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By B. K. Mishra, P. Patnaik, B. C. Tripathy, I. N. Bhattacharya

Cobalt is an essential metal considering its numerous industrial applications. The demand for the metal is increasing due to its wide range of use in, for example, rechargeable batteries and as an alloying element in super alloys. Cost effective production of Co is critical. Electrowinning from aqueous sulphate solutions is the preferred technology available for the production of Co. Attempts are being made to produce uniform, smooth and bright deposits of cobalt metal. Use of organic additives in the electrolytic bath improves current efficiency and deposit morphology of the metal. We investigated the effect of quaternary amines TEABr, TPABr and TBABr during cobalt electrowinning from aqueous sulphate solutions. Among the additives studied, TEABr yielded the best results. Smooth and bright deposits of cobalt were obtained at low concentration of TEABr (10 mg/L) maintaining a very high current efficiency of 99.6%. X-ray crystallography indicated that (100) is the most preferred plane of crystal growth.

Jan 1, 2014

By Rodney Trevor Jones, Arthur Robert Barnes

Anglovaal Minerals acquired the Nkana slag dump from Zambia Consolidated Copper mines (ZCCM) in 1998 and embarked on an ambitious project to pioneer the recovery of cobalt from slag using DC smelting technology. Anglovaal Research Laboratories performed initial pioneering smelting tests in a 250 kW DC furnace over a 3-year period before engaging Mintek for three piloting campaigns at the 1.5 MW level. Mintek had previously developed a reductive smelting process, patented in 1995, using a DC arc furnace for the recovery of cobalt from slags. The results of the pilot-plant test campaigns were used as the basis for engineering the commercial 40 MW operation installed at Chambishi Metals plc in Zambia in 2001. This paper traces the development of understanding of the metallurgical fundamentals ultimately used to predict furnace performance, reviews some of the extreme technical challenges faced, how solutions were identified and highlights some of the critical issues identified during piloting and how these impacted both positively and negatively on the final commercial operation.

Jan 1, 2011

By C. Pawlik, R. T. Jones

Cobalt occurs together with copper in the southern African copper belt, and a large portion of this cobalt ends up in copper smelting slags, mostly dissolved in oxide form. It is possible to achieve high recoveries of cobalt by reductive smelting of the copper slags, using some form of carbon as a reducing agent in an electric furnace. For example, a 40 MW DC arc furnace was operated at Chambishi Metals in Zambia from 2001 to 2008, and demonstrated cobalt recoveries of around 80% from slag to an iron-rich alloy containing copper and cobalt. The alloy was atomized prior to leaching. With the recent increase in demand for cobalt (and the resulting high metal prices), there has been increasing interest in this process route. There is also an alternative hydrometallurgical process for recovering the valuable metals from the slag. The choice between these process options requires a trade-off between capital and operating cost and environmental acceptability. This paper examines the potential for cobalt recovery from slags, and outlines various process options. INTRODUCTION Cobalt has had a number of important uses in society since antiquity, and its principal use has changed dramatically over time. Since at least 2250 BC, cobalt-based pigments (cobalt blue) have been widely used to colour manufactured goods such as glass and pottery. Later, cobalt became known for its magnetic and wear-resistant properties and high-strength alloys, and most of the cobalt produced was consumed in the production of cobalt-based superalloys. The greatest recent growth in cobalt demand is due to it being essential to the rechargeable lithium-ion batteries used in consumer electronic devices and increasingly to drive electric vehicles. Cobalt is usually produced as a by-product of copper or nickel. The copper belt in the Democratic Republic of the Congo (DRC) and Zambia supplies most of the world's cobalt production. In 2018, the DRC was expected to produce 90 000 tons of the world total of 140 000 tons of cobalt (Shedd, 2019). This paper focuses on the southern African copper industry, and specifically the cobalt that is able to be produced as a co-product from this. A BRIEF HISTORY OF SOUTHERN AFRICAN COPPER SMELTING Copper deposits in South Africa have been documented since at least 1685, when the Cape governor, Simon van der Stel, ‘discovered’ the 'Copper Mountain' at Springbok. South Africa's first public commercial mining company (imaginatively called the 'South African Mining Company') was established in Cape Town in 1846, to exploit the rich copper resources that were believed to exist in Namaqualand.

Jan 1, 2019

By J. Lu, D. B. Dreisinger, G. Houlachi

"Zinc metal is primarily produced by electrowinning from sulfate solution. Zinc electrowinning is very sensitive to impurities such as Co and Ni. These impurities have to be removed to produce high-quality zinc and maintain a high zinc current efficiency. Zinc dusts are used to remove these impurities by cementation. However cobalt cementation is extremely slow and it is typically activated by the addition of Cu and Sb. Even with the use of Cu-Sb activation, cobalt is still difficult to remove. The zinc dust used for cobalt cementation is negligible compared to that consumed for hydrogen evolution. In some plants up to 6-7% of electrolytic zinc is used for cementation. This is a great waste of energy. Cu-Sb activation is not well understood. The objective of this study was to further understand the Cu-Sb activation and then find a way to reduce hydrogen evolution and promote cobalt cementation. The investigation reveals how hydrogen evolution (or zinc dissolution) and cobalt cementation and re-dissolution change with temperature, zinc dust dosage, the concentrations of copper and antimony and time. In the Cu-Sb activation, copper is deposited on a zinc particle to produce a porous shell. The zinc particle as an anode dissolves while the shell as a cathode provides a place where cobalt cementation and hydrogen evolution occur and they are catalyzed by antimony. A certain level of antimony (around 0.1 mg/L) is a key to maintain the catalytic effect of the shell. At a higher antimony concentration, cobalt cementation is accelerated slightly while hydrogen evolution is increased greatly. When a zinc particle dissolves to a certain degree, cobalt loses its cathodic protection and starts to re-dissolve. The change in cobalt concentration is determined by the rates of cobalt cementation and re-dissolution. The operation conditions can be optimized to maximize the cobalt removal and minimize the zinc dust dosage.INTRODUCTIONMost of the world’s zinc metal is produced by electrowinning from sulfate media. Many impurities such as iron, copper, cobalt and nickel are co-extracted into solution with zinc. Iron, mercury, indium, lead and tin are removed by co-precipitation as hydroxides. Copper, nickel, cobalt, aluminum, arsenic and germanium are partially co-precipitated with iron while cadmium, magnesium and chloride remain in solution. Cobalt, copper, cadmium, nickel and etc. are subsequently removed by cementation with zinc dust to achieve an acceptable current efficiency and high purity metal product for the economical production of zinc. Zinc provides a strong thermodynamic driving force for the cobalt cementation:"

Jan 1, 2016

By Ian D. Pirie

Presentation outline ?Project location ?Geology ?Resources and reserves ?Results of the FEED study ?Social and environmental considerations ?Project path forward

May 1, 2010

By Chester J. Kuryliw

"The Geology of the Cochenour Willans mine, Red Lake district, was described by J. P. Nowlan in the Jubilee Volume. The complexity and intense alteration of the rocks obscured any clear relationship between ore and structure, and Nowlan recognized that future work might greatly modify the ideas then existing. This has proved to be the case. Subsequent detailed work has established the stratigraphic sequence in the Keewatin formations which are the host rocks of the orebodies, and has shown that the principal orebodies are confined to two adjoining bands of tuff.On this basis, it is now possible to map the complex structures with greatly increased accuracy. The amount of drilling and underground exploration required to find new ore has been much reduced, and indicated ore reserves are now substantially greater than at any time in the past. Daily production in 1955 averaged 187 tons per day at 0.578 ounces of gold per ton.The sequence of Precambrian events in the mine area is summarized in the following table:Intrusion of post-ore dykes.Ore formation.Intrusion of post-faulting, pre-ore dykes.Deformation: folding and shearing; alteration; faulting.Timiskaming sedimentation.Unconformity.Keewatin: volcanics and sediments, host rocks of the orebodies, described in detail in the next section.KeewatinFrom oldest to youngest, the Keewatin rocks in the mine area can be divided into six formations, which have been given local names:“Grey"" LavaA fine-grained dacitic to andesitic lava, amygdaloidal and locally containing well formed pillows. Certain areas are sheared and chloritized to a degree that makes identification difficult. The rocks are carbonatized throughout; the most persistent carbonate veins parallel the upper contact. Thickness more than 1,000 feet. (Minor mineralization, type 1 I -See section on Ore Formation)."

Jan 1, 1949

By J. P. Nowlan

"This paper is an attempt to outline the structural problems at the Cochenour Willans mine, in so far as their details have been tentatively worked out. It must be emphasized that there are considerable data that can be interpreted in more than one way, and that further work may modify or completely change some of the hypotheses presented herein. Certain features, however, are sufficiently constant to warrant reliance on them when searching for extensions of orebodies.As the individual ore shoots usually have relatively small dimensions, but are often very high grade, structural details are of more than usual significance in laying out a mining programme. An illustration of this is a small shoot recently located and mined as a result of studying a minor slip cutting off a part of high grade gold ore in No. 319 stope. The shoot, which is bounded on three sides by slips, and on the fourth by the original stoping, was roughly triangular in plan, 20 feet on the base, and 40 feet in length. The average width mined was 4.5 feet, but the gold obtained totalled over 1,800 oz.The property lies in Dome township, east of McKenzie island, and consists of an original group of thirteen claims acquired from the Cochenour Willans syndicate, plus one additional group of five claims obtained by purchase from the Kelson Red Lake Gold Mines, Limited, and one other claim that rounds out the southeast corner of the block.The claims of the original group were staked by W. M. Cochenour, Dan Willans, and Horace Young, during 1926 and 1927. The Cochenour Willans Syndicate was formed in 1928, and until incorporation of the present Company work was carried on at varying intervals by several different interests, including Ventures Limited, Hollinger Consolidated, who sank a shaft to open up the 150-foot level, and by the Syndicate itself. The first ore from the property was shipped to the Gold Eagle mill by the present Company in 1939, and amounted to 4,959 tons, from which 2,360 oz. gold was recovered. The first brick was poured in December, 1939, and production has been continuous since that date. To the end of June, 1946, gold having a value of $5,982,000 has been produced from 345,033 tons of ore treated."

Jan 1, 1954

By H. Nakano

The codeposition behavior of impurities such as Ag, Bi, Fe, Ni, Pb and Sb with Cu was investigated galvanostatically at 5-3000 A/m2 using a Pt cathode at 60 °C in acidic copper (I) chloride (cuprous chloride) solution at pH1-2 containing 1.0 mol/L of Cu+ and 4.9 mol/L of Cl-. The impurities were classified into two groups: Group I (Ag, Bi) which codeposits with Cu as a metal, and Group II (Fe, Ni, Pb, Sb) which is slightly involved in the deposited Cu in nonmetal form from the electrolyte. Silver and Bi in Group I behaved as more noble metals than Cu, and significantly codeposited with Cu, showing typical features of regular-type codeposition. When Cu was deposited dendritically, the Ag and Bi content in the deposit increased with increased duration of electrolysis as a result of decreased net current density caused by increased cathode area. The current efficiency for Cu deposition in impurity-free solution was 95-100% over 100-1000 A/m2, but it abruptly decreased at above 1000 A/m2 when the limiting current density of Cu was attained. Although Fe, Ni, Pb and Sb in Group II were involved to 0.01-0.02 mass% in the deposit, they had no influence on the current efficiency or morphology of Cu.

Jan 1, 2007

By Pravin Mathur

"Praxair's CoJet® technology was introduced in 1997 to effectively inject chemical energy in electric arc furnaces. Coherent jets were invented as a revolutionary means of injecting oxygen and other gases into the EAF and into converters. Today, steel makers have widely accepted this concept in over 70 EAFs worldwide. Indeed, the whole industry has shifted to this new standard for chemical energy input in EAFs. CoJet® technology has also been implemented successfully in BOF converters.This paper will review the principles of coherent jets as applied to steelmaking. The key learnings garnered from several furnaces are also reviewed. In addition, while the CoJet® program has been widely accepted worldwide, based on steady feedback received from customers and the market place, several programs are underway in development and commercialization. These enhancements and new applications of CoJet® technology are also overviewed in the paper."

Jan 1, 2004

By C. Desmeules

"Carbon addition in the oxide pelletizing process is a big concern at the Sidbec-Normines pelletizing plant since 1976.Laboratory pot-grate testing carried out before the initial start-up of the Port-Cartier plant indicated that the nominal pelletizing grate capacity could be increased by fifteen per cent with a suitable carbon addition. Also an improved induration cycle offered the possibility of a significant energy reduction within the process with no adverse effect on pellet quality. A one-month plant scale program duplicated the lab test results and confirmed the anticipated cost saving by using these techniques. Since March 1980, Sidbec-Normines used coke addition as a current operation.This paper reviews briefly earlier laboratory and in-plant test work carried out to investigate the effects of adding carbon materials to the Fire Lake hematite concentrate, and presents operation techniques and plant results of carbon addition in the Port -Cattier pellet plant.IntroductionThe Sidbec-Normines pelletizing plant at Port-Cartier, Quebec, is designed to produce six million ton s per year of oxide pellet s. It is a Dravo-built two-line plant; one line to produce three million s tons per year of blast furnace grade pellets averaging 5.5 per cent silica, and another line of three million ton s to produce direct reduction grade pellets of about 2.0 percent silica.The laboratory pot-grate test program was conducted in 1977 at the British Steel Corporation Research Laboratories in England, with the assistance of J .E. Appleby, consultant to British Steel Corporation (overseas services) Limited.The purpose of that test program was to determine the optimum energy saving cycle and to study the physical and metallurgical effects on blast furnace and direct reduction pellets."

Jan 1, 1983

By T. H. Wilson

In 1901, the Crow's Nest Pass Coal Company, Limited, began producing industrial coke in 212 beehive ovens at Michel colliery. By 1908, 486 ovens had been installed and in that year 147,623 tons of coke were produced. Coke manufacture has been continuous from 1901 until the present time (1946), with total production of 2,795,402 tons. At present writing, only 100 beehive ovens are operating and production is reduced to 1,800 tons per month, due to the shortage of suitable labour. These ovens are drawn by hand, on contract, and the workmen are exposed to considerable heat. A man draws three ovens in eight hours, thereby producing approximately 1072 tons of coke per day. In addition to the inefficient and costly method of drawing coke in beehive ovens, tremendous losses are experienced in the wastage of gas and tar, which are driven off into the atmosphere. Also, the yield of coke per ton of coal fed to the ovens is low as part 9f the carbon is utilized in producing heat to carbonize the remainder of the coal. A recovery of only 55 per cent of the carbon, as coke, is obtained. The coking process takes place from the top of the charge, which is 21/2 feet deep, downward to the floor. Six and a half tons of coal are charged and 3.6 tons of coke are drawn from the oven after 72 hours' carbonization. The beehive ovens using Michel coal produce a very hard and tough coke, large in size and of silvery appearance, which has served the requirements of both foundry and smelter for many years. In 1938, the Company made a careful study of coking processes with a view to introducing a more economical method than beehive ovens and one that would be less dependent on skilled labour, the supply of which was rapidly diminishing at that time. Various methods of by-product coking were investigated, and it was decided that the Curran-Knowles process offered the greatest possibilities because of the low capital investment in relation to output and also because the horizontal oven design was suitable for an expanding coal. Consequently, a test on Michel B seam coal, supervised by Mr. E. Burrough, of the Fuel Research Department, Ottawa, was run in the Curran-Knowles plant at West Frankfurt, III. The results of this test led to the construction of a ten-oven battery of 32 ft. 6 in. by 8 ft. 3 in. Curran-Knowles ovens at Michel, which were completed in November, 1939. This battery was built as an experimental unit, with provision for an additional ten ovens if the coke proved satisfactory for the market. In 1942, an expanding coke market led to the construction of a second battery of ten ovens, which were completed in April, 1943.

Jan 1, 1947

By K. Yoshida

Recently, light magnesium alloy with superior heat radiating ability has been attracting attention in various fields. However cold plastic working of the alloy is very difficult and hot working necessary. Furthermore, the magnesium of products with complicated shapes is difficult, the processing cost is high, and the applicability of the alloy is limited. In this study, a technique for obtaining fine wires and tubes by cold drawing is examined to obtain wires and tubes with high strength, quality and surface morphology, while decreasing production cost. In addition, the shearing strain of magnesium alloy wires and tubes drawn under various drawing conditions was calculated by FEM analysis. It was clarified that cold drawing of magnesium alloy is possible. It was also demonstrated that greater reduction of the cross-sectional area could be realized during cold wire and tube drawing by optimizing the drawing conditions.

Jan 1, 2006

By John Lund

INTRODUCTION GOLD-BEARING placers of Alaska and the Yukon Territories are buried under a layer of permanently frozen alluvial overburden, or 'muck', which varies in depth from twenty to one hundred feet. The placers, and the decomposed bedrock layers upon which they are deposited, are also permanently frozen. During the summer, surface muck which is exposed to the sun will thaw, but only to a depth of a few feet. To reach a valuable deposit, the frozen overburden must be either penetrated with shafts, or stripped from the deposit entirely. In either case, before the placer can be mined, it must be thawed. At modern dredging operations, the frozen muck is stripped from the placer by powerful jets of water from hydraulic giants. The placer, and several feet of decomposed bed-rock, are then thawed by forcing water through narrow pipes which have been driven into the deposit. Other methods of thawing frozen placers were used extensively during the early years of the Klondike 'gold rush', but experimentation later proved that creek water at its natural summer temperature was a more effective and economical thawing medium than any other which had been used. EVOLUTION OF COLD WATER THAWING Early prospectors of the far north reached placers by digging shafts through the frozen muck. They then thawed the placer sand and gravel by building wood fires at the bottom of the shafts.

Jan 1, 1951

By Zolfan F. Oszter

As exploration for new mineral deposits advances farther into the Canadian North, the more the design engineer is faced with the problems of cold weather conditions. This is especially true when designing belt conveyor systems for open-pit operations where the temperature in the winter may go to -40°F or below. Problems with the mechanical components and also with the belting will arise, which in turn may reduce the availability of the system. This paper outlines the problems encountered during cold weather operation and what precautionary measures must be taken into consideration in the design of equipment, as well as in the selection of materials, in order to ensure a system which will maintain production. THE conveying of ore and waste in the pit or to the processing plant poses problems during cold weather, when temperatures may drop to -4o?F or be-low. Troubles with the mechanical components, the belting or the supporting structure may arise, and this, in turn, will reduce the availability of the conveying system.

Jan 1, 1965

By George J. Thompson

This pa per deals with the internal characteristics of steel and its response under cold northern temperatures. General maintenance procedures and specific repair techniques are covered.

Jan 1, 1973

By M. Mohammadijoo, J. B. Wiskel, D. G. Ivey, S. Kenny, H. Henein

Cold-wire tandem submerged arc welding (CWTSAW) has recently been developed as a novel welding technique to replace the conventional tandem submerged arc welding (TSAW) process and improve the productivity of pipeline manufacturing. The process involves two electrodes with arcs and one electrically cold electrode. Since heat-input of the welding process is a key factor affecting the properties of the weld metal (WM) and the heat-affected zone (HAZ), and the additional cold-wire affects the heat introduced to the weldment, it is of interest to investigate property and geometry changes in the WM and HAZ when a cold-wire is added to the welding process. In the current research, the CWTSAW process is investigated and optimized by correlating the main welding parameters with the micro-hardness of the WM and HAZ and the geometry of the weld, i.e., the bead width (BW), penetration depth (PD), reinforcement area (RA) and coarse grained heat-affected zone (CGHAZ) area. Three statistical and mathematical methods are employed to optimize the CWTSAW process in terms of the mechanical properties and WM and HAZ geometry of a typical microalloyed steel used for pipeline manufacturing.

Jan 1, 2015

By Tony Breuer

Can international development NGOs and the mining industry find common ground and work together in the Third World? The Canadian Hunger Foundation/PARTNERS in Rural Development (CHF-PARTNERS) has, over the past forty years, implemented more than 800 rural community development projects in some 38 countries of Africa, Asia, and the Americas. Working with or for the Canadian mining industry offers both opportunities and risks. We can help a mining company ensure that the workers, their families and communities share adequately in the economic and social rewards from a mining operation in their area. We can contribute to the provision of sustainable livelihoods when an operation winds down. The company?s reputation as a good corporate citizen can be enhanced. On the other hand, mining companies and NGOs have generally very different values and missions. The risk of misunderstandings from conflicting motives and work practices is correspondingly high. Both partners must state their values and expectations clearly at the start of collaboration. The NGO must ensure that the company abides by acceptable ethical standards. It must not directly or indirectly subsidize a private company from its charitable donations. The mining company must satisfy itself that the NGO has the capacity, resources and experience to produce the results expected.

May 1, 2001

By W. E. Oching, M. M. Ghomshei

Attracting and retaining workers in mining industry has become an uphill battle to many mining companies. As workers with significant experience retire, it is getting more difficult to attract not only new workers but also top talent to the mining industry to replace professionals exiting the workforce. To make matters worse, students’ enrolment in the post-secondary mining programs in Canada and USA is continuously declining year after year for reasons not directly linked to job market. This raises a question of how can the future needs of mining be met? This paper focuses on avenues for collaboration of industry and educational institutions to meet the current and future needs of mining. It provides effective approaches that mining institutes can engage with program advisory committees, role of the mining industry in supporting both faculty and students, how to harness the benefits of diverse workforce in the country and use of innovative technologies to attract young workers in mining. This work presents Human Resources (HR) professionals with tools that they can use to hire and retain skilled workers with strong interest to work in the mining industry. It also provides HR professionals with an opportunity to re-evaluate their restructuring practices during economic downturns as they reduce number of employees on temporary or permanent basis. The paper stresses the need of working together of the mining stakeholders including mining industry, academic institutions, First Nations’ communities and provincial(state) and federal governments to meet the current and future demands of mining as the industry experiences shortage of labour and low students’ enrolment in post-secondary mining programs. It is shown that mining educational institutes can enhance their programs and recruitments through establishing a better communication with all stakeholders. This communication can be facilitated by creating a national advisory board, to work with all mining programs at the national level for sustainable mining.

Jan 1, 2023

By Terry Braden

"Meeting probable world mineral demand in the years ahead will almost certainly require an ability to economically treat lower grade and more complex ores. Achieving this will require extensive research and technical development across the full spectrum of mineral processing.For mid-sized or smaller companies the most effective way to participate in such extensive programs - and gain access to the technology required to stay competitive - may be through collaborative research.This paper explores the recent history of collaborative research in mineral processing and in particular its ability to attract world-class multi-institutional research teams with sufficient resources to make step-change advances. It chronicles the advances achieved, but also explores the research architecture and administrative structures required to deliver research outcomes and technology transfer mechanisms to a range of often disparate sponsoring companies.INTRODUCTIONIn medieval times the dream of alchemists was to turn base metals into gold. We modern alchemists, of course, don’t waste our time on that sort of foolishness: we turn base metals into dollars. When I see the profit reports filed by some companies recently, I can only conclude that a lot of those present today must be pretty good at this.But the fact that we are here at this conference reminds us that an alchemist’s work is never done; turning base metals into dollars is not a one-trick wonder but an art that we must extensively refine year after year if we are to survive in a competitive marketplace.It is not that demand for metals is likely to slow; most people seem to think that China, India, Brazil and other emerging economies are still at the lower end of their demand curve. They will need significantly larger volumes of metals in the years ahead. The challenge for us as processors is that to supply increasing tonnages of those metals profitably we will almost certainly need to process more complex or lower grade ores and probably to do so with reduced energy inputs."

Jan 1, 2009

By J. S. Redpath

Eighty feet of overburden, thirty feet consisting of fine, water-bearing sands, was encountered during the construction of a shaft collar for Chimo Gold Mines Limited at its Louvicourt, Quebec, property. This paper describes the excavation and construction methods used on the project. Open-cut methods, a sheet pile cofferdam, chemical grouting and special blasting methods were used during excavation. Concrete placement was hampered in the lower portion by a heavy water flow, and aided in the upper portion by an unusual method of form bracing. Plant and • pum11ing facilities are also described.

Jan 1, 1966