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By P. Hanniala, S. Harkki, B. Andersson

"The Outokumpu Flash Smelting Process was put into commercial operation in 1949. The original process was based on the use of preheated air. The adoption of oxygen enrichment of the flash smelting process air in 1971 was a crucial improvement, especially for smelter capacity. Oxygen use according to the Outokumpu method means selection of the most suitable oxygen content for the process air on the basis of the concentrate composition, capacity and matte grade. The furnace is not bound to only one fixed degree of process air oxygen enrichment; the oxygen content may vary from 21% to 100%.The degree of oxygen enrichment and the matte grade are the most important process parameters in reducing the operating costs of the whole system, including smelting, converting and acid production. Raising the matte grade allows more efficient use of the reaction heat in the smelting stage. Sulphur is recovered in a high-strength, constant-flow gas stream. The blowing time in the converters is reduced considerably.Oxygen enrichment and high matte grade improve the energy efficiency of the plant complex as long as the surplus heat from the system is not wasted. When the operating costs and investment expenditure of the total plant complex are taken into account, a reasonably high degree of oxygen enrichment (35-80°/0) is the best alternative in practice. Existing operating smelters have achieved single-stream thoughputs of over one million t/yr of concentrates.HistoryLocal capital and operating costs as well as lower energy consumption per unit of metal produced are now the crucial factors in determining the choice of process. In the late I940s, the same reasons prompted Outokumpu to develop the original flash smelting process in Finland. Between 1900 and 1940, very few technical changes in pyrometallurgical copper production took place. However, the commercial use of the flash smelting technique began a new era in metal extraction from sulphide concentrates. The characteristic feature of the method is that the concentrate is smelted in suspension: this offers the most favourable conditions for heat and mass transfer, and thus high reaction velocities. Outokumpu was the first to exploit the known advantages of flash smelting in a commercial installation at Harjavalta in 1949."

Jan 1, 1982

By D. W. Rogers

Several commercial polyacrylamide flocculants most widely used in Western Canadian mineral processing plants have been analyzed chemically and compared in standardized settling tests as aids to thickening and clarification. Data are included for both dry and liquid-type flocculants. Percentages of active ingredients in these commercial products varied Widely. Performances were compared on the basis of: equal additions of active ingredients, nearly equal molecular weights and nearly equal degrees of ionic character. Based on zone settling velocities and supernatant clarities of siliceous slurries coagulated by lime additions, dry flocculants proved more economical than liquid flocculants. Using these same two criteria, the most highly anionic were more effective than either weakly anionic or non ionic polyacrylamide- type flocculants.

Jan 1, 1978

By J. Beland

The Rimouski-Matapedia region is along the southwestern extension of the central Siluro-Devonian synclinorium of Gaspe Peninsula. As in Gaspe about 30,000 feet of Siluro-Devonian strata rest on a "basement" of tightly folded Ordovician rocks. The central synclinorium is divided up into two northeasterly trending belts each of which is characterized by distinctive lithologies and patterns of folding. The northwestern belt is gently to moderately folded and includes lithologies which point to a stable environment. The southeastern belt on the other hand is tightly folded and the lithologies indicate a less stable environment. A marked angular unconformity separates the basement from the Siluro-Devonian cover near the north-western margin of the northwestern belt. At the southeastern margin of the southeastern belt the relationship of cover to basement has not been as-certained because of a fault. The northwestern belt has several features significant in the search for petroleum; the Silurian strata are exposed in broad open anticlines

Jan 1, 1962

By J. Stiksma, R. Kalanchey, M. J. Collins, G. Owusu, R. Raudsepp, K. R. Buban, L. A. Barta, I. M. Masters

This paper describes the results of testwork for the treatment of Ambatovy laterite ore by a pressure acid leach process, with recovery of the soluble nickel and cobalt values as mixed sulphide intermediate by precipitation with hydrogen sulphide, and subsequent refining of the mixed sulphide to nickel and cobalt metals. These process development studies were carried out primarily in 2004, as part of a bankable feasibility study for the Ambatovy Nickel Project. The Ambatovy orebody is located in Madagascar. The mini pilot plant testwork was carried out in the Dynatec metallurgical laboratory in Fort Saskatchewan, Alberta. The results of the testwork were very encouraging, including nickel and cobalt extractions in the range of 95.5% to 97.0%, and 94.0% to 97.0%, respectively, in the ore leach step with sulphuric acid. High recoveries of nickel and cobalt were achieved throughout the remaining process steps, yielding separate nickel and cobalt metal powders with better than acceptable purity.

Jan 1, 2005

By J. E. Quinn, S. Wolstencrof, K. H. Soldenhoff

Ion Exchange (IX) using Strong Base Anion Exchange (SBA) resins is conventionally used to purify uranium from sulfuric acid pregnant leach solutions (PLS), particularly when uranium grades are relatively low. However, the presence of chloride in the PLS interferes negatively with conventional SBA based IX processes, by reducing the uranium loading on the resin. Chloride can be present in the PLS due to the use of saline bore or seawater in leaching, or chloride containing leach/IX reagents. ANSTO has been examining strategies to combat this problem for several years. ANSTO previously reported that a recently developed high-capacity SBA resin was capable of extracting uranium efficiently from saline leach liquors produced at Boss Resources’ Honeymoon in-situ recovery mine in South Australia. The resin was tested successfully in a 2017 Field Leach Trial carried out onsite in the existing wellfield area. While the piloting was extremely promising, the elution was more challenging, with eluate tenors limited to 2 g/L U3O8 using NaCl. This is due to the resin’s strong affinity for the uranium complex, which makes it difficult to elute efficiently by standard methods. In this paper, we describe a novel elution process developed for strong base resins that significantly improves upon conventional methods. The process, developed by ANSTO, is based upon conversion of the extracted uranyl sulfate species to uranyl carbonate, followed by elution with sodium chloride. The loading and elution process was demonstrated in continuous locked-cycle piloting conducted at ANSTO in 2019. The results were excellent, with eluate tenors of 8–9 g/L U3O8 achieved from Honeymoon PLS containing 50 mg/L U3O8, with very little transfer of impurities. In subsequent test work, the eluate was shown to be amenable to uranium peroxide precipitation. The results represent a huge step forward for the purification of uranium from saline leach liquors.

Jan 1, 2020

By S. Kursunoglu

The aim of this study was to investigate the effectiveness of Ascorbic (C6H8O6) Acid (AA), Activated Carbon (AC) and Guar Meal (C6H12O6) (GM) as a reductant for the simultaneous complete dissolution of zinc (Zn) and manganese (Mn) from a spent and mixed Zinc-Carbon (Zn-C) and alkaline battery powders in sulphuric acid (H2SO4) leaching. AA was tested previously as a reductant by other researchers while AC and GM were tested as a reductant for the first time in battery recycling. The effects of H2SO4 concentration, AA/AC/GM dosages, reaction temperature and leaching time on the Zn and Mn dissolutions were investigated according to 2k full factorial experimental design and Central Composite Design (CCD) technique; then, a simple optimization study was carried out for comparing the reductants. The optimum reductive acid leaching conditions for AA were determined at 3 hours leaching time, 70°C leaching temperature, 0.5M H2SO4 concentration, 13 g/L AA dosage, 1/20 g/mL solid/liquid (S/L) ratio and 200 rpm stirring speed. Under these conditions, the dissolution efficiencies were 99.9% for Zn and 99.3% for Mn. The best reductive acid leaching conditions for AC were determined at 3h leaching time, 80oC leaching temperature, 1M H2SO4 concentration, 3 g/L AC dosage and 400 rpm mixing speed. Under above conditions, Zn and Mn dissolutions were not complete. At 2M H2SO4 concentration, 10 g GM dosage, 700C leaching temperature, 200 rpm stirring speed, 1/20 g/mL solid/liquid (S/L) ratio and 3 hours leaching time, full dissolution of both Zn and Mn was achieved. As a result, three different reductants were evaluated in this study for complete simultaneous Zn and Mn dissolutions. This paper also compared present test results with previous spent battery recycling studies for Zn and Mn dissolutions. Full valuable metals dissolutions from spent batteries were achieved at low H2SO4 concentrations with AA and high concentrations with GM. Selective precipitations of Zn and Mn from acid solutions were carried out using NaOH and KOH. Using 3M NaOH as precipitating agent at room temperature and at pH 8; 95.4% of Zn and at pH 10; 93.7% of Mn were precipitated from the leach solution. Under the same conditions, using 3 M KOH at pH 8; 91.6% of Zn and at pH 10, 96.4% of Mn were precipitated. Based on the experimental results obtained, an appropriate flow sheet was proposed to recover both Zn and Mn.

Aug 1, 2013

By Mario E. Rossi

Geostatistical conditional simulations are becoming increasingly popular as tools that provide models of uncertainty at different stages of a mining project. They have been used as grade control tools in daily operations, to assess the uncertainty of minable reserves at the project?s feasibility stage, and to assess mineralization potential in certain settings. Other applications include assessment of recoverable reserves, resource and reserve classification, and drill hole spacing optimization studies. All large-scale applications of conditional simulations intend to benefit from the ?correct? (or ?accurate?) characterization of uncertainty, adequately describing the variability observed from the data and its impact on the final objective. The objective of this paper is to compare the ad-hoc ?uncertainty model? provided by a traditional classification scheme with the probability intervals resulting from a conditional simulation model. It is argued that the uncertainty model derived from the use of classification schemes is of little practical use to the mining company or operation. The paper emphasizes differences in uncertainty based on the size of the mining unit considered and the extraction method, and local geological differences. Most importantly, it discusses confidence intervals for these mining units, as compared to the relative precision envisioned by a typical classification scheme. The application described in this paper is taken from a medium-sized Cu open and underground mine in northern Chile, and it demonstrates the impact of several variables on the resulting conditional simulation models. It also compares a more ?traditional? resource classification scheme applied, and the wide difference in local confidence intervals for each mining unit.

May 1, 2001

By Kim H. Shikaze, John R. Hawley

"Even though acid mine drainage is an old problem, particularly in coal mining areas, its appearance in the form of a major environmental hazard in the hardrock mining districts of Ontario was unexpected. The yellow and amber coloured wastes that characterize an acid mine drainage situation were first noted by the Ontario Water Resources Commission in the uranium mining Elliot Lake district. Problems of a similar nature were also noted in the copper-lead-zinc camp at Manitouwadge, the nickel camp at Sudbury and at numerous isolated base metal properties, both in and out of the Province of Ontario.Without exception, when acid mine drainage type effluents were evident, the specific companies involved worked sulphide or sulphide-associated ores. Without exception, the ore bodies contained quantities of iron sulphide (in various mineralogical forms) and, without exception, the milling circuits serving these operations were such that the iron sulphides were rejected to the tailings areas as waste.Once in a tailings area and after a varying period of time, iron sulphides react to form water soluble salts which, when discharged in the effluents from the tailings area, can affect stream chemistry and stream ecology.It is not unusual that the minerals pyrite, marcasite and pyrrhotite (all iron sulphides) react to form a stable oxide under atmospheric conditions. The law of stability of rocks and minerals, for instance, states that rocks and minerals are stable only in the environment of their formation and, as the environment surrounding them changes, the rocks and minerals tend to change to other species which are relatively more nearly stable under the conditions of the new environment (a). Under atmospheric conditions, iron oxide exhibits a greater stability than iron sulphide."

Jan 1, 1971

By Pierre O'Dowd

"The southern Abitibi Belt is the major source of gold in Quebec. Although the northern part of the belt is quickly being developed, the area under study will not be downgraded in the near future because it still contains more than 75% of the known reserves in the belt.Gold is found in a variety of geological environments which are part of a small number of distinct structural patterns. For the exploration geologist, outlining such patterns might be easier and more productive than defining, when it is possible, the exact genetic nature of the gold mineralization.Exploring in the right place has always been one of the main concerns of explorationists. This paper briefly describes the various favourable geological settings, and outlines areas, types of structure and lithologies of high potential for gold exploration in the southern Abitibi Belt.IntroductionThe southern part of the Abitibi Belt is a profilic mining area for precious and base metals (Lulin 1990). Although mineralizing processes and controls of polymetallic deposits are well known and understood (Lydon 1984), almost every gold occurrence is a unique case and numerous models have been proposed (Roberts 1987; Hodgson and McGeehan 1982; Hodgson 1990).This study does not define new genetic models for the formation of gold deposits, neither is it meant to elaborate on the existing ones. A genetic approach, is by definition, theoretical and, to some extent, universal. It helps geologists define types of targets and exploration tools but does not outline or quantify target areas. To tentatively summarize the complexity of a genetic approach, a brief discussion on the various genetic models in vogue in Abitibi and the problems related to their use in exploration can be found at the end of this paper."

Jan 1, 1991

By Juan Asalgado

The JORC and NI43-101 codes impose that mineralized material has a reasonable prospect of economical extraction to be classified as Mineral Resource. For deposits close to surface and amenable to open pit mining, it is easy to show reasonable prospect of economic extraction running a Lerch-Grossman optimization. The Lerch-Grossman pit provides a transparent and repeatable way of separating the Mineral Resource (within the pit) from the remainder of the mineral inventory (outside the pit). Deposits amenable to underground mining are more challenging because of the variety of the underground methods. AMEC developed a stand-alone software package that outlines the material which has reasonable prospect of economic extraction for open stoping, block caving, sublevel caving and room and pillar. The software takes a block model file in ASCII and exports a 3D surface outlining the part of the mineralization that has a reasonable prospect of economic extraction, and which the Qualified Person can smooth out manually if required.

Oct 1, 2009

By K. Mayhew, K. Murray

The CESL Copper Process was developed as a hydrometallurgical alternative to smelting and refining for copper sulphide concentrates. As the majority of such concentrates contain appreciable gold and silver values, effective recovery of these metals is essential to the economics of this technology. Unfortunately, conventional cyanide processing cannot be used on the residue from the copper process, clue to its unusual characteristics when compared with naturally occurring gold and silver ores. An abundance of elemental sulphur, as well as the presence of cyanide soluble copper, leads to the formation of both thiocyanate and copper cyanide which is detrimental to process economics clue to excessive cyanide consumption. This, however, can be reduced to acceptable levels by process innovations such as pressure cyanidation and cyanide recovery. This paper outlines the successful application of the CESL Gold Process to various gold-bearing copper concentrates from bench to demonstration scale.

Jan 1, 2011

By T. R. Eger

Miners can be exposed to whole-body vibration (WBV), when sitting or standing to operate mobile equipment. In order to prevent vibration-induced injury it is important to understand how miners can be exposed to vibration, the health risks associated with vibration exposure, methods to evaluate vibration exposure, and strategies to reduce vibration exposure. WBV exposure typically occurs when operating mobile equipment, such as a load-haul-dump vehicle, haulage truck, or dozer. The probability of health effects such as low back pain, neck pain, headaches, and gastrointestinal track problems occurring from daily vibration exposure can be determined based on criterion values published in ISO 2631-1 and EU Directive 2002/44/EC. A special case of WBV termed foot-transmitted vibration (FTV) occurs when a miner is exposed to vibration that travels through the feet. FTV typically occurs when standing on vibrating surfaces associated with the operation of locomotives, jumbo drills, bolters, or raise platforms; however, there is no set standard to evaluate health effects associated with FTV. Recent medical evidence confirms workers exposed to FTV can develop cold induced blanching of the toes, in addition to numbness and tingling in the feet and toes. In order to reduce the risk of adverse health effects from exposure to vibration, the hierarchy of controls (elimination; substitution; engineering; administration; and personal protective equipment) should be followed. Best practices should be used to minimize vibration exposure through equipment purchases (i.e. vehicles with lower vibration emissions and seats that attenuate vibration), reduced driving speeds, and improved road maintenance for example. The elimination of other risk factors, which increase injury risk when combined with WBV exposure, such as awkward working postures, should also be eliminated. Very little is known about FTV exposure therefore further research is required in order to develop exposure standards and identify prevention strategies.

Aug 1, 2013

By D. M. Muir

The mineralogy of residues formed during the pressure acid leaching of arid region nickel laterite ore varies according to the salinity of the process water, alkali cation additives and the overall acid loading. In fresh water, hematite is the main iron-bearing leach residue component, together with amorphous silica and hydronium or sodium alunite/jarosite [(H3O,Na)(Fe,Al)3(SO4)2(OH)6]. As the process water salinity increases, or as NH4+ or K salts are added, alunite/jarosite is the kinetically favoured iron-bearing phase accompanied by an increase in acid consumption. The alunite/jarosite appears as two XRD distinct phases with different Fe:Al molar ratios. In weakly saline water, iron-rich alunite/jarosite slowly transforms to hematite and an aluminium-rich alunite/jarosite together with the release of acid. The addition of potassium salts forms a more stable alunite/jarosite whilst the addition of ammonium salts leads to greater transformation of alunite/jarosite at 250°C. Weakly saline process water gives enhanced nickel recoveries, whilst strongly saline process water gives lower nickel recoveries but higher soluble iron because of chloro-complexation. SEM and microprobe analysis shows very little nickel is associated with the alunite/jarosite and hematite phases. Nickel losses to the residues are attributed to adsorption on amorphous silica and to a lesser extent on alunite/jarosite.

Jan 1, 2006

By Alfred C. Lane

WE recently received from Professor A. C. Lane, Emeritus Professor of Geology and Mineralogy, Tufts College, Mass., and a Corresponding Member of this Institute, a very interesting account of some recent developments in radioactive methods of determining the age of minerals and, therefore, of the rocks in which they occur. It deals in particular with studies of the minerals of certain pegmatite dykes on the Huron claims and Bear claims in southeastern Manitoba, which, the results indicate, are among the oldest rocks of the earth's crust. The following article presents a non-mathematical summary of Professor Lane's paper . . It will be noted that he is anxious to obtain suitable samples of certain minerals and rocks for further age studies. We hope some o our members may be able to supply him with the material he needs. It may be well to explain briefly how the age determinations are made. Uranium is continually breaking down, or disintegrating in successive steps through radium, etc., to a final product which is lead (uranium-lead), and the rate at which this change takes place is known. Minerals containing uranium will therefore contain lead also, and the lead-uranium ratio mul-tiplied by a certain factor (approximately 7 ,600) will give the age of the mineral in millions of years. Thorium also disintegrates at a known rate to give lead (thorium-lead) as a final product, and the age of a mineral containing thorium can thus be calculated from the lead-thorium ratio. Thorium breaks down more slowly than uranium. In unit time, one gram of thorium produces about as much lead as 0.36 grams of uranium.-ED.

Jan 1, 1938

By J. C. Taylor, J. A. Davis

"Existing environmental, health and safety regulations have forced pyrometallurgical facilities worldwide to drastically change some of their traditional methods of operation. In extreme cases, a number of facilities have been closed due to their inability to conform to these existing regulations. Tougher future legislation and government policy will lead to more stringent regulations and enforcement policies. The efficient control of smelter secondary emissions will, therefore, become critical to successful smelter operation.Much attention has been paid to the smelter primary process off-gas systems, including the development of new process designs to reduce the number of uncontrolled transfer operations. However, even the most modem smelter design requires control of its secondary contaminant sources, which mayor may not be directly related to the process operation.This paper discusses some of the potential secondary emissions encountered in many of the present process technologies. A few of the emission sources presented are only periodic in nature, such as those caused by maintenance procedures, but which have the capability of forcing smelter shut-down because of their direct impact on worker health and safety. The paper deals with a variety of topics relating to the efficient control, maintenance and monitoring of secondary emissions in copper, nickel, aluminum, magnesium and lead smelters, as well as in iron foundries and steel making facilities. Examples of the typical problems encountered in each of the above process operations are presented, including fume control at furnace tapping and slagging locations, metal transfer stations, tapping launders, and ladle transfer operations. The parameters for the most efficient design of fume capture systems, problems encountered with the handling and clean-up of certain collected emissions, and examples of successful solutions in particular operations are discussed."

Jan 1, 1994

By F. Doxey

Introduction Numerous papers have been written dealing with the construction and functions of, and the environmental conditions created by, Diesel locomotives. Therefore, it is not my intention to attempt to deal with these phases of Diesel transportation other than to make reference to them in ?relation to and in connection with actual operation. The rapid expansion of industry during recent years and the necessity of products being made available at competitive prices in home and world markets has made the demand for cheaper coal a very serious factor for the coal industry. This condition has meant each coal producing country looking into ways and means whereby greater productivity and reduction in cost could he achieved. Surveys made show that, in addition to face mechanization, savings, in some cases substantial, can be made in transportation. Ventilation The most efficient mines are in-variably the well ventilated ones, for it is true that, where there is good ventilation, there are usually good roads. These combined factors are very essential where Diesel locomotives are used. Good roadways and track allow speed, and good ventilation dilutes rapidly any disagreeable exhaust gases. Locomotive Development In the older types of auxiliary rope haulage, coal hauled per haul-age hand is usually very low.

Jan 1, 1951

By M. T. Shehata, R. W. Revie, M. Elboujdaini

Environmentally assisted cracks in linepipe steels are initiated either as a result of stresses in combination with environmental effects, as in stress corrosion cracking (SCC), or as a result of trapped hydrogen in the steel, as in hydrogen-induced cracking (HIC). To understand better the mechanism of the crack initiation process, key metallurgical and environmental elements that can affect the cracking phenomena were investigated and are reviewed in this paper. The complexity of both cracking phenomena results from the dependence of SCC and HIC on multiple metallurgical, mechanical, and environmental parameters that may all influence both crack initiation and propagation; e.g., composition, microstructure and non-metallic inclusions in the steel, applied stress, water chemistry in the field, and ionic concentrations in the groundwater near the pipe surface to name a few for SCC. In addition, for HIC phenomena, one can add the concentration of H2S in the fluids transported in the pipe as well as concentration of CO2, pH, etc. In this paper, cracking of linepipe steels is analyzed critically, with particular attention to the crack initiation process. The paper is divided into two parts: The first part covers SCC and the second covers HIC.

Jan 1, 2005

By D. Tao

Froth flotation is widely used in the coal industry to clean -28 mesh or -100 mesh fine coal. A successful recovery of particles by flotation depends on efficient particle-bubble collision and attachment with minimal subsequent particle detachment from bubble. Flotation is effective in a narrow size range outside which the flotation efficiency drops sharply. A fundamental analysis has shown that use of picobubbles can significantly improve the flotation recovery of particles by increasing the probability of collision and attachment and reducing the probability of detachment. A specially designed column with a picobubble generator has been developed for enhanced recovery of fine coal particles. Picobubbles were produced based on the hydrodynamic cavitation principle. Experimental results with one metallurgical coal and one steam coal have shown that the use of picobubbles in a 2" column flotation increased fine coal recovery by 10-30%, depending on the feed rate, collector dosage, and other flotation conditions. Picobubbles also acted as a secondary collector and reduced the collector dosage by one third to one half.

Jan 1, 2006

By P. R. A. Andrews, R. K. Collings

"There are more than thirty-five deposits or occurrences of celestite in Canada, chiefly in Newfoundland, Nova Scotia, New Brunswick, Ontario and British Columbia. Deposits of economic interest are the Lake Enon and MacRae deposits in the Loch Lomond district of Cape Breton Island, Nova Scotia. Two Cape Breton deposits were operated from 1969 to 1976 by Kaiser Celestite Mining Limited, which supplied an upgraded celestite concentrate to an associated strontium carbonate plant at Point Edward, near Sydney.The MacRae deposit is of current interest because of its possible development for strontium carbonate production using the ""black ash"" process. This process involves chemical leaching, rotary kiln calcining with petroleum coke, washing and treatment with carbon dioxide.Celestite is the basic material used in the manufacture of strontium chemicals, principally strontium oxide, carbonate, nitrate, chromate, chlorate, chloride, sulphide and phosphate. Strontium chemicals, in turn, are used in the manufacture of glass and ceramics, in pyrotechnic devices, in the production of strontium metal and in other metallurgical applications. Recently, strontium ferrites have been introduced into permanent ceramic magnets."

Jan 1, 1991

By D. Seo, P. Au, X. Husang, D. Nagy

The production of single crystal (SX) turbine blades represents the current stateof- the-art in Ni-based superalloy design. With complex casting processes and alloy composition modifications, SX superalloys exhibit superior high temperature mechanical properties to their polycrystalline counterparts. Stresses and plastic deformation can occur in SX nickel-base superalloy engine components at various stages during their manufacture and use. For examples, stresses are created during initial solidification and also during solid state processing such as shot peening, grit blasting, blending, electrodischarge machining and welding. Stresses may also be created during service due to random events such as foreign object impacts. Subsequent exposure of SX to high temperatures during solution heat treatment and brazing repair can result in recrystallization which has been shown to be detrimental to both creep rupture strength and fatigue performance of the components. It is therefore the objective of this paper to understand the recrystallization behavior of two SX superalloys, PWA 1484 and 1483, subjected to pre-stressing and subsequent heat treatments.

Jan 1, 2006