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By Helge Rosenberg

Up to now, Topsøe WSA (Wet gas Sulphuric Acid) plants have been in operation for almost 30 years, and close to 80 plants have been sold. In spite of its unique features and ability to treat gases without any prior drying, the WSA technology has had certain restrictions with regards to SO2 concentration in the feed gas, and the overall conversion of SO2 by catalytic means has been limited to approx. 99.7%. In commercial scale sulphuric acid production on the basis of elemental sulphur and metallurgical off-gases, there is a demand for higher SO2 conversion and treatment of gases with a higher content of SO2. Therefore Topsoe has further developed its WSA technology to cope with these demands. This paper will explain more about the principles of such new development and leave the delegate with a better understanding of the potentials of the new generation of the WSA technology from Topsoe.

Jan 1, 2009

By Helge Rosenberg

Up to now, Topsøe WSA (Wet gas Sulphuric Acid) plants have been in operation for almost 30 years, and close to 80 plants have been sold. In spite of its unique features and ability to treat gases without any prior drying, the WSA technology has had certain restrictions with regards to SO2 concentration in the feed gas, and the overall conversion of SO2 by catalytic means has been limited to approx. 99.7%. In commercial scale sulphuric acid production on the basis of elemental sulphur and metallurgical off-gases, there is a demand for higher SO2 conversion and treatment of gases with a higher content of SO2. Therefore Topsoe has further developed its WSA technology to cope with these demands. This paper will explain more about the principles of such new development and leave the delegate with a better understanding of the potentials of the new generation of the WSA technology from Topsoe.

Jan 1, 2009

By B. Simser

At Brunswick Mine, an increase in the number of seismically-related falls of ground and in particular rockbursts occurred during 1999. This was due to the ever-increasing stress levels in the remaining ore reserves, mining in difficult highly stressed areas and in particular troublesome geological features. In conjunction with the Noranda Technology Centre, development of rockburst support systems started at the Brunswick Mine in 1996 and efforts were accelerated in 1999. A support package consisting of #6 gauge chain link mesh, #0 gauge heavy mesh straps, and a 1 m by 1 m pattern of modified conebolts was developed. The conebolts were modified to enable mixing of the resin anchoring. Two major rockbursts occurred during an intense seismic episode at the Brunswick Mine from October 13th to 17th , 2000.The area was evacuated approximately four hours before the first burst hit, and remained closed during the seismic ?flurry??. The first damaging activity occurred around midnight on Friday the 13th, and a second damaging episode occurred on the 17th that included a local Richter Magnitude 2.7 event. The second rockburst had dimensions of approximately 5 m by 5 m by 20 m or 2150 tonnes of massive sulphide material (density 4300 kg/m3). The first failure area was more extensive, caving approximately six metres of an intersection back with the lateral extent not safely measurable. This paper briefly describes the mining conditions that led to the bursting, the seismic response of the region, the mechanisms thought to have caused the bursts, and a yielding support system which had been partially installed before the burst.

Jan 1, 2002

By J. L. Fuentes-Cantillana, Á. Rodríguez, P. Morillo

Evacuation operations from work places in the case of an emergency are the key to minimising the effects of catastrophic type accidents such as fires, explosions, cave-ins, floods, etc. The correct planning of these operations, having the necessary means for sounding alarms and communicating and suitable training of personnel are the key factors for guaranteeing successful evacuation. The article gives an analysis of the problem in the case of subterranean mining and various types of work developed by AITEMIN in this field, including the development of new alarm and communication means specially adapted to the characteristics of mining operations, development of tools for help in the preparation of emergency plans and experiences in the education and training of personnel.

Jan 1, 2003

By B. S. Xakalashe

Keywords: Pyrometallurgy, silicon, solar cells Silicon has been the dominant material in the photovoltaic (PV) industry since its application in the space industry in 1958. This review focuses on crystalline silicon solar cells, primarily due to their dominance in the photovoltaic industry, omitting other photovoltaic cell technologies such as second generation (e.g. thin films) and third generation (e.g. nano-structured solar cells). The value chain for the production of crystalline silicon solar cells has been reviewed. The primary processing steps for the production of silicon solar cells from quartz are as follows: bulk production of metallurgical-grade silicon via carbothermic reduction in a submerged furnace, refining of metallurgical-grade silicon via the chemical means to polycrystalline silicon, or through the metallurgical route to solar-grade silicon, wafer manufacturing, and, lastly, silicon solar cell manufacturing. During downstream processing, solar cells are interconnected and encapsulated into solar modules (panels), which can be used individually or incorporated into a photovoltaic system for electricity generation and supply. The cost for crystalline silicon based solar cells is approaching one US dollar per watt peak ($1/Wp), while the most cost-effective solar modules in industry have reported costs below $1/Wp, and are based on CdTe thin films. Solar cell energy conversion efficiencies as high as 22% have been reported in industry for crystalline silicon solar cells.

Jan 1, 2011

By R. E. Wilmot

This paper is based on the experiences, over many years, on the part of numerous authors in the South African mining industry and that of the hot dip galvanizing process and its application as a corrosion protection system. The paper sets out the extensive development, financial resources and stringent operating requirements of the South African mining industry. After many years of research and operational experiences, hot dip galvanizing and when necessary, duplex systems, have been found to meet the demanding requirements of this particular industry. The paper sets out the requirements from the standpoint of corrosion criteria and is followed with a practical example; ?case history? where the corrosion protection properties of hot dip galvanizing are demonstrated. This case history traces the early investigation of the expected corrosive conditions to be encountered in a new mining operation (now 10 years on) and concludes with two follow up visits to the mine in order to examine actual performance of the corrosion protection system after ten years in service.

Jan 1, 2006

By R. Poisel, C. Scavia, Preh A., W. Roth, M. Pirulli

ABSTRACT: Two methodologies for the three-dimensional simulation of the run out of rock avalanches are presented: one based on a granular approach and the other based on a continuum equivalent approach. An evaluation of the possible run out area of the Oselitzenbach landslide (Carnic Alps, Austria) has been carried out applying the two methodologies. The combined use of these two approaches makes it possible a comprehensive assessment of the run out area. RESUME: Deux méthodologies pour la simulation tridimensionnelle de la propagation des avalanches rocheuses sont présentées: la première est basée sur un modèle de type granulaire et la deuxième sur un modèle du continu équivalent. Une évaluation de la propagation éventuelle de l’avalanche de Oselitzenbach (Alpes Carniche, Autriche) a été réalisée en utilisant les deux méthodologies. Les résultats obtenus montrent que la combinaison des deux approches rend possible une analyse plus complète de la phase de propagation. KURZFASSUNG: Für die dreidimensionale Modellierung eines Felsmassensturzes (sturzstrom) werden zwei Methoden, eine granulare und eine kontinuumsmechanische Methode, vorgestellt. Beide Methoden wurden zur Abschätzung der Ausbreitung (runout) der Massenbewegung Oselitzenbach (Karnische Alpen, Österreich) herangezogen. Die kombinierte Anwendung beider Methoden ermöglichte eine umfassende Beurteilung des möglichen Ausbreitungsbereichs.

Jan 1, 2003

By Deur T. A. M. Saayman

Die sesde jaarlikse Ingenieursimposium is in September by YSKOR, Vanderbijlpark gehou. Rierdie simposium, wat deur Ingenieurs-in-Opleiding georganiseer word, bied aan die Ingenieurs-in-Opleiding die geleentheid om referate te lewer oor projekte wat gedurende hul drie jaar opleidingsperiode uitgevoer word. Continuing education courses The following courses are to be given in the near future in The Netherlands. Coal trade, transportation, and handling . The 4th Coal Trade, Transportation and Handling Conference and Exhibition, CoalTrans '86, will take place the Rai Congress Centre, Amsterdam, from 10th to 12th June, 1986.

Jan 1, 1986

Statistics is essentially a study of variability, the use of some suitable mathematical model representative of such variability, and the application of this inferred pattern of behaviour to practical problems. Probability theory is the mathematical structure devised for providing models for chance happenings. Perhaps the simplest example of a chance happening is the result obtained in tossing a coin. Although the result of a single toss can never be predicted with certainty, there is no reason why in repeated tosses the expectancy of heads and tails should not be equal. In such a case the outcomes of the experiment are said to be equally likely, so that the probability of obtaining heads (or tails) is 1 in 2, that is, 0,5. This simple probability .model refers to a 'mathematical' or 'unbiased' coin. Whether such probabilities are meaningful for actual coins tossed in any particular way is a matter for experience to determine. Probability models have also provided the basis for representing observed variability in cases where the actual under- lying probabilities are only partly known or defy analysis. A typical example of the latter case is the variability observed in the values obtained from gold or other ore samples. The interacting natural forces which gave rise to this variability are obviously very complex and are unlikely ever to be unravelled completely. In spite of this, probability theory and the more recent geostatistical theories have provided us with models which can represent this variability on a reasonable basis. Applied statistics and geostatistics must therefore never be accepted as exact mathematical sciences. Furthermore, a basic and essential concept is that in the type of applications covered in these notes, no model must ever be accepted as necessarily the final and exact answer to the problem; thus, any model must prove and continue to prove its appropriateness in practice, preferably by follow-up comparisons.

Jan 1, 1981

By P. Lundman, L. Rosengren, T. Brandshaug

Tunnel 99’, the Swedish National Road Administration´s (SNRA) general technical specification for road tunnels requires that the load bearing system must be designed to withstand specified design explosion loads. This paper presents the results of an SNRA study to provide a perspective of design analyses tailored to comply with the new requirement. The paper provides an example of a design analysis for assumed tunnel conditions using a numerical model. Dynamic predictions of potential damage to the rock mass and ground support system (rock bolts and shotcrete) from the specified explosion loads are presented including the nonlinear response of the shotcrete. “Tunnel 99”, qui fixe les règles de l’Administration nationale suédoise des Routes (Vägverket) concernant la conception et la construction des tunnels routiers, requiert entre autres que la structure porteuse soit capable de résister à certaines contraintes spécifiques résultant d’explosions. Cette étude présente les résultats d’une étude effectuée par Vägverket en vue d’obtenir une perspective d’analyses de conception spécialement élaborées pour se conformer aux nouvelles règles. Il contient un exemple d’analyse en fonction de conditions déterminées, basée sur un modèle numérique. Des prévisions de’études dynamiques de dommages potentiels subis par la masse rocheuse et les systèmes de soutènement (boulons d’ancrage et béton projeté) du fait des contraintes libérées par la force d’explosion spécifiée sont également présentées, y compris dans le cas d’une réaction non linéaire du revêtement en béton. “Tunnel 99” - die Vorschriften für Strassentunnel der Nationalen Schwedischen Behörde für Straßenwesen - (Vägverket) - fordern vom Tragsystem eine Auslegung in der Form, dass es spezifischen Explosionsbelastungen standhält. Dieser Artikel präsentiert die Ergebnisse einer Studie der Behörde, um einen Ausblick über konstruktive Auslegungen zu geben, die geeignet sind, die neuen Vorschriften zu erfüllen. Der Artikel zeigt ein Beispiel einer konstruktive Auslegung für eine angenommene Tunnelsituation mit Hilfe eines numerischen Modells. Voraussagen unter Beachtung der vollständigen dynamischen Berechnung zu potentiellen Schädigungen des Gebirges und des Ausbaus (Anker und Spritzbetonauskleidung) durch die spezifizierten Explosionsbelastungen, einschließlich des nichtlinearen Verhaltens der Spritzbetonauskleidung, werden gezeigt.

Jan 1, 2003

By R. Dippenaar

The emergence of new steel grades is largely driven by the need to produce high quality steel at a competitive price. The principal aims are to attain ultra-high purity, (especially low interstitial elements) and ultra-cleanliness (by the control of the inclusion content and size). Whereas the steel used to build the Titanic contained 650 ppm sulphur, resulting in MnS stringer-inclusions 25 mm in length, modern quality requirements for arctic pipelines would only allow 10 ppm of sulphur and inclusions in ball-bearing steels must be smaller than 5µm. Most developments are aimed at hot-metal treatment before refining and ladle treatment after decarburisation. Because ferroalloys are added during or after the refining step, it is the secondary (ladle) refining production technologies that are of specific interest to the ferroalloy producer. Through ladle treatment, hydrogen and nitrogen contents are reduced, ultra-low levels of solute impurities are attained and the shapes as well as the composition of inclusions are modified. Steelmakers are concerned about the cost effectiveness of the use of ferroalloys such as consistent product analysis and delivery, improved financing arrangements and technical support. Minimal variation in product sizing is vital because it impacts on handling problems and because particle size determines the rate of particle dissolution. The required ferroalloy product quality depends on the specific use but in general sulphur, phosphorous and nitrogen contents are of concern. Apart from the presence of trace and impurity elements, ferroalloys also contain inclusions. For example, ferromanganese may contain MnO-MnS-SiO2 inclusions while high-carbon ferro-chrome may contain different kinds of Cr-Mn-spinels. The presence of these impurities and inclusions has a significant impact on steel production techniques and cost and hence, on the selection and use of ferroalloys. The interrelationship between ferroalloy quality and steel production technology is plant and product specific and hence, effective communication between ferroalloy suppliers and steel producers is essential.

Jan 1, 2004

By E. J. M. Jahnsen, I. Jauhari, T. Badrujaman, F. A. Stober, B. O. Wasmund, L. R. Nelson, T. Miraza, J. M. A. Geldenhuis, A. Taofik Hidyat

The role of dedicated operational support in the ramp-up and stabilisation of the FeNi-II furnace for ferro-nickel production at PT Antam?s smelter located in Pomalaa, Indonesia is described. The furnace was uprated to 32MW capability in a rebuild performed in 2005. This primarily involved installing a larger transformer, coupled with adoption of HATCH water-cooled copper plate, waffle and flanker coolers with integrated metal and slag tapblocks, HATCH air-cooled copper fin lower sidewall cooling and HATCH vertical sidewall binding system ? ?holddowns?. Following a smooth commissioning period, the progress in attaining the preliminary ramp-up target load of 24MW is described. This initial target was set by Antam, subject to some prevailing smelter equipment constraints, particularly kiln capacity. Stabilisation of the furnace operation is discussed, together with some of the specific commissioning and operational challenges surmounted by the joint Antam-HATCH team. These included: ?Mastering furnace integrity monitoring and operation with copper coolers, especially metal tapblock planned maintenance and repair strategies; ?Transition from traditional ?immersed electrode? to ?brush-arc? mode of operation approaching as closely as possible to the productive ?shielded-arc? mode of operation within existing equipment constraints; ?Reductant selection and control issues; ?Utilising the sophisticated furnace monitoring to provide detailed indication and warning of potentially destructive furnace upset conditions such as Si reversion and CO boils.

Jan 1, 2007

By V. Labiouse, P. K. Kaiser, F. Descoeudres, F. Rojat

In this paper some failure phenomena observed in the crossing of brittle rock formations at the Lötschberg base tunnel are presented. A brittle failure criteria, recently developed by Canadian researchers, is applied through finite element calculations together with a semi-empirical failure criterion, to explain these behaviours. Good agreement is found between predicted and observed failures at the tunnel walls. This study also shows some of the limitations of this approach. Dans cet article sont présentés certains phénomènes de rupture observés durant la traversée de zones de roches fragiles lors de l’excavation du tunnel du Lötschberg. Un critère de rupture développé récemment par la recherche canadienne est utilisé à travers des calculs par éléments finis. En parallèle, les résultats sont comparés avec ceux d’un critère semi-empirique. Au niveau des parements, l’ampleur des ruptures observées est assez proche des résultats de calcul. Cette étude a également permis de mettre en avant certaines limites de l’approche choisie. In diesem Artikel werden verschiedene Brucharten dargestellt, die bei der Durchfahrung von sprödem Gestein im Rahmen des Ausbaus des Lötschberg-Basistunnels beobachtet wurden. Zur Erklärung des vorliegenden Verhaltens wurden die erst kürzlich in Kanada entwickelten Theorien zur Beschreibung von Sprödbrüchen herangezogen und bei der Berechnung mittels der Finite-Elemente-Methode und eines semi-empirischen Kriteriums angewendet. Die so vorhergesagten Versagenszonen an den Tunnelwänden stimmen mit den Beobachtungen gut überein. Die Studie hat auch dazu beigetragen, die bei der Anwendung des Lösungsansatzes angetroffenen Schwierigkeiten aufzuzeigen.

Jan 1, 2003

By S. Heukelman

Zinc or, a zinc refinery in South Africa, uses oxygen enrichment of up to 26% O2 in its fluidizing air to increase concentrate-throughput in its fluidized bed roasters. The aim of the study is to determine whether O2 enrichment can be reduced by introducing micro-pelletized concentrate into the feed blend, while maintaining concentrate throughput rates and calcine quality. A laboratory scale fluidized roaster was used to determine the strength and oxidation kinetics of suitable micro-pellets. The strength of the pellets was determined by the extent of attrition during roasting. It was found that micro-pelletization decreases the fines in the feed to the roasters; the ?500 µm fraction decreased from 87% to 10%. The micro-pelletized particles do break down during roasting, which increases the -500 µm fraction to 31%. The general morphologies of the roasted particles are similar to those found by previous workers. Micro-pelletized concentrate particles require more time than non-pelletized concentrate particles to oxidize in the roasting step, although this is less than the mean residence time of the Zincor roasters. Roasting micro-pellets in O2-enriched fluidizing air increased the reaction rate.

Jan 1, 2011

By J. Morkel

During research on mainly the weathering of kimberlite, it became evident that its mineralogical composition is an important factor in the complex process of physical and chemical disintegration. The mineralogy of tuffisitic kimberlite breccias from two localities, the Cullinan and Venetia mines, is compared with special reference to the occurrence of associated clay minerals. The clay mineral composition influences the engineering properties of these rock types. It is illustrated how the presence of swelling clay components can be confirmed by ethylene glycol treatment and chlorite minerals by heat treatment using X-ray diffraction. Smectites are present in both tuffisitic kimberlites, dominant at Venetia while chlorite is more frequent at Cullinan. More tuffisitic kimberlite breccias samples from venetia were also characterized. It was found that kimberlite disintegration is correlated with the presence and abundance of smectite.

Jan 1, 2006

By W. J. Kotzé

Die derde colloquium van die Spesialiste-afdeling van die SAIMM is op 19 November 1980by die Universiteit van Pretoria gehou en is deur sowat 40 mense bygewoon. Dr J. P. Hugo tree as Voorsitter op en heet al die aanwesiges welkom, en stel elke spreker om die beurt aan die vergadering voor.

Jan 1, 1981

By R. Drummond

The fourth Teetered Bed Separator (TBS) has just been installed in Australia, and trials have been run in many sites. There is a growing recognition of the potential advantages of using TBS technology to treat coal in the ?3+0.25 mm size range, at cut points below 1.60. From these activities, there has been a substantial growth in knowledge with respect to application engineering and operational functions. The paper briefly describes the installations, including flowsheets, and so provides a background to the potential deployment of TBS technology. There are a large number of potential applications for TBS technology, including treatment of fine ROM coal in new plants, or in upgrade situations for re-processing of spiral product, or scavenging coal from coarse tailings. As well, cost effective capacity upgrades are possible by using TBS units for treating the sands size fraction. Issues arising from Australian TBS installations and application engineering are also discussed.

Jan 1, 2002

By M. Gomo, L. S. Mokhahlane

"Underground coal gasification (UCG) is an unconventional mining method that converts coal in situ into a fuel gas that can be used for electricity generation. Residue products from UCG have the potential to leach into surrounding groundwaters. The geochemistry and leaching dynamics of these products are explored in this study. The products include char, ash, and the heat-affected zone in the surrounding rocks. Core samples from the pilot plant at Majuba are the first ever to be recovered from a UCG cavity in Africa, and they give key insights into the geochemistry of the gasification zone. Mineralogical and chemical analyses were performed on the samples, and acid-base accounting (ABA) was used to predict the acid-producing capacity of the gasification zone, particularly for char samples. Some of the char contained pyrite, although not all samples were acid-producing as determined by the ABA analysis. The ABA results showed that some of the unburned coal has moderate levels of sulphur, which could be the driving medium for acidic conditions. The ABA analysis indicated that water in contact with the gasification zone would eventually have a pH lower than 7, which could lead to acid rock drainage. These results form part of a preliminary investigation into the geochemistry of the reaction zone, post gasification. IntroductionUnderground coal gasification (UCG) is an unconventional mining method that converts coal in situ into a fuel gas that can be used for industrial purposes, including electricity generation. The gasification process leads to the formation of a cavity composed of char, rubble, and void space (Bhutto, Bazmi, and Zahedi, 2013). Residue products from UCG have the potential to leach into groundwater. These products include char (devolatilized coal), which can generate acid rock drainage (ARD). ARD is caused by the oxidation of sulphide minerals, which acidifies the leachate, thus increasing the solubility of some environmentally toxic metals (As, Cd, Hg, Pb, Zn, etc.) (Bouzahzah et al., 2015).The main source of ARD is oxidation of sulphide-bearing minerals due to interactions with oxygen, water, and microorganisms (Simate and Ndlovu, 2014; Kefeni, Msagati, and Mamba, 2017; Bouzahzah et al., 2015). Although ARD occurs naturally, it can be enhanced by mining activities that escalate exposure of sulphide minerals to water, air, and bacteria (Simate and Ndlovu, 2014). At the Majuba pilot plant, the unburned coal remaining in the cavity has been in contact with groundwater since the gasifier was shut down in 2013. It is possible that in a commercial UCG plant, most of the coal will be consumed and no unburnt coal will be left in the cavity. Most of the sulphur will be converted to H2S during the gasification process and transported with the syngas to surface, where it can be removed and captured as elemental sulphur."

Oct 1, 2018

By J. P. Harrison, J. A. Hudson.

ABSTRACT: When considering the rock stress component of rock mechanics design, the basic procedure is to consider the pre-existing stress-state in the rock mass and then estimate the disturbance to this stress state as a result of engineering excavation. Failure criteria are applied to the final stress state to establish whether failure will occur. However, during the evolution of the stress state, the failure locus may be reached before the anticipated failure state and, in this case, failure will occur unexpectedly. This indicates that the complete stress path (defined as the variations in magnitudes and orientations of the stress tensor components resulting from engineering-induced or natural changes) must be considered. We list a set of stress path principles with their corollaries and then introduce a new and powerful method for simultaneously illustrating changes in the six independent components of the stress tensor. This method plots the magnitudes of the principal stresses above their orientational paths on the hemispherical projection, to provide a three-dimensional stress path locus for each of the three principal stress components. In connection with this presentational device, we illustrate a number of concepts associated with the stress path in rock engineering. For example, we show how the minor principal stress approaches zero at an unsupported excavation face, the interchange of the trajectories of two principal stresses when their magnitudes become equal, and the influence of the bounds on the principal stresses given by strength criteria. RESUME: Si on s’interesse à la composante “contrainte” lors d’un dimensionnement en mécanique des roches, la méthode de base consiste à considérer l’état de contrainte pré-existant dans le massif rocheux, puis d’estimer la perturbation à cet état générée par l’excavation projetée. Des critères de rupture sont appliqués à l’état de contrainte final pour établir si une rupture va se produire. Cependant, lors de l’évolution de l’état de contrainte, la surface critique peut être atteinte ce qui provoquera une rupture anticipée et, dans ce cas, cette dernière sera inattendue. Cela indique que le chemin de contrainte complet (défini par les variations de l’intensité et de l’orientation des composantes du tenseur des contraintes liées à des causes anthropiques ou naturelles) doit être pris en compte. Nous présentons un ensemble de règles pour les chemins de contraintes ainsi que leurs corollaires et, ensuite, nous introduisons une méthode, nouvelle et puissante, pour présenter simultannement les changements des six composantes du tenseur des contraintes. Cette méthode consiste à tracer l’intensité des contraintes principales sur le chemin d’orientation des contraintes à l’aide d’une projection hémisphérique afin d’obtenir le lieu, en trois dimensions, de chaque contrainte principale. En relation avec cet outil de représentation, nous illustrons certains concepts associés au chemin de contrainte en ingénierie au rocher. Par exemple, nous montrons comment la contrainte mineure tend vers zero à la surface d’une excavation sans soutenement, le changement de direction des deux contraintes principales quand leur intensité deviennent égales, et l’influence des conditions aux limites sur les contraintes fournies par un critère de rupture. ZUSAMMENFASSUNG: Bei ingenieurmassigen Taetigkeiten in Felsgesteinen ist es noetig die ungestoerten Gesteins Stress Componenten, die vor einem anthropogen Eingriff im Gestein vorhanden waren, zu kennen und erst dann Vorhersagen ueber Stoerung des Stress Zustandes, der durch einen ingenieurmaessigen Eingriff hervorgerufen wird, herzuleiten. Kriterien fuer das Versagen werden im letzten Stadium, des Stress Zustandes angewendet, um zu erfahren ob ein Versagen wohl eintreten wird. Es ist jedoch zu beachten, dass waehrend des Stress Aufbaus ein oertliches Versagen eintreten kann, welches vor dem eigentlichen, erwarteten Versagens Zustand auftritt. Diese Moeglichkeit weist darauf hin, dass der gesammte “Stress Path” (definiert durch die Variationen der Stress Tensor Komponenten in Richtung und Groesse, hervorgerufen durch ingenieurmaessig hervorgerufene oder natuerlich Vorgaenge) betrachtet werden muss. Wir fuehren eine Liste der “Stress Path” Prinzipien auf und stellen dann eine neue und wirksame Methode zur gleichzeitigen Darstellung der sechs unabhaegigen Komponenten des Stress Tensors vor. Diese Methode stellt die Groesse der “Principal Stresses” in Abhaengigkeit von ihrem rauemlichen Weg auf einer hemispherischen Projektion dar und erlaubt hiermit eine drei dimensionale Darstellung fuer jeden Ort des “Stress Path’s” in die drei Haupt Stress Komponenten. Im Zusammenhang mit der hier gegebenen Darstellungsart, verdeutlichen wir eine Reihe von Konzepten in der Felsmechanik. Wir zeigen zum Beispiel, wie der “Minor Principal Stress” Null zustrebt an einer Wand von einer nicht abgestuetzten Ausschachtung, den Austausch von Trajektorien zweier “Principal Stresses” wenn ihre Groessen sich gleichen, und den Einfluss der Groesse von “Principal Stresses” bei gegebenen Kriterien des Festgkeits Versagens.

Jan 1, 2003

By G. Apsey

Eutectic freeze crystallization (EFC) is a novel technique for the recovery of pure salt and pure water from hypersaline waste brines. It is therefore a promising technology for the treatment of industrial waste waters. The impurities caused by crystallizing salt out of multi-component brines by EFC have not yet been investigated, however. To these ends, the selenium impurity found in sodium sulphate, produced from the waste brine of a platinum operation, was investigated. It was believed that the similarity between sulphate and selenate ions allowed isomorphous substitution of selenate ions into the sodium sulphate crystals, which was the likely cause of impurity uptake. It was found that the presence of sodium chloride in the industrial brine promotes the uptake of selenium, while ionic strength of the brine and mass deposition rate of sodium sulphate did not have a significant effect on the selenium uptake. Isomorphous substitution is predicted to be the most significant mechanism by which all impurities will be taken up when applying EFC to other industrial waste brines.

Jan 1, 2013