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By K. A. Natarajan

Platinum electrodes are not inert as originally thought to be. The reactivity of platinum electrodes can explain their erratic behavior in many electrochemical measurements of metallurgical interest, e.g., in flotation systems, streaming potential measurements, contact-angle measurements, and in leaching systems. The anomalous behavior of platinum electrodes in redox potential measurements in aqueous systems was studied through Eh and pH measurements in water-oxygen, iron-water-oxygen and manganese-water-oxygen systems. Stability relations between Fe++ and Fe(OH)3 and between Fe(OH)2 and Fe(OH)3 were studied to judge the correspondence between experimental and theoretical equilibrium lines. The practicality of redox potential measurements in estimating ferric-ferrous ratios in aqueous systems was investigated along with their suitability as indicators in leaching operations, e.g., the removal of iron by aeration from manganese leach solutions.

Jan 1, 1970

By W. K. Katoto

The Tailings Leach Plant (TLP) of the Zambia Consolidated Copper Mines Ltd at Nchanga was commissioned in 1974 as the world's first largest successfully operated agitation leach SX-EW plant for copper production. The design, development and operation of the plant soon after commissioning termed as TLP stage II has been described by Holmes et al (1). In the initial phase the plant was designed to treat approximately 25,000 tonnes per day of current flotation tailings from the Nchanga Concentrator operations, and had a design capacity to produce 75,000 tonnes per annum of copper. Further expansion took place in 1986, and TLP stage III was successfully commissioned to treat an additional 20,000 -25,000 tonnes per day of large reserves (over 135m tonnes) of reclaimed tailings stockpiled since the early 1930's in four paddock type tailings dams (T01 to T04). The salient feature of TLP stage III expansion described by S K Mwenechanya et al (2 -3) was the installation of the world's largest Horizontal Belt Filter Plant with 26 filters each of 80 m2 filtration area.

Jan 1, 1996

By J. R. Cobble

The Bureau of Mines has developed a process to improve the leaching kinetics of diffusion controlled systems. The system features the Bureau-developed turbomill, an attrition grinder which scrubs the reaction product coating away from the unreacted mineral grains during leaching. The system can be continuously operated at any temperature up to the boiling point of the leaching agent. This paper describes the research on the dissolution of chalcopyrite with acidified ferric sulfate which forms a sulfur product on the unreacted chalcopyrite surface. This method is a hydrometallurgical alternative to chalcopyrite smelter technology which eliminates S)2 emission problems with its associated costs. Batch testing at 90? C with the chalcopyrite/ferric sulfate system resulted in better than 99-pct extraction of copper. At an optimal energy consumption of 1,520 kW h/st, 95 pct of the copper was extracted. Recent work has been directed to development of a continuous system and SX/EW treatment of the resulting pregnant liquor from the chalcopyrite/ferric sulfate leach.

Jan 1, 1991

By Fatima-Zahra Houmymid, Elena Chiriotti, Mahdi, Samy

"The Greater Paris projects involves the creation of a 200km extension of the actual public transport network on the close outskirt of Paris. In 2011, SYSTRA has been awarded the Engineering studies of a 20km underground section in the densely urbanized southeast quarter of the Parisian suburb. In order to both guide the TBM technology choice and identify and mitigate the risk due to soil settlement during tunnel boring, several analysis have been carried out and integrated into a Geographical Information System to share and manage this risk during the successive design phases of the project. The geological context‘s complexity and the Owner‘ requirements have led to the necessity of using an innovative analysis approach, leveraging both the numerical modelling analysis’s accuracy and the analytical method‘s ease of programming and implementation in a GIS, by the mean of the calibration of the analytical approach’ parameters on the FEM results.INTRODUCTIONThe Greater Paris Transport Project foresees the extension of the actual public transport network to the close outskirt of Paris through the extension lines 11 and 14, the creation of a circular new line around Paris - line 15 completed by lines 16 and 18 linking developing territories - and line 17 to Roissy-Charlesde- Gaulle airport.The SOCIETE DU GRAND PARIS (SGP) is the public institution that promotes this project and awards SYSTRA as Engineering for the 15th Line southeast section.Line 15th – South-East sectionIn 2011, the Owner SGP (SOCIÉTÉ DU GRAND PARIS) awarded to SYSTRA the preliminary and detailed design of a 20km-long underground section of Line 15, between the stations of Villejuif-Louis-Aragon and Noisy-Champs. The double-track, single-tube tunnel has an inner diameter of 8.5m (about 9.8m excavated diameter, 75m2 excavated cross-section). The tunnel is inserted in a densely urbanized context."

Jan 1, 2016

By Viktor Lishchuk, Olof Martinsson, Tobias E. Bauer, Elena Haller

Freely accessible and non-confidential real-life geological data sets from mineral deposits are desirable for the wide range of applications in research and education. However, publicly available statistical data are limited in their number and quality—they contain reduced information about geological, geophysical, geotechnical, chemical, mineralogical, and other relevant properties of deposits. This makes such data insufficient for scientific purposes. However, the amount of geological knowledge obtained for a variety of deposits in the past allows the construction of an idealized synthetic ore body model using analytical approach. Such a model could be used for education purposes and testing basic scientific theories, e.g., visualization of deposit structure; teaching sampling strategies; testing new algorithms for mine planning; or comparing geostatistical modeling methods. This paper presents an analytical approach to simulate volcanic massive sulfide (VMS) deposits and shows how synthetic deposit model can be constructed and further used for studying sampling with drilling and simulating folding and faulting.

Jan 14, 2021

By T. Karalis

Perlite is a generic term for naturally occurring siliceous rock. It is a form of natural volcanic glass the main constituent of which is amorphous silica (70-76%). Perlite, when heated rapidly to its softening temperature range, expands from four to twenty times its original volume, due to the presence of 2-6% ?combined? water, in a manner similar to popcorn as the H2O molecules vaporize and create countless tiny bubbles, which account for its exceptional physical properties: light weight (30-150 kg/m3), low thermal conductivity, cellular structure, in general. These properties make perlite adaptable for numerous end-uses, which can be distinguished into 2 categories: Expanded perlite applications in: a) Construction Materials market (e.g. Acoustical Tiles, light-weight insulating Mortars, self-levelling Concrete), b) Agriculture (e.g. Hydroponics), c) Food and Chemical industry (e.g. Filtration Media, Filler, etc.), d) Insulation and Heat resistance technology (e.g. Cryogenic vessels, Refractory Bricks, etc.). Unexpanded Graded perlite applications in: a) Phosphoric Fertilizers industry (additive in H3PO4 production), b) Foundry technology (slag-aid, insulating and heat resistance agent).

Jan 1, 2006

By Ahmet Tezcan, Zeki M. Dogan, Yalçin Kaytaz

Autogenous grinding in Turkey was first applied to quartzite where the mill is grate discharge type with an internal diameter of 2.99 m, having a length of 3.20 m and a capacity of as to 11.0 tons per hour. The second autogenous grinding was applied to a copper ore at Murgul Cakmakkaya Flotation plant of (KBI) Black Sea Copper Works having three mills 26 feet in diameter and 10 feet in length in close circuit with hydrocyclones. Recently, alterations were made in grinding circust by adding pebble mills. Furthermore, rubber liners and lifter bars were introduced pebble extractor and classifier were new features in the primary mills and circulating load was reduced by 20-50 tons per hour. At the end of these charges, capacity of each mill line was increased to 48 tons per hour with a full capacity of more than 9000 tons per day. Thirdly, autogenous grinding has been executed successfully on the slags of Samsun Smelting Plant of (KBI) Black Sea Copper Works with a mill of 20 feet in diameter and 6 feet on length having pebble mill following autogenous grinding.

Jan 1, 1992

By O. Ofor

Coal fines of less than 0.5 mm particle size, discarded as too fine for gravity separation, were subjected to flotation tests at varying pH and temperatures using modified dosages of kerosene as oil phase and methylisobutylketone (MIBK) as frother. Optimal coal recovery of over 74% was obtained using 200 kg kerosene and 4 kg MIBK per ton of coal fines at a pH of 9.7 and an ambient temperature of 26° C. The coal concentrate obtained under these optimal recovery conditions assayed 9.10% ash, 0.35% sulfur and 0.011% phosphorus, representing reductions in the ash, sulfur and phosphorus contents of approximately 75%, 43% and 8.3%, respectively. Its gross calorific value was 32.9 MJ/kg, its percentage of volatile matter measured 30.6 and the fixed carbon content was 66.3% (d.a.f). Caking tests showed the optimal concentrate has a standard welling number of 1 and is a Gray-King coke type C. These results show that the optimal flotation product could be utilized for such industrial purposes as steam raising or for processing in gasworks, but it would be unsuitable for metallurgical coke production.

Jan 1, 1993

By M. Misra, I. A. H. Schneider

The flocculation of -38 pm calcite, hematite and kaolinite aqueous suspensions by the yeast Candida parapsilosis and products derived from rupture of the microorganism was studied. Flocculation of hematite suspensions by the microorganism and its derivatives readily takes place between pH 2.8 and 11.4. Maximum flocculation occurs at about pH 6.5. Flocculation of calcite suspensions by the microorganism and its derivatives readily takes place between pH 7.0 and 11.8. Maximum flocculation occurs at about pH 10.0. Flocculation of kaolinite suspensions was less than that for the other two minerals. However, a soluble fraction derived from the rupture of the organism functioned as a good flocculant for the mineral, albeit at an increased concentration, between pH 2.6 and 11.5. Maximum flocculation occurs between pH 6.8 and 7.2. An attempt is made to relate the behavior of the various systems to the surface characteristics of the minerals and the surface and chemical properties of microorganism and its derivatives. Experimentation used to evaluate the flocculation includes actual flocculation tests, microelectrophoresis measurements and scanning electron microscopy.

Jan 1, 1994

By J. G. Groppo, A. E. Bland, B. K. Parekh, W. F. Stotts

Many coal preparation plants discard fine coal (generally minus 100 mesh) because it is difficult to beneficiate economically. At the Kentucky Energy Cabinet Laboratory (KECL), the waste streams from several Kentucky preparation plants were evaluated for cleaning with counter-current column flotation. A series of performance evaluations were conducted using a 0.05 m (2 in.) internal diameter (I.D.) 7.9 m (26 ft.) high laboratory column. The objectives of these tests were to assess the performance in terms of recovery and percent ash in clean coal and to optimize the operating parameters relative to combustible recovery and grade. Refuse streams containing 30-50 percent ash were upgraded to 2-8 percent ash with Btu recoveries of nearly 90 percent. A pilot scale column flotation cell was installed at the Bell County Coal preparation plant. This pilot plant utilized a 5.79 m (19 ft.) high and 0.15 m (6 in.) I.D. column to verify the performance data of the 0.05 m (2 in.) I.D. column for two different waste streams. Performance evaluation and pilot plant testing results related to scale-up are discussed.

Jan 1, 1988

By Mostafa Benzaazoua, Bruno Bussière, Mukendi Kongolo

The desulphurization process has been proposed over the last few years for acid mine drainage control at certain mines, which generate low to medium grade sulphidic tailings (-3 to +25 wt% S). The environmental sulphur recovery, which means the sulphur to be floated to produce a non-acid generating final tailings, depends mainly on the intrinsic neutralizing potential of the tailings. However, in some cases the sulphur cleaning is complicated by other parameters which affect the flotation probability of the sulphide particles. In this study, a number of tests were conducted with a Hallimond tube and Denver Cell on both pure mineral and mine tailings. To develop a better understanding of the mechanisms of non-selective sulphide flotation, three types of approach were investigated in this work: (i) pure pyrite at progressive milling degrees, (ii) artificial mix of pyrite and quartz at different calibrated granulometry and (iii) same composition tailings with 26 % wt sulphur at progressive milling degrees. The effect of the granulometry on the sulphide flotation was demonstrated both. The results allow us to define a granulometry model, which can then be considered in the whole desulphurization modeling.

Jan 1, 2000

By A. Tarigan

The integration of the ESZ orebody and DOZ orebody resulted in a much larger footprint than the original DOZ Mine shape. The significant change in footprint geometry presented new cave front management challenges, specifically: longer undercut drifts. Using a constant blasting rate, more time is required to complete caving in each drift which ultimately influences the number of active faces at any point in time. The number of manageable active drifts is controlled by the planned square-meters of undercut blasting, lead/lag restrictions and other specific conditions such as the need to blast pre-charged explosives. In early 2008, an evaluation of the existing plan showed that significantly more active undercut drifts and longer cave fronts would occur in the next five years. Difficulties associated with the long cave fronts led to a decision to redesign the caving sequence. Several different boundary options based on operational, geotechnical and ore grade parameters were investigated. This paper describes the issues faced with long cave fronts, the constraints and requirements to effectively manage the caving sequence and the options considered to mitigate this situation.

Jan 1, 2010

By B. Birol, M. N. Saridede

"Slag density is a significant factor in determining the process efficiency of the electroslag remelting (ESR) process, where calcium fluoride (CaF2)-based slag is formed synthetically to refine metal ingots. Although there are some former studies investigating the density of CaF2-containing slags, the prediction models focusing on them are applicable only to some specific systems. The present study aims to build a model to predict density for a wide range of CaF2-containing ESR slags. To investigate density for various slag compositions, CaF2-Al2O3-based and CaF2-Al2O3-CaO-based slag compositions were prepared. Additionally, some minor constituents like FeO, MgO and MnO were added to a 5:3:2 CaF2-Al2O3-CaO slag in order to investigate the effects of these constituents on the slag. The volumes of the prepared slags were measured in a tube furnace at 1450-1550 °C using the sessile drop technique, and their densities were calculated. The results showed that for the slags, density is related to optical basicity, and therefore a prediction model based on an Arrhenius equation was built. The model was tested with data from literature, and its limitations and validity are discussed.IntroductionThe electroslag remelting (ESR) process is a refining method in which a metal ingot is remelted under a synthetic slag. These synthetic ESR slags are mainly composed of calcium fluoride (CaF2), calcium oxide (CaO) and aluminum oxide (Al2O3). Other constituents like iron oxide (FeO), magnesium oxide (MgO), manganese oxide (MnO) and chromium oxide (Cr2O3) are added to this system in relatively low amounts, according to the type of steel ingot to be refined. The prediction of slag properties, such as electrical conductivity, viscosity and density, is crucial for the selection of the synthetic slag in order to obtain the required process parameters, like temperature, the passing time of the molten metal droplet through the slag, and metal-slag separation (Akbari, Reitz and Friedrich, 2009; Hara and Ogino, 1981; Mattar, El-Faramawy and Fathy, 2002; Mehrabi, Rahimipour and Shokuhfar, 2005; Presoly, Korp and Schneider, 2008).As slag density affects metal-slag separation in the ESR process, predicting the density of an ESR slag is important for appropriate refining and improved product quality. Although there are many studies investigating the density of slags (Akbari, Reitz and Friedrich, 2009; Aune, Hayashi and Sridhar, 2005; Hara and Ogino, 1981; Matsushita, 2011; Mills and Keene, 1987, 1981; Seetharaman et al., 2013; Shu, 2007; Shu and Chou, 2013; Sikora and Zielinski, 1974; Xu et al., 2012; Zhang and Chou, 2010), the prediction models built are generally valid for oxide-containing slags (Aune, Hayashi and Sridhar, 2005; Bottinga and Weill, 1970; Mills and Keene, 1987; Seetharaman et al., 2013; Shu, 2007; Xu et al., 2012; Zhang and Chou, 2010). These models were built on either the molar volumes of the constituents (Bottinga and Weill, 1970; Mills and Keene, 1987) or the thermodynamically calculated enthalpy or free energy of mixing, which can be applied to a system containing constituents sharing an ion, such as an O- ion for oxide systems (Aune, Hayashi and Sridhar, 2005; Hillert, 1980; Persson et al., 2007). Some recent studies modeled the density of some oxide slags on their optical basicity (Shu, 2007; Shu and Chou, 2013; Xu et al., 2012; Zhang and Chou, 2010)."

Jan 1, 2016

THE QUARTETTE Mine near Searchlight, NV, a mine that first operated in the 1890s, could begin processing ore again by September. Jetco Enterprises Inc. plans to work through the tailings and ore close to the surface followed by plans for an openpit mine. It is one of at least three new mining efforts in the region, the Associated Press reported. Another is north of Searchlight, with yet another across the Colorado River in Arizona, east of Bullhead City. Gold mining is rare in southern Nevada. The area generally lacks the rock type that contains gold deposits. Restrictions on federal wilderness areas and protections for the desert tortoise also play a role. Gold veins in the region are generally small and erratic in length and height, Bill Durbin, a geologist and chief of southern Nevada operations for the Nevada Division of Minerals told the Associated Press. L.R. Tad Tinnell, president of Jetco Enterprises, has long eyed the mine. From 1993 to 1995, he explored and drilled on the property, which was still owned by Searchlight Mercantile.

Sep 1, 2013

By R. Costa, A. Kozak, B. Fukuhara

Introduction The Jacobina mine is located in the state of Bahia in northeastern Brazil approximately 330 km northwest of the state capital city of Salvador and 9 km from the town of Jacobina. The Jacobina Mine (Figure 1) is owned by Jacobina Mineração e Comércio, a wholly owned subsidiary of Yamana Gold Inc. The gold mineralization of the Jacobina mine is hosted within quartz pebble conglomerate reefs of the Serra do Córrego Formation which together with the Rio do Ouro Formation forms the Serra do Jacobina mountain chain. The Serra do Jacobina mountains have been mined for gold since the late 17th century. Since the 1970’s, the Jacobina mined has been operated by Anglo American, Williams Resources Inc., Desert Sun Mining Inc. and now Yamana Gold Inc.

Jan 1, 2007

By D. Kruse, M. Sanaei

"A three dimensional nonlinear finite element model was constructed to simulate and analyze the behavior of large diameter segmentally lined shafts when subjected to seismic waves. To reduce computation time, a less complex shell model was also constructed. Transient excitation was applied to the supported nodes of both models, at the base of the shaft, with a time-function representing the 1994 Northridge earthquake. The models are developed at the end of an original phased construction-stage analysis of the shaft. Displacements, forces and moments are monitored and compared during the analyses steps. During the initial 15 seconds of the earthquake, the top and bottom of the shaft show similar displacements. The maximum horizontal displacement within the shaft is approximately 3.5 inches in the solid model and the shell model results conform to this by a factor of 50%. Keywords: Segmentally Lined Shaft, Soil Structure Interaction, Seismic Analysis, Finite Element Modeling, Ground Modification INTRODUCTION TO SEGMENTALLY LINED SHAFTS Large diameter segmentally lined shafts (SLS) are underground systems, constructed sequentially using precast concrete segments to form a ring which provides both temporary earth support during excavation and permanent structural support. The segments are connected via alignment pins, bolts, packer material and other structural components that ensure the continuity of the SLS. In this analysis, the construction process uses a top-down sequence wherein each soil layer is excavated, damp-proofing is installed and concrete segments are assembled to form each ring. This process is repeated until design depths are achieved completing the shaft. It is known that cylindrical structures sustain lateral (earth) pressure mainly through the mechanism of hoop-stress. As Timoshenko’s ring theory goes, a cylinder shell structure is prone to buckling under external pressure [1]. In typical designs of small diameter shafts and tunnel linings with small diameter to wall thickness ratios, nonlinear buckling analysis (i.e., nonlinear geometric analysis) is not considered, since the buckling capacities for those structures are much higher than typical pressures encountered at their design depths. However, in shafts with large diameter to wall thickness ratios, buckling could become a critical issue. In any given mode, as buckling occurs in a ring, some sections of the structure move inward while alternating sections protrude. Although the presence of the surrounding soil could mitigate the buckling by resisting the movement (Soil structure interaction) seismic loads can cause ground movements and lateral pressures, exceeding the capacity of the structure. It is therefore essential to design the load bearing capacities of the shaft to minimize the possibility of any catastrophic failure due to earthquakes. This study explores the structural response of the SLS when subjected to seismic loads."

Jan 1, 2016

By R. S. Mateer

Linear programming on desktop computers is commonly used to optimize coal blending proportions. The objective function is usually the cost of the blend. The constraints consist of materials and heat balances as expressed as linear functions of the blend. This is illustrated in Example 1. Inclusion of a sulfur compliance constraint in more complex because the maximum permitted sulfur percentage is not a pre-specified constant. Rather, it is a function of the calorific power of the blend itself. The current limit of 1.2 pounds of sulfur dioxide per million Btu may be expressed as: [Sulfur Max%= 0.6 . Hl10,OOO with H in Btu/lb.] A proper constraint equation may be formed by defining for each coal a function that is the difference between the actual sulfur percentage and the maximum sulfur percentage. This may be regarded us an excess sulfur percentage. For Coal A of Example 1. this would be: [ Sulfur Excess%=0.5-0.6 13,000/10,000=-0.28] This value would be used as the coefficient of the weight proportions of this coal in the blend. The complete constraint equation would then be the sum of such terms for each coal set less than or equal to zero. This is illustrated in Example II. [ ]

Jan 1, 1995

By John P. Dunford, Lewis A. Martin

Researchers from the Spokane Research Laboratory, National Institute for Occupational Safety and Health, in cooperation with engineers from the Department of Mining and Geological Engineering, Montana Tech, Butte, MT, conducted tests to evaluate the tensile strength, fiber count, and adhesion of shotcrete applied to panels at the Chief Joseph Mine, a research and training facility operated by Montana Tech. The tests were conducted in the mine ramp 45 m (150 ft) inward from the access portal at a 15.25-m- (50-ft) long test area divided into five 3-m- (10-ft) long sections. The shotcrete was applied with an Aliva 240.5 machine fitted with a predampener. Different amounts of fiber were entrained for each panel. Background data for the tests were obtained from earlier tests in Nevada, where the typical amount of fiber in the shotcrete is 6.54 kg/m3 (11 lb/yd3). All shotcrete was applied to a minimum thickness of 76 mm (3 in). Cylindrical cores were drilled at the wall-rock interface, and adhesion was tested after 28 days of curing. The goal of this research is to reduce the need to install multiple supports at the advancing face by creating a safer mining system that limits the time miners are exposed to unprotected roof.

Jan 1, 2005

By C. Flores, R. Y. Wan, M. C. Fuerstenau, T. S. Jordan

Most oxidized manganiferous silver ores contain manganese associated with silver and are not amenable to conventional silver extraction methods, including direct standard cyanidation techniques. However, it is known that dissolution of the manganese might yield a suitable material from which silver can be recovered by conventional methods. In the segregation process, which involves heating the ore with a small quantity of salt and with a source of reducing agent to 680°C - 800°C, the silver is volatilized, migrates and is reduced to metallic silver particles. Conventional cyanide leaching is applied to the resulting calcine. Laboratory investigations have been conducted on a manganiferous silver ore analyzing 0.02 % Cu, 0.09 % Pb, 0.33 % Zn, 12.55 % Mn and 187 g/ton Ag to study the influence of roasting temperature and time, quantity of salt and quantity of coke on silver extraction by the application of segregation roasting followed by cyanidation. Cyanide leaching tests were carried out at room temperature on the segregated calcines produced by using an alkaline cyanide solution containing 2.0 lb/ton of NaCN at pH 11 for 72 hours. The results indicated that 97.8 % of silver extraction can be attained at 850°C, with 2.0 % salt, 1.0 % Coke and 30 minutes of roasting time.

Jan 1, 1993

By T. J. Driscoll

The effect of coatings on the incendive properties of aluminum alloy 6061-T651 in air-6.4%CH4 was studied for collisions between rusted steel and both uncoated and coated projectiles with incident energies as high as 300 J (220 ft-lb) and velocities as high as 200 m/s (660 fps). These conditions were intended to simulate the rough handling of equipment in coal mines. The ignition probability using uncoated alloy projectiles increased with increasing relative humidity and appeared to be influenced by atmospheric ozone content. The incendive properties of both the uncoated and coated alloy depended on the type of rust used, but the dependence of the coated alloy was very different from that of the uncoated alloy. A number of coatings developed in the last 25 years were found to offer protection from ignition and to remain largely intact for occasional collisions or collisions randomly distributed over the coating surface, but probably not for repetitive collisions at any given point on the coating. These protective coatings utilize a hard anodized aluminum alloy surface coated with one or more layers followed by heat treatment of the coating. Coatings containing Teflon and MoS2 and thicker than 50 µm (2 mils) appear to be most effective.

Jan 1, 1987