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By L. A. Haas

Hydrogen sulfide was decomposed to elemental sulfur in an electrical discharge. With He, N., or Ar diluents, a threshold voltage between 1 and 3 kV was required for the decomposition reaction to occur in a laboratory ozonizer. Above the threshold voltage, the HAS decomposition rate increased with increasing voltage, but the increase was more pronounced with argon diluent than with either nitrogen or helium. In common with other reactions in an electrical discharge, the B2S decomposition decreased with increasing temperature in the range of -410 to +61° C. The reaction did not appear to be rate-controlled by a solid-gas sorption step because the introduction of activated charcoal into the electrical discharge zone did not significantly affect the decomposition yield. In the presence of polymeric chlorofluoro-carbon oil, 90 pct conversion of the 3 pct H2S in helium was obtained at 14 kV, 60 Hz, a 2-mm electrode gap, and a gas-residence time greater than 1 min. Under the same experimental conditions in the absence of oil, the conversion was only about 50 pct.

Jan 1, 1973

By J. P. Bennett

The Bureau of Mines is investigating the acid resistance of ceramic materials to identify construction materials for emerging technology in chemical and metallurgical processes. Eight commercial ceramic materials, including two red shale, two fireclay, a silica, a silicon carbide, a carbon, and a high-alumina brick, were evaluated. Samples were exposed to 40 wt pct HN03 at 70° and 90° C and 60 wt pct HN03 at 50°, 70°, and 90° C for time periods of 110 days. Statistically significant changes in cold crushing strength were generally small or not detected, except for a strength drop in the high-alumina brick, which decreased in strength when exposed to the chosen acid concentrations at 90° C. Vol-ume and weight changes were also measured. The leach rates of Al, Ca, Fe, K, Mg, Na, Si, and Ti were monitored. Increasing temperature or a decrease in the acid concentration resulted in an increased ion leach rate. Of the conditions tested, the most severe corrosion occurred at 90° C for a 40-wt-pct-HN03 solution. The silica brick had the best overall acid-resistant properties, followed by a red shale and a fire-clay brick. The carbon and silicon carbide bricks are not recommended for service.

Jan 1, 1984

By E. D. Gordner

U. S. Bureau of Mines

Jan 1, 1923

This Part is concerned with the theoretical study of UHF radio communication in coal mines, with particular reference to the rate of loss of signal strength along a tunnel, and from one tunnel to another around a corner. Of prime interest are the nature of the propagation mechanism and the prediction of the radio frequency which propagates with the smallest loss. Our theoretical results are compared with measurements made by Collins Radio Co. This work was conducted as part of the Pittsburgh Mining and Safety Research Center's investigation of new ways to reach and extend two-way communications to the key individuals that are highly mobile within the sections and haulage ways of coal mines.

Jan 1, 1974

By D. B. Eccleston

Natural gas and mixtures of natural gas and hydrogen were used as fuels in a laboratory engine to determine the relationship of emissions to air-fuel ratio and to establish practical lean limits for air-fuel ratio. Synthetic gas manufactured from coal (Synthane) and natural gas were used as fuels in a vehicle to obtain comparative data on emissions and performance. Results showed that lean limits for air-fuel ratio when using hydrogen-enriched natural gas were extended significantly beyond Chat of natural gas. Synthane pro¬duced exhaust that was significantly less reactive than exhaust from natural gas. With lean air-fuel ratios, the acceleration performance of a vehicle fueled with Synthane was improved over its performance when fueled with natural gas.

Jan 1, 1972

By Richard G. Sandberg

The Bureau of Mins, U.S. Department of the Interior, is investigating a hydrometallurgical procedure to conserve cobalt, nickel, and copper by recovering the metals from the matte byproducts of smelting Missouri lead ores. For want of adequate processing technology the mattes are now either unmarketable or marginally so. The procedure involves leaching with manganese dioxide and sulfuric acid to obtain copper, nickel, cobalt, lead, and manganese sulfates, and elemental sulfur as expressed by the following reaction: MS + MnO2 + 2H2SO4 ? MSO4 + MnS04 + S° + 2H2O, where M = Cu, Ni, Co, and Pb. The leach solutions, containing near theoretical amounts of sulfuric acid and manganese dioxide at 85° to 100° C, convert up to 98 pct of the cobalt, nickel, and copper in the mattes to sulfates in less than 2 hr. As they are formed, the cobalt, nickel, and copper sulfates are dissolved leaving a residue of lead sulfate, lead, sulfur, and gangue. The soluble metals are recovered from the leach solutions by caustic and sulfide precipitation, and the residue returned to the smelter for lead recovery. The manganese can be reclaimed from the spent leach liquor as manganese oxide and recycled to leaching.

Jan 1, 1979

By Oliver Bowles

"On January 15, 1920, a man was killed by falling rock in a limestone quarry in Utah. The quarry was visited by a representative of the Industrial Commission of Utah, and the cause of the accident was carefully determined. The facts concerning this accident, and the Bureau's recommendations are given in some detail in the hope that quarrymen may take steps to avoid dangerous conditions, and thus reduce the liability to accident.The quarry rock face is about 180 feet high, and the ledge is covered with an overburden of 10 to 20 feet of a mixture of soil and boulder. The rock face is not vertical, but slants at an angle of about 45° to 50°, while the stripping face stands at an angle of 70° to 80°, and is flush with the rock face. The conditions are shown in the accompanying figure.The man who was killed was employed in breaking rock at the foot of the quarry wall. The sun had been shining on the stripping face, and probably thawed the ground, thus permitting a boulder weighing about 20 pounds to roll down the slanting face, striking, and almost instantly killing the workman who was working with his back toward the quarry wall."

Feb 1, 1920

By R. L. Levens

Researchers at the U. S. Bureau of Mines conducted investigations to evaluate the potential for ground water contamination by mine waste used as backfill. Samples of cemented waste backfill and water discharging from drillholes and seeps were collected to use in chemical analyses and laboratory tests to determine the physical and chemical factors that control release of heavy metals to ground water. Greater water retention by cemented backfill (as compared to uncemented sandfill) reduces the surface area exposed to oxidation, which in turn reduces the amount of acid produced. The acid is neutralized by the cement and minerals contained in the backfill. The grain-size distribution of tailings used for backfill affects the structural integrity of cemented backfill under attack by acidic water; breakdown of the backfill structure releases neutralizing materials faster. Backfilled stopes in rock with low hydraulic conductivities will constitute preferential flow paths after mine flooding; however, the rate of flow through backfill will be much slower than when the stope is partially saturated during mine operation. Considering all factors, acid generation and release of metal ions from cemented backfill should be less than in uncemented sandfill.

Jan 1, 2010

By R. V. Ramani, J. Qin, R. A. Jankowski

"Longwall mining is generally recognized as safer, more productive and economic when compared to room and pillar underground coal mining. There has been, however, increasing concern for the control of airborne coal dust concentrations in long wall faces. The airborne dust cloud at a longwall face is a complex aerosol system containing particles of varied size, density, shape and state of aggregation. For the development of more effective dust control practices in longwall faces, it is necessary to understand more clearly the characteristics of the longwall dust cloud.In this paper, results of a research study on dust concentration distributions along longwall faces are presented. The objective of this study is to characterize the longwall dust cloud behaviour and provide necessary fundamental data for a better understanding of the longwall dust problem. MSA personal samplers and gravimetric total dust samplers were employed to collect respirable and total airborne dust samples. The size distribution of these samples was determined by MicroTrac SPA. The instantaneous respirable airborne dust concentrations were recorded using RAM-I. The dust concentrations are related to face operations, particularly the shearer location and activities. The size distribution of airborne dust, instantaneous respirable airborne dust concentration, and air quantity distributions along longw all faces reveal a complex dust flow phenomenon. Additional fundamental studies are needed for characterizing the temporal and spatial behaviour of the dust cloud at longwall faces.IntroductionModern mechanized longwall mining was introduced in the United States in the 1960's and has become more common in the last twenty years. United States longwalls are multiple-entry retreating faces. According to a recent survey, 91 of the 102 longwall faces employ double-drum shearers (1). Several recently installed longwall faces have consistently produced over 4 000 to 5 000 tons per shift over extended periods of operation. The trend in under-ground coal mining in the U.S. certainly is toward the introduction of longwalls. This trend is true not only for new mines but also for renovation of existing mines. While longwall mining has many advantages over other mining methods, including improved safety, such as higher pro-duction. greater productivity and enhanced reserve recov-ery, it is associated with severe problems of dust control. The increase in longwall production has been accompanied by an increase in respirable dust problems which limit realizing the full potential of the longwall mining system. Despite the efforts to develop improved equipment and operational procedures to control the dust levels at longwall faces, it is still difficult to bring several double-drum shearer operations into compliance with the Federal stand¬ards of 2,0 mg/m 3 respirable dust without loss of produc¬tion. In fiscal year 1987, fifty-eight of the longwall sections were found to be in non-compliance once, and an additional 31 were cited two or more times'''. If the full potential of the longwall mining method is to be realized, new measures must be implemented to control the dust concentration to mandated levels. There is a need for detailed and extensive sampling of longwall faces to understand the dust source-sink relationships and the transient ambient concentrations. These must be related to the mining activities on the face. This paper is to characterize the longwall dust cloud behavior through a series of experiments in operating faces and provide necessary fundamental data for further studies to develop improved dust control practices."

Mar 1, 1992

To develop effective noise controls for continuous min-ing machines (CMMs) to reduce worker noise exposure. Background Noise-induced hearing loss (NIHL) is an occupational illness caused by chronic exposure to excessive sound levels. For underground coal mine workers, NIHL continues to be a serious health issue. Analysis of hearing loss data suggests that by retirement age, 70%?90% of U.S. coal mine workers will have a hearing impairment. Operated in the confined spaces of underground mines, large industrial mining equipment often produces sound levels that can be harmful to workers. Of all equipment used in underground coal mining operations, CMMs account for the most noise overexposures. To reduce the occurrence of noise over-exposures, engineering noise controls must be developed for the CMM.

Sep 1, 2008

By Murray Jacobson

The respirable dust standard in the Federal Coal Mine Health and Safety Act of 1969 is designed to prevent disability and death from coal workers' pneumoconiosis. Beginning June 30, 1970, the operators of coal mines were required to maintain the average concentration of respirable dust in the active workings at or below 3.0 milligrams of dust per cubic meter of air. The standard is reduced to 2.0 milligrams per cubic meter after Dec. 30, 1972. This paper presents the equipment and procedures used by the coal mine operators in implementing the respirable dust sampling program established by the Secretary of the Interior and the Secretary of Health, Education, and Welfare and shows the effect of the law, during the first year, on the reduction of dust levels in selected mines. The system employed by the Bureau of Mines for analyzing and processing the dust samples is also presented.

Jan 1, 1971

By Henry Kreisinger, WALTER T. RAY

The investigation of the transmission of heat into steam boilers is one of several researches now being carried on by the Bureau of Mines that have for their object the testing of methods by which the mineral fuels in this country may be used more efficiently. A better understanding of the laws governing heat transmission into boilers will result in the design of more efficient boilers, and more efficient boilers will reduce waste in the use of fuel. The results of the investigations described in this report indicate that the conductivity of the heating plates of steam boilers is so high that the present steaming capacities can be tripled or quadrupled by forcing over the heating surfaces three or four times the weight of gases now passed over them. With well-designed mechanical-draft apparatus this greater weight of gases can be forced through the boilers at a small operating cost. It is possible to increase the capacity of many of the present boilers in this way without reducing their efficiency much; in fact by a proper arrangement of the heating surfaces the efficiency can be made higher than the present rating. The efficiency of any boiler can be increased by arranging its heating surfaces in series with respect to the path of hot gases. New boilers of high efficiency can be constructed by making the cross section of the gas passages small in comparison with the length. In Bryan Donkin's book, entitled "The Practical Physics of the Modern Steam Boiler," it is stated that James Watt obtained nearly as good an evaporation per pound of coal and per square foot of heating surface as is obtained now. The remark is probably true. At any rate, about the only decided superiority of the modern steam boilers over older types is in mechanical construction, and for this superiority credit should be given to the designers of machine tools quite as much as to the boiler engineer. The main reason for tardi- ness in boiler improvement probably lies in the reluctance of educated engineers to do the dirty and disagreeable work involved in boiler tests.

Jan 1, 1912

By S. H. Denny

"As the result of the work of an efficient safety organization, the Midwest Refining Co. at its various operations and particularly in the Salt Creek field has been able to show a definite accident reduction. Lost-time accidents during the past year have been reduced to a small number as compared with previous years, and infection cases have been almost eliminated.The accident-prevention work of the Midwest Refining Co. is in charge of the department of industrial relations, with a director as the administrative head; two safety men handle the work directly at Midwest, Wyo. A competent medical staff with a well-equipped hospital at Midwest is also an important factor in the prompt and proper treatment of injured persons when an employee is injured, he is given first-aid and then taken to the hospital with minimum delay.About 1,450 persons are employed in the 4 departments (production, gas, pipe lines, and electrical) and in the 34 districts of the Midwest Refining Co. The work at Midwest spreads over a considerable area, and new drilling operations, pipe work, and similar activities require the services of many small gangs of workers. Complete supervision, of each job, whether shall or large, is possible through the large number of superintendents, foremen, and gang pushers employed; thus, there are 20 superintendents, 78 foremen, and 115 gang pushers. The largest number of men under any one toss is approximately 15, and it is probable that much of the good safety record is due to this intensive supervision. These company officials, including the gang pushers, have been impressed with the idea that it is their duty to see that the men under them do not get hurt; the responsibility of instructing new employees in safety practices is placed directly upon them. Monthly meetings of the field officials, including superintendents, foremen, and gang pushers, and as far as possible the men, of each district are held with the safety engineer. Both officials and men are encouraged to bring up for discussion any practice or proposals looking to the changing of any conditions that will"

Apr 1, 1928

By George Bockosh

Mr. Bockosh is an electrical engineer with the U.S. Bureau of Mines In Pittsburgh, and has devoted the last two years to research on underground illumination. He formerly was a mine maintenance foreman and worked two years underground. He is a graduate of the University of Pittsburgh, where he is now working toward his masters degree in mining. When Congress first legislated light in American coal mines, it was a little like mandating a walk on the moon before the first satellite had been put in orbit. It was never a question, of course, of whether it could be done. But no one knew quite how. It's one thing to string a few light bulbs, and quite something else to provide uniform, sufficient, safe and reliable illumination, with fixtures that will hold up under some of the toughest conditions in the world - in the life-and-death circumstances of a craggy, black cavern filled with dangerous, moving machinery. In fact, in 1969 when Congress originally mandated illumination standards for the work places of underground coal mines, no one even knew just how much light was needed. That question was answered within a year by the National Bureau of Standards. In a study commissioned by the U.S. Bureau of Mines, the Bureau of Standards determined that underground mine should be illuminated with a light intensity of 0.06 foot-lamberts, a measurement of light reflected from surfaces in the lighted area-as opposed to foot-candles, a measurement of light from the source of illumination-in order for miners to adequately see what they are doing. That study was followed by more detailed research done at the Bureau of Mines' direction by the Research and Development Department of the Naval Ammunition Depot in Crane, Ind. This work evaluated the specific lighting needs of miners engaged In more than 100 different job tasks in all three types of coal mining- conventional, continuous and longwall. The Naval Depot report brought forth nearly 300 pages of detailed lighting data and concluded that proper illumination of mine work areas would serve more than just the cause of mine safety.

Jan 1, 1976

By C. Travis Anderson

"A recent critical study by Ralston3 of the iron system points out the importance of and necessity for work upon the preparation of ferrous oxide. Not only are ferrous oxide samples desired for determination of the important physical and chemical properties, such as specific heats and heats of formation, bat also information on the stability and behavior of this material is of considerable technical importance. Related. problems where the properties of Fe0 are important have to do with desulphurization of iron, the formation and occurrence of magnetite in copper smelter slags, and sulphur elimination in copperFerrous oxide also has valuable catalytic properties, as is demonstrated in nitrogen fixation.Pure ferrous oxide has never been prepared in quantities large enough to furnish adequate physical and chemical data on its properties. Only two or three experiments4 have produced a fraction of a gram in a state approximating purity and have collected evidence that has been sufficient proof of their having done so. Ferrous oxide is stable only above about 570°C., and below that splits into magnetite and iron according to the reactionUp to about 1920, those who had endeavored to prepare FeO made no provision for rapid chilling, so that although their product. may have had the proper iron oxygen ratio for FeO, in reality it-probably did not consist of pure FeO. The above reaction is reversible; above 570oC. magnetite and iron are supposed to recombine almost completely, and if so, should constitute a direct and easy method of preparation. The data, however, were somewhat conflicting, and the extent to which the reaction goes in either direction needed checking. Preliminary experiments on the interaction of molten Fe304 with solid Fe gave Fe0 of about 85 per cent purity, corresponding to. the approximate purity obtained by some previous investigators. The present work is concerned chiefly with the results cf repeated interaction between partly reduced magnetite and iron, and the calculations which may be made from such results. Repeated treatments are necessary, because molten impure ferrous oxide and iron can not be kept in contact for more than short periods of time."

Oct 1, 1928

By Ronald D. Hill, Elmore C. Grim

The United States is richly endowed with mineral resources. However, mineral recovery by its very nature, involves a destructive process, Figures 1 and 2. In the past, mining practices were all too often conducted with the purpose of removing minerals by the simplest and cheapest method possible, without plans for the preservation of land, water, and air, and with too little consideration for the rights of others. A mining company is in business to make a profit, but every company, regardless of the nature of its business, has moral obligations to reduce its undesirable effects on the environment and to safeguard the rights of others. The problem of environmental degradation caused by surface mining is widespread and serious. Minerals in some form occur in each of the 50 States and several States are extensively mined. Data on the acreage disturbed in the United States, by commodity and State are presented in Table 1. Thirty-one States have laws regulating surface mining, (Table 2). Briefly reviewed in Appendix A-1 are the basic provisions of State laws governing surface mining. It can be seen that these laws vary considerably from State to State owing largely to the mining conditions within that State. Of the 24 coal-producing States, only three (Alaska, Arizona, and Utah) do not regulate strip mining. Even the states that are often cited as models of comprehensive regulations still have problems minimizing environmental damages. Uncontrolled surface mining presents a situation as critical to the well-being of the society as any it has ever faced. Many mining activities have imposed huge social costs on the public at large. These costs are long-range and are in the form of stream pollution, floods, landslides, loss of fish and wildlife habitats, unreclaimed land, erosion, and the impairment of natural beauty. In a 1965 Department of Interior study,(1)it was estimated that of the 25,000 miles (1+0,225 kilometers) of contour bench in Appalachia, approximately 1,700 miles (2735 kilometers) are affected by massive landslides. Additionally, 1+800 miles (7723 kilometers) of streams and 29,000 surface acres (11,716 hectares) of impoundments and reservoirs have been seriously affected by coal strip mining operations in the United States.

Jan 1, 1974

By H. B. Freeman, E. J. Gleim

During the 12 months ended July 1, 1931, engineers of the Bureau of Mines examined electrical equipment in 80 bituminous-coal mines. The purpose of these examinations was to ascertain the condition of such equipment with respect to possible hazards of gas and dust ignitions, also of shock. Although only 3 of the 80 were being worked with open lights and therefore did not use explosion-proof equipment, there were others where electric cap lamps were used by the men but where it was apparently assumed that conditions as to gas and dust did not require equipment designed to give protection against ignitions. Early in its history the United States Bureau of Mines originated certain standards covering the construction and testing of electrical equipment in order to minimize the dangers of ignitions from exposed electric sparks and flashes ; accordingly, it is comparatively easy to determine wherein a machine built to these standards falls short of continuing to meet them if damaged or neglected. Many so-called flame-proof and dust-proof machines, however, have not been built to any standard comparable with that developed by the Bureau of Mines. In addition, certain machines have parts which pass Bureau of Mines tests, but do not satisfy the full requirements in other respects, and others make no pretense of inclosing the spark-producing parts. It is not uncommon to find two or more of these various types in the same mine with " permissible " machines, the type that has been built to conform to the Bureau of Mines standard. Consequently, inspection of nonpermissible machines becomes somewhat difficult without a standard of comparison. Because of its unprotected condition obviously open-type electrical equipment must be used with great care, if at all, in a mine where precautionary measures are adopted in guarding against gas and dust ignition. The unsafe nature of such equipment is widely recognized. For that reason it is to be installed only where there is no likelihood of gas being present. It is not apparent to some, however, why flame-proof and dust-proof equipment and equipment having tested parts should not be regarded in the same light as permissible equipment.

Jan 1, 1932

By F. W. Wood

Ingots of zirconium and other highly reactive metals such as titanium and hafnium produced by the consumable-electrode arc-melting process require conditioning before forging or rolling. A nondestructive, arc-conditioning technique has been developed as a substitute for lathe conditioning. The technique employs en electric arc under an inert atmosphere to fuse surface metal on the sidewalls of ingots without seriously affecting the general quality of the ingots. Advantages of the practice are Increased yields, lower accumulation of inferior scrap, and actual cost savings. The work cited in this report was done on zirconium. INTRODUCTION The consumable-electrode arc-melting process as practiced at the Bureau of Mines3 4/ has proved to be a technique for producing sound, homogeneous, commercial-size ingots of zirconium and its alloys. Ingots produced by this process, however, have as a characteristic a layer of partly fused metal on the sidewall to a depth of 3/16 to 3/8 inch. To prevent extension of surface imperfections during forging, the ingots are ordinarily conditioned by removing defective material in a lathe. If the metal were less reactive or the requirements less severe, the machine chips could be recycled and remelted. However, zirconium, being so oxygen sensitive, is contaminated by merely being machined despite extensive cooling of the tool bit. Further, being contaminated with oxygen, the chip metal upon remelting is 10 to 25 Brinell-hardnese numbers harder than the ingot from which it was machined. For this reason, the ingot specifications for naval reactor use have prohibited remelting machine chips, except as required for starting pads. Again, were zirconium less costly or less in demand this ever-increasing pile could be burned to oxide and recycled through the Kroll sponge process. Economics do not favor this, as melting feed stock has an estimated increase In value over oxide of about $8.80 per pound of contained zirconium. The efforts of the Bureau to solve the problem have been directed along two lines: To reduce the contamination of the machine chips produced and to reduce the quantity of the chips produced. This paper presents the technique developed to reduce the quantity of chips produced by arc-conditioning the remelted ingot.

Jan 1, 1955

By James V. Kelly

During the winter of 1946 and the spring of 1947, the Bureau of Mines conducted an investigation and drilling program in the vicinity of the village of Fairplay, Wis. Fifteen diamond drill holes totaling 2,457.6 feet of bore were completed. This work was part of a general study of the zinc-producing area of southwestern Wisconsin and had the particular purpose of investigating a structural trend, determined by the Federal Geological Survey, in an area some distance from known ore bodies or active mines.

Jan 1, 1948

By T. T. Campbell

Studies were conducted by the Bureau of Mines to develop a process for preparing thorium-magnesium master alloys or pure thorium metal by magnesium reduction of thorium tetrachloride in a semicontinuous reactor. Thorium tetrachloride was prepared in a fluidized-bed reactor by chlorination of thorium oxide or thorium oxalate. Conditions were established for producing a suitable thorium oxide feed for a fluidized-bed reactor. Thorium tetra-chloride was purified by vacuum sublimation and subsequently reduced by magnesium in a semicontinuous reactor to form thorium-magnesium alloys. Relatively pure thorium was produced by removing magnesium from the alloys by vacuum sublimation. Close to 100 percent of the thorium fed into the reactor was recovered either as metal (~93 percent) or as thorium oxide (~7 percent). The oxide can be recycled directly into the process.

Jan 1, 1971