obtained at high recoveries: 2) hexagonal nonmagnetic pyrrhotite constitutes over 90 percent of pyrrhotite. Since hexagonal pyrrhotite floats more readily than monoclinic pyrrhotite, this could be part of the reason for the undesirable high pyrrhotite recoveries into the concentrates. Further test work to establish both the optimal grind and the best conditions for pyrrhotite rejection is therefore mandatory.

Jan 1, 1981

By Mayer G. Hansen

A series of papers dealing with diamond drilling practices, compiled in accordance with an outline prepared by engineers of the United States Bureau of Mines, is to be published as information circulars by the bureau. This paper, the first of the series, describes the general practice at the United Verde mine during the last ten years; specific instances cited in the paper refer to 1930, the last year of full operation. The United Verde copper mine is located at the town of Jerome, Yavapai County, north central Arizona.

Jan 1, 1933

By J. M. Stuve

In this Bureau of Mines investigation, the low-temperature heat capacities of polycrystalline phases corresponding to the sulfide compounds CoSO?89' CoS1?33, and CoS2 were measured by adiabatic calorimetry within the nominal temperature range 5 to 300 K. The derived absolute entropies S298 were 10.36±O.02, 12.96±O.03, and 16.31±O.03 cal?mol-1?K-l, respectively, assuming third-law behavior. In addition, the standard enthalpy of formation 8Hf298 of CoSO?89 was determined by bromine solution calorimetry. The derived value of 8Hf298 was -50.63±2.1 kcal?mol-1, based on the 8Hf298 of Co0. This result is considerably more negative than previously published formation values based on high-temperature gas equilibrium studies.

Jan 1, 1985

Over a century ago the first ship designed solely for carrying a bulk cargo was launched. This vessel, the "John Bowes", with a deadweight of 660 tonnes was a single decked ship with machinery and accommodation aft. As such she was undoubtedly the fore- runner of the bulk carrier of today only some two hundred and fifty times smaller. Whilst the "John Bowes" pioneered the present accepted mode of transporting the bulk com- modities of the world, it is unlikely that her cargo was either loaded or discharged as quickly as that of a 150, 000 tonner of today. Two decades ago the bulk carrier was beginning to feature in the bulk handling ports of the world. Cargoes of iron ore previously carried in the 'tween deck vessels of the Empire type and Second World War Liberty ships began to be poured into the unrestricted open holds of bulk or ore carriers. The size of vessels catering for this relatively new innovation has rapidly grown to pass the 150, 000 deadweight tonne mark, but only in the last few years. The growth from now into the future is not simply one of ship size evolution. Neither is it a function of the depth of water available at ports. It is in fact a function of a number of features such as ports, loading and unloading facilities, ship trading characteristics, length of voyage and total economies of the transport task from supplier to destination.

Jan 1, 1973