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By J. G. Pharoah

Over the last two decades a variety of models for solid oxide fuel cells (SOFCs) have emerged ranging from one dimensional (1-D) to 3-D models, from steady-state to transient models; single- and half-cell and entire stack models. A majority of these models have focused either on the transport processes or on the chemical/electrochemical processes. The approach taken by our research group is to develop a comprehensive SOFC model framework based on the considerations of detailed electrochemical reaction mechanism and by accounting for complex transport processes occurring in the porous media at the micro-scale level. In this paper, we review the state-of-the-art in SOFC modeling and identify the existing gaps that need to be filled in.

Jan 1, 2005

By Sergio Bustos

A significant expansion project is under way at KATCO?s Torkuduk In Situ Leaching (ISL) operation to increase uranium production up to about 4000 tU/year. Higher flows and lower uranium concentration are expected in the rich solutions coming from the well fields. Therefore, extra adsorption and elution columns and modified operating conditions are required to deal with the increased demand for uranium transfer from the ISL solutions to the eluate solution, which goes to the uranium precipitation section. Resin adsorption and elution performance have been interpreted and projected by using Mac Cabe-Thiele equilibrium diagrams. The resin load, the adsorption mass transfer coefficient, the adsorption zone height and the eluate concentration have been estimated for the expected changing operating conditions associated to the future mine plan. This information has allowed to improve the present operation results and to define the main process design criteria for the expansion project.

Aug 1, 2010

By C. S. Lord

"The Regal Silver mine is 5 miles north-northwest of Albert canyon; a station on the main line of the Canadian Pacific railway; 21 miles east of Revelstoke; British Columbia.Development, commenced in 1918, comprises more than 8,000 feet of workings from six adits, one of which extends into the Regal Silver property from the adjacent Snowflake ground. Production has been limited to a little tungsten concentrate recovered recently from a few r..undred tons of ore treated in a small underground mill. The property has received some attention as a possible source of tin. The deposits are large quartz veins containing irregular sulphide bodies. Ore minerals normally make up less than 1 per cent of the veins and include pyrite, galena, sphalerite, scheelite, and stannite. The veins are approximately parallel with the bedding of the enclosing graphitic, siliceous to calcareous, slates and argillites. These strata are of Precambrian age, strike about northwest, and dip northeast. No other rocks are known in the vicinity of the workings . Granitic rocks, intrusive into t'he sediments, outcrop 4 miles to the southwest and 7 miles to the northeast and may underlie the property at no great depth."

Jan 1, 1954

By P. Hubert, J. P. Ildefonse, F. Qafssaoui, J. Poirier

Corrosion tests by corrosive alumina-lime slags were carried out on commercial high alumina bricks used in steel ladle linings and model refractories (with different raw materials : bauxite, andalusite, and different microstructures). Using (SEM) scanning electron microscope and (EDS) energy dispersive spectroscopy, microstructures of slag-corroded refractory interfaces were studied in detail. The monomineral and glassy phases, the composition of reaction products and chemical profiles were determined. A thermochemical analysis based on phase equilibrium diagrams has permitted to estimate the proportion and the composition of the high temperature intergranular liquid phase. These data were compared to the experimental microanalysis results. The viscosity of the high temperature liquids were calculated according to Urbain 's model and the relationship between the viscosity and the penetration of liquid phases were discussed. These theorical and experimental results were used to understand the complex phenomena of slag penetration and corrosion of andalusite and bauxite refractories at high temperature and to propose new ways of improvements for the formulation of high alumina refractories.

Jan 1, 2004

By Schoeman L., K. C. Sole

Evaluation and measurement of the influence of changes in conditions and electrolyte composition during early stages of a growing metal electrodeposit are crucial to predict changes in developing morphology. A galvanodynamic polarization technique was developed to reliably measure overpotentials for nickel electrodeposition from sulfate electrolyte. The validity of these polarization parameters as indicators of the relationships between changes in the electrolyte and resulting deposit morphology was evaluated for electrolytes of varying composition. Findings indicate that nucleation and plating overpotentials measured by the described technique can be used as indicative tools for monitoring, evaluating and ultimately improving control of the electrodeposition of nickel from sulfate electrolytes. The results predict that nickel deposits of desirable quality and morphology are obtained when plating overpotentials are higher than 700 mV vs. Ag/AgCl and nucleation overpotential is less negative than plating overpotential.

Jan 1, 2017

By P. Maltby

"Smelter Feed Preparation Falconbridge Nickel Mines Limited, Sudbury Operations, operate 4 mills and a smelter to produce Bessemer Ni-Cu matte for refining in Norway. Approximately 1400 tons of Ni-Cu concentrate are produced daily which are dried from a filter cake containing 14% moisture to 7.5% moisture pellets. Concentrate drying is done by 4 rotary dryers as shown in the 'Dryer Performance Data' at four separate locations. The dryers all form part of the feed preparation stage prior to sintering.The rate at which concentrate can be produced through the Sinter Plant largely depends on the quality of the dried product which makes up the feed. A feed consisting of mostly hardened pellets will sinter much faster than a feed which consists of broken pellets and dust. Dryer products require:1. Good green strength to survive shipment and handling.2. Correct moisture content.3. Sizing within a range ideally from 1/4"" to 10 mesh in diameter.Dryer performance data is shown in Table 1. Capital costs between the two types of dryers are comparable with the Roto-Louvre producing generally a larger better-formed pellet. Dryer feeds differ in that at both Hardy and Fecunis, Ni-Cu concentrate filter cake is the only feed while at the Falconbridge slurry plant the dryer feed can consist of up to 10% by weight of smelter flue dust resulting in a combined concentrate-dust pellet for feeding to the Sinter Plant. To the Falconbridge Sinter Plant dryer, dust and limestone are added for the smelting process in addition to Ni-Cu concentrate."

Jan 1, 1972

By T. G. Carter

"This paper traces the introduction and use of fire-resistant (FR) fluids in hydraulic systems at underground mines in British Columbia. Reasons are given for the decision to make compulsory the use of such fluids in underground mines after January 1, 1975 by provincial government legislation. Examples are quoted of fires caused, or supported by, mineral oils which have resulted in loss of life and property.The basic principles of hydraulic systems are reviewed in order to present the effects of changing a system operating on mineral oils to one which must operate on FR fluids. Approximations of the cost of system conversions are given for certain machines and a brief survey is made of the various pieces of underground equipment which contain hydraulic systems operating on FR fluids.IntroductionIn 1948, Admiral Ben Moreel , who was then president of Jones and Laughlin Steel Corporation in the United States , wrote:""Although safe and healthful working conditions can be justified on a cold dollars-and- cents basis, I prefer to justify them on the basic principle that it is the right thing to do. ""(1)This paper will outline the introduction and use of fire resistant fluids at mine operations in the Province of British Columbia. That it was the right thing to do in enhancing the safety and well-being of every person employed at the mines was the prime consideration. That it may be justified on a cold dollars-and-cents basis is left for the reader to judge. The prime purpose of this paper is not so much to trace the efforts made by the individual mines to successfully introduce and use fire-resistant (FR) fluids in hydraulic systems, but to present an over-all picture of what occurred, in a collective sense, at the majority of mines which have ended up with a working FR fluid system. The problems attendant to the introduction of an FR fluid will be recounted in a manner which, it is hoped, will prove useful to those contemplating system conversions. Because the predominant fluid now in use is an invert, or water-in-oil. emulsion, this will be the FR fluid considered.Fluid Loss from SystemsThe quantities of various fluids required for use in hydraulic systems are extremely high. This statement in itself may appear to be redundant in that the capacities of the various systems should demand that a fixed amount of fluid is required for the initial filling of a system, with a further amount of fluid scheduled for use during subsequent fluid changes, i.e. at the recommended change intervals . If only this were the case!"

Jan 1, 1981

By N. Schreithofer, M. Aspiala, R. Serna

The novel attachment timer apparatus presented in this paper serves as a diagnostic tool that allows the detection of changes in bubble-particle attachment probability and therefore floatability caused by alterations in the chemical environment and particle properties. The apparatus consists of six identical capillaries where bubbles with defined size are produced simultaneously in a measurement chamber. The bubbles at the capillary tips are placed in contact with the submerged particle bed for specific time periods, controlled with the help of automatic actuators. The advantage of the instrument is that hundreds of bubble-particle contacts can be measured automatically within a short time period. Microscopic pictures of each measured bubble are taken while recording the movement of the bubble before, during and after contact with the solid particles. The recorded pictures can be used to determine the actual bubble size and its corresponding deviation, and to detect the attachment of particles. The attached particles are collected in a detachable chamber for subsequent characterization. Furthermore, the device is portable and can be taken to the mineral processing plants for quick evaluation of particle-bubble attachment efficiency with particles and process water sampled directly from real processes.

Jan 1, 2017

By Dallas W. Davis

Twin - Kennecott Deal Announced April 15, 2004 ! Kennecott earns 56% interest, if in 4 years, spends C$10 million and recovers at least 200 cts of +1 mm diamonds in all dimensions from any contiguous body ! Earn-in can take up to 6 years, but incurs stepped reduction of interest from 56% to 46% or 0% if $C10 and 200 carats not achieved ! By funding all costs through feasibility study, Kennecott earns 71% in 7 years, or, stepped reduction to 62% if completed after 8 years ! By achieving production within 10 years and funding Twin?s share of development and construction costs, Kennecott earns further 4% ! If no election to develop a mine within 2 years of feasibility study completion, Twin may present development proposal which Kennecott has 60 days to elect to follow or transfer management to Twin and dilute to 49% ! Each party has one time right to elect to market its diamond share ! On signing and annually, Kennecott will purchase $C250,000 of Twin shares at 130% of then prevailing market price until achieved earn-in

May 1, 2004

By Ken Steele, Pam Sangster, Myra Gerow

Ontario leads Canada in production of structural materials and ranks third in production of non-metallic minerals. The total value of industrial mineral production in 1997 was $1.6 billion. The province is the leading producer of nepheline syenite, salt, talc, clay products, cement, lime, sand and gravel, stone and a major producer of gypsum and silica. Barite, sulphur in smelter gas, elemental sulphur, tremolite, serpentine, gemstones and peat are also produced. Table 1 shows recent actual industrial mineral production levels in Ontario. Other industrial minerals, including phosphate, petalite, diamonds, wollastonite, vermiculite, kyanite, garnet, graphite, silica, kaolin, dimension stone and anorthosite, have been the target of exploration and development projects. Investment opportunities exist at all levels from grass-root prospect through to production level.

Jan 1, 2001

By H. Tudeshki

A great amount of aggregate is utilized in civil engineering applications such as road construction, railway infrastructure, concrete production, etc. Igneous rocks are the preferred raw material due to their high strength and abrasion resistance. Rock quality assurance is a key factor and has great influence on the quality of constructions in civil engineering. One of the major problems encountered by both the producers and users of igneous aggregate rock is the fact that, with the passage of time, some specific rocks lose their strength, up to a complete loss of structure, i.e. disintegrate and degrade. This phenomenon has a great influence on the quality, strength and durability of aggregates. In the last decades, different methods and procedures such as the glycol test, the methylene blue dye test, as well as the Los Angeles test, have been introduced to distinguish rock properties, and to identify these problems. However, as these wet-chemical methods are time consuming, hard to perform, only to be applied to hand-piece samples, requiring special laboratory equipments, and are only possible to be accomplished under laboratory conditions, their application has always been severely limited. To address this widespread quality management problem of the quarry industry, a relatively quick, easy and user-friendly approach is necessary. It calls for a systematic solution with a device that can simply be used in the day-to-day routine of a mine for quality control of the quarry´s daily production. Our research is concentrated on developing a systematic method for early recognition and diagnosis of rock quality, in order to control and manage the quality of the quarry production in advance. Our new approach is based on two rock parameters: magnetic susceptibility and loss on ignition. The measurement of these parameters provides reliable information on the quality of the rock and allows the quality control process to be accomplished and performed at the borehole location. Our new approach has been assessed through extensive field and laboratory studies and has been implemented on the drill-cuttings of a basaltic andesite quarry. The results of the experiments are discussed in detail, including their impact on increasing resources and environmental protection.

Aug 1, 2013

By B. Jena, M. Rigaud, S. C. Panigrahy

"The influence of flux addition on the structure and properties of pellets produced from low silica specularite with peat moss and bentonite as binders was investigated. Specific pellets basicities in the range of 0.4 to 3.2 were obtained by the addition of limestone or a combination of dolomite and limestone as flux. A t basicities < 1.6, the bonding in the pellets was provided by a glassy silicate phase. At basicities =1.6, calcium ferrites were the predominant bonding phase. When dolomite was added as a flux, presence of magnesia-ferrite was noted. The reduction behaviour of pellets at different basicities was found to be influenced by the type of flux and binder. The pellet compression strength and swelling characteristics were improved with increased basicity.IntroductionThe properties of iron ore pellets are influenced by the type and nature of the ore or concentrate, additives and their subsequent treatment to produce pellets. The interaction between various constituents of the concentrate and additives, i.e. iron oxides, gangue and fluxes etc. result in the formation of various mineralogical phases which affect the degree and nature of bonding achieved in the pellet and the structure and distribution of pores. The pellet properties such as pellet strength and reducibility are influenced by the extent and type of bonding achieved between the ore particles. In view of the present emphasis on the production of high quality pellets to meet progressively stringent quality control requirements, it is essential to investigate the effect of additives on the bonding mechanism and properties of the pellets.In the past, the effects of additives on the bonding mechanism of pellets have been investigated. It is important to note that the conditions and parameters to be controlled are typical of a given concentrate/ore. In this paper, the results of the investigation on characterization of fluxed pellets produced from a low silica specularite concentrate are reported.This investigation was also aimed at assessing the suitability of peat moss for use as a binder for the production of low silica fluxed pellets. Peat moss is abundantly available in the vicinity of iron ore mines in Quebec and encouraging results have been obtained du ring the production of high silica acid and fluxed pellets."

Jan 1, 1992

By John H. Fowler

Nova Scotia has been mining and exporting industrial minerals for over two hundred years. As an industrial mineral producer, this province continues to rank as the number one gypsum mining and exporting region in North America. Mining of many other commodities is ongoing, supplying many local and export markets. In all, excluding aggregate producers, there are nineteen industrial mineral producers operating at thirty sites producing nine commodities including anhydrite, barite, clay and shale, dolomite, gypsum, limestone, salt, silica sand and stone (Fig. I). Numerous aggregate producing operations supply all the province's aggregate requirements and export some of these materials to other regions of Atlantic Canada and as far away as Bermuda (Fig. 2) . Production value of industrial mineral commodities in Nova Scotia for 1982 was $105 million , representing 39% of the total value for all mineral production for the year. Because of the general improvement in the economy, indications are that the 1983 value of production will be higher.

Jan 1, 1984

By C. Peña, C. A. Zaror, M. Bustamante, M. Vega

The goal of this paper is to present the carbon footprint of Chilean cathodic copper, as a function of the electricity generation mix, ore grade, and process efficiency. Ore grades and acid leach-solvent extraction-electrowinning (LX-SX-EW) yields in the range 0.5-1.0% and 60-80%, respectively, were considered here. Additionally, electricity supply from two Chilean suppliers, SING (1.0 ton CO2/MWh) and SIC (0.4 ton CO2/MWh) was assessed. Simulation results show that oxide plants located in northern Chile, served by the SING network, feature carbon footprint within 4.3 - 11.4 MWh I ton cathodic copper, as compared with 3.5 - 9.3 MWh I ton copper in plants served by SIC. The footprint was found to increase as ore wade and process yields decrease.

Jan 1, 2011

By J. A. C. Fortescue

"Reconnaissance geochemical mapping, based on the chemical analysis of waters, stream, and / or lake sediments had its origin in geochemical prospecting surveys carried out in New Brunswick during the 1950s. More recently, reconnaissance geochemical surveys carried out by government agencies for mineral resource appraisal purposes have been seen as a special case of regional geochemical mapping which is carried out with the aim of describing geochemical patterns f or elements which may he interpreted for mineral resource appraisal, environmental or geological purposes. The interpretation of pal/ ems on regional geochemical maps is based on the concepts of landscape geochemistry, in this paper, the regional approach 10 geochemical mapping is described with reference to an experimental regional geochemical survey which was completed in southwest Ontario during 1981-82. II is concluded, on the basis of data pal/ems for one element only (i.e. arsenic), that the new approach has much potential for solving modern problems in geoscience.""If things don &apos;I alter they will stay as they are... An old adage.IntroductionDuring the past hundred years topographic, geological, and geophysical maps have been made for all, or nearly all, of Ontario. During the past thirty years these maps have become related as components of what is now called geoscience. Geoscience maps at the regional (i .e. 1 :250,000) scale are often used together to solve general problems in earth science especially in relation to prospecting, or mineral re source appraisal."

Jan 1, 1986

By Mike Power

Geophysical techniques have played a pivotal role in northern kimberlite exploration since the initial discovery at Point Lake in 1991. In the Slave Craton and surrounding regions, there are definite contrasts in physical properties between kimberlite intrusions and surrounding bedrock. Kimberlite commonly displays higher magnetic susceptibility, distinctive remnant magnetism, low electrical resistivity and lower density than surrounding rocks. In addition, the distinctive geometry of kimberlite pipes is reflected in geophysical responses which further facilitates target discrimination. There has been an evolution in geophysical exploration strategies over the past 12 years. Helicopter total magnetic field and electromagnetic (HEM) surveys have proven to the most cost-effective means of conducting first pass investigations in prospective areas. During the early 1990&apos;s, total magnetic field and frequency domain electromagnetic surveys were virtually the sole techniques employed during follow-up surveys. Inevitably, the initially high rates of kimberlite discovery declined in the areas surrounding the original finds. Marginal magnetic and EM anomalies were all that remained to be tested and this spurred interest in the improvement of existing interpretation algorithms and in the application of additional complementary techniques to reduce the exploration risk. Gravity has become a popular third survey following the deployment of the Falcon (TM) airborne gravity gradiometer system by BHP Billiton in 1999 and improvements in ground techniques. Ground penetrating radar (GPR) has proven to be particularly useful in delineating kimberlite pipes following drill discovery and in exploring for kimberlite dykes in settings where indicator mineral trains indicate such targets are likely. Seismic methods have been tested for both reconnaissance and delineation but remain underemployed. Given the high cost of drilling in the North and the proven success of geophysical techniques in reducing exploration risk, it is likely that an increasingly diverse range of geophysical techniques and innovative interpretation techniques will continue to be applied in kimberlite exploration.

May 1, 2003

By Michael L. Free, Zongliang Zhang, Joshua M. Werner

In the copper electrowinning process, short-circuiting between the anodes and the cathodes is a critical problem that changes the current allocation among local electrodes and reduces the current efficiency significantly. Possible reasons for the short-circuiting include the improper alignment of the electrode, bent electrode, and nodules on the cathode surface. In typical tankhouses, there is often a time between shorting and harvesting as well as between shorting and clearing. Therefore, it is inevitable to have short-circuiting affect the operation performance in practical electrowinning operations. However, one key piece of missing data is the actual measurements of the current efficiency as short-circuiting is approached and allowed to continue. Consequently, short-circuiting tests that allow tracking of electrowinning parameters before and after short-circuiting were performed in a laboratory scale Cu electrowinning cell. In the tests, the electrode spacing change, the mass of electrodeposited Cu, the deposition morphology, and the current allocation as well as the current efficiency before and after short-circuiting were studied. Results show that the short- circuiting affects the current allocation and the current efficiency significantly. Moreover, it changes the Cu deposition on the short-circuited cathode and therefore causes problems for Cu electrowinning. INTRODUCTION Electrowinning (EW) is commonly used for copper production around the world, with a rated production from 120,000 to 200,000 tons per year per operation (Wiechmann, Aqueveque, Henríquez, Muñoz, & Morales, 2014). In Cu electrowinning, Cu ions in the electrolyte are reduced on the cathode surface as metallic copper with a DC current, while on the anode, a counter anodic reaction occurs with oxygen gas generation (Werner, Zeng, Free, Zhang, & Cho, 2018; Zhang, Werner, & Free, 2018; Zhang, Werner, & Free, 2018). In copper electrowinning, an average current density of 200 to 400 A/m2 is applied to the electrowinning cell (Wiechmann et al., 2014). As the Cu deposits on the cathode, the distance between anode and cathode reduces and most of the time, short-circuiting forms between some anodes and cathodes in a large tankhouse containing thousands of electrodes, reducing the current efficiency and increasing the energy consumption significantly. The current efficiency in well-run copper EW operations is typically above 90 %. Most of the unused current is wasted through short circuits, stray currents, and by-byproduct formation (Davenport, King, Schlesinger, & Biswas, 2002; Wiechmann, Vidal, Pagliero, & Gonzalez, 2002; Wiechmann, Morales, & Aqueveque, 2010). Usually, in the tankhouse, the short-circuiting increases the current in the involved cathode by up to 1500 A (Wiechmann et al., 2010). Multiple reasons can cause the short-circuiting in the cell, and the most common reasons include the uneven current distribution among cathodes, tilted electrodes, bent electrodes, and nodules formed due to the large deposition roughness. Recognition of this challenge in the Cu electrowinning process has led researchers to perform many investigations on approaches to avoid and reduce the short-circuiting in the cell. A series of research investigations have been conducted to develop and improve a new type of intercell bar for Cu electrowinning (Wiechmann et al., 2002; Wiechmann, Morales, Aqueveque, & Burgos, 2007; Wiechmann, Morales, & Aqueveque, 2009; Wiechmann et al., 2010; Wiechmann et al., 2014). The associated test results show that this new design limits the occurrence and magnitude of short circuits and allows operation at higher current densities. Sandoval, Clayton, Dominguez, Unger, and Robinson (2010) stated several keys to control short circuits, such as maintaining the straightness of the cathode, removing “edge hair” from the cathode starter, and maintaining electrode alignment in the cell. Prengaman and Siegmund (1999) from RSR technologies developed a new Pb-Ca-Sn anode to prevent the anode deformation, thereby reducing the short-circuiting in the Cu electrowinning cell. Although the negative effects of short-circuiting on the Cu electrowinning have been recognized, and various investigations have been conducted to address this issue, the actual measurements of the electrowinning behavior and performance as short-circuiting is approached and allowed to continue are seldom reported. However, in typical tankhouses, there is a time between when shorting occurs and harvesting/clearing are performed. One key factor in determining the harvest time is the frequency of shorting. Consequently, we have performed short-circuiting tests that allow us to track electrowinning parameters before and after short-circuiting.

Jan 1, 2019

By W. A. D. Edwards

"The Edmonton region accounted for 40% of Alberta&apos;s sand and gravel production in 1981 (about 12 million m3). Most of this production was by commercial operations (75%) for use in essential public works projects (64% in road and asphalt production).Although the Alberta Geological Survey delineated 1157 million m3 of gravel, a number of areas are considered to be in short supply. An econometric model was used for forecast demand in the region. Predictions, based on this forecast and estimated supply, are that 15% of the region&apos;s gravel and 3% of the sand will be consumed by the year 2010.The City of Edmonton is the largest consumer of aggregate in the region. Approximately 40% of the gravel in Edmonton&apos;s current supply area (about 55 km radius) will be used by 2010. These estimates are considered optimistic because the supply figures do not account for sterilization of deposits - some has already taken place in the region. If 25% to 50% of Edmonton&apos;s current supplies (one major deposit) were sterilized it would result in $1,000 million of additional cost due to increased haulage alone.Information on the value of aggregate resources, the location of sand and gravel deposit s and forecast demand has been made available to all municipalities in the region to aid planners and regulators in effective future use of this important resource.INTRODUCTIONAlberta is the second largest producer of sand and gravel in Canada at ab out 50 million tonnes annually. Value of provincial production exceeded $120 million in 1985. In Albert a, aggregate is used primarily in road and building construction (about 50% and 15%, respectively) and is important in such activities as petroleum exploration, oil sands development and the forestry industry.The Edmonton region (Fig. I) accounts for about 40% of provincial production and has a per capita consumption rate of about 13.4 m3 of sand and gravel per annum. Although Edmonton dominates, with approximately 50% of regional production going into the city, aggregate is produced in every county and municipal district in the region.Sand and gravel is essential to the current way of life in the Edmonton region. The resource is valuable and dwindling. The Alberta Geological Survey (a department of the Alberta Research Council) has collected information on aggregate in this region for the last decade which ca n aid government planners and regulators in pre venting sterilization and misallocation of this critical resource. This paper is a summary of that information."

Jan 1, 1989

By Rick Hyndman

? Context: Ø Global action on climate change ? The situation of trade-exposed industry sectors ? The federal government?s draft plan for industry ? CAPP?s position ? Canadian emissions & Canada?s Kyoto target Simple Economic Theory of Dealing with Externalities ? Put cost on emissions Ø Carbon tax Ø Emission trading with auctioned permits ? GHG costs get reflected in the prices of energy alternatives, goods & services Ø Decisions driven by changes in relative prices ? Switching to lower emission fuels ? More energy efficient ways of producing ? More energy efficient appliances, cars, housing ? Reduced demand for energy intensive goods & services ? Anticipation of higher CO2 price drives low CO2 technology Development

Nov 1, 2002

By S. Masambi, S. M. Bradshaw, C. Dorfling

The presence of iron in base metal leach solutions complicates nickel and copper recovery processes. Leach solutions are commonly purified by precipitating iron as hematite, jarosite or goethite. Fast oxidation of ferrous to ferric is an important step to remove iron by precipitation at low pH values. This study reviews the ferrous oxidation mechanism and reaction rates in chloride media using molecular oxygen. This work contributes to the development of a better understanding of iron precipitation processing steps, which continues to be an important matter in hydrometallurgy. The specific objectives were to investigate (1) the effect of key process variables (acid concentration, copper concentration, and temperature) on the rate and extent of ferrous oxidation by dissolved oxygen and (2) the oxidation mechanism by varying chloride and hydrogen ion concentrations separately. Batch oxidation tests were performed using synthetic chloride solutions containing 45 g/L Fe and 3 g/L Ni at 50 and 80°C, dissolved Cu concentrations (0.3 to 3 g/L) and HCl concentrations (2 to 4.6 M). Regression analysis indicated that the significance of the effect of different variables on the extent of oxidation achieved after five hours decreased in the following order: HCl concentration > Cu concentration > temperature. Increasing the HCl concentration from 4 M to 4.6 M caused the degree of oxidation achieved after two hours to increase from 58.3% to 98.1%. The catalytic effect of dissolved copper on ferrous oxidation was more significant at low acid concentrations. Experimental data suggest that rapid oxidation of ferrous is possible at high HCl concentrations for two main reasons. First, the formation of ferrous chloride complexes allows ferrous oxidation to proceed without the formation of superoxide as an intermediate product (the rate limiting step in dilute acid solutions). Second, the formation of ferric chloride complexes stabilises the oxidation product.

Jan 1, 2016