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By James Rowland, Marcia Harris, Richard Mainiero, Michael Sapko

All explosive materials produce a cloud of reaction products, the most toxic of which is nitrogen dioxide (NO2). In the study reported here, 4.5-kg (10-lb) charges of blasting agent confined in either thin-wall 10-cm (4-in) diameter galvanized pipe or 10-cm (4-in) schedule 80 seamless steel pipe were detonated in a closed chamber. The detonation gases were analyzed for NO2, nitric oxide (NO), ammonia (NH3), hydrogen (H2), carbon monoxide (CO), carbon dioxide (CO2), nitrogen (N2), oxygen (O2), and methane (CH4). Data were evaluated to determine the kinetics of the oxidation of NO to NO2. Analysis revealed that the only mechanism for NO loss for the conditions existing in the chamber was the reaction 2NO + O2 6 2 NO2. The rate constant was 2.08 ?? 10-38 cm6 molecules-2 sec-1 for the rate equation -??d [NO]/dt = K ?? [NO]2 ?? [O2] for NO concentrations up to 100 ppm. The rate constant is in agreement with that recommended by Baulch, Drysdale, and Horne (1973).

Jan 1, 2006

By Stephen Mansfield

Analysing how accurately a blast design is implemented is one of the cornerstones of a successful operation, and critical for mine optimisation. This paper presents a concept that involves the collection and analysis of data for the five stages through which a blast transitions, from budget through to implementation.

Feb 1, 2020

By Robert L. Martin, Brian W. Stump

"The Black Thunder Mine is located in the Powder River Basin of Northeastern Wyoming. Over 39.2million tons of coal were produced at the Black Thunder Mine in 1996. Just over 100 million pounds ofANFO/Emulsion blend were consumed in that same year. Currently around 30% of the overburden is cast to final with the use of explosives. With plans for a mine expansion, explosives will continue to play a very vital roll well into the future."

Jan 1, 1997

By Steve Dillingham

The origin of the written blasting log or shot report can likely be traced back to the earliest annals of blasting and record keeping. These records were, for the most part, a way of checking inventory, production progress, or billing, and not necessarily designed with the intention of being used as a legal document in a court of law. As our litigious society has evolved to include far reaching regulatory requirements, however, the blasting log has developed to support and aid in the defense of the common blaster from blasting lawsuits by providing a comprehensive written report of his or her actions.

Jan 1, 2002

By Mark A. Williams, James D. Humphrey

Without question, draglines are one if not the most effective tools available to the surface mining industry for overburden handling. With few moving parts and a two- or threeman crew, this machine silently sits and chews into millions of yards of overburden annually. A 100 cubic yard machine operating for 30 years will excavate three-quarters of a billion yards of material during that time. That is 750,000,OOO yards of material!

Jan 1, 1990

By Anderson da Cunha Meireles, Pedro Garcia, Ernst Young, Leandro Coelho, Carlos Eduardo Soares Feliciano, Key Fonseca de Lima

Rock blasting is a crucial technique employed in mining construction and quarrying industries to fragment large rocks into smaller, more manageable pieces. However, it often generates ground vibrations that can pose significant challenges. This study explores the application of Conformal Prediction (CP) in the context of rock blasting to develop predictive models that estimate blasting-induced vibrations and quantify the associated uncertainties. Various machine learning models were integrated within the CP framework using MAPIE and CREPES libraries. The results demonstrated the effectiveness of CP in providing statistically reliable prediction intervals, making it particularly useful for applications where the stakes of underestimating uncertainty can be high.

Jan 21, 2025

By M Dandeneau, P I. Rajic, K D. Murphy, M B. Johnson, T J. Tope

"Manufacturers and users of energetic material [i.e., propellants, explosives, pyrotechnics (PEP)] generate unserviceable, obsolete, off-specification, and damaged items that are characterized as reactive waste. These items must be safely treated and disposed of or reclaimed/recycled, thereby controlling existing waste inventories at manageable levels. The most commonly used disposal and treatment method, particularly at U.S. Department of Defense (DoD) installations, is open burning/open detonation (OB/OD). However, regulatory constraints and the inability of operators toobtain permits required for treating these waste has led to the recent reductions and limited use of OB/OD treatment at many installations."

Jan 1, 1995

By Frank Wilder, Mark Ferrero

One of the challenges currently facing the explosives industry is how to transition its workforce and its business systems to respond to the increasing pressures for improved inventory and records management. The pressures applied by many U.S. federal and state agencies, such as the Bureau of Alcohol, Tobacco, Firearms and Explosives (ATF) and the Department of Environmental Protection (DEP), as well as regulatory agencies around the world, are increasing the need for accurate inventory accounting of explosive materials and blast documentation. With blasting companies now facing regular documentation audits, potential liability issues may arise due to the inconsistent or missing documentation.

Jan 1, 2006

By Ann Barron

“Hurry up” is the latest battle cry at explosives companies struggling to stay in compliance with the ever-growing onslaught of government regulations. The pressure continues to mount on industry professionals who face stiff penalties if their companies fail to comply with the law. Such penalties can range from monetary fines and revocation of blasting permits and licenses, to increased liability for civil claims or even criminal charges.

Jan 1, 2006

By Catherine Johnson, Barbara Rutter

The shock tunnel located at the Missouri University of Science and Technology Experimental Mine is 65 feet 9 inches (20.0406 m) in length. The tests performed inside of this tunnel are either arena tests or shock interaction and transfer (SIT) tests. Arena tests simulate a large open air blast, with lower explosive weights, by elongating the impulse of the blast wave. SIT tests are conducted to determine how the produced shock wave interacts and transfers its energy into a target object located at the end of the tunnel. The target used in this research is multilayered, with each layer being a different material. The targets are 2 ft. by 4 ft. (0.6096m by 1.2192m) pieces of Medium Density Fiberboard (MDF), DOW polystyrene foam insulation, and gypsum drywall. The order of these materials varies with each test. This shock tunnel is unique, because the geometry changes along its length. To fully understand how the shock waves are affected by these changes, a working model was needed. The second purpose of this model is to confirm the maximum charge size of 400 grams (14.11 oz.) of C4 that can be detonated inside the tunnel without causing damage to or failure of the tunnel, thus reducing the amount of time needed in downtime and repair. The model predicts pressures in various locations both within the tunnel and the attached target, thus assisting in determining where failures would likely occur. In the process of generating this model, several problems were encountered, including filling the tunnel with air, meshing the complex geometry, and creating the tunnel in a CAD system. This paper will discuss how these problems were solved. A working model was created by using ANSYS Explicit Dynamics and ANSYS Autodyn. The tunnel geometry file was created using SolidWorks and includes the complex geometry changes along with the target and its mount located at the end of the tunnel. The results produced by the model were compared to the field SIT tests. The comparison of the results from both the model and the experimental testing showed a similar trend in the pressure traces.

Jan 1, 2018

By Gene Baker

A new Safety Library Publication (SLP), SLP-27, which is titled “Security in Manufacturing, Transportation, Storage and Use of Commercial Explosives” was recently released by the Institute of Makers of Explosives (IME). SLP-27 makes recommendations for both general security and enhanced security at explosives sites when security risk levels, declared by the Department of Homeland Security (DHS) using its Advisory System, have temporarily increased.

Jan 1, 2006

By MacDonald B. Johnson, Douglass P. Bacon

With the advance of science, rise of public interest in environmental matters, and continuing erosion of air quality, Federal and state regulators are demanding an increasing complex array of data concerning emissions produced by burning and detonating energetic materials. The U.S. Department of Defense, one of the world's largest consumers of energetic materials, now must characterize combustion products resulting from open burning/open detonation disposal operations. The catch-all phrase "below detection limits" no longer satisfies the regulators who now want testing to delve into the ppt level for volatile organic compounds and ppt level for semivolatile organic compounds.

Jan 1, 1995

By Satish Kate

Indian limestone mines which are highly mechanized in operation and supply limestone to the cement plants have been quite successful in devising ways and means to optimize blasting parameters, so as to have best fragmentation, powder factor, and cost of excavation. In primary blasting mechanized or manually mixed ammonium nitrate Fuel Oil is quite popular in dry holes, and in case of watery holes conventional packaged slurry/emulsions are being used. In order to avail the low density characteristics of the ANFO, some limestone mines have also used Saw Dust and Rice Husk along with ANFO. A number of field trials have been undertaken to explore the suitability of mixing rice-husk and saw dust with ANFO. Presently, about 10% of rice husk/saw dust is being used only to expand the explosive column. The main technical consideration for the use of saw dust/rice husk, has been to reduce the final density and increase the occupancy of explosive in the blast-hole. This not only lowers the detonation pressure in the blast holes, but also reduces cost of explosive without compromising on the fragmentation quality. Besides, with sleeping of the charge there is no substantial fall in the blast quality.

Jan 1, 2006

By W. De Graaf, C. Mkumbo

Bulyanhulu Gold Mine Limited (BGML) commissioned a project of sinking a Bulk Air Cooling Shaft during its programme to improve the ventilation system on the mine. As part of this project, a ventilation drift had to be developed and holed into the Main Shaft at 4920 Level. AEL Mining Services (AEL) were requested to provide a technical solution, which included monitoring of blast induced vibrations and to design drilling and timing plans to ensure blasting activities on the vent drift were conducted without disrupting the main shaft’s infrastructure.

Jan 1, 2011

By Paul Ross, Harry Burchett, Lou Case, Calvin J. Konya

"The Cumberland River in Harlan, Kentucky has flooded the town for numerous years. TheU.S. Army Corps of Engineers funded a project to divert the river. The project consisted oftunneling through a mountain to divert the river. The approaches to the tunnels requiredcontrolled blasting to create noses to help channel the water and debris into the tunnels.The geologic structure was such that conventional presplitting techniques were notproducing the desired results and were causing severe backbreak. Replacement of the rocknoses with concrete would cost about a million dollars; and therefore it was important tosave them if at all possible. Blasting techniques were developed which allowed the projectto be successfully completed. This paper will discuss the case history of the controlledblasting procedures."

Jan 1, 1993

By Italo Onederra, Miguel Araos

"In order to characterize non-ideal explosives, the explosives industry rely on unconfined velocity ofdetonation tests and where possible underwater pond tests. The information obtained from such tests isquite helpful, however it cannot tell us much about the dynamics of the detonation reaction process. The detonation process has been studied for ideal explosives and the reaction zone length have been measured. However, for non-ideal explosives, that type of information is not available. Therefore, the primary aim of this work was to capture the detonation process of a non-ideal explosive using high speed video camera to determine the zone length."

Jan 1, 2017

By Dyno Nobel

Impact of Enhanced Security on Operations Budgeting - What is the “value” I receive for enhanced security? Is there a “return” for the money I spend? Regulatory driven Economic driven

Jan 1, 2006

In the office, on the wall to the right of my desk is a large map of the world. Some people stick pins in maps like this to show where they’ve been. If I did that my map would be a mess and look like a pin cushion. I was so fortunate to have been able to see how people live and blast in other parts of this beautiful planet. We l l , maybe some parts weren’t so beautiful and maybe some parts that were beautiful were hell holes for those living t h e re . Every time I re t u rn to the good old US of A, I say a small prayer in thanks for having been born and raised in a land of freedom and plenty. So many places and people have not been so blessed.

Jan 1, 2004

By John Brulia

It has been said that the only thing that remains constant is change. After more than 33 years in the explosives industry, I do not take any exception to that adage. I have seen changes in people, changes in ownership of companies-both small and large, domestic and international; changes in products; changes in the way we use products; changes in the way we handle products; changes in regulations; and last, but not least, changes in our perceptions of threats to our industry.

Jan 1, 2008

By Pharis E. Williams

The ability to predict the performance of an explosive relies upon having a Reaction Rate Law and knowing its functional dependence upon various parameters of the explosive. In particular, emulsion explosives have a matrix cell size and may be sensitized with glass or plastic microballoons. The cell size dependence should. be very nearly the spherical grain burning dependence upon web that appears in the reaction rate laws for ball gun powder. The dependence of the reaction rate law upon the parameters of the sensitizing microballoons has been explored using hydrocode analysis of the pressure field produced by the collapse of a microballoon. This pressure field provides an increase in pressure in the vicinity of the microballoon which, in turn, increases the rate of reaction within this field and provides the energy release that must be achieved in order to have a steady state detonation for use as a blasting agent. Hydrocode analysis allows the determination of an approximate functional form for the reaction rate law which shows the dependence upon the size, type, and quantity of microballoons. This presentation includes the theoretical background and the determined functional form of the reaction rate law.

Jan 1, 1995