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By Arel B. McMahan

The U.S. Bureau of Mines investigated mines, prospects, and mineralized areas in the Owlshead Mountains Wilderness Study Area (WSA) in 1982. Within the WSA, subeconomic manganese, iron, zinc, and lead resources were identified at two mines; sample analyses indicate five other mines and prospects may have gold, silver, iron, manganese, and copper resources. Three mines examined adjacent to the WSA have identified manganese and iron resources; and sample analyses indicate manganese, iron, and gypsum resources may exist at two prospects. Greatest likelihood for future identification of mineral reserves is for manganese at the Black Magic Mine in the southeast part of the WSA. The southern half of the WSA contains nearly all identified mineral resources, and properties at which sample analyses indicate additional resources. The most significant are manganese and iron resources at the Black Magic Mine in the southeastern part of the WSA; and the Ellie, New Deal, and Owl Hole Mines adjacent to that part of the area. Manganese and iron minerals filled fractures and replaced limestone in brecciated and faulted contacts with intrusive granitic rocks. In the southwest corner of the WSA, sample analyses indicate four prospects may have gold and silver resources. These precious metals are in gouge zones along contacts where diorite has intruded volcanic rocks. A small identified resource at the Kennedy Boys Lead Mine in the western part of the WSA consists of quartz veins with zinc and lead minerals along a brecciated contact between granite and limestone roof pendants.

Jan 1, 1985

By W. E. Miller, Kennedy. R. E., G. W. Jones

"INTRODUCTION Ethyl mercaptan (CH3,CH2SH), a combustible organic liquid of the thioalcohol type, is employed at an odorant in many types of fuel gases and dangerous atmospheres, which in themselves are devoid of characteristic odors, to give warring against leakage of such gases or atmospheres into places where they might constitute health or explosion hazards.Ethyl mercaptan has a penetrating disagreeable odor resembling that of onions, garlic, hydrogen sulfide, or rotting cabbage, that exceedingly low concentrations of it can be detected. The of odorants as a beans of detecting leakage of gases and atmospheres has been investigated extensively by chemists and engineers of the Bureau of Mines, and numerous reports as to its value have been published."

Jun 1, 1942

By Robert P. Vinson

The U.S. Bureau of Mines evaluated a light-scattering technique for discriminating between spherical and nonspherical particles. This evaluation was a three-step procedure. The first step required collecting light-scattering data for a variety of particles. This was accomplished with a particle analyzer called the DAWN-A. The DAWN-A measured the scattered light intensities of individual particles at a forward scattering angle of 40°. These DAWN-A measurements of individual particles are called scattering signatures by the Bureau researchers. The second step in this evaluation was to calculate a sphericity index number using the scattering signatures produced by the DAWN-A. The sphericity index number can range from 0 to 1. A calculated sphericity index of 1 would show that based on the intensity of scattered light, the particle was a perfect sphere. The third and final step of this evaluation was the comparison of the calculated sphericity indices of the various particles. Comparing these indices made it possible to discriminate between the nearly spherical waterdrops and the nonspherical coal and rock dust particles.

Jan 1, 1993

By G. W. Jones, R. E. Kennedy

Most gasolines and naphthas are mixtures of paraffin- series hydrocarbons and comprise such substances as pentane , hexane , heptane , octane , and others up to perhaps dodecane . Many of these hydrocarbons , when mixed with the proper proportions of air and ignited , are highly explosive . It is due to this characteristic that gasoline has become so important as a fuel in internal -combustion engines . Gasoline and naphtha also are used in the industry as solvents and cleaning agents . Because of their explosive properties they are dangerous to use unless the composition is so chosen that the vapor pressure of the mixture is not high enough to produce explosive mixtures with air at the temperature at which they are used . Hydrocarbon mixtures may be made less hazardous by adding some incombustible liquid , such as carbon tetrachloride . Barrier reports the amount of carbon tetrachloride that must be added to different naphthas to render such mixtures free from fire and explosion hazards . He found that the amount of carbon tetrachloride that must be present in the final mixture of naphtha and carbon tetrachloride varied with the density of the naphtha . Of the naphthas tested the amount of carbon tetrachloride necessary to render such mixtures free from fire and explosion hazards ranged from 30 to 70 percent . .. Determination of the fire and explosion hazards of carbon tetrachloridehydrocarbon mixtures would be easy if the boiling points and vapor pressures of the two were the same at any given temperature . The fact that carbon tetrachloride boils at 76° C. while the boiling points of the hydrocarbons found in gasoline and naphtha may range from 37° , the boiling point of pentane ,

Nov 1, 1934

By John H. Hild

The topography of the Jamestown fluorspar area is rough and ranges from 6,400 to 8,000 feet in altitude. Some fluorspar was mined as early as 1870, but mining really did not begin in earnest until 1940, and up to July 1947 it is estimated that 272,500 tons of fluorite was mined and milled. In 1947 the General Chemical Co. was mining fluorite and milling it in a 200-ton-a-day mill at Valmont, 7 miles east of Boulder, and the Ozark-Mahoning Co. was milling ore in a 100-ton-a-day mill at Jamestown, using ore mined, by H. M. Williamson & Son. These fluorite deposits comprise veins in a granite country rock. The Bureau of Mines drilled eight holes, aggregating 2,579.1 feet, on the Blue Jay vein; four holes, aggregating 1,434 feet, on the Chancellor; and one 350-foot hole on the Nations Treasure. Fluorite of a minable grade and width was found in 10 of the holes drilled. In this report the location and accessibility, physical, features and climate are described and a brief history of the district is given. The deposits and character of the ore and sampling and analyses are described, mine workings are outlined, and work performed by the Bureau of Mines is summarized. Diamond drill logs are shown in appendix I, and 'Sample analyses are tabulated in appendix II.

Jan 1, 1949

By David M. Hyman

The Bureau of Mines has developed two experimental designs for deter- mining the volumes and relative proportions of the various gas species, particularly methane (CH4), occluded in rock salt. To date, the rock salt samples analyzed have been relatively small (400- to 1,000-gram) grab samples from Louisiana Gulf Coast domal salt mines. The results obtained are comparable to results in Polish domal salt mines, in terms of occluded gas volumes per mass of rock salt. The notable difference between the Louisiana and Polish occluded gas mixtures is in the relative proportions of the individual gas species. The two methods used by the Bureau are ballmill crushing and dissolution. Of the two, the dissolution method appears to be more versatile because it can be performed in situ. The relevance and applicability of data on the occluded gas contents of rock salt are dependent on sample size, sample collection method, geologic context of the sample, and the correlation with gas emissions that occur as a result of mining-induced fractures and pressure differentials.

Jan 1, 1982

By G. S. Scott, G. W. Jones, F. E. Scott

An important activity of the Bureau of Mines is the promotion of safety in mining and industry . In connection with these activities , the Bureau determines the explosion hazards of combustible gases , liquids , and solids , and investigates means by which explosions may be eliminated or reduced in violence . The limits of inflammability and ignition temperatures of combustible gases , vapors , and solids are of practical importance because such materials can be manufactured , transported , and used with greater safety , provided the range of concentrations and temperatures that cause explosions are known. Acetic anhydride , ( CH3CO) 20 , with which this report is concerned , is a liquid at ordinary temperatures . It is used in the preparation of a number of organic chemicals and in the manufacture of photographic film and of artificial silk . It is perhaps the most important acetylating agent for industrial uses - a property that is especially important at this time because of its direct application in the manufacture of munitions . The sample tested was supplied by the Carbide & Carbon Chemicals Corporation . Its specific gravity was given as 1.083 at 20/20 . The vapor pressures , supplied by the manufacturer , are plotted in figure 1 .

Dec 1, 1943

By Walter C. Lorenz

Samples of materials containing pyrite from various coal mines and coalbeds were studied to compare their compositions and oxidizing characteristics. Pyrite was the only form of iron sulfide identified, but X-ray diffraction, emission spectrography, and microscopic analyses revealed similar suites of minerals and trace elements. The pyrite occurred usually in spherical clusters of very small crystals. The oxidation of pyrite in solutions of PeSO4 and Fe2(SO4)3 and in the presence of an iron oxidizing bacterium Ferrobacillus ferrooxidans, was studied through a manometric technique. FeS04 or Fe2(SO4)3 solutions had no appreciable influence on pyrite oxidation under the test conditions, The bacterium acted as a catalyst, greatly increasing the oxidation rates; however, in three samples that also contained calcites, bacterial oxidation was greatly reduced. The oxidation rates also increased approximately as the percentage of pyrite in the samples increased. For the series of samples studied, there was no definite correlation of the results with the location of the various mines nor with the acidity of alkalinity of the mine drainage.

Jan 1, 1963

Flexible hoses with rated working pressures up to 40,000 psi are used when high-pressure water jets are employed to cut rock or improve the performance of mining machines. Hose failures at such high pressures can result in serious injuries to workers. The Bureau of Mines used fatigue and burst tests to investigate the failure modes of high-pressure hoses at their rated working and burst pressures. Fatigue failure, at rated working pressures, occurred when the inner liner of the high-pressure hose broke, allowing water to seep through the wire wrapping, although the reinforcement wires did not break. At the burst pressure, all hoses failed catastrophically when the reinforcement wires broke. Low-pressure hoses placed over the high- pressure hoses for safety failed to contain water released by catastrophic failure.

Jan 1, 1987

By A. C. Johnson

The Ellington manganese deposit in Reynolds County J Mo., had been known for some time; and limited exploration, consisting of test pitting and sinking a shaft 54 feet deep on the property, had been done by private interests. Late in 1941, the Bureau of Mines cleaned, deepened, and sampled many of the existing pits and dug and sampled 27 new ones. The shaft was unwatered and sampled, and several pockets of manganese ore were trenched to determine their extent. Samples were analyzed and beneficiation tests on 1 ton of the ore were made at the Rolla, Mo., station of the Bureau of 'Mines. Results of the investigation indicated that the deposit was small and low in manganese content.

Jan 1, 1948

By W. P. Stroud

In this U.S. Bureau of Mines report, the conditions required for the direct reconstruction of a tomogram from observed line integrals are examined. Because of the limited access to the working faces in coal mines, the special case of access to only two opposite faces is emphasized. Classical matrix methods were used for small dimensional (2 by 2, 3 by 3, and 4 by 4) applications to determine the limitations and the requirements for a solution. The results for large (n by n) grids were then inferred and generalized from those of the smaller grids and matrices. Limited access tomography is found to be appropriate for in-seam hazard detection from seismic and microwave data, but it is shown that additional data must be added to obtain a direct solution.

Jan 1, 2010

By W. H. Forbes

The prevention of accidents from falls of roof and coal requires a considerable amount of personal judgment , for conditions are different even in adjoining working places in the same mine , and conditions may change from hour to hour even in the same working place as the coal is shot down and loaded . Experience has shown that many men can not or do not exercise enough care to protect themselves from injuries ; moreover , where the foremen have been made directly responsible for the safety of the men under them , accidents from falls of roof and coal have , in many instances , been reduced as much as 50 per cent . There is now no question that careful , constant , and intensive supervision is essential in preventing acci- { dents and more especially accidents of this class . Falls of roof and of coal account for approximately 50 per cent of all coal mine accidents and annually result in the death of approximately 1,000 men and cause lost - time injury to approximately 50,000 men . These and other accidents are recurring with little or no diminution , usually not because of the lack of knowledge of safe and dangerous practices , or of the technique of safety , but largely because of the lukewarm interest of major executives in safety or the failure of mine officials to formulate and to enforce common - sense rules and regulations . When failure is the outcome of a sincere attempt of the managing officials to teach safety to the miner , the fault may usually be attributed to misguided effort . Various solutions for the problem of eliminating accidents from falls of roof or coal have been suggested , some of which are : Standard system of timbering for the specified mining districts ; departure from the room-and - pillar system to a more concentrated system of mining ; more intensive supervision - that is , 1 section foreman for every 25 loaders instead of 1 section foreman for 75 , 80 , or even more loaders the practice in most mining districts . - However , investigations conducted by the writer at numerous mines operated by a number of mining companies in several districts show that employees and officials alike are inclined to work under loose and unsupported roof , relying solely on the " drummy " sound and on their judgment and experience as to whether the roof will stay in place for one hour or for several hours . With but few exceptions , men who had been injured by falls of roof or ccal or were found working under loose and unsupported roof , admitted that they knew of the possibly unsafe condition , but it was their opinion that the roof or coal was not loose enough to fall for some time .

May 1, 1931

By Edward W. Parsons

The explosive-expansion center-hole anchor was designed and developed for the specific purpose of use as a component of an instrument system that measures differential ground movement within a small drill hole in rock. Such anchors should have an unobstructed center hole, should be installed without a twisting action which could tangle connecting wires, and should be capable of being installed at depths in excess of 100 feet. The anchor has a thick-walled center tube and a thin-walled outer tube. Low-energy detonating cord, wrapped around the center tube and detonated with a mild end primer, expands the outer tube to produce anchorage. The explosive-expansion center-hole anchor can be installed easily in drill holes of any inclination but cannot be installed under water. Centering of the anchor is critical with regard to its subsequent holding power. The anchor is safe to make and handle.

Jan 1, 1965

By John Nagy

Limited experiments in the laboratory with specimens of mine rock from a Virginia bituminous coal mine indicate that natural gas-air mixtures can be ignited by sparks generated by rubbing friction of sandstone against sand-stone, shale against sandstone, sandstone against (roof-bolt) steel, and shale against steel. Such sparks, generated during a roof fall, may have initiated a recent gas explosion in this Virginia mine, although this cannot be stated with certainty. No ignitions of gas were produced by sparks or heat generated by impact friction between mine rocks or steel, during tension breaks of roof bolts, or by pull tests of roof bolts through their washers and roof plate. However, this negative result of limited experiments does not preclude the possibility of gas being ignited by these conditions.

Jan 1, 1960

By C. E. Saxon, F. E. Cash

"Adequate lighting for all mining operations would unquestionably tend to promote both safety and efficiency; this would be true not only for men but also for the animals that man impresses into service in mines. The Markeeta Coal Co. and the Alabama Fuel & Iron Co. both operating mines in Alabama, have found that equipping mine mules with portable electric lights is more efficient, much more humane, and far more safe for both men and animals then the more or less usual method of forcing the animal to do its work essentially in darkness.This report is intended to give the mining industry data, that will aid in trying to bring about safe and efficient operation of mines.The authors desire to thank Charles F. DeBardeleben, president, Fred R. Bell, general manager, Hewett Smith, C. H. Shepherd, and R. A. Sensing, superintendents for the Alabama Fuel & Iron Co.; and Charles F. DeBardeleben, Jr., president, and H. M. House, superintendent for the Markeeta Coal Co., for their cooperation in furnishing the data for this paper.The eight mines operated by the Alabama Fuel & Iron Co. and one operated by the Markeeta Coal Co. in Jefferson and St. Clair Counties, Ala., are the only mines in Alabama where mules are provided with portable electric lights, and there are few if any mines in other States in which this system is in use.These two companies are convinced that equipping all mine mules with good lights decreases underground haulage cost by animals by prolonging the useful life of the animals, increasing their efficiency, lessening haulage wrecks and delays on haulage, and increasing production. Last but not least of the advantages would be the more humane treatment of the animals.The nine mines are developed by slopes along the dip of the coal bed, with double-room entries on 200- to 300-foot centers turned right and left off the slopes and with approximately 1 per cent grade in favor of the loads. Rooms are driven up or diagonally up the pitch from these entries.A surface hoist delivers the empties from the surface to the entry sidetracks at the slope and pulls the loads to the surface. From these sidetracks, mules pull one to four wooden cars, each of which holds 1-1/2 to 2-1/2 tons of coal, deliver the empties to the rooms and entry faces, and pull the loads to the slope sidetracks. The mule haul varies from 100 to 3,000 feet; there are no locomotives or trolley wires in any of these nine mines, seven of which are rated as gassy and two as nongassy by the Alabama state Mining Department."

May 1, 1933

To determine the relative permeability of the soil a series of percolation tests were performed at the three locations of interest at Lanse, i.e., 3C, 03A and strip bank, and KA and KB at Kato. Soil cores were removed to 2, 8, 16, 24 and 32 inch depths with the thin wall sampler tube, each core separated from the next by about fifteen feet. Then two-foot-long thin-wall tubes were inserted into the 2, 8, and 16 inch deep holes and three-foot long tubes were inserted into the 24 and 36 inch deep holes. Each tube was tamped down about one inch further to assure a bottom seal; the tubes were filled with water and the rate of fall was measured. The test is similar to those done for septic tank percolation studies 6; but is not quantitatively related to Darcy's coefficient of hydraulic conductivity because the water can flow in three dimensions from the bottom of the tube. The measurements are dependent on the length of test, since the rate of fall is a function of the head. Therefore, it should be noted that the 24 and 32 inch deep tubes should give faster percolation rates because of the one foot greater head. At locations 03A and 3C the data show a sharp decrease in percolation at increasing depth, Table XV. However, the percolation at 03A and 32 inch depth is much higher than at 3C (0.2 vs. 0.01 inches/hour); the fragipan layer must be deeper at the 3C location since this area does experience a perched water table. On the strip bank the rates of falling head are randomly variable, appearing to be as much dependent on the particular location of insertion as on depth of placement. For example, water drained from the 16 inch tube as fast as it was added, probably into a sub-surface cavity or crevice. At Kato the tubes were more difficult to place because of interference of tree roots. For this reason 2 inch deep tubes were not inserted. These short tests at Kato were inconclusive, varying extensively when the tubes were moved. Field permeability tests were also performed in two (previously described) eight-inch diameter permeater tubes at Lanse and one at Kato. Because the soil is confined inside the tube, hydraulic conductivity can be calculated according to Darcy's flow equation. The high values reported in Table XVI experienced when the tubes were rewetted from a dry surface condition, enable us to conclude that infiltration is faster than the saturated permeability of the soil. In contrast to the falling head percolation tests, these permeability results do not show a high variation between locations.

Jan 1, 1972

By H. J. Van der Veer, F. E. Griffith

"Reflector button signs similar to those used to attract the attention of motorists on the public highways at night are now being used to good advantage by a few mining companies in underground workings for danger, warning, direction, and safety signs and signals. Most safety signs and signals used in underground mining are of the electric light painted-board, or enameled or porcelain metal-plate,type, all of which have good features as well as some disadvantages; among the disadvantages are: The filament of electric incandescent lamps is prone to ""burn out"" occasionally anti usually the lamps are not replaced promptly; painted-board and enameled or porcelain metal-plate signs can be seen only a short distance and often are ""passed up"" unintentionally by employees, consequently these signs do not always serve the purposes intended and may be the cause of injury or death through failure to warn the men of danger.The advantage of using reflector button signs in mines or underground workings is that the cap lamps or headlights with which employees and locomotives generally are equipped, if directed at these buttons will reflect the light back to its source, and if they are arranged to spell words of warning or direction, or if suitable symbols are used, they are discernible and can be read at a distance of several hundred feet. The distance the light is reflected depends largely on the color of the buttons used. The reflector buttons also in many instances can be used to good advantage in conjunction with other methods previously mentioned.Several types of reflector buttons are available, among them the flat-lens type with mirrored metallic foil or plate back, the facet-cut-lens type with a mirrored metallic foil or plate back, and a type with a hemispherical smooth lens with a parabolic mirrored metal back. Lenses for the different types are available in several colors. Crystal, amber, red, and green are the colors of the buttons used to the greatest extent in underground signs up to the present time. These buttons may be had in different sizes, also.It has been observed that crystal-colored buttons reflect light the greatest distance (about 1,000 feet) and red-colored buttons the least (about 500 feet); reflection from green and amber colors ranges somewhere between the red and crystal colors in distance.Reflector buttons for underground use should be designed to reflect light a maximum distance; they should be made of materials that resist oxidation and corrosion, especially of the mirrored backs, and should be relatively free of protruding parts or projections that will collect dust.Reflector buttons approximately 3/14 inch in diameter seem best suited for underground use in general because fewer reflector units are required for a signal of given size."

Dec 1, 1937

By C. A. Herbert

"Haulage accidents usually are responsible for about 17 or 18 percent of all coal-mine fatalities and about 21 percent of all non-fatal coal-mine accidents. When the relatively small number of employees continuously exposed to haulage hazards is considered, it would appear that haulage is more hazardous than any other phase of coal-mine operation.Haulage accidents have increased from year to year, doubtless due to the increase in electrical haulage, and particularly to the use of larger cars, heavier locomotives, longer hauls, and greater speed. Unless very definite steps are taken to eliminate the causes of these accidents, they will continue to increase rather than be reduced, as they can and should be.Underground haulage in many of the large modern mines of today is similar in many respects to railroad practice. In recent years the railroads have made wonderful strides in reducing accidents, and instead. of being one of the most hazardous occupations, as it once was, railroading is now one of the safest. Doubtless, if thought and action, similar to that given to reducing accidents among railroad passengers and employees, were given to safety in mine haulage, under¬ground haulage accidents could be reduced in about the same ratio.Haulage accidents may be classified, according to responsibility, into two groups - those for which management is largely responsible and those for which the employee is largely to blame; there is, however, an overlapping of responsibility from one group to the other. If, therefore, haulage accidents are to be reduced, it is absolutely essential that both management and employees cooperate to this end.In the first group, for which management is largely responsible, may be included accidents due to faulty equipment, moor track, a poorly arranged system of haulage, lack of clearance or of overhead protection, and dirty roadways; even in these features, however, the employee is not without a measure of responsibility, as failure of haulage equipment possibly may be due to lack of care on his part, failure to report when equipment is out of order, or failure to do a good workmanlike job of installing or repairing or operating.To the second group of accidents for which the employee may be largely responsible, belong those caused by such careless practices as jumping on and off fast-moving trips, coupling on the ""fly"", running at excessive speeds, failure to properly block cars, and similar hazardous and unnecessary acts of omission or commission. If, however, management condones such practices, or, as in some instances, insists upon them, it must accept its share of responsibility for the accidents that inevitably result.Some of the most prolific sources of haulage accidents will be discussed briefly, together with the steps that may be taken to minimize their occurrence."

Oct 1, 1939

By M. G. Cherniack, A. J. Brammer, D. R. Peterson

Over the past two decades, there have been significant reductions in industrial exposures to hand-arm vibration, especially when specific tools and work processes have been redesigned to incorporate anti-vibration and ergonomic principles. Nevertheless, Hand-Arm Vibration Syndrome (HAVS) remains a significant occupational health problem as disease symptoms continue to occur even when vibration exposure levels believed to incur low risks have been reached2. This inconsistency may be related to the methodology that is typically used to estimate workday vibration exposure levels, involving laboratory and/or very short duration field measurements coupled with estimates of overall eight-hour tool operation times determined from brief observations of tool tasks and/or self-reported surveys. One solution is to use small, commercially-available, personal vibration dosimeters to calculate, record, and display long-duration vector sums and energy equivalents of vibration. However, since these devices are attached to the worker and require tool-mounted accelerometers, they are incompatible with the worker performing normal duties involving putting down or changing tools. In addition, these commercial systems do not allow for the characterization of the transmission of vibration to the hand such as monitoring the mechanical coupling between the hand and the tool handle (e.g., grip forces). O’Boyle and Griffin showed that variations in applied force can alter vibration transmission characteristics by 50% or more indicating that the measurement of grip force is essential for modeling vibration transmissibility and vibration exposures5. In summary, a need exists for the development of a method and device that will more accurately characterize workday-long vibration exposures. Methods A portable, light-weight, Vibration Exposure Monitor (VEM) system was developed to record user-specific tool-operating times, vibrations, and grip forces throughout all, or a representative part, of a workday. It monitors frequency weighted and unweighted accelerations from a palm-mounted uni-axial accelerometer (Model 352C22, PCB Piezotronics, Depew, NY) and calculates exposure levels using the root-mean-square (RMS) and higher power mean values, such as the root-mean-quad (RMQ) and the root-mean-oct (RMO). Grip forces are also monitored using a palm-mounted force sensor (Model 400, Interlink Electronics, Camarillo, CA) from which average grip force levels and exerted grip extrema are calculated. At the core of the VEM system is a commercially available, battery-powered microcomputer (Tattletale, Model 8v2, Onset Computer, Onset, MA) with one megabyte of memory and eight analog channels using 12-bit sampling at a single-channel maximum of 100 kHz. Analog signal processing (i.e., anti-aliasing, with cutoffs at 4 and 1250 Hz, and ISO 5349-13 frequency weighting) is accomplished using custom circuitry that is directly interfaced with the microcomputer. An embedded C-based protocol governs the data collection from each channel

Jan 6, 2006

By J. E. Schiller

The Bureau of Mines has investigated the surface charge of amphibole asbestos fibers and nonasbestiform cleavage fragments, as part of the Bureau's fundamental studies to provide new knowledge on the physical and chemical properties of the amphibole minerals. Microelectrophoresis was used to measure the electrophoretic mobilities, in water, of particles from six asbesti-from amphiboles and seven nonasbestiform amphiboles over the pH range of 5 through 9. The particles generally ranged in size from 2 to 5 µm wide by 10 to 30 µm long. The isoelectric point was determined for four of the minerals, and values were found to be between pH 3.5 and pH 5. The minerals studied had zeta potentials that generally ranged from -25 to -so mv in neutral solution. Attachment of colloidal positively charged AgI was also studied as a means of determining surface charge. Scanning electron microscopy of amphibole particles that had been in contact with aqueous AgI showed equal attachment of AgI to asbestos fibers and to cleavage fragments; the extent of AgI coating was the same for both. The electrophoretic mobilities of asbestos fibers were essentially the same as those of elongated cleavage fragments of the same aspect ratio (particle length divided by width). Blocky particles from both asbestiform and nonasbestiform specimens had lower mobilities.

Jan 1, 1980