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By J. E. Misiewicz, A Rozendaal

Paper presented at Geofluids '93, held in Torquay, UK, 4-7 May 1993. The tin field consists of a fragment of Lower Proterozoic volcanosedimentary rocks surrounded by granitoids. Almost all the significant deposits are hosted by arkoses and are classified as replacement and space-filling types, with particular styles of mineralisation dominating at different mines. Petrological and geochemical investigation of borehole cores from four centres indicated the presence of a stratified zone 500-600 m thick and continuous over at least 20 km along strike, consisting of pervasively altered clastic arenitic sediments. The alteration is zoned into a grey-green sodic albitised footwall, an 80 m thick sericitised-tourmalinised sulphidic tin zone and a red haematitic potassic hanging-wall. The zoning and the localisation of three cassiterite phases are consistent with the tectonic history and with multiple pulses of stanniferous hydrothermal fluids derived from late differentiates of the granites over a prolonged period. Areas of high fracture density acted as conduits for the fluids, whose initially rapid ascent was retarded by decreasing pressure contrast, limited development of fracturing and/or impermeable shaly arkose to cause lateral spreading and pervasive alteration over a broad, stratified front. Lateral overlapping of local fronts at the various centres suggests a continuous zone, while the many petrological and geochemical similarities point to a shared fluid composition

Aug 1, 1995

By W. P. C. Duyvesteyn, B. J. Sabacky

Reprinted with revisions from Extractive metallurgy of copper, nickel and cobalt, volume I: Fundamental aspects. ed. Reddy R.G., Weizenbach R.N. Warrendale, Pennsylvania: The Minerals, Metals and Materials Society, 1993. Development work on the Escondida process, concluding with the successful operation of an integrated leach-SX-EW pilot plant and a pilot flotation plant for the upgrading of leach residues, demonstrated that all major process objectives could be achieved. Extraction of 40% of copper in concentrates containing monovalent copper was achieved with essentially no oxidation of sulphide sulphur. The Cu contents of leach residues from four different types of concentrate were successfully upgraded to the original feed grades, giving a product that has potential as a high-quality concentrate for the smelter market. A compact solvent extraction section effectively recovered the ammonia lixiviant for recycling to leaching and selectively transferred Cu into a conventional acid sulphate electrowinning system. High-quality "six-nines" copper cathode was produced on commercial-scale stainless steel blanks, demonstrating that the process will be able to compete effectively in the premium cathode market

Dec 1, 1995

By L. J. Barnes

The process for bio-remediation of sulphidic slag (BROSS) operates at 45 degrees C in a neutral (pH 7), aerobic aqueous environment in which sulphide in the slag is converted to sulphate. A two-stage version has been developed that involves quantitative chemical pre-oxidation of total sulphide to thiosulphate, followed by complete biooxidation of thiosulphate to sulphate. Ferric hydroxide, also produced, acts as a flocculant in the bioreactor effluent, concentrating heavy metal precipitates in the thickener as a sludge which can be returned to the smelter. The process has a high sulphate production rate and low acid and nutrient consumptions. Microorganism growth is the rate-limiting stage, requiring a minimum liquid residence time in the bioreactor of about 7 h. Although large quantities of oxygen are needed, sufficient gas mass transfer can be attained in an air-lift reactor. Products are an aqueous stream containing sodium sulphate with only trace levels of toxic heavy metals and a benign, toxic metal-containing sludge

Jun 18, 1905

By P. H. Morris

The profile of a delta formed by fine-grained mineral processing wastes, disposed of as aqueous slurries by subaerial deposition from a pipeline, has a significant bearing on the volume that is available for waste and water storage in a given containment structure. Earlier field data and laboratory experiments suggested that mine waste delta profiles could be predicted with high levels of accuracy using data from small-scale laboratory deposition tests. The relationships between the profiles of full-size and laboratory-model deltas were analysed using the principles of kinematic similarity and a recent theory of delta formation based on engineering hydraulics. Measured profiles of full-size and model coal-mine tailings deltas are compared and the prediction of full-size profiles discussed. It is shown that the data-derived laboratory-model deltas are insufficient to allow accurate prediction of full-size delta profiles. Initial slope data or other, equivalent data for the full-size delta are also required

Apr 1, 1996

By P. H. Morris

The exponential delta profile equation matches the profiles of a wide range of coal and metalliferous subaerial tailings deltas well, but the original model implies unrepresentatively low solids concentrations. A revision, based on analysis of the governing equations of mobile bed flows with high concentration values, has shown that for exponential delta profiles to form there must be quasi-steady, slowly varying flow and slow deposition as well as tailings with a log-uniform sorting-parameter distribution. Deposition on tailings deltas is slow and the flow in many natural streams and, by analogy, tailings deltas is quasi-steady and slowly varying; the assumption of such flow is justified by the strong congruence of the revised model and the available data. The predictions of the theoretical model are essentially unchanged but concentration and flow Froude number are now not explicitly limited

Jun 19, 1905

Two concentrates from Palabora, in South Africa, containing 0.056-0.068% undesirable Cu and 0.8 or 2.2% Ti, were chlorinated with air:chlorine ratios of 10:1, 15:1 and 20:1 at temperatures between 1 200 and 1 329 K. The resulting volatile chlorides were condensed and the solutions analysed for Cu, Fe and Ti. Recovery of Cu was less than 25% at low temperatures and short reaction times, but at 1 258 K almost all Cu was removed from the magnetite at all ratios of chlorine to air. At higher temperatures, the increased carrying over of iron as FeCl3 could be minimised by decreasing the partial pressure of chlorine. No titanium was detected in the volatile products and the percentage of Cu recovered was independent of Ti concentration in the concentrates, though as a function of Cl2 vol%, more Cu was recovered at 1 200 K from the low-Ti than from the high-Ti concentrate. In a fluidised-bed reactor, Cu recovery was 58-90% and iron carry-over less than 10 ppm

Jun 21, 1905

By P. Mousset-Jones, G. Danko

Variations of the temperature and steam/moisture content of the air with distance and time are modelled for a single airway. The input for the simulation is an air temperature that varies with time, together with the moisture/steam content that results, for example, from a fire with a given distribution of heat and of fume concentrations at the beginning of the airway. The transport of heat and moisture to the surface of the wallrock is assumed to be simultaneous. Such multiphase convection may result in evaporation from the moist wall close to the fire and recondensation downstream. The modelling of this non-linear effect is a unique feature of the new simulation. A new analytical solution is used to calculate the conduction of transient heat within the rock mantle, which, in the event of a fire, is typically a short-term process. This allows for an arbitrary variation of surface temperature with time - unlike that permitted by the age function solution, which is limited to stepped temperature changes. An iterative numerical scheme that has recently been developed to simulate mine climate is used to calculate the coupled transient heat conduction and multiphase surface heat transport in successive length increments along the airway. To demonstrate the simulation procedure a numerical example is presented in which a fire with a given distribution of heat and fume concentrations with time is located at the beginning of an airway

May 1, 1991

By G. J. Hearn

between particles in the classifying region is then

Apr 1, 1995

By S. Kelebek

DETA exhibits a highly selective depressant action on pyrrhotite without adversely affecting the collectorless flotability of pentlandite and chalcopyrite in nickel-copper ores of the Sudbury region. A simplified Eh-pH diagram has been constructed to illustrate the extended stability of elemental sulphur and to explain the collectorless flotation of pentlandite and chalcopyrite. Cu and Ni ions, which are known to exist on the surface of pyrrhotite, promote the flotation of this mineral whether a collector is present or not. Thermodynamic calculations indicate that the action of DETA involves the sequestration of Cu and Ni ions from surfaces under a wide range of redox conditions; analysis of flotation test filtrate indicates as much as a 20-fold increase in the concentration of Ni and Cu ions. It appears that DETA may enhance the self-hydrophobicity of chalcopyrite and pentlandite by exposing more of the sulphur-rich surface sites for bubble contact in flotation. There are various possible explanations for its depression of pyrrhotite

Jun 18, 1905

By G. B. Harris, A. R. Laplante

Fine tungsten was used to mimic gold and fine and coarse silica and magnetite to mimic gangue. The optimum flow rate of fluidisation water varied from 1.7 l/min for fine silica to 5.6 l/min for coarse magnetite. Overloading at optimum flow rate was then investigated. With fine silica gangue no overload occurred under any of the conditions studied, and there was very little overload with fine magnetite. Coarse silica caused appreciable overload, but only after a significant bed of tungsten had been formed; with fine magnetite gangue the onset of overloading occurred earlier. Finally, with coarse magnetite severe overloading occurred almost immediately. Overloading was modelled using a first-order kinetic rate constant for erosion of the concentrate bed and a critical mass of constant above which it takes place. The results clearly demonstrate the importance of removing oversize to maximise recovery, particularly with a high-density gangue

Jun 18, 1905

By R. O. Suominen, P. A. Taskinen, K. R. Lilius, A. T. Jokilaakso

Chalcopyrite concentrate was flash-oxidised in a laminar-flow furnace in oxygen-nitrogen atmospheres that ranged in composition from N2 to N2 + 50 vol% O2. Gas pre-heating temperatures were 500-1100 degrees C and four particle-size fractions were studied: 28-38, 38-44, 44-62 and 62-74 micrometres. The effect of the residence time of the particles on sulphur removal was studied in the range 0.1-0.35 s. Scanning-electron microscopy combined with energy-dispersive analysis and back-scattered electron analysis was used to determine the morphology and mineralogy of the reacted particles. Total desulphurisation was achieved under the most oxidising conditions. Particles were observed to undergo fragmentation during oxidation, the violence of this depending on the iron and sulphur contents and the original particle-size fraction. The melting and/or reaction stages of the particles under different conditions were studied in powder samples. Polished sections were examined to follow the development of porosity and the mineralogy of the particles. A model for the fragmentation process is described

Jul 1, 1991

By E. Niehuis, J. Y. Kim, H. G. Cramer, S. L. Chryssoulis, K. G. Stowe, C. Bendel

TOF-SIMS was used to detect, identify from parent molecular ions and determine the relative concentrations of collectors sorbed on the surface of mineral particles in concentrate and tailings samples from three Canadian concentrators. In the Kidd Creek Zn circuit, sphalerite lost to tailings carried on average a quarter of the amount of isobutyl xanthate present on that recovered to Zn concentrate; amyl xanthate, which is not reported as added to the circuit, was also detected on floated sphalerite and pyrite. At Brunswick, sphalerite particles lost to the scavenger tailings had ten times less amyl xanthate and isobutyl xanthate than those recovered to the Zn final concentrate, while both xanthates were detected on sphalerite floated to the Cu-Pb cleaner circuit. At Matagami, significantly more isopropyl xanthate and isopropyl dithiophosphate were detected on sphalerite recovered to the final Zn concentrate than on that lost to the Zn rougher tailings

Dec 1, 1995

By B. S. Terry, C. L. Harris

After measuring the kinetics of Ni reduction from a SiO2-saturated fayalite slag into a Cu-based metallic phase on a laboratory scale, a general model was developed that is capable of simulating mass transfer to and from metal-slag, slag-gas and metal-gas interfaces for multiple species. The model was used to simulate the reactions that occur when Cu and Ni are reduced from fayalite-based slags into a Cu-based metallic phase. Good agreement was achieved between model predictions and experimental data

Aug 1, 1995

By P. H. Carr, G. G. Marino, K. A. Patel

Extensions to a correctional institution at Wabash Valley, Indiana, required development over abandoned coal-mine workings, at 90 m depth, where subsidence was possible at surface. Backfilling of the flooded mine in critical areas was determined to be the most cost-effective method of limiting the risk of damage to the buildings. Containment grout was first placed in selected entries and cross-cuts of each mine area; the remaining volume was then filled with a readily flowing infill grout. Where a high proportion of an area was taken up by rubble, calcium lignosulphonate was used as a retarder and plasticiser to increase penetration. Grout movement was monitored from adjacent boreholes with an electrical resistivity probe during grouting, while after the work was finished core samples were obtained from verification holes drilled in the backfilled areas

Jun 19, 1905

A production drill rig at a site in Sweden was equipped with a monitoring system to estimate production statistics. Drill running times, drill hole depths, penetration rate, rotation speed, thrust, air percussive pressure and torque pressure were recorded for every 10 mm of hole length for a period of 5 months. Operational activities (rock penetration, tube handling, moving and set-up time) accounted for almost 62% of the time consumed, the remaining 38% being different types of stoppage. Drilling itself, as opposed to handling, took less than 24% of the total time. The results give an indication of how the overall drilling capacity can be increased and which activity should be emphasised. The impacts of automation, new developments and reorganisation on production can also be predicted. Average production was found to be around 100 m/day, but varied between 50 and 160 m/d. The company's specification for the drill rig, before purchase, was that an average production rate of 130 m/d be attained over two consecutive months of drilling - a rate which monitoring shows will not be achieved

Jun 19, 1905

By A. R. Naderian

Laboratory strength and deformation testing of freshly blasted sandstone and claystone overburden from Jeebropilly colliery in Queensland and in-situ plate-bearing tests on four backfills of different ages showed that the bearing capacity of backfill is a function mainly of compaction, not of age. The modulus or stiffness of the backfill is significantly increased by previous loading, in some cases up to threefold. Backfill material experiences some compaction through the passage of mining vehicles, likely to provide a bearing capacity that will support normal construction activities; the limited testing performed suggested that completed backfills are capable of supporting loads of up to 200 kN/m2 while sustaining displacements acceptable for a wide range of residential and industrial uses, but may be susceptible to collapse settlements due to saturation in the long term

Jun 19, 1905

By D. M. Evans, D. L. Buchanan

Paper presented at the IAGOD international symposium on mineralisation related to mafic and ultramafic rocks, held in Orleans, France, 1-3 September 1993. The Zinca area was chosen as a suitable location for an investigation of the weathering and secondary dispersion of platinum group metals from the Zone. It was concluded that platinum is immobile while within weathered rock, its mineral phases tending to alter from primary sulphides and tellurides to secondary Pt-Fe alloys. Palladium is variably mobile in weathered rock. In stream sediments Pt occurs mainly as small, dense, discrete particles, giving rise to a nugget effect, whereas Pd probably occurs as much finer particles or chemically adsorbed on to a suitable substrate. Pt shows a rapid decrease in sediments downstream from mineralisation, whereas Pd has a much slower downstream decay

Apr 1, 1994

By C. A. Jeffrey

The Dirtlow Rake vein deposit, which is up to 12 m thick, contains a range of paragenetically linked replacement mineralisation styles typical of many Mississippi Valley-type deposit environments. The main ore zone lies within the solution collapse breccia domes, the more southerly of which has recently been well exposed, allowing its relationship to the associated mineral-hosting structures to be studied. The domes were largely formed during early silicification, propagated by dissolution collapse and infilled by subsequent fluorite-barite mineralisation. The location of pipes and pervasive replacement was also controlled by early silicification. Structurally controlled bow tie shears were formed as a result of fluid access at fracture-bedding plane intersections. The nature and distribution of the mineralisation styles indicate that the degree of fluid access, residence time of solutions in contact with the wallrock and susceptibility of the limestone to silicification each played a major role in dictating mineralisation

Jun 19, 1905

By N. Krauland, A. Nystrom, M. Board, S. Sandstrom

Several deep Swedish cut-and-fill mines experience severe ground control problems, including roof collapse and wall sloughing, as a result of variable rock quality and high in situ stresses. A project to examine the problem included two main areas. The first was prediction of mining conditions at depth and the adaptation of cut-and-fill mining to such conditions; the second was the assessment and improvement of support methods at present and future depths. Simple, elastic, mine-scale numerical models were used to optimise stope sequencing and more detailed, stope-scale models to simulate the failure processes around a stope and the interaction of rock mass and support. Kristineberg was chosen for testing and calibration of the predictive methods because of its long history of severe ground conditions and the large base of observational and monitoring data available for comparison. Horizontal cut and fill was found technically suitable to depths beyond 1 000 m and economically viable if ore value covers support costs. Stability can be achieved with the present support technology down to 1 000 m but the 7-strand 15.2 mm cables have poor deformation properties (5% failure strain) compared with rebar rock bolts (17%). Reducing the intervals between levels from 100 m to 50 m will cut support costs and improve production reliability and capacity. Simulation of sill-pillar mining indicated that conditions would be most severe when pillar height was reduced to 15-20 m; mining of a sill pillar has been carried out successfully to the last 3 m, whose extraction is planned for the near future

Dec 1, 1995

By V. Krupa, E. Lazarova

A method is proposed for the continuous calulation of a rock mass in real time while tunnelling with a TBM. Rock properties are investigated through models of the fracture stress under the disc cutters, the quasi-shear stress between the disc cutters and the specific energy of cutting under the disc cutters. Comparison of theoretical and monitored data of cutting specific energy can be used to determine theoretically the prevailing shape and size of the bulk debris. The shape and size of the chips from a given rock vary with the boring parameters. Introducing shape and volume corrections into the models of the evaluated stresses suppresses the influence of the boring regime and allows the rock properties to become dominant

Dec 1, 1996