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By L. E. Mordberg, E. N. Nesterova

Geochemical studies of the bauxite deposits show that the primary composition is gibbsitic. Some trace elements were relatively mobile during bauxite formation with the content of Th, U and Zr increasing and that of Rb, Ni and Co decreasing. Y and Pb were relatively immobile during lateritisation; their contents and ratios were inherited from different types of underlying rocks. The supply of Ni and Co took place at the diagenetic or epigenetic stages; their ultimate source was the crystalline basement in the region. The studies support the view that the bauxite was likely to have originated as a result of in-situ lateritisation and not through sedimentary transport and redeposition

Jun 18, 1905

By G. Adachi, K. Machida, T. Ozaki, K. Murase

The chlorination rate with CCl4 was unexpectedly slower than carbochlorination using chlorine under the same reaction conditions. Chlorination with CCl4 was topochemical and the amount of monazite reacted after different periods suggested that the kinetic control step was the reaction between CCl4 and the monazite core at the interface. The kinetic order of the reaction was 0.5. The presence of a complex former, AlCl3, promoted the chemical vapour transport of rare-earth chlorides as complexes

Jun 18, 1905

A study of the thermodynamic properties of magnesium chloride ammines was carried out with the ultimate objective that the thermal decomposition of the hexammine MgCl2.6NH3 may prove successful on a commercial scale for the manufacture of anhydrous magnesium chloride, which is required for the efficient electrolytic production of magnesium. The experimental data are presented in the form of an equilibrium diagram that aids the understanding of the conditions associated with the thermal decomposition of ammines

Jun 13, 1905

By J. S. Coats, G. E. Patts, N. Hughes

Conventional sampling methods are known to suffer from the variable loss of fine gold by elutriation. Freeze sampling yields representative and quantitative data that, when combined with information on the sedimentology of gravel-bed rivers, may facilitate the development of improved dispersion models for source detection. It is suggested that freeze sampling may have particular application to the orientation stage of a large gold exploration survey

Jan 1, 1991

By F. Tailoka, G. Zhao

Pb is an unwanted impurity in Al for which there is no established method of removal. As it interacts strongly with alkali metals, separation was achieved by adding Na or K to molten Al at 953-1 003 K. Direct Na addition led to considerable evaporative loss but in-situ addition by electrochemical titration from a eutectic NaCl-KCl or KCl-BaCl2 mixture was found far more effective, in some cases reducing Pb content below detection levels within 2 h of titration. K appeared more effective than Na at low Pb concentrations but the use of Na was preferred as it is less toxic and explosive. Na removal from Al-Na and Na-Pb alloys was also carried out electrochemically, the use of these two alloys rather than the eutectic salt as a source of Na avoiding liberation of Cl2 at the anode

Apr 1, 1995

By G W. Clamp

The most traum atic event within the lUK coal industry during the last 30 years was its privatisation. Who were the relatively unknown people from RJB: white knights or robber barons? This paper highlights the strong safety and progressive engineering cultures th at existed and continues within the company. A long-term view of the business coupled with proven professionalism is amply developed. Quite dearly, to revert to private ownership is not a return to Victorian values but ‘back to the future’.

Jan 8, 1997

By T. Ogasawara, J. P. Barbosa, A. J. Monhemius, F. T. Da Silvia

A thermodynamic analysis of the sulphation of rare-earth phosphates and the water-leaching of rare-earth sulphates was used to guide experimental work on the sulphation and leaching of concentrates from Pitinga. It was concluded that the sulphuric acid digestion of xenotime is technically feasible and could be used industrially to produce yttrium and other rare-earth oxides. Yttrium extractions of more than 90% were obtained by digestion at 503 K for 4 h at an acid:concentrate ratio of 2:1 with particle size -0.053 mm. The apparent activation energy at temperatures less than 473 K, as determined from the Arrhenius plot, was 11.0 kJ/mol, indicating that the reaction is controlled by the diffusion of the reactants or products through the sulphate layer

Jun 19, 1905

Paper presented at the Mining Institute of Scotland's annual general meeting held in Glasgow, 8th April 1916. Although there is nothing novel or difficult about the sinking described, circular shafts are not numerous in Scotland so the details connected with such a sinking may be of interest. The shaft was sunk at Dykehead Colliery, Larkhall, which has been worked for over 50 years from the upper seams. It became necessary to sink another shaft to serve as a replacement downcast, by which the output might be maintained and some of the lower seams won. As the sandy clays regularly caused bulging into the rectangular shaft and sinking of the surrounding ground it was decided to make the new shaft circular and to enclose its mouth in a foundation-block of concrete resting on the solid clay. Details are given of the sinking, brick seating and lining, kettle strike, water-rings and doorhead lintels as well as the permanent fittings, winding gear and the cages themselves

Dec 1, 1916

By Schwartz M.

Respect for mining in Botswana is long-standing. This article looks at Africa's most transparent mining regime and some of its ambitious plans. Botswana's mining industry value is forecast to average 5.2% growth from 2014-2018 with solid growth for the diamond sector and acceleration of coal production. Respect for the country's mining regime is maintained in the Fraser Institute 2014 annual survey where Botswana occupies the 26th position of 122 administrations. Botswana's transparency is illustrated by Mupane gold mine near Francistown, Ghaghoo diamond mine in the Gope area and the Morupule coal mine

Mar 1, 2015

By F. Boudreault, M. J. Scobie, J. Szymanski, C. Hendricks

The development of new stoping methods and more effective control over dilution, recovery and fragmentation depends on improved accuracy in blasthole drilling. The mechanisms and factors which control accuracy are poorly understood. Canadian blasthole stoping and the practices adopted for monitoring and controlling drilling accuracy are reviewed. The techniques and problems associated with blashole set-up and trajectory surveying are discussed. Four new blasthole trajectory survey systems are evaluated on the basis of their performance in recent underground trials. Conclusions are drawn as to the technological developments required so that more precise control over drilling accuracy can be achieved.

Jan 12, 1992

By Ruddle R. W.

Solid mattes are generally held to be either (a) eutectiferous mixtures of the component sulphides Cu2S and FeS or (b) mixtures of complex sulphides. This chapter shows that liquid mattes consist essentially of a homogeneous phase in which iron, copper and sulphur are present. The amount of sulphur is generally less than that required to account for all the metals as stoichiometric sulphides; mattes cannot therefore be regarded as mixtures of FeS and Cu2S. Some iron oxide may be dissolved in the sulphide phase and magnetite is often present as a second phase. If the sulphur content of the matte is reduced the composition enters the miscibility gap in the ternary system and either an iron- or copper-rich solution (depending upon the composition of the matte) separates as a new phase. On solidification any one of four phases (iron, copper, Cu2S and FeS solid solutions) may crystallize as primaries. The remainder of the matte solidifies as a ternary eutectic. It is possible that iron oxides enter into this eutectic. Knowledge of the ternary Cu-Fe-S system is far from complete and nothing is known of the quaternary system Cu-Fe-S-O

Jan 1, 1953

By J. H. E. Jeffes, K. T. Jacob

Solid oxide galvanic cells, of the type: Pt,Ni-NiO | Solid electrolyte | O(metal),Cermet,Pt, were used to measure the activity coefficient of oxygen in liquid Cu at 1 100 and 1 300°C and in Pb at 1 100°C. Similar cells were used to study the activity coefficient of oxygen in the whole range of Cu + Pb alloys at 1 100°C and in Pb-rich alloys at 900 and 750°C. The results obtained are discussed in terms of proposed solution models. An equation based on the formation of 'species' of the form M(2)O in solutions of oxygen in binary alloys is shown to fit the experimental data

Dec 1, 1971

By D. C. Yates, G. V. Jolliffe

In the five coalfields of Staffordshire, there have been some 43 incidents of spontaneous fires and heatings which have required special attention in the past ten years. This total excludes incidents in the Thick Coal Seam of South Staffordshire, which was worked until 1967, and which was subject to an almost continuous series of heatings. The incidents have been classified to show the sites of occurrence, the contributory factors which may have caused them and the treatments applied to them. The remedial techniques, as practised in Staffordshire, are dealt with in detail, with particular reference to standard methods of stopping-off. Precautionary measures taken are described, including a "liability to spontaneous combustion" classification of all seams, and the setting up of an emergency organization with emergency stocks of materials and equipment. The paper is concluded by a few words on the organization and control at the time of an incident.

May 23, 1905

By L. G. Billington

"The Agnew nickel deposit occurs in a major linear greenstone belt in the Archaean Eastern Goldfields Province of Western Australia, and has been subjected to mid-amphibolite facies nietamorphism of dynamic style. The largest dunitic ultramafic body in the Perseverance Block is host to the bulk of the nickel mineralization. The Perseverance Ultramafic is mineralogically zoned and has an embayed western margin against a mixed metasedimentarv-metavolcanic wallrock sequence.Three categories of nickel sulphide mineralization are concentrated on this western margin at the thickest part of the ultramafic exposure. Massive sulphides characteristically occur as contact mineralization, internal mineralization and as remobilized concentrations in vein form structures. Disseminated ore constitutes the largest volume of mineralized materials in the deposit and occurs in three separate shoots in en-echelon relation. Weakly mineralized 'cloud sulphide' zones surround and envelop the shoots and persist much further along strike. In the upper mine levels the shoots are truncated by a shear or crush zone, which inhibits geological knowledge to the south but marks a major fundamental structural break.Most of the ore types have suffered supergene alteration and there is a complex variable distribution of the mineralogical facies. The ore types have been metamorphically retextured, but the oreshoots can be characterized by their Ni tenor and some chemical ratios. S/Se values, PGF. and precious metal values are distinctly different from those of other nickel sulphide ores extracted.Despite intense structural and metamorphic modification of the mineralizations, some features support an original magmatic derivation for the sulphides. These include the localization of massive sulphide ore types on one marginal contact within an emhayment structure, the general distribution of disseminated mineralizations located immediately above the massive sulphides and the Ni/Cu, Ni/Co, Fe/Ni ratios of the oreshoots being similar to those of deposits that typify the intrusive dunite- associated class of nickel sulphide deposit. Varying S/Ni ratios between different shoots suggest a revision of the single magmatic intrusion model in favour of a changing composition between successive magmatic episodes."

Jan 1, 1984

By M. L. Schmulian

"The Windarra nickel deposits display many of the characteristics that typify Archaean volcanic peridotite-associated nickel sulphide ores of Western Australia. The Fe-Ni-Cu sulphide mineralization, which comprises dominantly disseminated sulphides, occurs at the base of a differentiated ultramafic volcanic pile grading upwards from massive meta-peridotitic flows to thin, locally spinifex-textured meta-picritic units. The entire mafic-ultramafic belt has been subjected to mid-amphibolite- facies metamorphism. The ore-bearing ultramafic is immediately underlain by dominantly sulphide-facies banded iron formation (BIF), which commonly contains nickel sulphides adjacent to its contact with mineralized ultramafic. BIF-hosted ores are formed both by physical remobilization of ultramafic-hosted sulphides and by migration of Ni and Cu into pre-existing iron sulphides.At Mt. Windarra the mineralization comprises eight steeply dipping, steeply plunging elongate oreshoots, which display a marked parallelism with major and minor fold structures in the underlying BIF. Seven of the shoots occur at or close to the base of the ultramafic pile, and are hosted by at least three overlapping flows. The zone of overlap occurs at the northern end of each flow, where picritic ultramafic, representing a dominantly liquid portion of the flow, occupies the basal contact. A gross south- north ultramafic flow direction is inferred. The eighth shoot occurs in a stratigraphically higher position within the ultramafic sequence.At South Windarra at least two overlapping mineralized flows occupy the basal contact, the ore zone having a strike extent three to four times its downdip extent. There is no obvious structural control to the mineralization."

Jan 1, 1984

By W. H. McAllister

The paper considers the geology and the coalfields that comprise the Scottish south area. It traces the history of known sources of spontaneous combustion and indicates the collieries concerned, with the position of the seams in the geological series where heatings have occurred. The methods of work over the years are described. It relates in detail the circumstances surrounding a fire at Bilston Glen Colliery in the Lothian Coalfield, and the heating at Killoch Colliery in the Ayrshire Coalfield, and the steps taken to deal with them. It also describes some of the difficulties in steep seam working. Methods adopted to prevent spontaneous combustion throughout the area are discussed, and some detail of the UNOR gas analyser is given. Finally, it comments on the present techniques in use in the area, particularly at Bilston Glen Colliery, to prevent spontaneous combustion.

May 23, 1905

By A. L. W. Lips, B. P. J. Stevens, T. J. R. Barclay, E. Rothery, S. H. White

Discussion by B.P.J. Stevens of the paper, published in Trans. IMMA, vol.104, 1995, p.B1-B17, is presented together with the authors' response. Stevens questions the authors' radically different interpretation of the structural geology of the Broken Hill Block, considering that the descriptive part of the paper is a useful addition but that the conclusions are unwarranted on the basis of the data presented. A number of major points of disagreement are outlined and half a dozen additional minor points listed. In response, the authors admire Stevens's contribution to unravelling the geology of the area but defend their attempts to take the regional studies a step further, pointing out that he has misquoted what they wrote and arguing that because of the assumptions underpinning the derivation of the present stratigraphy it cannot be used to constrain structural models. With regard to shear zones, they cite the extensive earlier literature and refer to horizontal displacements shown on maps produced by Stevens et al. Detailed discussion follows of the stratigraphy and of the stratigraphic correlation problems resulting from failure to recognise the presence and significance of shears, particularly those parallel to stratigraphy. The remobilised position of the Pb mineralisation in the North Mine open cut is reiterated. It is concluded that there is an urgent need for systematic isotopic dating in the area to constrain the stratigraphy

Apr 1, 1996

By S. Vardy

The paper notes that the extraction of 22% of the remaining workable reserves in the north western area involves a risk of spontaneous combustion higher than is normal in Britain. Mining systems have been tailor made in order to minimize the risk of spontaneous heatings, and these systems are described. Well-proved methods of combating spontaneous combustion are referred to, as well as the limitations which now apply to them as the result of the introduction of modern mining techniques. A substantial part of the paper is devoted to the circumstances in which spontaneous combustion occurs underground in the north western area. Several actual incidents which have occurred in the last few years, along with the practical application of the lessons learned, are described. Of particular note are: a) the procedure adopted in the north western area to equalize pressure differences across stoppings using pressure chambers, and b) a retreat mining system, primarily designed to deal with high methane emission and steep gradients, which also affords some protection against spontaneous combustion.

May 23, 1905

By L Zhang

The Chinese coal industry is the largest coal producer in the world. The total production in I995 was 1.28 bnt. On the way towards introducing a market economic system, this mature industry is facing major challenges. The main problems are a large surplus of manpower, shortage of current assets and capital, low productivity, high casualties and a huge deficit. This paper discusses the present situation and the future developments in the Chinese coal industry. The current policy can be stated as ‘rapidly developing the state collieries and improving the village and private mines; integrated development to achieve an economic operating scale and encouraging a diversified economy; rapidly exploiting and developing in the North west and South west; promoting productivity and efficiency; welcoming multi-sources and types of investment; setting up coal exchange markets; and the careful control of resources and the environment'.

Jan 11, 1996

"The Archaean komatiite-associated nickel sulphide deposits at Kambalda, Western Australia, exhibit a number of stratigraphic features that are indicative of a strong volcanic control on ore localization, including (1) a restriction to specific basal cumulate metakomatiite host units, (2) confinement within distinctive synvolcanic embayments in the footwall and (3) variations in the internal structure and composition of overlying and adjacent barren metakomatiite flow's and the distribution of interflow metasediments with proximity to the ore zones.The high magnesium content of the host units (up to 45% MgO volatile-free) in comparison with that of aphyric or spinifex- textured lavas (16-32% MgO) has been considered previously to indicate either magmas/lavas rich in intratelluric olivine or selective accumulation of olivine phenocrysts. The marked linear trend of the oreshoots, basal host units, footwall embayments and the volcanic stratigraphic relationships have been used as evidence for local linear feeding fissures. Rare relict igneous olivine in some host units is, however, demonstrably not intratelluric, and there is no direct or indirect evidence of a proximal eruptive site (e.g. footwall feeders, pyroclastic breccias, ultramafic intrusives) at Kambalda such as at some other deposits of this type. Kambalda is interpreted as a distal rather than proximal volcanic environment.Emplacement of the komatiite sequence at Kambalda was probably controlled by the locations of a few specific eruptive sites relative to regional topographic gradients and influenced by the topography of the pre-existing volcanic surface. Olivine enrichment in the basal host units occurred by in-situ fractionation and cumulus crystallization of olivine during longitudinal lava flow within linear lava conduits, possibly centralized on depressions between non-overlapping footwall basalt flows. The distinctive stratigraphic relationships are attributed to localization of lava conduits along the volcanic pitchline, flanked by more slowly moving parts of the flows. There are analogies with the physical volcanology of Modern basaltic and Proterozoic komatiitic lava flows.A corollary of this model is that the lava conduits thermally eroded and assimilated sulphidic sediments, contributing additional sulphur to sulphur-saturated komatiites or possibly inducing sulphide separation in originally sulphur-undersaturated komatiites. The latter would account for the restriction of ores to linear cumulate komatiite host units (thermally active lava conduits) and the locally mutually exclusive, but stratigraphically equivalent, relationship between the ores and sulphidic metasediments at Kambalda."

Jan 1, 1984