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By O. N. Carlson, A. L. Eustice

The tensile properties of iodide vanadium were determined as a function of hydrogen concentration. It was shown that the presence of 10 ppm H is sufficient to cause embrittlement of vanadzum over a limited temperature range. The temperature of the observed ductility mininlum is approximately -l00°C, this being a function of strain rate and hydrogen concentration. The yield stress of hydrogenated vanadium is raised sharply in the brittle temperature range. THE present investigation was initiated to determine the effect of hydrogen on the tensile properties of high-purity vanadium as a function of temperature and the role of hydrogen in the brittle-ductile transition. Loomis and Carlson&apos; reported a change from ductile to brittle behavior in iodide vanadium at -110°C with a return of ductility at temperatures below -140°C. Vanadium wire containing 270 pprn of hydrogen was brittle at room temperature while wire containing 100 ppm was ductile under the same conditions. Roberts and Rogers&apos; reported a ductile-brittle-ductile fracture sequence in vanadium containing 400 to 600 ppm of hydrogen. Their data show that hydrogenated vanadium is ductile at 150"C, brittle at room temperature and ductile again at -196°C. Magnusson and Baldwin found a minimum in ductility in vanadium containing 80 ppm hydrogen from tensile tests performed at several strain rates. Information available on the vanadium-hydrogen equilibrium system4 is somewhat incomplete. The absorption of hydrogen is exothermic in accordance with the decline in solubility with rising temperature. The limit of solid solubility at temperatures below 400°C has not been determined due to the difficulties in obtaining equilibrium at these temperatures. Data on the hydrides of vanadium are rather limited. Roberts6 studied the structure of VD,., by neutron diffraction, and observed the ordering of the deuterium atoms below -65°C into a primitive cubic cell with a lattice constant about twice that of the disordered bcc vanadium solid solution. EXPERIMENTAL PROCEDURE Vanadium of 99.9 pct purity was prepared by the iodide refining process6 for use in this investigation. This vanadium contained the following analyzed impurities; <20 pprn calcium, 150 ppm carbon, 200 ppm chromium, 30 ppm copper, 10 ppm hydrogen, 200 ppm iron, <20 ppm magnesium, <20 ppm nickel, <5 ppm nitrogen, 150 ppm oxygen, <50 ppm silicon, and <20 ppm titanium. specimen Preparation—Tensile specimens were machined from swaged rods of iodide vanadium. The

Jan 1, 1962

By H. Landssberg

Subsidence caused by mining operations has been a matter of interest for the mining engineer for just 111 years, since the Belgian committee for study of subsidence in the city of Liege submitted its first report in 1825. This interest is fairly expressed in the enormous amount of literature that has since appeared on this subject. A bibliography, probably far from being complete, which preceded this study as a preliminary survey, comprises more than 800 titles. In spite of this fact the problem remains today as acute as it has ever been. The questions of as good a recovery as possible of the national resources, the safety of the operations, and the protection of private and public property are the important angles from which to look at the problem. The Problem To systematize an investigation regarding the effects of mine excavations two different aspects have to be dealt with: (1) the subsidence of the immediate roof above the workings, affecting the safety of the workers and the progress and efficiency of the operations; (2) the subsidence of the surface, which is also, from the point of time, the second event. The immense importance of surface subsidence as regards the impairment of surface structures of every kind in a mining area is self-evident. Both effects result from reactions of the strata overlying the excavations and they depend mainly on the extent of the excavations and the structure and geological condition of the strata. It has been stressed repeatedly, in this country principally by G. S. Ricel,† that for the understanding of the phenomenon of subsidence accurate surveys are the most urgent necessity. In the past, however, at least in the normal course of mining operations, these surveys have been very crude. The control of the roof in the mine is left to the observation of the behavior of the timber, warning cracks and sounds in roof and walls and to the general judgment and experience of the worker and his supervisors. In any given case this may or may not be sufficient to prevent fatalities but certainly it does not give any accurate information as to what is happening in roof and strata. On the surface, principally in endangered areas, surveys have been conducted more frequently, but also in this case usually weeks or even

Jan 1, 1936

By J. Gurland

The strength variation ofWC-Co alloys with composition and particle spacing falls into two ranges. 1) Above a critical value of the mean free path, the strength follows a dispersion hardening relation; it is proportional to the volume fraction of WC and in-versely proportional to the particle size. 2) Below a critical value of the mean free path, the strength variation is based upon the Griffith criterion of fracture and is controlled by the case of crack propagation. The maximum strength is attained when the structure and load just satisfy the critical conditions for spontaneous crack propagation. THE relation between the strength and the structure of cemented carbides is of interest not only for its own sake but also for its contribution to the understanding of composite materials in general. The cemented carbides are essentially aggregates of a brittle carbide constituent and a ductile binder phase and, at certain structures of intermediate composition, the composite alloys attain strengths far higher than those of the separate constituents in bulk. It is this variation of strength with structure which will be discussed. The experimental procedures of sample preparation, mechanical testing, and quantitative metallo-graphic analysis have been described in Ref. 1. The reported strengths are the maximum fiber-stresses in bending calculated on the basis of completely elastic behavior. The plastic contribution to the over-all deformation is small and was neglected in the calculations (the elongation at fracture of the most ductile alloy, 50 pct WC-50 pct Co, is less than 0.5 pct).2 The pertinent structural parameters are: f, the volume fraction of tungsten carbide; p, the mean free path through the binder phase; the contiguity C, defined as the average fraction of surface area shared by a particle of wc with all neighboring particles of the same phase; and d, the average equivalent spherical diameter of the WC particles. The strength variation of WC-Co alloys with composition and particle spacing is shown in Fig. 1 and Table I, which are based partly on previously published data&apos; and partly on new experimental work which extends the range to higher values of the mean free path. Each data point represents the average of five samples. For a given composition, the transverse rupture strength reaches a maximum

Jan 1, 1963

By A. J. Lyon

The stability and permanence of any structural material used in aircraft are of paramount importance. The spontaneous hardening, or age-hardening, which takes place in some of the aluminum alloys under ordinary conditions of temperature and atmosphere, is accompanied by an increase in tensile strength and proportional limit and a decrease in elongation or ductility. Within the last few years the introduction of a number of strong and ductile casting alloys led to a study by the Materiel Division, Air Corps, of the permanence of the physical properties in several of these alloys. It has been found that even though some alloys have good properties directly after casting or heat treatment, they are not satisfactory for stressed parts that require a combination of strength and ductility. It has also led to the conclusion that all alloys that can be hardened by artificial aging—heating in a temperature range below 170" C. (340" F.)—will harden spontaneously if allowed to stand for a sufficient length of time. It follows that, in aircraft work where the factors of safety are limited on account of the necessity of keeping the weight of the structures as low as possible consistent with their safe operation, the properties of the alloys in the stable or final condition should be used as a basis for design rather than the properties obtained on the material directly after casting. The work of Wilm in Germany, Hanson and Gayler at the National Physical Laboratory in England, and Merica, Jeffries, and others in the United States, has shown that the spontaneous hardening is characteristic to a greater or less extent in all aluminum-base alloys in which the solubility in the solid state of the alloying constituents decreases with the temperature. It has been shown that, by heating to a temperature as near as possible to the melting point of the material and soaking at that temperature for a sufficient length of time and then quenching or cooling rapidly, a maximum amount of the soluble constituents can be retained in solution and the condition of maximum hardening effect upon aging can be obtained. Also, in ordinary sand and chill castings, without heat treatment, a sufficient amount of the alloying constituents is held in solution to cause important changes in the final physical properties.

Jan 1, 1929

By H. E. McKinstry

MOVEMENT on a fracture of irregular shape can cause local widening of the fissure and thereby offer freer channelways for circulation of ore-depositing solutions. This influence, coupled with large areas of wall rock available for reacting with ore solutions in brecciated and shattered ground can account for locally active deposition of metals and the resulting ore shoots. Such irregularities in the fracture system may be caused by local variations in the strength of rocks and by pre-existing lines of weakness, especially if these stand at favorable angles to certain components of the fracturing stress. Therefore correct interpretation of the mechanics of fracturing should permit deductions as to structurally favorable places on unexplored portions of the vein system. INTRODUCTION IT has long been recognized that movement on a curved or irregular fault surface is capable of separating the walls in certain portions of the fault, but until very recent years the importance of this mechanism as a factor in localizing ore shoots has escaped proper recognition. A short time ago W. H. Newhouse&apos; presented a careful analytical study of displacements and their corresponding open spaces. For reasons that will be discussed later, it frequently happens that portions of the vein which are favorably oriented are not merely wider but also richer than the average. In many cases the widening with its accompanying richness coincides with very minor changes in the dip or strike of the vein, irregularities that commonly escape notice unless the vein is mapped in detail and a careful geometrical analysis made. While the relationship between the width of the vein and the changes in dip or strike has been recognized as a matter of observation, the irregularities have been accepted as more or less the result of accident. There has been very little effort except in isolated cases to find out the causes of these changes in dip or strike. Yet it is clear that if the causes can be recognized and expressed in terms of geologic structure the geologist will know where to look for repetitions of these favorable conditions either on extensions of the same vein or on adjoining veins. Any lack of understanding of the causes is due to the limitations of our ability to interpret our observations and not to the sheer capriciousness of

Jan 1, 1941

By J. B. Cheatham

An analysis of indexing is given for an idealized plastic rock. Indexing refers to chipping from a bit tooth to a previously formed crater. A method is indicated for computing the dependence of chip size and shape as well as force on the tooth for various tooth shapes as a function of crater configuration and distance to the previous crater. Pressure on the tooth is found to vary with depth of penetration after a critical depth has been reached. Damp sand model experiments indicate that simple solutions using linear and logarithmic spiral slip-line fields for Coulomb plastic materials give reasonable approximations to the failure patterns. Both idealized roller cone bits and fixed blade or drag bits are considered, and methods are presented for approximating the force on the bit and the chip volume when the rock is subjected to sufficiently high pressure to behave plastically. One of the primary objectives of drilling research investigations is to develop theoretical equations which can be used to predict the behavior of rock under drilling loading conditions. Since rocks usually fail in a brittle manner at atmospheric conditions, much current research is directed to studies of the brittle failure of rock under the action of drilling too1s. 1,2 The results of triaxial test on rocks indicate that both rock strength and ductility increase at high confining pressures.3 Recent results from single bit-tooth indentation experiments on dry rocks indicate that the transition from brittle to ductile failure under a bit tooth can occur at pressures sufficiently low to be of interest in oil well drilling.4 Single bit tooth experiments and analyses are not directly applicable to the drilling process since one of the important facets in drilling is the interaction between a bit-tooth and the previously formed crater. This interaction is referred to as indexing.&apos; The purpose of the present paper is to indicate how plasticity theory can be applied to the analysis of indexing for plastic rock. Drag bit or fixed-blade drilling is considered and a discussion is given of the drilling action of an idealized roller cone bit. Results of simple experimental studies using a damp sand model are given as a method of visualizing the failure patterns in rocks under high confining pressures. These results are compared with plasticity theory using simple solutions based on linear and logarithmic spiral slip-lines. Discontinuous stress fields are proposed for drag bit drilling based upon the soil mechanics analysis of Shields. SINGLE BIT TOOTH RESULTS Single bit tooth indentation experiments using dry rocks under pressures from 0 to 5000 psi have indicated a correlation between the shape of a force-displacement curve and the nature of the rock failure beneath the tool.4 Continuous linear curves are in-

Jan 1, 1965

By D. C. McLean, S. A. McKay

The purpose of this paper is threefold: 1) to describe actual ground control installations made at the various mines of the International Nickel Co. (Canada) Ltd mines in Sudbury, Ont. during a planned test program. 2) to suggest new ground control techniques which are now possible by the use of fully grouted bolts 3) to indicate the possible economic advantages to be gained by the use of resins and resin grouted bolts to control difficult ground conditions. Were a theme selected for this paper it would be: "Preserve the original roof in best condition possible by the use of smooth blasting techniques and fully grouted roof bolts — since the original rock is the best and cheapest material available for ground support." TYPES OF BONDED BOLTS As has been shown previously, there are several ways in which a bolt may be bonded. These are illustrated in Fig. 1 and 2. There are three general types of grouted bolts: 1) pretensioned, 2) post-tensioned, and 3) untensioned. The type which will be of most benefit to the user will depend upon the particular ground support problem involved. Despite the many arguments propounded for the necessity for using a tensioned bolt, ample evidence exists from actual experience that untensioned bolts can be effective in many instances. The outstanding characteristic of a grouted bolt is that it provides the user with a variety of rock consolidation techniques heretofore unavailable with conventional rock bolts. Many of the unusual characteristics of grouted reinforcing bar have been evaluated by researchers in the concrete structure field.&apos; Underground application has largely been pioneered in the construction field, with especially good work being reported from the Snowy Mountains Hydroelectric Authority in Australia. Techniques developed there using cement grouted bolts are now being adapted in many large government construction projects in this country with excellent results. The ap- plications described in this paper are those in which Cyanamid&apos;s Roc Loc Mining Kits were used exclusively. SLUSHER DRIFTS AND FINGER RAISES (BOX HOLE BROWS, DASHES) A common mining problem especially where block caving methods are applied is that of maintaining the roof in slusher trenches particularly at the intersections of the trench with the feed raises (box holes) through which the large fragments of broken ore tumble. Typical sections are shown in Fig. 3 and 4. In Fig. 3, the drift is normally driven 7 ft wide by 8 ft high initially. The rock involved is a hard norite (diabase) which is usually competent but has "block cleavage". This roof has a tendency to fall out in large blocks when subjected to operating stresses. Depending upon the initial condition of the roof, the drift is either lined with 2 to 3 ft of concrete immedi-

Jan 1, 1964

By Blake M. Loring, Robert A. Colton

MELTING procedures for most metals and alloys usually include some provision for the control of oxygen, since this element frequently has some undesirable effect on the properties of the metal or alloy concerned. In the melting of the various bronzes, this is especially true, since oxygen can be introduced into the melt in a number of ways, most of which are difficult to control. In making bronzes from virgin materials, oxygen is usually present in the commercial grades of copper used; electrolytic he refined copper ingots usually contain from 0.02 to 0.05 per cent oxygen. When ingot metal or scrap bronze is used in the charge, oxides are almost always present to some degree. Under certain melting conditions and in certain types of melting equipment the atmosphere over the metal may be highly oxidizing. This, of course, may be desirable in the melting practice used, but is certain to introduce appreciable amounts of oxygen into the melt, and that may not be entirely desirable. From the foundry viewpoint oxygen may have several harmful effects on bronzes. The formation of excessive amounts of oxides may produce drossy metal, which, in turn, means dirty castings and a potentially high rejection rate. It is claimed, too, that oxides in the metal may combine with hydrogen to form steam and thereby produce porosity in certain of the bronzes. The presence of certain refractory oxides, such as SnO2, may be undesirable from the viewpoint of making machining difficult, or as possible stress-raisers in the metal matrix. It is often said that excessive oxide present in the liquid metal makes the metal run sluggishly. Since it appears impractical to try to control the amount of oxygen introduced into the metal beyond taking the economical limit of precaution about charging dirty scrap, it would seem that control of the oxygen content of the liquid metal offers the most promising approach to this problem. This might be done by using slags, or covers, or by the use of some element or compound added to the melt to remove oxygen preferentially. Most aspects of this problem have been considered and considerable work has been done along these lines. A reconsideration of the problem is indicated, however, by the controversial nature of the evidence at hand, especially on the possibility of using a chemical deoxidizer to control the oxygen content of bronzes. CHOICE OF DEOXIDIZER The choice of the chemical agent selected as a deoxidizer would naturally depend first on the alloy in which it is to be used; in this particular case the alloy is Navy gun metal. In Table I are listed a group of elements that might be considered as

Jan 1, 1946

By H. l. Burghoff, C. H. Mathewson

THE study of the creep of metals under conditions of prolonged loading has received the attention of many investigators for several years and almost innumerable papers have been published on the various aspects of the subject. As it appeared that much could still be learned from a study of single crystals, the present work was carried out to study the effects of temperature and conditions of loading upon the properties and deformation in tension of single crystals of alpha brass containing about 70 per cent copper and 30 per cent zinc. In particular, it was hoped to obtain information from tests below and above the recrystallization temperature of the material, so that properties such as elastic limit, yield point or critical stress, and manner of deformation might be compared for tensile tests at an ordinary loading rate and for prolonged. loading. Accordingly, short-time tensile tests and creep tests were made at room temperature, 300º, 500° and 700°F. The two latter temperatures are above the lowest possible recrystallization temperature of polycrystalline 70-30 brass. PREVIOUS WORK Clarke and White1 have made creep tests of some copper-zinc alloys, including 70-30 brass, and copper-zinc-tin alloys at temperatures both below and above the recrystallization temperature of the materials considered. Hanson and Wheeler have studied the flow and fracture of single crystals of aluminum for short-time and prolonged tensile loading over a range of temperature extending from room temperature to 400°F., their experiments being made without consideration of the orientations of the test specimens. Extensive creep and fracture tests on single crystals of lead at room temperature have been made by Betty3 and by Baker, Betty & Moore.4 Results of the last-named investigation were published while the present work was in progress. Millers examined the elastic limit of zinc single crystals at and above room temperature by means of creep tests, while Miller and Milligan6 reported the results of tests designed to show the influence of temperature on elastic limit of single crystals of aluminum, silver and zinc. The behavior, of iron crystals under static tensile loading at room temperature was reported by Gensamer and Mehl7 while the present investigation was in progress. Their specimens exhibited a well-defined yield point, below which no appreciable creep could be detected. The manner of yielding proved interesting, as the shape of the creep-time curve for the iron crystals differed from the common type of creep curves. Elongation did not begin immediately, or at least was initially very slow. The rate of elongation then increased continuously and finally decreased to zero. This S-shaped type of elongation-time

Jan 1, 1941

By James K. Stanley

PREFERRED orientation, particularly in irons and low-carbon steel, is a phenomenon that is both of considerable importance and theoretical interest. At times it is a liability and at other times an asset. In deep-drawing operations, preferred orientation is extremely undesirable because it necessitates trimming operations and increases scrap loss. Furthermore, oriented metals are likely to crack more easily than randomly oriented material because the forming of symmetrical and unsymmetrical shapes out of preferentially oriented metals and alloys increases the probability of rupture in regions of high stress, owing to differential ductility.1 In the electrical industry, on the other hand, preferentially oriented silicon irons are in demand for transformer application because of the improved magnetic permeabilities in the rolling direction.2 This phenomenon of preferred orientation in soft magnetic materials has been responsible for the tremendous improvement in transformer design and construction in recent years. Directional properties in metals have received a great deal of attention in the metallurgical literature,3-9 in which much of the information reported about orientation has been obtained by conventional methods, mechanical properties and X-rays. A wealth of data has been obtained and often at a great expenditure of time. The recent introduction of the magnetic torque measurements on ferromagnetic materials provides a very simple and rapid method of evaluating orientation. The judicious use of the method can supply important in- formation, but it should be borne in mind that such studies must be supplemented by X-rays, optical methods,10 and etch and pressure figures" to get a rational under- standing of the orientation phenomena. No claims are made that the magnetic torque of evaluating orientation will reveal the behavior of the metal in deep drawing. For this purpose the accepted tests for deep-drawing quality must be used. For a good drawing &apos;stock, which must have low impurities, desirable grain size, ductility, strength, hardness, good surface, random orientation, and good recrystallization behavior, it cannot be expected that any simple test will be satisfactory for appraising all the factors. The only factor on which the magnetic method can be used is orientation, which is, of course, of considerable importance. When directionality can cause a 10 to 15 per cent change in tensile strength and a IOO to 300 per cent change in tear length,12 it goes without saying that a reliable as well as rapid method for detecting these changes would be desirable. There are certain inherent advantages in testing orientation by the torque method: The method is rapid with the proper type of equipment; no elaborate preparation of specimens is required-it is only necessary punch or machine a disk of the sheet material and insert it into the testing device.

Jan 1, 1943

By T. R. Wright

THE Corporation operates concentrators in four camps: Casapalca. Morococha, Cerro de Pa-co, and Mahr. The present concentrator at Cerro de Pasco is the newest having been completed in 1943. and that at Casapalca the oldest, having been built originally as a gravity concentrator, in 1889. Prior to 1925 the Corporation&apos;s milling operations were confined to the beneficiation of silver-bearing copper ores, and treatment of these ore: by flotation was started in 1918. Although fairly large deposits of complex, fine-grained lead-zinc ores existed, little progress had been made in the treatment of such ores--in Peru or elsewhere-until the early &apos;twentics. The Casapalca concentrator began the selettive concentration of complex leadzinc ores by all-flotation methods in 1925, or contemporaneously with the commercial development of selective lead-zinc flotation in the United State:.

Jan 1, 1945

By Geo. T. Lynch

PALEOLITHIC MAN, laboriously shaping a stone implement in his cave, discovered that the dust irritated his eyes and nostrils and hindered his labors, whereupon, muttering a few incantations, forerunners of modern profanity, he removed himself and his work outside. There, ignoring the jeers of the hairy ?old-timers,? he turned his back to the wind and resumed operations in comparative comfort. Thus originated the dust problem in the mineral industries, and its solution. Despite long familiarity with the annoyance, danger, and loss occasioned by dust, little progress was made in the engineering solution of its problems until recent years. Some advance can now be reported but too many traces of ancient tradition and practice still remain. Considerable published information is available but only a part of this is of proved accuracy and utility. The greater portion is either misleading, being derived from too few cases to be of general application, or entirely erroneous, originating in guesswork, legend, or individual inspiration, divine or otherwise. The engineer, confronted with a dust problem, has neither the time nor the special training required to extract the values from this mass of low-grade. It is, therefore, desirable that we attempt to correlate the known values and to put them into a form upon which actual progress can be based. This discussion is, then, for the benefit of that engineer, particularly the engineer in the mineral industries and more particularly in ore-dressing plants, and is merely a gathering of facts already known but difficult to segregate.

Jan 1, 1938

By Stanley W. Ivosevic

The South-Central Osa Peninsula produced around 30,000 kg (100,000 troy oz) of gold since prehistoric times. Gold freed by erosion from quartz lodes in the Mesozoic Nicoya ophiolite complex was reconcentrated through three generations of Quaternary sedimentary deposits. Resultant gold placers grade upward from 1 g/m3 (0.03 troy oz/m3) and are of moderate size.

Jan 1, 1980

By Francis H. Crockard

During the past five years we have probably witnessed greater technological advances than in any similar period. Industry and science have steadily marched ahead. The makers of iron and steel products have watched with great interest the development of streamlined trains, faster and safer airplanes, the entirely new science of air-conditioning and the widespread use of stainless steels. Since 1930, we have witnessed the erection of the world&apos;s largest suspension bridge, the largest and fastest ocean liner and the spectacular Boulder Dam, while even greater things are planned in these particular fields. Other industries, too, have been moving ahead rapidly. This advance in a few years has been caused primarily by the fierce competition of the depression. Now, more than ever, is the emphasis placed upon quality and service. Makers of southern merchant pig iron have been no exception and have been confronted with increasingly strict chemical specifications and with much greater stress on physical characteristics than ever before. For example, sulfur in the iron must be held very low, competition demanding that it be in the 0.020&apos;s and low 0.030&apos;s; silicon content must be held within a very narrow range, and definite requirements of phosphorus and manganese are an essential part of the specifications. Physical characteristics are becoming of increasingly greater importance. The introduction of triple-skimmed, slow-cooled iron several years ago was the first step in this direction. Now there are a few customers who buy iron by chemical analysis and physical appearance, having found that the analysis alone is an insufficient guide to their requirements. In addition to questions of quality, the subject of cost has greatly altered the southern furnaceman&apos;s viewpoint on many things. Formerly we had low-grade but cheap raw materials, but recent developments, such as greatly increased labor rates, have raised the cost of the same

Jan 1, 1936

By Donald C. Barton

OF the four papers that comprise this Technical Publication, three are case histories of individual geophysical prospects, subsequently tested by drilling. The bibliography of Dr. Barton&apos;s published scientific paperst includes investigations in physiography and surface geological mapping, as well as his geophysical papers, and from this list it is to be observed that he early recognized the place of different types of geophysical prospecting methods in the search for geological structures of economic importance. Moreover, his viewpoint was not merely that the structures should be found, but that the geophysical data should be examined quantitatively to determine the geometry of the structures. In other words, that although these data are insufficient to deduce a unique form for the structure that caused the effects measured in the data, the engineering computations should be carried out to give as much of a definite configuration to the structure as the data permitted, in order that the testing of the structures could be conducted in the most economical manner and with the idea that the experience so gained could be later incorporated in the study of structures subsequently found. Dr. Barton continually emphasized the quantitative use of geophysical observations, whereas at the time that he began his specialization in geophysics it was considered sufficient to use observations only qualitatively. He, more than any one else, was responsible for the first volume on geophysical prospecting issued by the Institute in 1929, and his three articles in that volume stressed the quantitative use of geophysical prospecting. The fourth article in this present Technical Publication is a further contribution to this branch of geophysical interpretation, and is a supplement to the paper in the 1929 volume, "Calculations in the Interpretation of Observations with the Eötvös Torsion Balance." From the successful demonstration by Dr. Barton of the usefulness of quan-

Jan 1, 1946

By Francis H. Crockard

During the past five years we have probably witnessed greater technological advances than in any similar period. Industry and science have steadily marched ahead. The makers of iron and steel products have watched with great interest the development of streamlined trains, faster and safer airplanes, the entirely new science of air-conditioning and the widespread use of stainless steels. Since 1930, we have witnessed the erection of the world&apos;s largest suspension bridge, the largest and fastest ocean liner and the spectacular Boulder Dam, while even greater things are planned in these particular fields. Other industries, too, have been moving ahead rapidly. This advance in a few years has been caused primarily by the fierce competition of the depression. Now, more than ever, is the emphasis placed upon quality and service. Makers of southern merchant pig iron have been no exception and have been confronted with increasingly strict chemical specifications and with much greater stress on physical characteristics than ever before. For example, sulfur in the iron must be held very low, competition demanding that it be in the 0.020&apos;s and low 0.030&apos;s; silicon content must be held within a very narrow range, and definite requirements of phosphorus and manganese are an essential part of the specifications. Physical characteristics are becoming of increasingly greater importance. The introduction of triple-skimmed, slow-cooled iron several years ago was the first step in this direction. Now there are a few customers who buy iron by chemical analysis and physical appearance, having found that the analysis alone is an insufficient guide to their requirements. In addition to questions of quality, the subject of cost has greatly altered the southern furnaceman&apos;s viewpoint on many things. Formerly we had low-grade but cheap raw materials, but recent developments, such as greatly increased labor rates, have raised the cost of the same

Jan 1, 1936

By Donald C. Barton

OF the four papers that comprise this Technical Publication, three are case histories of individual geophysical prospects, subsequently tested by drilling. The bibliography of Dr. Barton&apos;s published scientific paperst includes investigations in physiography and surface geological mapping, as well as his geophysical papers, and from this list it is to be observed that he early recognized the place of different types of geophysical prospecting methods in the search for geological structures of economic importance. Moreover, his viewpoint was not merely that the structures should be found, but that the geophysical data should be examined quantitatively to determine the geometry of the structures. In other words, that although these data are insufficient to deduce a unique form for the structure that caused the effects measured in the data, the engineering computations should be carried out to give as much of a definite configuration to the structure as the data permitted, in order that the testing of the structures could be conducted in the most economical manner and with the idea that the experience so gained could be later incorporated in the study of structures subsequently found. Dr. Barton continually emphasized the quantitative use of geophysical observations, whereas at the time that he began his specialization in geophysics it was considered sufficient to use observations only qualitatively. He, more than any one else, was responsible for the first volume on geophysical prospecting issued by the Institute in 1929, and his three articles in that volume stressed the quantitative use of geophysical prospecting. The fourth article in this present Technical Publication is a further contribution to this branch of geophysical interpretation, and is a supplement to the paper in the 1929 volume, "Calculations in the Interpretation of Observations with the Eötvös Torsion Balance." From the successful demonstration by Dr. Barton of the usefulness of quan-

Jan 1, 1946

By James Aston

THREE years ago the writer presented a paper on the trend of development in the wrought iron industry,1 wherein was described a process in the development of which he has been a factor, which at that time had passed through several years of progressive experimental development but which had not then been put upon a commercial scale of operation. The present paper deals with two years of observation and experience in the commercial operation of a plant by the A. A Byers Co. at Warren, Ohio. It will not enter into the controversial field of the relative merit of wrought iron and steel in various classes of service, nor will it elaborate upon the characteristic services or fields of utility to which wrought iron is particularly adapted. It is sufficient to state that the wrought iron industry is upon a substantial basis and that the material finds service in pipe, where its advantages are in superior corrosion, fatigue, welding and threading qualities; in bar iron for staybolts, engine bolts, and rivets, demanding maximum service against corrosion and fatigue; in plates for corrosion service; and in chains, because of welding and shock-resisting characteristics. In short, ability to withstand the stresses of shock and vibration, or the ravages of corrosion, to hold protective coatings, and to give maximum efficiency in welding, are its features of relative superiority. If these features were not well recognized, the wrought iron industry would have shrunk to insignificance in the face of high costs and acknowledged limitations in manufacture. To charge that this industry is built upon a structure of assumption, psychology, and improperly weighed evidence is an impeachment of the integrity or belittling of the powers of observation of users through many centuries of service experiences.

Jan 1, 1929

By Paul Weaver

OF the four papers that comprise this TECHNICAL PUBLICATION, three are case histories of individual geophysical prospects, subsequently tested by drilling. The bibliography of Dr. Barton&apos;s published scientific papers† includes investigaions in physiography and surface geological mapping, as well as his geophysical papers, and from this list it is to be observed that he early recognized the place of different types of geophysical prospecting methods in the search for geological structures of economic importance. Moreover, his viewpoint was not merely that the structures should be found, but that the geophysical data should be examined quantitatively to determine the geometry of the structures. In other words, that although these data are insufficient to deduce a unique form for the structure that caused the effects measured in the data, the engineering computations should be carried-out to give as much of a definite configuration to he structure as the data permitted, in order that the testing of the structures could be conducted in the most economical manner and with the idea that the experience so gained could be later incorporated in the study of structures subsequently found. Dr. Barton continually emphasized the quantitative use of geophysical observations, whereas at the time that he began his specialization in geophysics it was considered sufficient to use observations only qualitatively. He, more than any one else, was responsible for -the first volume on geophysical prospecting issued by the Institute in 1929, and his three articles in that volume stressed the quantitative use of geophysical prospecting. The fourth article in this present TECHNICAL PUBLICATION is a further contribution to this branch of geophysical interpretation, and is a supplement to the paper in the 1929 volume, "Calculations in the Interpretation of Observations with .the Eötvös Torsion Balance." From the successful&apos; demonstration by Dr. Barton of the usefulness of quan-

Jan 1, 1944

By R. C. Gifkins

R. C. Gifkins (CSIRO)—In this paper evidence is put forward to support the idea of grain boundary shearing in aluminum at 4.2°K and the phenomenon is explained in terms of a low-temperature "equicohesive temperature". It is stated that these findings show that grain boundary shear cannot be ruled out in any situation by temperature arguments alone. We believe, from our own recent study of "apparent grain boundary sliding&apos;&apos; at temperatures below 0.45 Tm, that it can be ruled out on temperature arguments alone.45 Our experiments were made principally with magnesium and a Ms-A1 alloy ("Magnox A12"). Careful examination of offsets of marker lines or steps at grain boundaries produced by deformation at room temperature (-0.3 Tm) showed many of these to result from curvature over narrow zones along the grain boundaries. A significant residuum did, however, appear as a sharp offset or step. It was found that the mean value of this step rose to a small value during the first 0.5 to 1 pct strain and then remained at this level with further strain. Moreover, exactly the same values were obtained (at the same stress) at 75°C instead of 21°C. That is, in this range of temperature the "apparent sliding" was not temperature-sensitive. At 125°C and above there was sliding which increased with strain and which was temperature-dependent. When this temperature-dependent sliding was used to calculate the sliding to be expected at room temperature, this underestimated the "apparent sliding" by a factor of 104. The conclusion drawn is that the "apparent sliding" consists of shear localized in a zone of a width measured perhaps in microns, whereas it seems that true sliding occurs on the boundary surface.46 A model for such localized shear has been developed in general terms, following a similar model of Urie and Wain.47 Other strong evidence for low-temper- ature sliding has been based on the offsets of marker lines consisting of a substructure seen using the electron microscope to resolve these.48 We have repeated this work and found that the effects can be accounted for in terms of cracks in an oxide film which is produced when the substructure is etched up; these cracks form over zones of shear rather than at actual interfaces. However, in aluminum at room temperature (-0.3 Tm) there is no "apparent sliding" which is optically detectable. We suggest that, when the temperature is much lower (and possibly the rate of strain higher, too), as in the experiments of Chin et al., then aluminum behaves like magnesium at room temperature, and a narrow zone of shear develops to accommodate differences in strain across the grain boundary. Such a zone could well give rise to triple-point cracks. It is hoped to investigate these suggestions further. B. Y. Chin, W. F. Hosford, Jr., and W. A. Backofen (authors&apos; reply)—It is interesting to have Dr. Gif-kin&apos;s comments, although it is somewhat difficult to reply in detail without the reference containing the work that he describes. Apparently though, he does find a low-temperature temperature-independent sliding that would seem to be related to the observations reported here. Perhaps some of the difficulty has semantic origins, growing out of the distinction between (&apos;true sliding" and "apparent sliding".

Jan 1, 1965