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By V. Vorontsov

Catalysts Mo-Ni-S were prepared by combining MoS2 and NiS in weight ratios 1:1, 1:2, 1:4 and 2:1, each of which was admixed with 5%wt Ag and 5%wt YSZ to increase three-phase boundary surface area of the electrode. For comparison catalysts comprising Co-Mo-S in weight ratio of 1:1 of CoS to MoS2 admixed with 5%wt Ag and YSZ and pre-sulfided NiMoO4 were made. The catalysts were examined for electrochemical oxidation of hydrogen sulfide in solid oxide fuel cells (SOFC) at 850°C temperature. The catalyst prepared from 1:1 (wt. %) NiS:MoS2 demonstrated highest performance. Current density up to 1,330 mA/cm2 and power density up to 300 mW/cm2 were achieved using pure H25 gas, which are the highest among the reported H2S-powered fuel cells ever published in the literature. Anode materials of different NiS:MoS2 ratios have been characterized by means of X-ray diffraction (XRD), simultaneous TG/DSC analysis and Neutron Activation Analysis (NAA). TG/DSC and NAA results show that addition of NiS and Ag increases fuel cell performance due to improved structure/integrity of the anode. It has also been demonstrated that MoS2 is a suitable anode material in H2S-powered SOFC, with high activity towards H25 oxidation and thermally and chemically stable up to 850°C.

Jan 1, 2005

By F. E. P. PEARSON

Sandstone quarried from an island in Lake Winnipeg is barged 130 km to a processing plant at Selkirk on the Red River. The stone is white, poorly consolidated, and consists of rounded quartz grains of high natural purity. It is an important supplier of silica in Western Canada for glass, fiberglass, foundry and other industrial uses.

Jan 1, 1984

By Harold L. Gibson, David H. Watkinson

"Volcanogenic massive sulphide deposits of the Noranda Camp cur throughout the Noranda Shield Volcano but are concentrated and along the margins of the Noranda Cauldron. The deposits are realized along synvolcanic faults that also accommodated subsince and controlled the location of eruptive centres. Deposits within e 3 000 m thick Mine Sequence formed during a period of active volcanism and subsidence coinciding with the onset of two cauldron subsidence cycles. The Noranda Cauldron was a restricted site of 10malously high heat flow and structural permeability that favoured e development of a high-temperature hydrothermal system. Metals may have been derived from leaching of aquifer rocks by convecting a water or directly from a shallow underlying magma chamber, now presented by the Plavrian Pluton, that was at its highest position !thin the crust during cauldron subsidence. The deposits formed rough a combination of sulphide precipitation from exhaled fluid td replacement at and below the seafloor in a manner analogous to ose on the modern seafloor.RESUMESi les dépôts de sulfures massifs volcano gènes du camp minier de ~uyn-Noranda sont présents dans les différentes parties du volcanluclier de Noranda, ils se trouvent concentres toutefois, en plus ·and nombre, sur le pourtour de la caldeira (cauldron) de Noranda. ~s dépôts sont localises le long des failles synvolcaniques qui ont cilite la subsidence et contrôle la position des centres d’éruption.~dépôts situes dans la séquence des mines (3 000 m d’épaisseur) sont formes durant un épisode d' activité volcanique et de subsiden qui coïncide avec l' amorce de deux cycles d' affaissement de la rldera (cauldron) de Noranda. Celle-ci Jut le site exclusif d’unflux : chaleur anormalement élevé et d’une perméabilité d’origine cucturale qui ont favorise le développement d’un système hydrothermal a haute température. Les métaux proviennent soit directement d’une chambre magmatique situee afaible profondeur, so it d’un lessivage des roches de l’aquifère par l’eau de mer circulant par convection. Cette chambre magmatique, représentée maintenant par le pluton de Flavrian, se trouvait à son niveau le plus élevé dans la croute au moment de l’affaissement de la caldeira (cauldron). Les dépôts se sont constitués par un mecanisme combinant remplacement et précipitation de sulfures à partir des fluides exhalatifs, au niveau ou au-dessous du plancher océanique, de la même manière que se forment de nos jours, les dépôts de sulfures massifs au fond des océans."

Jan 1, 1990

By W. Abdellah

Underground mine developments, such as haulage drifts and cross cuts, play a vital role in providing access to ore extraction areas for mine production. The stability of mine developments is thus of crucial importance during the life of a mine plan. Many Canadian mines use longhole mining methods or one of its variants. These methods require access to the orebody through mine developments such as haulage drifts and cross cuts on multiple levels. This paper examines the stability of mine development access intersections with respect to the planned mining sequence. A case study, the #1 Shear East orebody at Vale?s Garson Mine in Sudbury, Ontario, is presented. A three-dimensional, elastoplastic, finite difference model (FLAC 3D) was created for a development intersection situated 1.5 km below ground surface. The stability, or performance of the intersection, is evaluated in terms of the strength-to-stress ratio. The ratio threshold is set at 1.4 for temporary openings. Unsatisfactory performance is defined as a strength-to-stress ratio less than this threshold value. The performance of the intersection stability is evaluated at various modelled mining stages and the probabilistic method of analysis is then invoked to study the probability of unsatisfactory performance of the intersection. The results are presented and categorized with respect to probability, instability, and mining stage.

Aug 1, 2013

By F. Awotwe-Appiah, P. Koshy, A. Y. Fosu, J. Dankwah, J. R. Dankwah

Ghana currently exports its bauxite raw without any value addition. Gradual depletion of high grade bauxite (with high alumina content) and the emergence of low grade bauxite (with high iron oxide content) calls for novel and inexpensive ways to recover alumina from these low grade ores. Bauxite users have indicated their willingness to pay 10% to 50% higher for a corresponding reduction in impurities by a similar amount. This project therefore investigates the carbothermal upgrading of the Ghana Awaso bauxite using waste polypropylene as reductant in a locally designed gas-fired furnace. Composite pellets of low grade bauxite sample (assaying 45% Al2O3) containing pulverised waste polypropylene were formed, oven dried, placed in fireclay crucible and fired for 30 minutes. The magnetic fraction after reduction was separated by a Low Intensity Magnet and weighed. It was observed that up to 97% of the iron oxides (occurring as hematite and goethite) could be separated into the magnetic fraction as magnetite leaving a nonmagnetic fraction with over 98% Al2O3 as opposed to the 45% Al2O3 in the as-received bauxite sample. This research direction provides yet another simple but effective way for simultaneously upgrading low grade bauxite and recycling waste polypropylene, whilst at the same time decreasing the amount of waste material generated as red mud after the Bayer process.

Jan 1, 2015

By I. Thobadi, C. Pawlik, K. Bisaka, S. Mokoena, M. Erwee

The PyEarth™ process developed at Mintek has been demonstrated successfully at pilot scale. Nine tons of ore containing 2.3 mass % of total rare earth oxides (TREO) from a dormant mineralogically complex iron-rich ore deposit, was subjected to a concentrating smelting step in a 200 kW DC open-arc pilot furnace and the rare earths from the resulting slag were extracted via a hydrometallurgical route. This ore deposit is practically not amenable to extraction by conventional methods. The testwork results proved that the PyEarth™ process was able to optimize the extraction of rare earths while minimizing waste through the removal of iron as a saleable iron alloy. Reduction of iron to the alloy in the smelting step was found flexible, efficient, and controllable, while rare earths were left virtually unreduced in the slag phase. The slag chemistry is selected to optimize both the smelting and leaching performances as well as the alloy composition. Leaching of the resulting slag was found possible and most efficient in hydrochloric acid amongst other lixiviants tested.

Jan 1, 2017

By J. C. Nicholson

The "V" system was first introduced by the West Virginia Coal & Coke Company at their No. 9 mine, Norton. Norton is a small mining village on the B. & 0. railway, about seven miles from the town of Elkins. This year, accompanied by G. D. MacDougall, I visited this mine to obtain first-hand information regarding this modem system and to determine its adaptability to conditions in Nova Scotia. The following is a brief account of my observations. The seam that is being worked is known as the Lower Kittaning, which, at this point, has an average thickness of 7 feet. This includes a band of hard clay varying in thickness from 8 to 14 inches, which occurs about 2 feet from the pavement, also 8 inches of inferior coal at the roof. The latter is not recovered, which leaves to be mined about 5 1/2 feet of clean coal. The roof is slate and shale for the first 30 feet, followed by 40 to 60 feet of sandstone; the total cover is from 80 to 250 feet thick. The seam lies very flat, with a dip of only 2 per cent., and, as the dip is toward the main entrance, it' is in favor of the load, also providing natural drainage for any water the mine makes. As the mine is not gassy, and there is no water to be pumped out, one can understand that mining conditions are practically ideal.

Jan 1, 1924

By Grant S. Diamond

THE BIBLIOGRAPHY on the use of static electricity in mineral beneficiation consists largely of patents. Some references are found in mineral textbooks, but very little data on flow-sheets of commercial installations are known to the writer. As a matter of fact there have been relatively few successful commercial applications of importance. Johnson prepared and published a Table showing the polarity and static field intensity requirements of many minerals. There have been reports of successful beneficiation of rutile, zir-con, coal, potassium chloride, and phosphate rock. Otherwise, the field of success has been very limited. This may be due to three reasons: first, the mining industry has been averse to dry processes, be-cause of dust nuisances in dry crushing; second, the electrostatic processes used in the past apparently developed no substantial economic advantages; and third, because flotation or other . methods have proven successful on many minerals, the industry has not felt the need for a radically different process. In the feldspar industry there was ?an attempt at electrostatic beneficiation about twenty years ago which was based on the use of fluoride fuming of the pegmatite head feed, in order to make the mineral reactive in a static field. This process was originally said to be successful, but was discontinued because of corrosion damage to machinery. Another effort by use of a chemical additive such as an or-ganic hydroxyl compound has also been attempted. Neither of these processes is known to be in use today.

Jan 1, 1957

By A. J. Oliver, C. E. O’Neil, I. J. Itzkovitch, V. A. Ettel

A new solvent extraction process for the separation of cobalt, copper and zinc from nickel sulphate process streams has been developed. It involves selective extraction of these elements with a quaternary ammonium thiocyanate dissolved in an aromatic diluent. The chemical principles of this process have been investigated and are described, together with background physico-chemical data relating to the use of this solvent. Long-term testing in a continuous "mini-plant" circuit gave high-purity nickel and cobalt products (Ni/Co —200011 and Co/Ni ~1000/1 respectively).

Jan 1, 1976

By Malcolm Black

Introduction Before beginning to write this paper, I decided that I should first find suitable definitions of the words Sample and Sampling. The dictionary gives: "Sample.-A portion indicative of the whole"; and according to Baillie (1), sampling is "That process whereby a representative and comparatively small portion of material is selected from a large bulk, and preserved under such conditions as shall prevent contamination or avoidable alteration, with a view to the formation of valid conclusions regarding the suitability of the bulk for specified purposes". These comprehensive definitions are alike in substance, and indicate that unless a truly representative portion is taken, it is not a sample. Ore 'as mined' generally varies a good deal in composition, and, in crushing, segregation takes place. Some of the minerals present, due to differences in hardness and friability, break into smaller pieces than others, and, on reaching the bin, the coarse particles roll away, leaving the fines behind. The result of this segregation is generally quite noticeable on the conveyor feeding the mill, especially when the bin is nearly empty and the crushing plant shut down. Should the sampling period synchronize with either the coarse or the fines, the sample obviously would not be representative. I agree that this is rather far fetched, but I maintain that such a condition is possible. Assuming that a representative sample may be procured from the feed conveyor, the method of cutting it down for assay has considerable influence in maintaining the original condition of the sample. The finer the material is ground after each cut, the more uniform the sample will remain. To illustrate this point, let us take a quantity of fine sand and add, say, three grains of rice to represent metallic particles. We may mix this sample by any of the known methods, then cut it into four equal portions. It is obvious that at least one of the portions will be without a rice grain. But let us grind the three grains of rice into flour and proceed as before. Now there will be a much greater chance of including some of the rice in each portion.

Jan 1, 1935

By W. G. Scott

IT IS APPROPRIATE that your Institute should have chosen, for its 1956 Annual General Meeting, the Capital City of a province which is making such rapid advances in mining. The railway industry is proud to be playing an active role in this development, expenditures on equipment and railway construction in the Province of Quebec alone in recent years being in ?excess of a quarter of a billion dollars. In looking up some background material for this address I ran across a definition of a mine by Mark Twain, the great American humorist, which I thought might amuse you. He said that a mine was "a hole in the ground owned by a liar". I am sure that if he were alive to witness the enormous value attached to Canada's mineral resources today he would quickly change his definition. Canada's postwar record of mining development has been staggering in its variety and enormity. Historically, only the ?construction of our transcontinental rail ways outranks the largest of three of these development projects - the aluminum undertaking at Kitimat; the Quebec-Labrador iron ore deposits ; and the petroleum and natural gas developments in Wes tern Canada.

Jan 1, 1956

Lonmin RoM ball mills are treating two types of feed ore produced by conventional mining and mechanised mining methods. It was reported that reduction in mill throughput was observed when treating the mechanised mining ore. Detailed grinding surveys were conducted for troubleshooting. Ore samples were collected for breakage characterisation using a JKRBT based on different particle density components. XRD analysis was conducted to investigate the association of minerals with density components. The plant surveys and the breakage characterisation tests all suggested that the two mining methods did not significantly affect either the ore breakage properties or the RoM mill performance. Instead, the mill discharge open area exerted a remarkable influence on mill throughput. The RoM ball mill operated at Lonmin K4 Concentrator has been proven to be a versatile mill that performed stably with variations in feed size distribution and feed ore changes by different mining techniques. The reasons are elucidated by the multi-component breakage characterisation and the plant surveys data.

Jan 1, 2012

Arguably the SMC Test® has become the most popular laboratory hardness test in the world with over 17,000 tests having been completed to date, covering over 650 different ore bodies. It is now routinely used in design, optimisation and orebody profiling projects. The test is unique in that from relatively small amounts of drill core it simultaneously provides parameters that are used in simulation modelling of AG/SAG and crushing circuits as well as work indices that are used in power-based equations for predicting the specific energies of AG/SAG/Crushing and HPGR circuits. The very large data base that has been accumulated has provided the opportunity to study the differences in variability from deposit to deposit. This paper describes and discusses the trends that have become apparent from the study of this data base. Recommendations for appropriate selection of sample numbers are also made which are based on these trends.

Jan 1, 2012

By D. W. R. Haysom

"I AM CONSCIOUS of the honour you pay me by having invited me to address you on the subject of the Rehabilitation of the Sydney Steel Corporation. The true architect of the revival and rehabilitation is Robert Burns Cameron. Because of the numerous myths which have grown up around what seems to be the miracle of the revival of the Sydney Steelworks, I propose to go back to the time when they came under the full control of the Province, on the 1st of January, 1968. Late in 1967, the decision was taken by Premier G. I. Smith to keep the Steel Plant running for at least another year, in an endeavour to see whether the enormous losses being sustained by Dosco could be reduced to a level which would permit their continuing operation. When that decision was taken, Dosco was to continue management until the 30th of April, 1968, and in the intervening period, the Provincial Government would seek management of the right calibre to ensure that an objective view of the Steelworks operations could be secured. By a combination of circumstances which can only be described as most felicitous, the man selected for the task was R. B. Cameron. He very quickly determined that to permit Dosco to continue management of the Steelworks until April 30 could only result in heavy losses to the Province and a consequent deterioration in the already critical financial position and a declining morale of the worke"

Jan 1, 1972

By A. F. Banfield

"IntroductionELEMENTAL sulphur occurs in three types of deposits: in salt domes in the Gulf Coast region of the United States and Mexico, from which over 90 per cent of world native-sulphur production is obtained; in sedimentary deposits such as those in Sicily, which are thought by some authorities to contain the largest world reserves of elemental sulphur; and as surface deposits, associated now or in the past with some phase of vulcanism, the type which bas the greatest world-wide distribution.Deposits of the volcanic type are the subject of this paper.From antiquity until the successful development of the sulphur-bearing salt domes at the beginning of this century, important sulphur production for local needs was obtained from volcanic deposits in many parts of the world. Due to technical and economic factors, however, producers could not compete in price with sulphur from salt domes. •The result has been that, except in Japan and Chile, little sulphur was produced from volcanic deposits from about 1910 until the start of the Korean war in 1950. Shortly after the outbreak of the Korean war, an acute world sulphur shortage developed and prices skyrocketed in many countries up to several hundred dollars a ton. Interest in volcanic deposits was renewed and exploitation of many was undertaken. Few of these operations have been successful, mostly due to inability of management to solve technical problems.While important volcanic deposits of elemental sulphur have not been reported ( 1) in Canada, and it is doubtful that any will be found, data presented in this paper may be of interest to students of ore genesis.This paper is based on field examination of numerous deposits of the volcanic type in North and South America."

Jan 1, 1954

By S. Banisi, A. Haji-Zadeh, A. R. Hasankhoei, M. Maleki-Moghaddam

At the concentration plant of the Gol-E-Gohar Iron Ore Company (Iran) three 9m × 2.05m AG (Autogenous) mills (fixed speed) are used in parallel in a dry operation. The test works conducted in a scale down mill with a diameter of 1m indicated that conventionally used "deflector" type liners did not provide efficient environment for grinding. In this research, to improve the grinding efficiency, a new design using low profile end liners incorporating radial ribs of proper height was investigated. In order to determine an appropriate liner design at different operating conditions, a 100cm×10.8cm model mill was used for experimentation. The special design of model mill made it possible to increase the radial ribs height in steps of 6mm up to 18.5mm. The transparent end of the mill enabled accurate trajectory determination by image analysis. The results indicated that the new lower height profile deflectors and 15.5mm-height (14.5cm in industrial scale) radial ribs improved the mill performance while avoiding excessive pressure drop across the mill and wear on the liner. The image analysis showed that the use of new liners increased the distribution of coarse particles across the mill cross section from 28% to 35%. A new liner design was proposed by decreasing the number of liners in each slice from 5 to 4 pieces. The thickness of the inner head liners reduced from 45cm to 30cm and the outer deflector liners replaced by radial ribs. The distance between the feed and discharge inner head liners increased from the original 115cm to 145cm which increased the effective length of the mill by 26%. The new design reduced the weight and volume of end liners by 9% and 23%, respectively. It was predicted that the new liners design increases the mill throughput by 10% and reduces the metal consumption by 20%.

Jan 1, 2016

By Donald L. Mordell

Introduction A very large part of the world's fuel resources are in solid form, as various grades of ?coal, but an increasing proportion of fuel demands on this Continent and else-where are having to be met by liquid fuels. Convenience and, in many cases, cost weigh heavily in favour of the liquid: fuels, and there are many fuel burning applications where the use of coal would be impractical, such as for automotive or air transport. By extrapolating the present trends one might conclude that, in future years in Canada and the United States, coal will be used only in a few power stations close to coal fields. If such a state of affairs should arise, it will obviously prove embarrassing to those accustomed to make their livelihood from the winning and marketing of coal, but it is perhaps not so obvious that it must also prove an embarrassment to the nation. The major reasons for this are two in number. Firstly, if present coal production is to be replaced by oil production, a large capital expenditure is necessary, which must inevitably be paid by the consumer; and secondly, in times of emergency, large amounts of oil fuels are required for military purposes which cannot be achieved with solid fuels. It is obviously unwise, therefore, to discontinue the use of coal for those non-military jobs that it can do. If we examine the major fuel markets we find that there are three: Domestic heating Steam generation Transport by air, sea, and land For domestic heating, the extreme convenience of oil, in spite of its greater cost, has captured much of the coal market.

Jan 1, 1952

By J. Chretien

The ability to continuously monitor the air quality within a mine has become instrumental in becoming a low cost producer. The many considerations involved in monitoring air quality include sensor type, hardware placement, as well as data storage medium. BESTECH has had the opportunity to gain insight into these air quality monitoring considerations through deployments of NRG1-ECOTM, a minewide energy consumption optimization system. This paper explores the particular challenges overcome through these installations, and provides a set of guidelines for mines that want to maximize data capture while minimizing costs. It provides a view of additional benefits of air quality monitoring, such as ventilation control, reporting and trending.

Aug 1, 2013

By I. Farr, H. Wittens

"In 1989 and 1990 abnormally high levels of arsenic in ore from the Thompson Open Pit Mine threatened Manitoba Division's electro-nickel production. The paper will discuss our development of a flotation process to separate pentlandite and gersdorffite (the prime nickel and arsenic bearing minerals).The presentation will focus on the development of the process from conception, through lab and plant test work, to plant optimization and full scale production. The paper will conclude with the benefits and cost of the completed project.INTRODUCTIONRejection of arsenic from nickel sulphide ores was not a primary concern in the Manitoba Division until 1989. At that time increased production in the Thompson Open Pit mine, which contains high arsenic ore zones, resulted in excess amounts of arsenic in the Thompson Refinery affecting electro-nickel quality. This problem was resolved through extensive efforts by Mill personnel. The purpose of this paper is to familiarize the reader with- the Thompson Mill.- the mineralogy of the Thompson orebody.- the evolution of Ni/As separation in the Mill.- the metallurgical impacts of the separation on the Mill.- the importance of the separation to the Manitoba Division."

Jan 1, 1991

By T. M. Waterland

A GREAT deal of work has been done at Britannia during the past three years in improving and standardizing rounds for development headings, and the results obtained have been very gratifying. The round which has recently been adopted as a standard for all drifts and cross-cuts has, in some instances, doubled the average length of break formerly obtained. It has also increased the footage of advance per labour shift and reduced explosives' consumption. At the present time, with a shortage of skilled labour, more control is necessar7 in directing the drilling of rounds. The use of a standard round has been o great assistance to the foremen and shiftbosses. NATURE OF GROUND Most of the ground encountered consists of a moderately silicified chlorite schist, known locally as G.M.S (green-mottled schist). It cannot be termed hard ground, because a three and one-half inch Leyner will drill at an average rate of twelve inches per minute. Due to the abrasive nature of the ground, the gauge of the steel wears rapidly and in most cases one set of steel is needed for each hole. The ground is not 'free breaking and holes must be spaced correctly to obtain a maximum break. DEVELOPMENT OF STANDARD ROUND FOR THREE-SHIFT OPERATION Late in 1940, a development programme was started involving 7,000 feet of drifting, 6 ft. By 7 1/2 ft. In cross-section, in two headings. Plans were drawn up to advance the headings on three shifts. Equipment used in the headings was as follows: D.A.35 Leyner?machines, Eimco Model 12B mucking machines, nine one-ton end-dump cars, one Mancha Little Trammer on the longest heading, 20-pound rail, 4-in. 15 compressed-air line, 15-in. Fan pipe connected to 5 h. P. Coppus fan. Diamond-drill cross-cuts, 16 feet in length, were cut every 250 feet. Switches were installed at these cross-cuts and they served as passing points for the cars. One siding seventy feet in length was cut in each heading at approximately the half-way point. The cycle of operations planned was to muck out, drill, and blast each shift. Previous performance in this type of ground indicated that a daily advance of 12 feet to 14 feet might be made. However, if a better type of round could be developed, an increased daily advance would be possible. A study of the time available for each operation in a net working shift of six and one-half hours indicated that the maximum depth of round that could be mucked, drilled, and blasted each shift would be six and one-half feet. When this maximum depth was decided upon, the next problem was to develop a satisfactory round. Due to ventilation difficulties and to the short net working shift, the whole round had to be blasted at one time. In other words, no blasting of the cut-holes could be done.

Jan 1, 1942