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By Quinlan M. J, Ratcliffe J. S

Chemical kinetics is a dependent process which usually correlates the rate at which a reaction proceeds with the mechanism descriptive of the manner by which reactive particles interact. Given the latter, the object gen- erally is to find the reaction rate dependency in terms of an intensive property of the system - number of reactive particles present, and of the energetics of the system - usually temperature. Chemical kinetics depend on a dem- onstration that reaction considerations alone control the phenomenological process under study. For these rea- sons, chemical kinetics are usually involved in homogeneous gaseous systems. Even in liquid homogeneous sys- tems earliness or lateness of reactant mixing rather than chemical kinetics may be controlling. Considerations of transport phenomena are involved in heterogeneous systems and often control the observable rate:an additional problem in such systems is to apportion the rate due to mass transfer - usually a linear process - and that due to reaction which may be linear or non-linear. Experimentally, conditions are often chosen so that only one consideration controls but this becomes more difficult where solid phases are involved. Kinetic modelling involves considerations of chemical kinetics, transport phenomena, and factors attributable to the physical environment in which the process takes place. The latter two considerations may be quite different as between experiment and plant. The kinetic model may be a mathematical representation of a conceptual mech- anistic model of the reaction. Alternatively, it may be an empirical relationship resulting from, for example, some curve fitting procedure applied to experimental data. The latter approach may be necessary where the system is particularly complicated.

Jan 1, 1975

The Escondida Porphyry Copper Deposit, located in Chile's II Region 160 Km to the southeast of the city of Antofagasta, is currently owned by Minera Escondida Limitada, a company comprising The Broken Hill Proprietary (57.5%), Rio Tinto Zinc (30%) a group of Japanese companies represented by Mitsubishi Corporation (10%), and the International Financing Corporation of the World Bank (2.5%) (Fig.l)By 1983, most of the reconnaissance drilling was completed and prefeasibility studies were regularly updated as new drilling results were reported and project concepts re-evaluated (Fig.2). In October 1982 the project was transferred from Exploration Management to Operations. By the end of 1984 project pre-development activities, including inpit development drilling, geological exploration, water resource definition, an underground bulk sampling program and the initial project feasibility report, were completed.

Jan 1, 1990

The mechanisms of fragmentation in homogeneous materials and structured rock mass are reviewed. A method previously used to predict vibration damage to the remaining rock is extended and shown to be valid for the prediction of fragmentation in the rock mass removed by blasting. The effectiveness of different explosives in different types of rock blasting is discussed.

Jan 1, 1990

By Knasmillner

During blasting body wave interaction with geometrical surfaces induces Rayleigh-waves which propagate along free surfaces, e.g. crack faces or delaminated rock layers. These Rayleigh-waves carry most of their energy within a very shallow surface layer and propagate with very little attenuation in real rock materials. Upon interaction with a crack front a very strong mixed mode stress intensity factor may result and lead to fracture initiation. On the basis of experimental photomechanical results the history of dynamic stress intensity factors Kt and K2 will be studied in Detail.

Jan 1, 1990

By Erceg MM

The Waft River gold deposit is hosted by low grade metasediments which have been intruded by a dacite/andesite porphyry complex. Wafi River is classified as a high sulphur, epithermal type gold deposit having: a high sulphur content, a close association with calc-alkalic igneous rocks, zoned advanced argillic and argillic alteration, and enargite group minerals. Gold occurs as minute inclusions in pyrite and pyrrhotite within intermediate dickite/kaohnite - interlayered illitic clay alteration zones. Central leached silicic, alunite and pyrophyllite zones and peripheral chloritic zones are low in gold. The gold mineralisation at Wafi is interpreted to have been predominantly caused by mixing of hot upwelling acidic magmatic mineralised fluids with cool, neutral meteoric/hydrothermal fluids within permeable sediments. Locallised high grade breccia zones are encountered within the porphyry. An initial resource in excess of I million ounces Au has been defined.

Jan 1, 1990

By Landy D. M, Ward M. O, Power W. L

Geological structures are irregular and intricate, so creating a 31) solid geology model is a complicated process. A software system can only partially automate this process, since geological knowledge and experience are required. Therefore, the interaction of a geologist is critical for such a system. This paper discusses some useful advanced functions for enhancing the visualisation and manipulation of 3D solid geology models: flexible attribute display, multiple views, auxiliary display objects, and geologically sensitive operations. It also describes some experiments to explore the effectiveness of these functions and presents sample output. Most existing 3D solid geology modelling systems are implemented in an ad hoc way, which greatly reduces their reusability and extensibility. This paper presents a generic framework for 3D solid geology modelling systems, which is based on object-oriented technology. The deficiencies of current systems may be improved by using this generic framework. A modelling process based on drillhole data is discusses as a case study.

Jan 1, 1995

By Grey D, Turner R, Capsanis J

Coal fines are recognised to have a major impact on the cost and efficiency of the recovery of saleable coal. Fines affect the productivity of the whole mining cycle because of the low yields obtained in washing this material as well as affecting the moisture content and handling characteristics of the final product.In 1990, Coal and Allied Hunter Valley Mine initiated an internal study into coal fines based on the assumption that a reduction in fine coal in ROM material will lead to increase yields in the preparation plant. The initial results of this study indicated that the level of fines in the ROM coal can be reduced by more than 40 per cent by simple changes in blast design and implementation.

Jan 1, 1992

By Arumba J

In the Mount Victor area of the Eastern Highlands Province, re- connaissance geological mapping and new micropalaeontological data have revealed the existence of at least three small thrust- bound windows exposing late Middle to Late Cretaceous (Late Aptian-Early Albian and Late Santonian-Maastrichtian) sedimen- tary rocks and pillow lavas, Latest Paleocene- Earliest Eocene pillow lavas, and Latest Paleocene-Earliest Eocene bathyal micrites. Late Middle Eocene to Late Eocene inner neritic bioclastic micrite units also occurs in thrust contact with Middle Miocene Yaveufa Formation volcanolithic conglomerates. The Cretaceous and Early Tertiary units appear to be thrust-bound and are best exposed in a window just south of Mount Victor, and in two smaller windows to the east. The inner neritic Eocene limestone occurs in a thrust-bound sliver within the Yaveufa For- mation near Obura. The windows occur within extensive out- crop of Early Miocene Omaura Formation and the Yaveufa For- mation. Thin-bedded grey mudstone, siltstone and sandstone, typical of much of the Chim Formation form only a small part of the exposure of Cretaceous rocks. Thick-bedded volcanolithic conglomerate, spilitic pillow basalts, and welded basic tuffs domi- nate the Cretaceous section. The stratigraphy and structure of the Mount Victor area is similar to the Menyamya area, the Aure Scarp, and perhaps the Tapini area. This study has raised the possibility of widespread thrust- ing in the Kainantu area, and suggests that the boundary between the Omaura and Yaveufa Formations is thrusted, at least locally.

Jan 1, 1997

The paper reviews some characteristic features of feasibility studies and discusses the need for a wide scope at the pre-feasibility stage. The performance of recent Australian gold mines against the predictions contained in their respective feasibility studies is examined, resulting in a recommendation that feasibility studies need to be improved The advantages to be gained from having a feasibility study reviewed by an independent authority are discussed, and some of the reasons for using consultants are listed. Two examples of successful optimisations in the early stages of pre-development studies are described briefly and the benefits achieved are presented. The paper concludes that feasibility studies need improvement to enhance the confidence of investors in the mining industry.

Jan 1, 1991

The uptake of nickel into the lattice of pyrrhotite,Fel_oS has been studied experimentally in the temperaturerange 200 DC to 760 DC. Nickel from both aqueous solutionsand salt melts diffuses rapidly into the sulphide latticewith ,an accompanying rel~ase of iron into the solution ormelt. The rate of uptake of nickel and its diffusion intothe sulphide lattice have been followed ,by opticalmicroscopy and by analysis with an electron probe microanalyser.Some geological consequences of this phenomenonaffecting the distribution of nickel in rocks associatedwith nickel-iron sulphide ores are discussed.

Jan 1, 1980

By S Rice, A Midlin

Many of the stacking and reclaiming machines employed in the mining industry today are operating in ways that were never envisaged in the days before they were commissioned, with greater throughput, increased annualised operating hours and load cycles well in excess of their original specification requirements being the norm. In many cases these machines were supplied prior to the widespread use of finite element modelling or, in the era when such software became commercially available, those supplied designed using simplified and/or coarser meshes than would be employed today. With many of these machines being expected to operate for many years to come, it is important that their ongoing reliability be maintained and their operational limits understood. In this paper, a case study is used to outline the method required for estimating the fatigue life already consumed and the likely real life left in a machine. By reference to the machineÆs prior operating history, the use of strain gauges in the field and the development of finely meshed finite element analysis (FEA), a coherent picture of the machineÆs operational state can be generated and then investment/maintenance decisions made to ensure continuity of machine operation.

Jan 1, 2007

By Wang SS, Frattaroll DR

In the development of novel sulfide collectors, especially for the low-lime and acid circuits, flotation of chalcopyrite, chalcocite, covellite and pyrite was studied with both new and commercially available S- containing collectors. The natural float- ability of sulfides, water quality, and redox potentials - all of which were considered im- portant in assessing collector strength and selectivity - were also investigated. Chalcopyrite exhibited the highest natural floatability. The response to most collectors, however, was chalcocite > covellite > chalcopyrite > pyrite. Water quality had a very significant effect on both natural and collector-aided floatability. De- ionized water and tap water had a flotation suppression effect compared with doubly- distilled water. Flotation results with single minerals are correlated with those for copper and pyrite from natural ores. Several novel collectors have now been developed for sulfide flotation in acid, neutral or mildly alkaline circuits. The results for four of these collectors, which have shown promise in commercial applications, are discussed in this paper.

Jan 1, 1986

By P J. Clark, A W. Fisher, R G. Ford

Site characterisation of subsurface contaminant transport is often hampered by a lack of knowledge of site heterogeneity and temporal variations in hydrogeochemistry. The use of a regional-scale data compilation derived from satellite imaging is discussed with respect to directing design of site characterisation to monitor the fate of a Dense Non-Aqueous Phase Liquid (DNAPL) plume in Nevada. Evaluation of the drainage basin contributing to the groundwater flux into the study site was used to re-assess the site conceptual model and re-direct the characterisation effort. The use of highly resolved measurements of subsurface hydrogeochemistry in space and time were employed to identify the predominant biogeochemical processes controlling arsenic transport during discharge of groundwater into a pond at a site in Massachusetts. Direct-push conductivity measurements coupled with vertically-resolved sampling within the pond and adjoining aquifer demonstrated spatial and temporal variations in dissolved arsenic within groundwater and the pond water column and sediment pore water. Spatial variability was observed over the scale of centimetres to metres, and temporal variations were observed over the scales of days (following storm events) to seasons. Microbially-driven redox processes maintained anoxic conditions in groundwater and at the sediment-water interface (iron and sulfate reduction) and exerted both a direct and indirect influence on arsenic solution speciation and partitioning to surface water sediments.

Jan 1, 2004

Techniques and results achieved during the excavation of the Melbourne Underground Rail Loop (HURL) are summarised and discussed in the context of the various restraints present in a typical urban construction project. Mechanical methods (as distinct from those utilising blasting)accounted for the bulk of the excavation. Ground support was critical in this particular geological excavation setting, but is not discussed in detail except insofar as it constitutes a restraint to excavation progress.

Jan 1, 1978

By A Suokas

Boliden Tara Mines Ltd, located in County Meath Ireland, produce in excess of 2.5 million tonnes per annum of ore from the underground resource located 40 miles north west of Dublin. The zinc-lead ore is mined using long hole open stoping techniques, with ore treated on site. The operation is continually searching for new ways to improve productivities at the mine, and have employed a detailed data acquisition and reporting system on site to provide feedback around performance. One area where both Boliden Tara Mines Ltd and Orica Mining Services believed improvements could be made was in the application of bulk emulsion technology through an Orica supplied but Tara operated Maxipump Delivery System for all production and development blasting at the mine. Both parties committed to the evaluation of this technology at the mine, however the capital cost and technical and economic changes meant the project needed to be diligently investigated and any improvements documented. The first stage of this project was for Orica Mining Services personnel to visit the operation, and conduct a detailed analysis of the operationÆs performance over the past 12 months. The next step in moving forward was then to commission and utilise the customer operated emulsion system at the mine. This was then followed with the collation and analysis of data from the demonstration period to examine and document the benefits of the system. This paper is a summary of the observations made during the site inspection and the data analysed to date, and has been used in determining operational and financial improvements in the comparison between a Maxipump Emulsion Service and the current ANFO loading systems.

Jan 1, 2005

CONTENTSSummaryIntroductionGeographical and Geological Outline of the RegionGrowth of the Mining IndustryTable 1: Production StatisticsGeneral GeologyRecent Alluvium and River GravelsSambeto SeriesMudstone and Basalt ContactVatukoula SeriesIntrusivesStructureGeologic HistoryLodesTable 2: Principal Lodes and Their OrebodiesMineral Assemblage and ParagenesisOre Shoots and Their ControlEmperor MineLoloma MineDolphin MineExplorationConclusionAcknowledgmentReferencesSUMMARYThe Tavua Goldfield was found in 1932 within a basin, both topographical and structural, near the sea on the north side of Viti Levu, Fiji, and has produced over £13,000,000 (Fijian) worth of gold and silver from the three mines...

Jan 1, 1953

By Field R. V, Graieg O, George T. J

The design, construction and operation ofa laboratory scale rotary pot kiln are outlined. Charges ofup to 3 kg can be heated to temperatures up to 1200°C in a controlled atmosphere. Some examples of pyrometallurgical investigations carried out using the kiln are briefly described, including thermal reactivation ofcarbon using steam at 550-850°C, high temperature testing ofkiln liners for corrosion resistance to fluoride, and calcination oflimestone. Results obtained from these trials allow either direct scale-up to the Engineering Chemistry Laboratory's pilot-scale (50-100 kg/hr) rotary kiln or modifications to be made to commercial scale processes and/or equipment.

Jan 1, 1986

Mixers are commonly used for the transfer of oxygen in gas-liquid-solid reactions in minerals processing. The process rate is usually controlled by two steps: gas-liquid mass transfer and reaction kinetics. Some examples are described along with the factors used for analysis of the mass transfer design problem. Typical oxygen rates and appropriate types of aeration systems or mixers are reviewed. The commonly used Rushton turbine has limitations in a number of mineral processes. The development and characteristics of the LIGHTNIN A315 axial flow gas dispersion impeller are described. Some practical examples which highlight its advantages are briefly described.

Jan 1, 1992

By Penttila V

The Paleoproterozoic Hitura Ni-Cu deposit in western Finland is in an ultramafic igneous complex composed of two subvertical plug-shaped bodies embedded in intensely migmatised felsic gneisses. The ultramafic complex is not far from a north-south trending graphitic and sulphidic gneiss zone interpreted to be a primary sulphide-graphite unit in the metasedimentary sequence. The sulphide accumulation exists as a zone parallel to the contact of the northern ultramafic body. The ultramafic rock types, now mainly serpentinites, have primarily been olivine adcumulates in the core grading to olivine orthocumulates and pyroxenites towards the margins. Coarse-grained felsic pegmatite veins injected serpentinite where they now exhibit prominent zoned alteration rims of chlorite, antophyllite and talc. The serpentinite core of the body was primarily an olivine adcumulate derived from a tholeiitic or high-Mg basalt parental magma with about 11 wt % MgO. Metamorphism and alteration have totally changed the igneous mineral compositions and the rock types are serpentinites (from olivine adcumulates), ambhibole-bearing serpentinites and amphibole-chlorite rocks (from pyroxenites). As the result of CO2 alteration talc is an accessory mineral throughout the serpentinite. Like silicates, also sulphide minerals are altered. In the core of the body the low-grade sulphide dissemination still reveals primary igneous interstitial forms. The core sulphides are now mackinawite, pentlandite and valleriite instead of primary igneous pyrrhotite and pentlandite derived from Mss. At the marginal zone the heavy dissemination and net-textured sulphides display pyrrhotite-pentlandite-magnetite intergrowths with magnetite films along cleavage of sulphides, mackinawite in pentlandite and exsolution textures of different low-temperature pyrrhotite phases as the result of alteration processes. Mechanically weak rocks, complicated structures and textures of the ore, magnetite and mackinawite intergrowths in pentlandite and readily-floating MgO silicates cause problems in exploitation of the deposit. Solution to problems come from selective stoping, three-step classification in grinding, froth-washing technique and on-line process control based on ore type determination from process data using an expert System

Jan 1, 1996

Broken Hill is situated at an elevation of approximately 1000 ft. above sea-level, on the Barrier Ranges, in the State of New South Wales, Australia. It is approximately 700, 280 and 330 miles from the ports of Sydney, Pirie, and Adelaide, respectively.The summers are usually hot and dusty, with a recorded maximum shade temperature of 114° F. The rainfall averages approximately 9 in. per annum.

Jan 1, 1932