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By A. J. Paul Laprairie

The process for which it is to be used is too often the only consideration in the design of a vessel. A de-sign allowing for practical manufacture and erection, as well as for proper maintenance, can often give over-all economies. Most platework in-stalled today is of welded construction. Therefore, metallurgical control is important in its manufacture. Also, because many concentrating and re-fining processes tend to be corrosive, the subject of protective coatings as a part of the manufacturing process is extremely important. The plant de-signer should know how to evaluate and specify controls for the metallurgy and for the coatings. Mining operations are becoming more sophisticated in the field of mechanical engineering. More and more emphasis is being given to preventive maintenance. The first step in any maintenance program, however, is good inspection service. This paper will suggest methods for the inspection of platework, and outline methods for repair and replacement.

Jan 1, 1963

By Philip J. Guerney, S. O’ Leary, André R. Laplante

"Concentration of dense mineral phases (s.g. greater than 7) for characterisation of individual particles and mineral grains by electron microscopy is a well established technique for the detection and characterisation of valuable mineral phases. This presentation describes the type of data that can be generated when both the concentration and characterisation steps are carried to higher levels than typical. The concentration step is the gravity recoverable gold (GRG) protocol that has been used for over 100 ore samples. This protocol yields three concentrates that represent three progressive degrees of grinding and liberation. Three ore samples were subjected to the GRG protocol and three size classes of each concentrate were characterised using the mineral liberation analyser (MLA), an automated, EDX-based tool. This presentation briefly presents GRG and MLA technology, and then focuses on the results obtained: photos, images and databank, the latter used to evaluate the extent of particle liberation and particle shape.INTRODUCTIONThe practice of gravity concentration prior to characterization of mineral samples using electron beam microscopy is solidly established. Typically, a dense liquid such as tetrabromoethane (density: 2.97 g/cm3) is used to reject the light phase, typically carbonates and silicates. The heavy phase, mostly sulphides, oxides and precious metals, is then mounted in a polymer matrix and examined using beam microscopy.Both the pre-concentration and the sample preparation/examination steps have seen significant advances over the past ten years, but are not without problems. A major issue of preconcentration is that most dense liquids used are toxic, tetrabromoethane being a prime example. More recently, a dense liquid with little or no toxicity (sodium polytungstate, distributed by Sometu Inc.) has become commercially available, but its use is limited to relatively low s.g. splits around 3 g/cm3. Dense liquids are viscous, and their use is limited to particles coarser than 37 µm, although centrifuge separation can probably lower this limit to around 10 µm. Magnetogravimetric separators can achieve much higher specific density cuts, but upgrading below 100 µm or in the presence of magnetic minerals remains a problem. The use of centrifuge separators such as the 3-in Knelson Concentrator (KC MD3) or the Falcon 4-in SB (SB4) is particularly attractive since these units can easily process large masses (by laboratory standards) and achieve a cut density well above those of dense liquids."

Jan 1, 2003

By C. George Miller

"As the influence of governments has become more widely felt, the use of research techniques to analyze policy has increased. Mineral economics, as one of the foundations of mineral policy research, has grown accordingly. Policy research and analysis has been carried out within governments, university departments and the private sector. Each of these institutional environments has characteristics which influence the topics of study, the approach, the methodology and the output of the research. A brief survey of recent research activities provides illustrations of trends and developments occurring within this organizational framework.A radically different organization, the independent research institute, has begun to make an impact on policy research in recent years, and will have an increasing importance in the future. Combining certain features of the traditional research organizations, it nevertheless has important differences which are essential to its effective functioning. An overview of the formation, goals, organization and operation of one such institute is presented."

Jan 1, 1976

By James K. B. Booth

The natural crustal abundances of the principle metals of commerce are examined in relation to production and prices for each metal. Two factors, the abundance x price ratio (BP factor) and abundance/production (B/T factor) are listed for each metal. Ideally, for these desirable commercial metals, each factor should be a constant and the same for all metals; comparing the divergences for the full list of metals allows conclusions to be drawn on the relative degree of natural availability of each metal and the ease or difficulty of winning the metal from the earth's crust. Plotting the two factors for each metal over the past decade of steady industrial usage illustrates the anomalous position of copper and, to a lesser degree, molybdenum and it is concluded that over the long term the price of copper will continue to rise steeply. Possible future prices for copper are examined and a suggested preferred order of ranking of the metals as exploration targets would be copper, nickel, tin, zinc, silver, molybdenum and lead, for the near term, with molybdenum possibly increasing its ranking in the list within the next decade.

Jan 1, 1971

By D. A. Grieve

"Mineable coal seams in the East Kootenay region belong to the Mist Mountain Formation of the Jurassic -Cretaceous Kootenay Group. Three structurally separate coal fields (Crowsnest, Elk Valley and Flathead) are recognized, all of which are characterized by compressional tectonic features such as f aiding and thrust faulting, and by /ate-stage normal faulting. Tectonic history has greatly influenced coal mineability and quality. Coals range in rank from low to highvolatile bituminous, and reactive maceral content ranges from less than 60% to greater than 90%. A wide range of metallurgical and thermal coal qualities is found. Measured reserves (up to 1981) include 1.03 billion metric tonnes metallurgical and 165 million metric tonnes thermal coal. Introduction a) Location -Coal fields of the East Kootenays region occur in the Front Ranges of the Rocky Mountains, within 30 km of the Alberta -British Columbia boundary (Fig. 1). They extend over 175 km north from near the U.S. border, and occupy the regions of the Crowsnest Pass and Elk and Flathead River drainages. The deposits are accessible from Highway 3 (Fig. 1) and various secondary roads. The towns of Fernie, Sparwood, Elkford, Coleman and Blairmore serve the coal industry. East Kootenay coal deposits are contained in three structurally separate coal fields, the Crowsnest, Elk Valley, and Flathead coal fields (Fig. 1). Coal is currently being produced by B.C. Coal (now Westar Mining Ltd.) at Sparwood, by Fording Coal 20 km north of Elkford, by Crows Nest Resources at Line Creek 15 km southeast of Elkford, and by Byron Creek Collieries at Corbin. Westar Mining has also constructed a new mine on the Greenhills Range 8 km northeast of Elkford. Pre-requisite engineering and environmental studies have been carried out on the Elco Mining property, 35 km north of Elkford, and on the Sage Creek coal property near the U.S. border (Fig. 1). b) Coal land tenure -Coal rights in the East Kootenays are either held as freehold land, or are licensed from the provincial government. The former category includes lands acquired under the Railroad Act of 1890. Shortly after this the federal government also obtained 50,000 acres of coal-bearing lands from the Crown Provincial, the so-called Dominion Government Coal Blocks. Major holders of coal rights in the area are Westar Mining and Crows Nest Resources. Large blocks are also held by Fording Coal and related companies, Sage Creek Coal, and Canada Permanent Trust Company as trustee for Elco Mining, and small blocks are held by Byron Creek Collieries and Coleman Collieries. In addition the provincial government holds an area in reserve for possible future use of B.C. Hydro at the extreme north end of the Elk Valley coal field."

Jan 1, 1985

By Donald Strickland, Peter Kresin, Dave Hall

"Have your parents or grandparents ever tried to share with you their wisdom and you ignored it because it did not relate to you‘? I have been ignorant and inevitably grew older and wished I had listened. The result: learning the hard way. As British Astronomer Fred Hoyle once said. “It is the true nature of mankind to learn from mistakes not from example.“ Hopefully we will continue to learn from the examples shared by our fellow mineral processors in these conference proceedings. It is the intent of this paper to share wisdom from the Musselwhite Mine that you may apply to your own operation.This paper is divided into three sections:1. Feasibility3. Operation3 . DesignKey points of the Feasibility and Design stages are summarized. followed by an analysis of actual operating statistics. An attempt is made to relate these statistics back to the feasibility and design with emphasis on areas of success and those with potential for improvement."

Jan 1, 1999

By J. R. Giegerich

"IntroductionMINING operators in common with other operators are confronted today with two serious problems, shortage of experienced workmen and rising costs. The following review of practices at the Sullivan mine of The Consolidated Mining and Smelting Company of Canada, Limited, outlines certain measures that have been responsible, during recent years, for minimizing the effect of these two problems. The paper is divided into three main sections:( 1) Training programmes and job studies( 2) Improved mechanization and equipment( 3) Large-scale methods of operationTraining Programmes and Job StudiesJob TrainingJob training courses were introduced at Cominco immediately after the last war and proved to be a great benefit to the operations. There were three courses given, Job Instruction Training, Job Safety Training, and .Job Relations Training. These were spread over a period of two years and were taken by all operating supervisors and some key operators.The courses were introduced by a trained instructor from the British Columbia Department of Labour. This man trained twelve of our employees as instructors by giving them an intensive one-week course. Similarity between the three courses was such that the instructors trained in the first one were very readily trained for instruction in the two succeeding courses."

Jan 1, 1952

Building off the enthusiasm generated by Credit Suisse First Boston on the potential benefits of an industry-wide effort to market gold jewellery, a group of gold producers, led by Randall Oliphant, CEO of Barrick Gold, decides to investigate the long -term impact of launching a significant marketing initiative to stimulate demand for gold jewellery. The group establishes an international Steering Committee representing producers of differing sizes, members and non-members of the World Gold Council. This Committee comprises representatives from AngloGold, Barrick, Gympie Gold, Kinross, Randgold, and Sons of Gwalia and is supported by the Australian Gold Council, the Gold and Silver Institute, and CSFB. The Steering Committee hires McKinsey to assist it by conducting an independent review of whether investment in a large-scale marketing initiative for gold jewellery would be effective in increasing demand for gold, and ultimately of significant economic benefit of the gold industry. Based on McKinsey?s review* and its own discussions with key stakeholders across the industry, the Steering Committee strongly believes the case for marketing is compelling and sufficiently proven to persuade the industry to undertake a major initiative over the next few years. The Steering Committee, supported by McKinsey, conducts briefings with a range of gold producers to share its findings and to understand producers? perspectives on an industry-funded marketing campaign. The Steering Committee is asking for your support to bring this industry-funded marketing campaign to life.

May 1, 2002

By Zhuo Chen, Jun Zhou, Jiemin Zhou

Samples of the reacting suspension particles were taken from the reaction shaft of a commercial flash furnace at different heights. The processes of matte and slag formation and morphology of the samples in the shaft were observed and analyzed. Variations of matte and slag composition in the shaft were investigated. By analyzing the samples taken from the settler at different locations, settler processes were studied such as slag formation, agglomeration and separation of matte-slag phases, Fe3O4 reduction, copper-in-slag reduction etc. In accordance with the characteristic of matte and slag formation the flash furnace can be divided into 6 functional regions, and a mechanism model called as “Micro bath process” is proposed for matte and slag formation in a commercial flash furnace. INTRODUCTION During flash smelting, concentrate particles scattered in the reaction shaft complete their oxidation reactions in suspension. The droplets produced fall into the settler beneath with a small amount of un-melted solid particles, agglomerate and separate into matte and slag layers which are tapped out from their tap holes separately. With respect to the extent of slagging reaction in the reaction shaft, there isn’t any commonly accepted understanding in literature (Kimura, Ojima, Mori & Ishii, 1986; Kemori & Kondo et al.,1988; Kemori, Denholm & Kurokawa, 1989; Fagerlund &Jalkanen, 2000). Some assume that the slagging reaction in the shaft can be ignored and some propose that all slag is produced in the shaft. With regards to the characteristics of the physical-chemical changes of concentrate particle in the reaction shaft, although there are some research results reported from pilot scale and commercial scale experiments (Kemori, Ojima & Kondo, 1988; Hagni, Vierrether & Sohn, 1988; Jorgensen, Taylor, Dickinson & Stevenson, 1992; Swinbourne, Simak & Yazawa, 2002; Kivinen & Tuominen, 2005), they are generally limited themselves to theoretical analysis and calculations. No studies are published concerned with the processes of matte and slag generation in the shaft, quantitative analysis of the processes, variations of matte and slag composition and morphologies of the melts along the axis of the shaft, etc.

Jan 1, 2019

By M. R. Saharan

A brief overview of rockburst control measures is presented. The paper then elaborates on one key rockburst control measure, which is known as destress blasting. A historical background of the technique is presented in order to understand different aspects of its field application. The publication enumerates key aspects of the technique as being used in practice in South Africa and North America. The paper also presents an analysis of three case studies in order to demonstrate difficulties associated with the field application of distress blasting in hard rock mines.

Jan 1, 2006

By N. Hmidi, T. Yalcin, M. Papadakis, B. Hilscher

Mill tailings, containing iron sulphides in particular, pose an environmental concern since they constitute a potential source of acid mine drainage which can damage vegetation, harm soil and living organisms, and contaminate groundwaters. Proper disposal of acid generating tailings is therefore an important issue that must be addressed and resolved in a satisfactory manner. Placer Dome Canada operates a 4000 t/d gold cyanidation facility at Musselwhite mine, in northwestern Ontario, where the mill tailings have been classified as acid generating. This study was conducted to explore the effectiveness of froth flotation in removing the sulphide minerals from these tailings and producing a low-sulphur, non-acid generating material that could serve as a capping material for previously deposited tailings. Laboratory semi-batch flotation tests were carried out in accordance with an experimental design procedure, and a computer simulation program was developed to facilitate the evaluation of flotation performance. In this investigation, pH, collector concentration, and airflow rate were considered as the relevant flotation variables, and their effects were examined both experimentally and by simulation. Results have demonstrated that flotation can successfully desulphurize the Musselwhite mine tailings and render them non-acid generating.

Jan 1, 2004

By K. Gie Tan, Frank Wright

"Misty Mountain Gold Limited (MGL - TSE VSE, MGLCF - NASDAQ) of Vancouver, owns the Harmony Gold Project located in the Queen Charlotte Islands of British Columbia. The deposit contains a mineable reserve of 2.3 million ounces of gold, at a 1.2 g/t cut-off and an average grade of 2.1 1 g/t Au.Discovered in 1970 and frequently investigated by previous owners, full-scale production has not yet occurred because of the complex metallurgy of the deposit. Recent process studies that were completed in six months at Process Research Associates Ltd. (PRA) of Vancouver resulted in significant improvements to the project viability. The work involved detailed mineral processing studies aimed at achieving a marketable concentrate. An option for bio-oxidation and cyanidation to allow on-site dor6 production was also investigated.The main findings at PRA followed the front-end recovery of finely divided free gold (Au) by gravity concentration. Approximately 20% of Au reported to less than 0.2% of the mass, resulting in a grade exceeding 500g/t Au. The resulting gravity tailing provided a uniform feed for flotation evaluation. The optimization of this step allowed for a reasonable primary grind size of 80% passing (&) 50pm. Efficient slime’s rejection was made possible by flotation at a reduced pulp density, and pre-oxidized sulphides were reactivated with Na,S. The regrinding of the bulk flotation concentrate followed by up to five stages of cleaning resulted in a combined gravity + flotation product of 50g/t Au with 82% recovery in less than 4% of the feed mass.Further studies indicated that the flotation concentrate was amenable also to tank bio-oxidation. At 65% sulphide oxidation the gold recovery improved from less than 70% to 90% by cyanide extraction using CIL (carbon in leach). This compares to less than 45% gold recovery from whole-ore cyanidation in several previous studies. Heap leaching may also be considered for lower grade material. PRA’s methodical approach and consistent results dispelled the uncertainty about predicting the material behavior for the Harmony Property."

Jan 1, 2000

By Marco A. Vera

"This paper investigates the froth function in flotation and the associated upgrading process. Flotation literature has revealed that one of the main functions of the froth phase is the cleaning of bubble-particle aggregates by rejection of entrained material. The cleaning and transport processes across the froth phase exert straining forces on these aggregates on their way up to the froth surface. These forces will impact on the recovery of bubble-particle aggregates.The grade at the top of the froth (TOF) is a parameter related to the quality of particles collected by bubbles in the pulp zone (true flotation). It has recently been demonstrated that TOF corresponds to the maximum practically attainable grade described by the recovery-grade (or enrichment ratio) curve. TOF lumps all the processes experienced by the bubble-particle aggregates before reaching the launder concentrate. This paper describes a methodology for quantifying flotation performance by means of the top of the froth sample - a touch of froth.INTRODUCTIONFroth flotation may be the most important mineral processing technique, but its theory is complex and is not completely understood even though many aspects have been studied and reviewed (Teague, 1998; Wills, 1992).Two distinct particulate systems prevail in the flotation process: a pulp phase and a froth phase (Figure 1). The pulp zone had been studied extensively; however, it is only recently that techniques to measure the froth zone performance have been developed (Contini et al., 1988; Falutsu and Dobby, 1992; Feteris et al., 1987; Seaman, 2002; Vera et al., 1999b).Flotation involves a number of mass transfer processes, occurring in the pulp phase and the froth phase. The formation of the froth and its subsequent removal are considered to be two important steps of the process. Phenomena that occur in the froth phase are known to affect flotation performance significantly (Cutting et al., 1981).Because the froth has a high free surface energy (as a result of the extensive interfacial surface between liquid and air), it appears thermodynamically unstable. The foaming is a dynamic balance, as new bubbles are added continuously from the pulp, while others disappear from the top. Under steady-state conditions, the volumes of added and subtracted air are equal (Booth, 1953)."

Jan 1, 2003

By G. E. Rowan

"DURING the dark ages, the cherished dream of chemists was to find a process for converting base metal into gold. Many a wealthy-but-gullible patron lost a fortune in the search. Men who work with metals today are a bit more realistic. I haven't heard of a metallurgist who expects to develop any one alloy that will resist all corrosive media. In the field of stain-less steels, there are about forty different types of alloys that are used where corrosion is a •problem.A stainless product is ordinarily selected because it offers one or more of the following qualities:(1) Resistance to corrosion (2) Resistance to oxidation at high temperatures (3) Good mechanical properties at room temperature (4) Good mechanical properties at high or low temperature (5) Attractive appearance (6) Ease of maintenanceToday we are interested in discussing the stainless steel family of alloys because of their .ability to resist corrosion. We• will not try to explain the Theory of Corrosion. Let us assume that, when surface potential and oxide formations are properly controlled, iron will resist attack in various chemi.cal solutions. The addition of alloying elements to iron does this for stainless steels. The principal stainless alloys used by various Canadian industries are listed in the accompanying Table."

Jan 1, 1959

By B. Goard

"IntroductionCemented backfill has been placed underground in slurry form in Inco Limited's Ontario Division mines since the early 196Os. The slurry was traditionally mixed on surface at between 65 and 70 wt% solids* and transported underground via gravity through a borehole-pipeline distribution system. This method of placement, while simple and dependable, has proven to be costly because of the large amounts of transport water involved.A significant quantity of the slimes buildup on mine levels is caused by the backfill water carrying cement and other fine material out of the stopes. The level cleanup and eventual pumping or hoisting of the slimes and water back to surface result in substantial indirect backfilling costs.The cement that remains in the stope is always overhydrated because of the high water cement ratios that exist. As a consequence, high concentrations of Portland cement must be added to the backfill to produce the fill strengths required for the different mining methods.Pouring backfill at these densities also demands extensive fill preparatory work in the stopes to withstand the hydraulic heads created by the slurried fill. This, along with the delays in pouring necessary to allow for water drainage, result in significant losses in productivity.These negative aspects of slurry placed fill has led Inco Limited to investigate several methods of transporting backfill underground via pipeline, at higher densities (i.e. 75 to 95 wt.% solids). Three separate transport methods are presently being experimented with by the Company's Mines Research Department. Each utilizes a different technique or form of flow transport, i.e. concrete pumping technology, high density slurry flow, and pneumatic conveying."

Jan 1, 1987

Microseismic (MS) methods offer one of the few ways to monitor a 3D volume of rock and essentially see into the rockmass and the regions of real time rock fracture. This is a critical component when considering workplace safety as well as the economic viability of a mining operation. New Gold Inc. New Afton Mine, an intermediate copper-gold mining company located 350km northeast of Vancouver in the south-central interior of British Columbia, Canada, has recently installed a MS system to help understand the block caving process in space and time. For a block cave mining operation is it important to utilize the MS events to map out the seismogenic zone related to the regions of stress concentration and fracturing mechanisms which lead to caving. The geological setting within the local array is complex, consisting of several distinct lithologies with unique material properties that each affect the microseismic signal differently. The block cave consists of a muck filled void, also affecting the seismic waveform path. This paper compares the use of a single velocity model to a variable velocity model which accounts for the differing lithologies and cave. The variable velocity method determined 3D raypaths for all source to receiver possibilities through five irregular shaped geological domains and the estimated cave. For calibration blast data, the variable velocity model is found to successfully decrease the error for event location from an average of 38m to 20m (47% improvement), and its importance to location accuracy is expected to increase as the cave develops in size.

Aug 1, 2013

By B. St. Pierre

"The alchemists' symbol for antimony is a diamond with a dot in the centre. The latin name ''stibium'' gives this mineral its chemical symbol ""Sb"" and the name to the principal ore containing antimony. This is Stibnite, a sulphide of antimony, and the valuable mineral at the Consolidated Durham operations. Stibnite chemically pure contains 71.69% antimony metal.Antimony is used in many forms, as an alloy in the production of metal products and as chemical compounds of oxides and sulphides. In Biblical times, antimony was used as a medicine and as eyebrow makeup.Today, the largest single use of the metal is as a hardener and strengthener of lead, and corrosion inhibitor in storage batteries. New applications for antimony in its oxide form as fire retardants are broadening the overall demand especially in the chemical, plastic and fabric industries. Other users include the Military for such things as tracer bullets, shrapnel, smoke screens and flame throwers. An unusual property of the metal is that it contracts when heated which has made it a valuable alloying metal in the printing industry, for heat shields on re-entry vehicles used in the space programmes, and also for the manufacture of bearings."

Jan 1, 1977

By I. L. Sills

Introduction So many minerals and mineral products are used in the glass industry that it would require an unduly long paper to deal adequately with all of them. Only those that go to make up the batch for the more common types of glass will be discussed here, and even with these only, the list is a lengthy one. It is true that for the body of the glass comparatively few materials are required-as silica sand, soda-ash, lime, and feldspar. The others are used mainly to colour or decolorize the glass, or to give it some other desired characteristic, such as high lustre, greater physical strength, or opalescence; but, although they may be present in very small quantities, they are just as in-dispensable to the glass industry as are the main constituents of the batch. Sand Sand is essentially quartz, the dioxide of silicon, Si02. Most glass contains from 71J to 75 per cent silica. Sand for use in the glass industry, or 'glass sand', is obtained both from deposits of unconsolidated material, commonly referred to as 'sand', and from solid rock-sandstone, quartz, or quartzite. For the manufacture of glass, the material must possess a high degree of purity, as noted below, so that, although sand is widespread in most parts of the world, and sandstone, quartz, and quartzite are not at all uncommon, it is only in certain places that suitable deposits are found. At the present time, most of the glass sand used in Canada is imported from France, Belgium, and the United States. The French material, from Fontainebleau, near Paris, is known the world over as a very high quality glass sand. That from Belgium is nearly as good and is lower is price.

Jan 1, 1934

By Norman O. Lotter, André R. Laplante

"The pursuit of concentrator surveying for purposes of metal accounting or process optimization has not yet connected with the well-published realm of geostatistics. The reality of lognormality in time has seldom been discussed. One publication by Krige, 1962, examined such effects for a gold concentrator in South Africa, towards an information system that would provide feedback to the mining and surveying teams on grade control of ore mined.During present studies which are designing and testing a new survey model, called statistical benchmark surveying, it was found that the distributions of feed, concentrate and tailings bear significant residual signs of the parent lognormality in space. The multiple hosting of paymetals in different mineral species complicates the understanding of these distributions. These features have to be recognized and treated in order to perform appropriate quality control on the diagnostic sampling performed in the pursuit of statistical benchmark surveying.It is shown in this paper that the above two features can actually be used to advantage in the diagnosis of continuous periods of operations data ahead of such surveying, including the estimation of recoverable paymetals in flotation tailings from a graphical method.INTRODUCTIONAssessment of Concentrator PerformanceMilling and flotation, sometimes accompanied by gravity separation, are well-established unit processes, which have traditionally been used to treat ore that has been mined. This is because these processes liberate, then separate, the valuable minerals, which contain paymetals, from host gangue. This is often done by a combination of crushing and grinding processes, or autogenous grinding, to liberate the paymetal minerals, followed by gravity separation and/or flotation, to separate these valuable minerals into a concentrate, or several concentrates. These concentrate(s) have a lower bulk than the parent ore from which they are derived. Further, they contain a high percentage of the valuable minerals. Accordingly, they are more economically treated in subsequent beneficiation processes than the ore from which they were produced."

Jan 1, 2005

By W. A. Gow, J. A. Vezina

"A new process for treating scheelite for the production of tungstic tri-oxide is described. The novelty of the process resides in that an ion-ex-changer is used to convert sodium tungstate to either ammonium tung-state or tungstic acid.The process consists of a conventional hydrochloric acid leach of the scheelite concentrate, and the dissolution of the impure tungstic acid thus produced with sodium hydroxide at pH 8. The sodium tungstate solution is clarified and passed through a column of Dowex 50Wx8 ion-ex-change resin to exchange the sodium ions for either hydrogen or ammonium ions, both being suitable. The tungsten-bearing column effluent is evaporated to crystallize the tungsten as ammonium tungstate; the crystals are washed with nitric acid and water and decomposed by heat to pro-duce tungstic trioxide of high purity.Ninety-six per cent of the tungsten in the concentrate may be re-covered as tungs tic trioxide (W03), and the reagents consumed are 0.7 g HCl, 0.41 g NaOH and either 1.73 g NH.Cl or 225 g HCl per gram of tungsten."

Jan 1, 1966