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By V. L. Gravitis

Radioisotope X -ray techniques of analysis for nickel have been tested in laboratory and plant trials. In the laboratory tests. a comparison was made of radioisotope and conventional analyses for nickel in solid s samples taken from streams of a nickel concentrator. Coefficients of variation of 1.7% for feed and concentrate samples , and equal to 10% for final tailing samples, were obtained. Continuous determination of nickel in final tailing slurries was demonstrated in a trial lasting 20 days at a nickel concentrator (Western Mining Corporation), nickel being determined with a standard error of 0.036% Ni in the slurry solids within the range of 0.24 to 0.68% Ni. This error, obtained by comparison of on-stream probe analyses with assays of samples taken from the stream, includes errors in sampling and assay by conventional techniques.

Jan 1, 1977

By F. Tanaka

Copper losses to discard slag have long impacted on the profitability of copper smelters. Businesses based on the treatment of secondary materials have also revealed that copper losses are indices of precious-metals losses. Many custom smelters are thus required to obtain more reliable controls for reducing copper losses than ever before. Mitsubishi Materials Corp. has cooperated with academic research institutes in conducting research projects on the pyrometallurgical fundamentals of copper smelting systems, including mutual evaluation of magnetite behavior between synthetic and industrial slags. The state-of-the-art pyrometallurgy has subsequently been introduced to Naoshima smelter for controlling the Mitsubishi process. The revised controls function successfully and the operational results demonstrate that avoiding the discharge of solid magnetite from the S-furnace is quite effective to reduce copper losses. Magnetite behavior has been controlled over the Mitsubishi process so as to reduce copper losses while satisfying the needs of recycling businesses growing in Japan. In-situ estimation of magnetite behavior using the absorbed heat from the melts to cooling water will also be discussed.

Jan 1, 2007

By Alyson Morley

The mining sector in Canada is facing significant challenges to develop a competent workforce, including increased technical and logistical operational demands, and the imperative to promote local content. There is an increasingly unpredictable labour pool which can be aging, or have skill shortages, or non-aligned skills. As globalisation continues, companies also require efficiencies during operation across various locations. AMEC has met these challenges in the global oil and gas sector by developing our Capability Development and Competence Assurance (CDCA) program. CDCA is applicable across all process industries, including mining. CDCA supports simultaneous consistency and flexibility by defining competence at task level, with corresponding best practice blended training programs, and evaluation criteria and processes. CDCA then defines role profiles mapped to local task definition. When combined with web-based technology, this granularity allows us to manage high volume workforces, while retaining individual learning plans and progression, aiding job satisfaction, and employee retention.

May 1, 2007

By Beaumier. M., J. -P. Lalonde

"Les réultats obtenus dans les sols sur quatorze aires d'essai et six cheminements régionaux dans I'A bitibi-Témiscamingue indiquent clairement qu'il existe des variations régionales importantes dans les teneurs en éléments traces de l'horizon A1 formé sur l’épais recouvrement glacio-lacustre de cette région. Les anomalies obtenues correspondent à celles qui ont été décelées lors de précédents levés des eaux souterraines et du till de base.Selon les critères d'évaluation utilisés, treize des quatorze aires d'essai ressortent comme anomales dans Ie contexte abitibien; dix de celles-ci sont tres anomales. Ceci suggère fortement qu'un levé régional de sols, fondé sur une approche multi-éléments, identifierait entre 70 et 90 % des cibles géochimiques reconnues par des échantillonnages en profondeur. Les résultats d'un échantillonnage systématique effectué sur une région de 1000km2 viennent aussi appuyer cette hypothèse. Conséquemment, les sols formes sur les sédiments glacio-lacustres sont un médium très utile pour inventorier de grandes regions recouvertes par ce typ e de sédiments.L 'horizon A1 est Ie plus utile pour ce type de levé parce qu'i1 est facil e d échantillonner, qu 'it assure une plus grande constance du typ e de matériel échantillonne et qu'il contient des teneurs accrues.De multiples mécanismes de dispersion géochimique ont joué des rôles d 'importance variable pendant et après la mise en place des sédiments glacio-Iacustres. Les plus importants sont la pression hydrostatique, la diffusion chimique et électrochimique ainsi que la bio-accumulation. Si on veut progresser dans la connaissance de ce milieu complexe, on devra adopter une approche plus systemique tenant compte de I'interaction des mécanismes agissant dans l'environnement global avant, durant et apres Ie depôt du mort-terrain."

Jan 1, 1984

By Corrie Pitzer

Safety performance in many companies and even industries has stalled in the last decade. Accidents rates are improving but more slowly and yet, serious accidents and fatality rates are not: in fact, these rates of more serious incidents have plateaued or deteriorating. In more dramatic cases, organizations that had ?exemplary? safety statistics, suddenly had a catastrophic or multi-fatality event occurring. Popular books such as In Search of Excellence of Peters and Waterman or Good to Great of Jim Collins created many delusional ?secrets? or recipes, to achieve great performance and yet, most of those ?great? or ?excellent? companies have now declined in their performance, some dramatically and some have fallen from grace, like Fanny Mae, a company Jim Collins identified as a ?great? one, that had to be bailed out in the latest financial crisis. These organizations share several ?delusions? about managing a business, and often, these delusions are created by academics, consultants and authors of popular books about (safety) management. More damaging however is that safety management is defined by a set of key practices or axioms: a focus on human error, compliance to rules and regulations, creating consistency of systems and actions, reacting to accidents and incidents and on prevention of those, measuring safety with performance metrics and rewarding employees on those measurements. All of these axioms contain the seeds of destruction, and they create conditions and dynamics that precede the disaster - and ironically, they are all 'good things' we do in safety management. For example, a mere focus on safety in the business, and the measurement of it, create a culture of repression of mistakes and incidents, leading to a situation where the organization knows incrementally less and less of risks and risktaking behaviour - until the day it all coincides destructively! This paper discusses seven such safety delusions and how they impact on the views and safety management approaches. They are: ??The delusion of (risk) control, that risks can actually be identified, analyzed and mitigated. ??The delusion of compliance, that mere compliance to rules will safeguard the business ??The delusion of consistency, that standard operating procedures will ensure safe operations ??The delusion of predictability, that accidents and trends tell us everything about the risks of the future ??The delusion of human error, that people are the weakest link and that it can actually be dealt with through discipline and enforcement. ??The delusion of statistical trends, that safety is measurable with statistics ??The delusion of invulnerability, that we have achieved high levels integrity and capability to deal wit risks. Organizations that suffered catastrophes all share some or all of these delusions and this paper traces how these played a role in many disasters, ranging from the Titanic, Challenger, Piper Alpha, Bhopal, BP Deepwater Horizon and many more.

Aug 1, 2013

By W. A. Jones

THE estimation of the average value of gold ore involves many considerations, among them the correct sampling of the deposit, the dilution by waste, and the loss of high-grade fines. It is a common experience that, after all these factors have been evaluated, adjustment of the assays is necessary before satisfactory agreement between the calculated mine grade and the mill heads is obtained. In fact, at many mines the latter correction overshadows all others in the preparation of routine estimates. For this reason it is proposed to deal only with the mathematical treatment of mine assays and the problem of bringing estimates into conformity with the corrected mill heads. Mine assays differ from physical measurements because the range of values is very great and these are not symmetrically distributed above and below the average, there being fewer high than low results. There is no widely accepted mathematical procedure for determining the average of series of measurements which exhibit these characteristics. Customary practice consists in empirically reducing high assays until a satisfactory agreement with mill heads is reached. It was thought that more confidence could be placed in grade estimates if a logical basis for calculations could be devised .. In an attempt to find a fundamentally sound procedure, amenable to practical application, many series of assays comprising over 235,000 channel samples (1) were studied at Hollinger Consolidated Gold Mines, Limited. Such an investigation could only be made where records covering many years of operation are available and where tabulating and calculating machines are in use. The results are recorded in the hope that the relationships noted for the large groups of assays used are of fundamental character and that the data will be useful to others dealing with the problem of grade estimation.

Jan 1, 1943

By Jerry C. Tien, Yingjiazi Cao

"Coal spontaneous combustion (SponCom) is a natural phenomenon in underground operations, which can either happen naturally or be triggered by human activities. For underground operations, espe-cially in coal, SponCom can happen frequently as a result of air leakage, although its incubation period may vary depends on types of coal and surrounding environment, resulting in uncertainty in control. In China, most of the underground coal operations now use longwall mining method because of its superior safety, high productivity and efficiency. With an increased popularity, there is also an increasing necessity to study spontaneous combustion, its occurrence and management. There have been many theoretical analysis and experimental studies over the past half century hoping to understand the occurrence of coal combustion and its control measures to better understand the occurrence and to design controlling measures to limit the dam-age it causes. In this paper, research on coal spontaneous combustion fundamentals from these three aspects will be reviewed, gaps highlighted and possible directions for future studies. INTRODUCTION The history of anthropic development is the history of human's energy utilization progress. From the first usage of fire, people have been continuingly seeking energy resources on earth. Coal, as an abundant, economic and convenient source of fuel quickly became indispensable and made significant contribution to economic growth worldwide. With technology and societal development, people are becoming more and more coal-dependent, but at the same time, problems of fossil fuel combustion came into sight. In global coal mining industry, spontaneous combustion has now presented one of the most challenging safety issues, it is also believed that it has contributed significantly toward the climate change. It is essential that more effort be invested to examine the cause of SponCom and its control measures. Coal SponCom is a complex process, with both physical and chemical inter-actions among various interrelated factors such as local airflow distribution, ventilation pressure, methane emissions (if any), and physical surroundings underground. With the advent of powerful computers, simulation techniques and af-fordable modelling packages in recent years, significant advances have been made in understanding sponta-neous combustion. But because of the complex nature of combustion and varying underground conditions, there are still areas that need further examining. This paper will focus on illustrating the current research of coal spontaneous combustion and addressing research gaps and future study areas."

Jan 1, 2019

By B. Caldwell

"The CompanyCardinal River Coals is jointly owned by Luscar Ltd. and the Consolidated Coal Company of Canada (Consol). The Luscar mine is operated by Luscar Ltd. and is located 40 km south of Hinton near Cadomin, Alberta (Fig. 1). The plant sits on the old townsite of Luscar, Alberta, which was founded in order to develop the coal in 1912 (Fig. 2). Initially, the coal was mined by Luscar Ltd. for heating and steam generation and used quite heavily by the railways for their steam locomotives. In 1955, the mine was decommissioned as the demand for coal for tl1ese purposes had dropped off. In 1969, the mine was re-established by Cardinal River to provide metallurgical coking coal for its customers in Japan. The coal is mined from the 13m thick Jewel Seam by open pit methods at a 10 to 1 stripping ratio. The run-of-mine coal is then cleaned to meet customer demands.The PlantThe clean coal preparation facilities at Cardinal River were extended in 1980 in order to increase the feed rate from 450 t/h to 800 t/h. The extension is a separate plant which can be operated on its own or in parallel with the old plant. In addition, modifications have been made to the fine coal circuit (hydrocyclones added), the coarse refuse circuit, (refuse bucks replaced by a refuse conveyor which backfills a pit), and the fine refuse circuit (solid bowl refuse centrifuges, refuse classifying cyclones, and hydra-rake thickener no longer utilized) since the plant was built in 1969. The plant production of 3 M t per year with a yield of 78% is achieved by first screening and breaking the run-of-mine material to a top size of 1 ½ in. The feed is then slurried, sized, and processed in three different washing circuits. The washed coal is mechanically dewatered, thermally dried, and then stored in a 14 500 t capacity silo or on a 300 000 t stockpile. The fine refuse is thickened and pumped to the same pit to which the coarse refuse is being conveyed"

Jan 1, 2000

Mirador - Overview ? Located in Andean foothills of SE Ecuador ? Copper-gold porphyry hosted by calc-alkaline Late Jurassic granitic and porphyritic rocks ? 438 MT of 0.61% Cu and 0.19 g/t Au measured and indicated resources (at 0.4% Cu cut-off) ? Additional inferred resources of 235 MT of 0.52% Cu and 0.17 g/t Au ? Initial 25,000 tonnes/day production, expanding to 50,000 in year 6 320 MT of 0.62% Cu, 0.2 g/t Au ore mined at an average 1.4:1 strip ratio over a 21 year mine-life

May 1, 2006

By E. R. Weltevreden, C. Klauber, C. Vernon

"In this paper a review of the current status in recycling technologies for cathode ray tubes is given for both the glass and phosphors. Particular emphasis is placed on the opportunities for the recovery of the rare earth elements (REE) from the phosphor coatings. This is placed in the market context of alternative virgin sources and some of the advantages and disadvantages for REE waste recovery. Future opportunities are explored and also some experimental detail on a low cost leach system is presented. INTRODUCTIONThe disposal of cathode ray tube (CRT) based colour televisions has accelerated world-wide with the development of high definition flat screen panels. The total number of colour CRT televisions that have been sold in the United States in the mid-20th century is estimated to have been over 2 billion (U.S. Environmental Protection Agency, 2007), with high current rates of disposal. It is estimated that of the 20 million televisions annually discarded, 78% are send to landfill (Nnorom, Osibanjo & Ogwuegbu, 2011). However, this easily accessible item of electronics cannot only be turned into a valuable resource using the right recovery procedures, it can also prevent the substantial environmental contamination arising from improper disposal. In this review we focus on previous and current work performed on the recycling of CRT based televisions. Due to the increasing demand for rare earth metals, the main focus will be on the possibilities and challenges of recycling the fluorescent phosphor powders on the CRT’s panel glass.CATHODE RAY TUBE’S GLASS RECYCLINGConventional cathode ray tubes consist of three main parts, the panel, the funnel and the neck (Figure 1). To produce the different colours on the screen, the inside of the panel is coated with a matrix of hundreds of thousands of small phosphor dots. Each dot is one of three types of coloured phosphors, emitting either red, green or blue light. These emit light when excited by a beam of electrons generated by electron guns located in the neck of the CRT. These beams pass through holes in the shadow mask and excite the phosphor coating on the inside of the panel, to give light of variable RGB composition, see Figure 1."

Jan 1, 2012

By Shugang Li

Coal and coal-bed methane are valuable energy resources. If they can be extracted simultaneously and safely, the triple purposes of mine safety production, new energy resource supply and environmental protection can be fulfilled. After mining, the mining induced fissure distribution feature and methane delivery behavior in overlying strata were closely related to the relieved methane degasification. Using physical simulation and numerical simulation, it was explained that the distribution feature of mining induced fissure was the Elliptic Paraboloid Zone (EPZ) in three-dimensional space. Based on the key stratum theory, the types, parameters, characteristics and dynamic evolution behavior of the mining induced fissure EPZ were analyzed. Applying environmental fluid mechanics and the mass transfer theory, the relieved methane floating-diffusion equation of the EPZ was established, and the corresponding transport process was analyzed. Using the field practice of relieved methane degasification in Tianchi Coal Mine, it explained that the mining induced fissure EPZ was the storage and delivery area of relieved methane. The degasification effect will thus be useful if the drainage system is laid in the EPZ. Such studies can provide the theoretical basis and technical support for the safe simultaneous extraction of coal and methane.

Aug 1, 2013

By M. Remillard, M. Garon, D. Hodouin, M. Therien

"Nineteen streams in the copper and zinc flotation units of the concentrator of the Matagami Division of Noranda Inc. have been sampled f or particle size distributions, chemical assays, and gold and silver contents in each particle size interval. The data are upgraded by the mass balance package BILMA T. These results, in conjunction with microprobe analyses, are used to quantify the silver losses in the copper cleaning flotation stages and to determine how over-all silver and three silver-bearing minerals are recovered in the plant final products. RESUMEDix-neuf produits des circuits de flottation du cuivre et du zinc de la division Matagami de Noranda Inc. ont été échantillonnés pour leur distribution granulométrique, leurs analyses chimiques et Ie contenu d'argent et d'or des fractions granulométriques. Le bilan métallurgique a été obtenu à l'aide du programme BILMA T. Ces résultats, couples avec une étude minéralogique a fa microsonde, sont utilisés pour quantifier les pertes argentières aux diverses étapes de nettoyage du circuit de cuivre et pour déterminer la répartition de l'argent et des trois minéraux argentifères dans les produits finals de l'usine."

Jan 1, 1988

By E. H. Hall

"Perhaps .I should start this talk on Arsine poisoning, by giving a brief background and history of the Bralorne Mill.The present Bralorne company started milling operations in 1932, with amalgamation and flotation, and operated continuously until 19 61 . In 19 59, it was decided to change over to cyanidation, and to use double filtration rather than counter current. The cyanide portion of this new plant was completed and went on stream in August 1961 utilizing the grinding circuit of the old flotation plant. The new grinding circuit was completed and started operating December 15, 1961.The grinding circuit consists of a 7 1 x 101 Hardinge Rod Mill, and a 7 1 x 101 Hardinge Ball Mill. In series with the rod mill is a 16"" x 24"" Denver Duplex Jig, and two of these jigs are also in parallel with the ball mill. The rod mill product is classified by a Kreb cyclone, the oversize going to the ball mill. The ball mill is in closed circuit with this same cyclone. The jig products are amalgamated daily, and the amalgam barrel tails are returned to the ball mill for regrind. Arsenious oxide (As203) is one of the reagents used in amalgamation. Approximately 39 ozs. per day is used.The cyanide circuit consists of a 481 x 121 thickener, three 24' x 24' agitators, two 141 x 161 drum filters and a Merrill Crowe precipitation unit.The Krebcone overflow is thickened to 60 - 62% solids. Hydrated lime, along with a settling agent is added to the thickener. Some of the overflow water from the thickener is returned for use in the jigs. The balance of this overflow water goes to waste. To the thickened pulp entering No. 1 agitator, barren solution is added, along with sodium cyanide and hydrated lime. Cyanide strength is held at 0. 9 - 1. 0 lbs/ ton solution and lime at 0. 8 lbs/ ton solution. The lime content usually drops to 0. 5 lbs/ ton in No. 3 agitator. The two drum filters are in series and are washed with barren solution. The discharge of No. 3 agitator is fed to No. 1 filter and the discharge of No. 1 filter is repulped in barren solution and feeds No. 2 filter. No. 2 filter discharges to tails, The filtrate is clarified, deaerated and the gold precipitated. One hundred to two hundred tons of barren solution are bled to waste each day. The ore contains 1 % Arsenopyrite and 1. 5% Pyrite."

Jan 1, 1964

By Staff

"The Weyburn Oil Field, located 80 miles southeast of Regina, Saskatchewan, was discovered by Central-Del Rio Oils Limited, in January, 1955. As of January 1st, 1959, the field had 357 wells capable of producing an estimated total of 45,100 barrels of oil per day.Highly portable, economical, drilling rigs are used to penetrate the pay at a depth of 4,400 to 5,100 feet. Presently, the complete drilling operation for an average field well, including drilling, coring, testing, and running casing, requires 12 days. Drilling procedures are conventional for a field of this depth and no serious problems exist. Central-Del Rio core the productive section of all their wells, which provides valuable information for well completions and reservoir studies. Production casing procedure is to set through the zone and perforate the productive inter-val. This was found advisable due to the lensing nature of the porosity and permeability throughout the reservoir, and to the high connate water saturation encountered in the tighter sections of the reservoir in the north and northeast areas of the field.Although a few wells in the field have produced naturally by flowing or pumping without acid treatment, it has generally been necessary to acidize the wells to make them commercial producers. To date, acid treatments appear to effect better stimulation of the limestone reservoir than fracturing treatments. Perforation sealing balls have been used as an aid in selectively treating all of the perforated interval.The majority of the field is on pump, producing at a low gas-oil ratio. The main part of the field has water-free production, with most of the water being produced in the north and northeastern area. Salt-water disposal is now available in the field through two disposal wells completed in the Basal Blairmore sand.The Midale Beds ""Marly"" and ""Vuggy"" zones form the principal reservoir, which is a stratigraphic trap, with the north and northeast edges terminated by a porosity and permeability pinch-out and the south-west and west edges bounded by water-laden porosity. There is no evidence to date of a gas cap. The reservoir apparently is producing on a fluid-expansion-type mechanism. The increasing water production in wells on the southwest and west edges of the field indicated water encroachment from these directions, and suggests some recovery energy may be available from this source.The total probable ultimate remaining recoverable reserves have been estimated at° 332,469,000 barrels of oil. Markets have not been able to keep up with the rate of development of the medium crude re-serves. However, it is felt strongly that substantial additional markets for Weyburn medium crude will be developed by the producers in the near future at realistic wellhead prices."

Jan 1, 1959

By R. Anthony Hodge

1. Today?s Reality: Voisey?s Bay EIA Activities of the Canadian Environmental Assessment Agency The Tulsequah Chief Decisions The Bank of Montreal The World Bank World Business Council on Sustainable Development The Government of Canada Many company policies

May 1, 2002

By Pritii Tam Wai Yin, Tony Leong, Neetu Bansal, James Vaughan, Amiel Boullemant

Mercury is a toxic element that is associated with many industrial activities including the Bayer process. Mercury is known to enter the Bayer process with the bauxite feed material and has the potential to accumulate as the process solution is recycled. This paper explores the speciation of mercury in Bayer process streams. The process parameters considered are the oxidising-reducing potential, basicity and temperature. The results of a refinery circuit survey are presented and compared with the thermodynamic predictions. Electrochemical measurements on relevant synthetic systems are also included.

Jan 1, 2014

By F. Crundwell, N. Steenekamp

"The leaching of sulphide minerals generates a significant amount of energy. There are three systems that might be used to remove this energy. These are: cooling coils, quench water, and flash recycle. Flash recycle is the recycling of slurry from the autoclave to the feed tank. Heat is removed in this arrangement when the slurry at elevated temperature and pressure is flashed to atmosphere, releasing steam. The slurry is returned to the autoclave at lower temperature, resulting in cooling. The cooling is directly proportional to the steam released from the recycled slurry. Design equations and results for the flash recycle system are presented. A fourth proposal for removing heat is to recycle slurry from the back of the autoclave. These four alternatives not only remove the heat, but also have an effect on the leaching efficiency. Amongst the four alternatives, design calculations indicate that the flash recycle option is the optimal solution in terms of leaching efficiency and heat removal, and recycling product from the back of the autoclave is the worst. In spite of its efficiency in terms of heat removal and leaching, the implementation of the flash recycle system is limited to a few operations in the platinum industry.INTRODUCTIONIn considering ways to improve leaching operations, focus is placed on the chemistry, on the kinetics, the agitation and perhaps even on the gas mass transfer conditions. Attention is less frequently placed on the removal of energy from these reactors and how this might limit performance.The pressure leaching of sulphides releases a significant amount of heat. For example, the reaction for the leaching of chalcocite, Cu2S, given by"

Jan 1, 2012

By Hans E. Madeisky, Bruce W. Downing

The acid rock drainage (ARD) buffering capacity of mine waste is governed by its bulk chemical composition and its mineral assemblage. Conventional acid base accounting (ABA) tests can be used to predict short-term buffering, but should be used with caution to model or predict the long-term ARD buffering capacity of mine waste. ABA data for mine waste samples from four different deposit types: an orthosite-hosted magmatic sul?de nickel, dunite-hosted magmatic sul?denickel, porphyry copper-gold, and volcanic-hosted high sul?dation epithermal silver, were compared with whole-rock geochemical and petrographic data obtained from the same samples. Our objective was to devise and test a method of predicting ARD buffering capacity based on bulk chemistry and modal mineralogy. In other words, we developed a quantitative theoretical method for calculating neutralizing potential, relying on easily obtainable and relatively inexpensive whole-rock and sulfur XRF analyses, which could substitute for conventional ABA procedures in situations where these procedures are either too costly or too time consuming. For each deposit type, models were devised that reasonably approximate the net neutralization potential estimated by the ABA data obtained from laboratory tests. Once an appropriate model has been developed and tested, portable X-ray ?uorescence equipment, already used for grade control at many mine sites, could provide the whole-rock and sulfur analyses required to estimate the ARD potential of the waste material. Although this approach is not intended as a substitute for the legally mandated ABA test procedure, it could facilitate the timely and cost-effective management and mitigation of ARD at a mine site.

Jan 1, 1997

By Hans E. Madeisky, Bruce W. Downing

Abstract-The acid rock drainage (ARD) buffering capacity of mine waste is governed by its bulk chemical composition and its mineral assemblage. Conventional acid base accounting (ABA) tests can be used to predict short-term buffering, but should be used with caution to model or predict the long-term ARD buffering capacity of mine waste. ABA data for mine waste samples from four different deposit types: anorthosite-hosted magmatic sulfide nickel, dunite-hosted magmatic sulfide nickel, porphyry copper-gold, and volcanic-hosted high sulfidation epithermal silver, were compared with whole-rock geochemical and petrographic data obtained from the same samples. Our objective was to devise and test a method of predicting ARD buffering capacity based on bulk chemistry and modal mineralogy. In other words, we developed a quantitative theoretical method for calculating neutralizing potential, relying on easily obtainable and relatively inexpensive whole-rock and sulfur XRF analyses, which could substitute for conventional ABA procedures in situations where these procedures are either too costly or too time consuming. For each deposit type, models were devised that reasonably approximate the net neutralization potential estimated by the ABA data obtained from laboratory tests. Once an appropriate model has been developed and tested, portable X-ray fluorescence equipment, already used for grade control at many mine sites, could provide the wholerock and sulfur analyses required to estimate the ARD potential of the waste material. Although this approach is not intended as a substitute for the legally mandated ABA test procedure, it could facilitate the timely and cost-effective management and mitigation of ARD at a mine site.

Jan 1, 1997

By J. Dong

"A “green” collector project has been initiated at Vale Base Metals Technology Development to replace xanthate. Bench and miniplant testwork showed comparable metallurgical results between xanthate and DTC (sodium dibutyl dithiocarbamate), a “greener” collector. During the first DTC plant trial, a strong interaction between the process water and DTC negatively impacted the metallurgy. The subsequent investigation showed that the quality of process water including suspended solids and dissolved metal ions had a significant impact on the performance with DTC, while less so with PAX. This paper explains these differences using UV spectrophotometry and batch flotation tests. INTRODUCTIONVale Base Metals is dedicated to sustainable mining and mineral processing. One of the key activities is to find a “greener” collector to replace xanthate (PAX: potassium amyl xanthate), which decomposes during storage and flotation causing CS2 emissions in the work place. As the most promising candidate, DTC (sodium dibutyl dithiocarbamate) was evaluated in the lab and miniplant (Dong & Xu, 2011). Consequently, a plant trial was conducted in the winter of 2010. However, the results were not as good as expected. The subsequent investigation showed that the quality of process water played a significant role in the metallurgical performance with DTC but less so with xanthate.From test work in 1996 and 1997, a series of batch tests were performed at Clarabelle Mill to investigate the winter/summer metallurgical shift with xanthate. As shown in Figure 1, the winter metallurgy was considerably worse than the summer metallurgy (Xu & Wilson, 2000). At 80% pentlandite recovery, the concentrate (Cu+Ni) grade was 21% in the winter and 26% in the summer. At 23% (Cu+Ni) concentrate grade, pentlandite recovery was 85% in the summer and 70% in the winter. In the summer, the process water is much cleaner, with very low concentrations of dissolved metals ions and suspended solids; while in the winter, the water is yellow and cloudy, with much higher suspended solids. Based on these results, it was concluded that the process water in winter has a detrimental impact on metallurgy."

Jan 1, 2012