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By Mridul Gautam, Alex Bugarski

Size Distribution and Deposition in Human Respiratory Tract: Particle Mass and Number Aleksandar Bugarski and Mridul Gautam National Research Center for Alternative Transportation Fuels, Engines and Emissions Department of Mechanical and Aerospace Engineering West Virginia University TOXICITY OF ULTRAFINES (MAUDERLY et al.) ? FINER PARTICLES PENETRATE MORE READILY INTO CELLS AND TIXROUGH TISSUE BARRIERS ? FINER PARTICLES HAVE GREATER SURFACE AREA PER UNIT MASS, AND A LARGE NUMBER OF TOXIC REACTIONS OCCUR AT THE SURFACE ? FINER PARTICLES DISSOLVE MORE READILY THAN LARGER PARTICLES THUS ENHANCING THE BIO- AVAILABILITY OF SOLUBILIZED COMPOUNDS EPIDEMIOLOGICAL STUDIES INDICATE THAT THE IMPORTANCE OF ULTRAFINES REMAINS SPECULATIVE

Objective Develop a method to warn of hazardous conditions and enhance safety during operation and inspection of vertical mine shafts and hoists. Background Mine hoisting is the most critical and potentially the most dan¬gerous operation in underground mining. Many hazards are related to falls of miners and materials, ground instability, and malfunction or lack of safety devices. All have the potential to cause a cata¬strophic accident. A condition known as "slack rope" is particularly dangerous, expecially if it occurs without the operator's awareness. The most common occurrence of slack rope is in metal or nonmetal mines that have a history of ground control problems near the "haft. Approach Studies of hoist safety features and Mine Safely a and Heath Administration (MSHA) accident statistics suggests a need to measure wire rope tension, conveyance speed and position, and shaft guide misalignment. The most accurate data are obtained directly from the conveyance. Such data could warn of potentially dangerous situations during hoisting operations, as well as during inspections, maintenance, and lowering of large equipment. Figure I shows the concept for monitoring wire rope tension, conveyance position, and guide displacement. Progress to Date A conveyance-mounted system has been developed that monitors rope tension: hoist conveyance position, speed, and load; and shaft guide misalignment. A "flex-beam" load sensor mounted just above the- conveyance protects against slack and tight rope. The measurements are transmitted 60 times a second via wireless equipment from the conveyance to the hoist room. An encoder mounted on the conveyance eliminates the need to correct the position because of rope stretch. Figure 2 shows the encoder wheel and guide displacement sensors being mounted on a cage in¬spection deck. A potentiometer monitors misalignment of the shaft guides during inspections. Information about the cage or skip can be acquired by the shaft inspector using a hand-held indicator. Inspection can also he conducted remotely from a station or hoist room using the wireless link to a laptop computer. Figure 3 shows test results from a simulated slack rope condition. Patent Status NIOSH has a patent pending on this device entitled "Cable-Load¬Sensing Device." For More Information NIOSH is seeking cooperators to assist in further tests of this technology to improve hoisting safety. Additional information can he obtained by contacting Michael J. Beus, Steven Iverson, or Elaine Cullen, Technology Transfer Officer, NIOSH, Spokane Research Laboratory, Spokane, WA 99207 at (509) 354-8000.

Feb 1, 1998

By Jeffrey M. Listak

The Bureau of Mines has conducted a rock mechanics study to monitor deformation of near-seam strata above a longwall panel in the Pittsburgh Coalbed. The primary goal was to determine the height of caving immediately behind advancing longwall face supports. This study, although site specific, provides information on the caving mechanism associated with longwall extractions so that strata behavior and its interaction with longwall face supports can be better understood. Two holes were drilled, approximately 550 ft apart along the center line of a longwall panel, from the surface to the coalbed approximately 650 ft below. Various downhole geotechnical instruments were used to monitor strata deformation. In addition, surface elevation surveys were conducted to differentiate between surface and subsurface activity. This report discusses the caving characteristics of the strata as the longwall panel approached and passed beneath the boreholes. Physical property data are also presented to demonstrate the relationship between caving behavior and local geology. Data show that immediate caving of strata above the longwall face occurred at a height less than 23.5 ft and that strata behavior above longwall extractions is highly dependent upon lithology, with major disturbances occurring at weak lithologic zones.

Jan 1, 1986

By Bertrand L. Johnson

Langbeinite, a comparatively rare mineral that has been reported from only five countries in the entire world, has recently attained considerable economic importance in the United States and Poland. Since September 1940, several hundred thousand tons have been produced in one of the Carlsbad (N. Mex.), potash mines for chemical and fertilizer use. As it is a newcomer in this field, and as it is the source of fertilizers possessing special advantages, notably for soils deficient in magnesium or requiring sulfate fertilizers, a discussion of its properties, occurrences, uses, mining, and treatment is appropriate at this

Jan 1, 1944

By D. E. Redmon

Linear programing provides a mathematical technique by which activities can be planned in such a way that an optimal result is obtained. Routine applications of linear programing require only a knowledge of algebra. However, a complete understanding of the fundamentals of linear programing requires a knowledge of advanced mathematics. The purpose of this publication is clarification of terminology and illustration of applications in comparatively simple mining problems. Two mining situations are considered: Mine stopes from which ore is to be produced at a minimum production cost; also, uranium mines from which ore is transported to one mill, a maximum monetary value is desired. The details of data arrangement for solution by linear programing are described and the solutions are presented. Results of these solutions indicate successful applications of linear programing to mine production scheduling.

Jan 1, 1964

By L. B. Berger, W. P. Yant, J. B. Littlefield

"INTRODUCTION Hydrogen sulphide (H2S) is one of the most toxic industrial gases and of relatively wide occurrence in industry. Among its common industrial occurrences are, in the production and refining of high-sulphur petroleum, in natural gases, in gypsum and sulphur mining, in rock strata and underground waters (where it is encountered in tunneling and caisson work) in blasting with black powder and in blasting high-sulphide ores with other explosives, in gas manufacture, in the carbonization of coal, and in the manufacture of chemicals.The usual methods of detection, other than by the sense of smell, which is lost in 2 to 15 minutes' exposure to 0.010. to 0.015 percent of this gas, 5/ either are too cumbersome for frequent and rapid analyses or, like the wet lead acetate paper test, afford only qualitative results. A qaantitative determination usually involves the use of solutions, bubblers, flowmeters, standard solutions, burettes, and indicators manipulated by trained technical men. All apparatus and methods in common laboratory use are, in general, unsuitable for the field.The physiological response attending exposure to various Concentrations of hydrogen sulphide in air, is as follows, in percent by volume 6/:0.005 to 0.010: Subacute poisoning - slight symptoms, such as mild conjunctivitis and respiratory-tract irritation after 1-hour exposure."

Jun 1, 1935

By M. H. Kline

The Chestatee mine is one of several well known pyrite deposits in Georgia that are reputed to carry appreciable quantities of copper with the ore. The deposit is? in Lumpkin County on the Chestatee River, 6 miles northeast of Dahlonega (fig. 1). Old records and reports indicated the probable existence of an extensive unmined ore body, but the mine is inaccessible at present. The Bureau of Mines, after studying old maps and records, decided to cor8-drill along the strike of the lense beyond the limits of the indicated old workings in an attempt to extend the possible reserves. The advantageous location of the property indicates that it could become an economic source of pyrite to be used for the manufacture of sulfuric acid. Iron sinter resulting from the roasting of the ores could be sold at a premium in the Birmingham, Ala., area, and the copper content could be extracted to help replace the nation's depleted resources of this metal.

Jan 1, 1949

By G. H. Cobb, J. L. Johnson, H. H. Heady

An infrared absorbance technique is described for analyzing anodic gases produced during the electrowinning of uranium , thorium , and rare - earth metals in molten fluorides . Typical components determined qualitatively in a gas sample are CO , CO₂ , CF4 , C₂ Fe , C3F8 , COS , CS₂ , and SiF4 . About 20 minutes are required to record and interpret the spectrogram , and report quantitative results for CO, CO₂ , CF4 , and SiF . The procedure is used for control during electrolysis .

Jan 1, 1964

By G. B. Gait

This report is the fourth in a series concerning the Bureau of Mines program for microfilming maps of abandoned mines in the Pennsylvania anthracite region; a catalog of the microfilmed maps of 70 mines in the Western Middle field is presented. Previous reports were catalogs of microfilmed maps of mines in the Eastern Middle field and in the Wyoming and Lackawanna Basins of the Northern anthracite field. Additional catalogs will be published as the microfilming of significant mining areas is completed.

Jan 1, 1971

By H. H. Schrenk, F. E. Griffith

"The increase in tunneling operations that requires working under pressures greater than that of ordinary atmosphere has raised the question of the use and possible limitations of respiratory protective devices under such unusual conditions. As little, if any, information is available, there is need for a comprehensive study of this subject before specific recommendations can be made. In the absence of such data it seems desirable to make a few preliminary observations regarding the problems associated with wearing respiratory protective devices under increased air pressures.Two distinct problems must be considered--the mechanics of the apparatus used under such conditions and the physiological effects of increased pressures on wearers of respiratory apparatus. This report is confined to the use of oxygen breathing-apparatus and gas masks under pressure.ACKNOWLEDGMENTSThe data presented were obtained at the Queens Midtown Tunnel under construction at the east end of 42d Street, New York City, during a study of compressed-air illness conducted by the Bureau of Mines in cooperation with the United States Public Health. Service and the New York City Tunnel Authority.Grateful acknowledgment for cooperation and the use of facilities is made to Dr. R. R. Sayers and his associates, particularly Dr. J. W. Crosson (who acted as observer during the oxygen breathing apparatus tests), of the Division of Industrial Hyiene, National Institute of Health; to the Port of New York Authority, through Dr. Edward Levy; end to the contractors, through Doctor Emery."

Jan 1, 1940

By W. P. Yant

[At the majority of mines where flame safety lamps are used either as working lights or as a means of detecting gas, no check it made on this condition of the various parts of the lamp and their assembly other than a visual ink inspection. Although this inspection should be made carefully in view of tae serious consequence that may follow Vie use of a faulty lama, In many instances the inspection is of a perfunctory nature. The Bureau of Mines has therefore designed a small box or gallery for testing lamps for defects and improper assembly before they are taken into the mine. The test simulates the condition when a lamp is extinguished by its introduction into an explosive mixture and the operator attempts to relight the wick while the lamp contains the explosive mixture. This test is more rigorous than merely subjecting a lighted lamp to an explosive methane-air mixture. In the latter test the products of combustion tend to blanket the propagation of flame from within the lamp to the exterior, especially if there are defects at the top of the gauzes. Moreover, when the lighted lamp is subjected to an explosive methane-air mixture the methane builds up slowly within the lamp until the lower inflammable limit is attained, whereupon a feeble explosion occurs within. If the nonlighted lamps is first filled with the methane-air mixture that gives the maximum violence and is than ignited, the dampening effect of products of combustion is obviated and the strain on defects is]

Jan 1, 1930

By R. J. Seibel

A statistical comparison of the dust exposures of coal miners with identical occupations in Pittsburgh, Pocahontas, Freeport, and Kittanning seams was conducted. Results indicated that, in some cases, identical occupations have different dust exposures in different seams. For example, the continuous miner operator in the Pittsburgh and Pocahontas seams is exposed to more dust than the same man in the Kittanning seam, but the Kittanning seam has more dust along the haulage roads than the other seams. Also, average dust exposures for similar occupations in continuous and conventional mining operations are similar.

Jan 1, 1974

By James A. West

THE South Asian countries of India, Ceylon, Pakistan, Afghanistan, Nepal, Bhutan, and Sikkim have a large variety of mineral resources; however, in spite of mineral industry growth during 1964, development of resources remained far short of possible development, and, in terms of value of trade in minerals, the area remained a sizeable net importer. India's mineral industry is by far the most significant; its minerals production in 1964 accounted for more than 90 per cent of the total value of all minerals produced in the area. The total value of all minerals produced in South Asia in 1964 was only about 1 percent of the area's estimated gross national product of $55,125 million. Despite the rather small current contribution of minerals to the economy, development of mineral resources figures prominently in plans for the industrial development of the nations of this area.

Jan 1, 1966

By H. R. Babitzke

The purpose of this Bureau of Mine- investigation was to develop columbium and tantalum alloys suitable or u at elevated temperatures. Columbium and tantalum were combined with tungsten, hafnium, zirconium, molybdenum, vanadium, and titanium, and the resulting alloys were evaluated with respect to workability, hardness, electrical resistivity, strength at elevated temperatures, oxidation resistance, and weldability. Cb-33Hf-10W-10Ti, Cb-20111-5Mo, and Cb-30Hf-5Mo exhibited superior high temperature properties. Cb-33Hf-10W-10Ti had tensile strength values of 44,300 psi at 1,200° C and 16,500 psi at 1,400° C, Cb-20Hf-5Mo had values of 35,700 and 20,700 psi, respectively. The corresponding values for Cb-30Hf-5Mo were 38,900 and 17,800 psi. These alloys are fabricable by conventional methods with excellent strength at temperatures up to and including 1,400° C. An oxidation rate of 7 to 21 mg/cm2/hr was observed up to 1,000° C.

Jan 1, 1967

By Raymond F. Helinski, Linda J. McWilliams, Sean Gallagher, Thomas R. Battenhouse, August J. Kwitowski, John R. Bartels, Dean H. Ambrose

This report examines the boom arm vertical speed for roof bolting machines to study a moving boom arm appendage at different speeds during different work scenarios. The goal of this study is to determine the impact of the appendage speed on the likelihood of the operator's hand, arm, head, or leg making contact, such as touching the moving appendage. The overall research goal is to reduce workers' risks to injury from exposure to underground mining machinery. Accident investigation reports from the Mine Safety and Health Administration do not usually contain enough information to aid in studying this problem, and lab experiments with human subjects are not feasible because of safety issues. As an alternative, researchers used a unique computer simulation model that uses a virtual human, vision tracking, and generates random virtual human motions and risky work behaviors. By using specialized software to simulate the computer model, researchers accurately identified potential hazards of tasks where it is not possible to perform experiments with human subjects. Results of a frequency distribution analytic approach show that, regardless of other variables, contact incidents were always greater when the boom was moving up, always greater on the hand, and always greater or the boom arm part of the machine. The reason why the subject experiences more contacts when the boom arm is moving up rather than down is that more risky behaviors occur during drilling and bolting when the boom is ascending. Results of a cross-tabulation analytic approach show that the 25th-percentile operators experienced more contacts than other operator sizes and had most of their contacts during a boom speed of 13 in/sec. The hand-on-boom behavior during drilling and bolting tasks experienced more contacts than other work behaviors, and both tasks had most of their contacts during speed 13 in/sec. The 60-in seam experienced more contacts than other seam heights and had most of the contacts during speed 16 in/sec. For univariate logistic regression models, seam height is the most important predictor of the probability of a contact. However, a multivariate logistic regression model predicted contacts are more likely with the both-knee work posture in the 60-in seam, a 25th-percentile operator compared to a 55th-percentile operator, and speeds 16 and 22 in/sec compared to 7 in/sec. Results of a survival analytic approach suggest that controlling the boom speed is the most important factor in determining the risk of an operator making contact. Based on the data collected, boom speeds greater than13 in/sec result in a substantial increase in risk to the roof bolter operator making contact. Speeds less than or equal to 13 in/sec are associated with a more modest relative risk of making contact, which represents a decrease in potential hazard. Virtual operator's response time has little effect on the number of contacts experienced. The mining industry can use the information in this study to reduce the likelihood that roof bolter operators will experience injury due to contact with a moving roof bolting machine's boom arm.

Jan 5, 2005

By C. W. Owings, L. D. Tracy

"IntroductionMany bituminous coal-mining companies have inaugurated extensive safety Programs, but the failure to have approved or permissible equipment or safe practice in only one part of a mine has resulted in disaster. The necessity of using only equipment bearing the U. S. Bureau of Mines approval plate is emphasized by the fact that many accidents are the direct result of carelessness on the part of trusted employees using non-permissible equipment. A concrete example is found in the case of an explosion on October 26, 1926, in a mine in the Pittsburgh district, Pennsylvania.Story of the ExplosionAt about 10 o'clock on the night of the explosion an examination was made in No 2 butt left and parallel off 7o. 14 north, and was found to be clear of dangerous accumulations of gas. (See figure). Several hours later a crew of two men brought a self-propelling rock-dusting machine within 50 feet of the face of Po. 2 butt parallel before they examined for gas. The machine operator found an accumulation of explosive gas about 18 inches from the roof. He began to wave his arms thoroughly mixing the gas and air. Undoubtedly a highly explosive mixture was created, and as the men attempted to run the machine back to fresh air an explosion occurred.The helper dropped to the floor and was burned about the face and wrists. The machine operator ran down the entry and was more severely burned about the face, neck, and arms. He later developed pneumonia and died. Both men reached the door in the chute between No. 14 and No. 15 north. A pumper, who had felt the rush of air, found the men and helped them to walk outside."

May 1, 1927

By Charles B. Kenaban

The possibility of using ultrasonic energy as a tool to improve the electrolytic deposition of copper and zinc from several electrolytes was investigated by the Federal Bureau of Mines. Sound with frequencies of 20, 26, 38, and 400 kilocycles per second and acoustical intensities of 0.25 to 1.5 watts per square centimeter was employed. Measurements of cell voltage, anode and cathode current efficiencies, and electrode potentials were made at various current densities. Effects of ultrasonics on the quality of the deposit and on anode corrosion also was noted. In the electrolytic recovery of copper from an acid copper sulfate solution at 50° C., adherent, well-consolidated deposits are normally obtained up to a current density of 30 amperes per square foot. As the current density is increased above this value, the deposits normally become progressively more spongy and less adherent. Ultrasonic irradiation resulted in adherent and well-consolidated deposits at current densities up to 300 amperes per square foot. Radiation also produced smaller grain size and preferred orientation of the copper crystals. In addition, radiation caused as much as 3-volt decreases in cell voltages at the higher current densities. These decreases were caused chiefly by depolarization of the anode, although small depolarization effects were also noted at the cathode. Radiation apparently did not greatly affect cathode-current efficiencies, but prevented excessive anode corrosion at the higher current densities and resulted in more uniform corrosion. Ultrasonic radiation at a frequency of 400 kilocycles per second was not as effective as radiation at the lower frequencies. Circulation of the electrolyte at rates up to 5 percent of the cell capacity per minute did not produce results comparable to those effected by ultrasonic radiation. Rapid rotation of the cathode up to 1,800 revolutions per minute gave results approaching those obtained with ultrasonics.

Jan 1, 1961

By Thomas O. Llewellyn

This U.S. Bureau of Mines (US8M) report presents a concise review on sources, processes, supply, and historical use patterns of domestic cadmium. It also covers a preliminary estimated cadmium material balance for the year 1989.

Jan 1, 1992

By S. A. Matthes

This Bureau of Mines report describes analysis of a copper slag for 13 elements from a single sample solution by flame atomic absorption spectroscopy. Samples are dissolved with 7 ml of an HC1-HF-HN03 (3:1.5:2) mixture in heated plastic pressure vessels. A 1.5-pct boric acid solution is added to dissolve precipitated fluorides and to reduce matrix effects that interfere with atomic absorption analysis. Preparation time is less than 1 hour per batch of 10 samples. Total analysis time is less than 6 person-hours for 130 determinations with an average relative standard deviation of 1.83 pct for the 13 elements. Simple acid standards were used for all determinations. Values obtained by this method are in excellent agreement with values obtained by slower, more costly procedures.

Jan 1, 1980

By J. W. Griffith, J. L. Stauffer, L. M. Demers, D. C. Kuhn, S. Riliog

"The relative activation of eicosanoid production which results from the exposure of the alveolar macrophage (AM) to mineral dusts is thought to be a key factor in the pathophysiology of occupational lung disease. We compared in vitro basal and silicastimulated production of prostaglandin E2 (PGE2) and thromboxane A2 (TXA2) by AM from normal humans and non-human primates (Macaca nemistrina). In addition, we instilled mineral dusts directly into one lung of the non-human primate and evaluated AM eicosanoid production at two week intervals following dust instillation. Unstimulated AM from humans produce more PGE2 and TXA2 than do AM from M. nemistrina. However, in vitro exposure of AM from both species to silica dust produced a qualitatively similar increase in TXA2 production accompanied by no change in PGE2 production. Sequential analysis of AM eicosanoid production following a single bolus exposure to bituminous or anthracite coal dusts, titanium dioxide (Ti()i) dust or crystalline silica showed marked variability among individual non-human primates in qualitative and quantitative aspects of dust-induced eicosanoid production. However, the rank order of potency of the different dusts (silica> anthracite> bituminous) correlated with epidemiological evidence relating the type of dust mined to the incidence of pneumoconiosis. These studies suggest that the non-human primate may serve as a model for the study of both the role of eicosanoids in the etiology of dust-induced occupational lung disease and the biochemical basis for individual variability in the response of lung cells to mineral dust exposure. IntroductionOccupational inhalation of mineral dust can lead to chronic debilitating lung disease ( 1,2). One of the key components of the disease process is thought to be the interaction of mineral dust with the alveolar macrophage (AM) and the subsequent release by the AM of inflammatory and fibrotic substances (3,4). Chronic inhalation of mineral dust, depending on the type and amount of dust, may then produce a situation in which ongoing inflammation, accompanied by the destruction of functional lung tissue by products of activated AM and polymorphonuclear neutrophils, stimulates the production of nonfunctional matrix by lung fibroblasts.The AM produces several oxygenated derivatives of arachidonic acid (AA) which may play important roles in dust-induced lung pathophysiology (5,6). In previous studies in the rat, we found that prostaglandin E2 (PGE2). thromboxane A2 (TXA2) and leukotriene 84 (L TB4) were the major AA metabolites produced by AM (7). PGE2 is associated with pro-inflammatory activity (8) as well as anti-fibrotic activity since it downregulates interleukin -1 (IL-1) and tumor necrosis factor (TNF) release by AM (9-11). TXA2 is known to stimulate platelet activity, cause bronchial and vascular smooth muscle contraction (12) and to possess chemotactic activity (13). LTB4 is chemotactic for neutrophils and monocytes (14) and has been suggested as an additional regulatory factor in the release of TNF by AM exposed to silica dust ( 15)."

Nov 1, 1995