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By F. Y. Kang

Graphite with layers structure is easily to form graphite intercalation compounds (GICs) by means of intercalation reactions due to the weak cohesion force among carbon layers, van der Waal?s interactions. By controlling the oxidation-intercalation, high quality exfoliated graphite with low residual sulfur content and MClx-GICs (M=Fe, Co, Ni, Cu, Zn) powder for electromagnetic wave absorbing and shielding materials have been invented. The expansion volume of expandable graphite can be larger than 160 mL/g while the residual sulfur content is less than 800 ppm. The MClx-GICs powder can shield infrared ray and laser completely up to 15 min. We have also in-vented exfoliated graphite for heavy oil adsorption and mild-expansion exfoliated graphite for anode materials in lithium ion battery by controlling the intercalation/de-intercalation. The exfoliated graphite can adsorb heavy oil up to 80 g/g, it also exhibits better performance than commercial active carbon in sewage treatment. The mild-expansion exfoliated graphite as anode material shows high capacity of 370 mAh/g and good cycle performance.

Jan 1, 2014

By V. Sheikhzadeh, M. Saghaeian, R. Hejazi, A. Abazarpoor

Green pellet strength including drop number and green compression is highly depended on particles size and shape. The used grinding method, ball mill or high pressure grinding roll (HPGR), directly vary the particle size and shape. Considering mode of pellet crack, green pellet is composed of particle-binder-moisture system. Different type of forces existed in such a system to create a stable green pellet: solid particle interaction, magnetic, binding and cohesive forces in the interface of particle-moisture. The pellet failure can occur at solid-liquid interface and/or through liquid phase. Pellet crack occurs when crack passed through entirely the plane failure. In this research, the effect of particle size and shape of pellet feed on green pellet strength has been investigated. It was deduced that green pellet strength highly improved by increase of specific surface area. The drop number and green compression strength of pellets prepared by HPGR was higher than ball mill. It was found that the main reason responsible for this difference was the particle shape. Capillary force is responsible for part of pellet force and improves by decrease of particle size. Also more elongated shape of HPGR particles resulted in higher capillary force due to thinner interface layer between particles. The less circular shape of particles lead to improvement of capillary force as can be occurred for HPGR particles. The rougher shape of HPGR particles resulted in higher wettability of particles and better diffusion of water among particles. In fact the rougher particles means lower connection angle. Aspect ratio of particles was of great importance of crack growth because the required energy of pellet failure increases directly. The required energy for pellet failure increases by increment of particle aspect ratio. The relationship among crack failure force, roughness and aspect ratio has been modeled considering 3 shape descriptors.

Jan 1, 2018

By D. X. Chen

Comprehensive utilization of the copper associated with the complex lead and zinc sulphide ore is a recognized and difficult technical issue in ore dressing field. Qi Baoshan lead-zinc mine is a typical complex copper-lead-zinc polymetallic ore deposit and difficult to process. The application of the. traditional process is not able to make the substantive progress. According to its mineralogical characteristics, the association of copper minerals with lead minerals is very close, and their particle sizes are very fine, and the copper and lead minerals are partially oxidized. Based on the laboratory tests and comparison between different process flowsheets, preferential flotation of copper minerals, being suitable for this ore, was chosen to recover copper. The separation of copper from lead applies the following technology: regrinding middlings with cyclones to classify, which improves copper lead mineral liberation, and increases copper and lead recovery; using new high-efficient collector with good selectivity, which is able to float copper minerals; and non-toxic combined depressant which depresses lead minerals. The above technical innovation, optimizing the process flowsheet, overcoming the complex traditional process flow with high production cost, obtained good technical and economic indicator. The difficult technical problem of copper lead separation was solved smoothly. After successful performance of the bench-scale experiment, commercial-scale test was carried out. In industrial trial, a copper concentrate containing Cu18.60 %, Pb7.40 % and Zn2.50 % was obtained with copper recovery of 58.49%, lead concentrate quality improved largely. The process opened up an unique path for the comprehensive recovery of Cu from similar lead and zinc non-ferrous metals mineral to comprehensively recover copper.

Jan 1, 2014

Large quantities of electrical and electronic equipments are discarded at the end-of-life (EOL) in different industries and house hold applications. Their disposal is creating a challenging environmental problem due to the presence of hazardous metals and non-metallic materials such as epoxy resins and plastics including brominated flame retardants etc particularly in printed circuit boards (PCBs). The recovery valuable metals and separation of hazardous materials from discarded PCBs will not only conserve the resources but also mitigate the environmental pollution. From a recycling point of view for a sustainable society, the studies have been carried out for the recovery of metal values from EOL-PCBs of DVD video players (DVD-PCBs) and vacuum cleaners (VC-PCBs) using physical beneficiation techniques. The concentration of the metals was found to be 43 wt.% and 30 wt.% in DVD-PCBs and VC-PCBs, respectively. Both the PCBs samples were ground in a hammer mill after cutting and their size analysis was carried out. The liberation of the metallic and non-metallic fractions was investigated under the microscope for different size fractions. Subsequently, froth flotation and pneumatic air separation studied were carried out to enrich the metallic constituents. The studies showed the enrichment of metals in coarser particles (-1000 +150 µm) and non-metals in the finer particles -150 µm following mechanical recycling process. A grade of 90 % with 75% recovery was achieved by froth flotation, but lower grade and recovery of 75% and 65% respectively were obtained by pneumatic separation with -1500 µm powders for DVD-PCBs. A grade of 86% metal was obtained by froth flotation with 76% recovery in the case of VC-PCBs. The lower grade of 65% with almost same recovery was achieved during pneumatic separation studies due to lower concentration of metals in VC-PCBs. The studies also showed that the froth flotation is an efficient process for enrichment of metals from both the samples. The process is environmental friendly as no chemicals are employed during entire processing. The higher recovery and grade of metal is expected to be obtained on a large scale beneficiation process.

Sep 1, 2012

The ultimate goal of a mineral processing plant is to recover as much of the target mineral(s) as possible from the ore being treated to achieve the best economics. Selection of the mineral processing techniques is the most important step in achieving this goal. However, due to the complexity of the ore, the recoveries of valuable minerals may be not satisfactory even when the mineral processing technique(s) are well chosen. In other words, minerals of interest can be lost to the tailings for mineralogical reasons. For example, gold is mainly extracted from the ore by gravity, flotation, cyanidation, or a combination of these processes, and high recovery (>90%) can be achieved when gold occurs as coarse grains. However, when a refractory ore is being processed, gold extraction will be challenged by mineralogical factors, which often cause gold losses to various tailings. Mineralogical factors affecting gold recovery mainly include grain size, shape, surface coatings and rimmings, presence of cyanicides, oxygen consumers and preg-robbers, presence of slow-dissolving gold minerals and the refractory nature of submicroscopic gold. Among these factors, locking in sulphide, silicate and other minerals as fine-grained gold inclusions and/or as invisible submicroscopic gold is by far the most common factor leading to poor gold recovery encountered in gold ore processing. Processing of PGE ores faces the same challenges as gold. Small grain size and locking of PGM in sulphide and non-sulphide minerals often cause PGM losses. When silver ore contains significant amounts of pyrargyrite, proustite and stephanite, silver recovery by cyanidation can be very low because of the slow dissolving kinetics of these minerals. In the processing of base metal ores, high content of pyrite, intergrowth of chalcopyrite with sphalerite and presence of clay miner-als may cause problems in recovering Cu-, Pb- and Zn- bearing minerals. Process mineralogy helps address all issues and problems related to mineral processing with predicting and trouble-shooting being two major objectives. It provides useful information on process selection, flowsheet development, recovery improvement and reagent consumption optimization. The information acquired from a process mineralogical study can be used as a guide for a metallurgical testwork program for process design or optimization.

Jan 1, 2014

By M. J. Lottering

Gold deposits in South Africa are invariably associated with uranium bearing minerals. Although it is low grade uranium by international standards, averaging around 0.3 kg U3O8 per ton of ore, recovery of uranium as a by-product improves the overall economics of gold extraction. Moreover, the current high uranium prices as well as increased demand due to renewed interest in nuclear power provide significant incentives for dedicated uranium production. An understanding of the uranium leaching response to changes in operating conditions is an important first step to-wards optimisation of uranium recoveries. In South African acid leaching plants, uranium dissolutions higher than 90% are difficult to achieve, and the chemical origin of this limit is not clear. To study leaching behaviour, an important consideration is the mineralogical characteristics of the ores. Typically, a diagnostic leaching approach can be followed. In this paper, a mineralogy-leachability explanation is presented to rationalise the difficulty in exceeding 90% dissolution from low grade uranium ores on the basis of a simple diagnostic leaching method. It was found that brannerite was the main reason for the existence of a dissolution limit in Witwatersrand ore and that chemical liberation was more effective to increase end dissolution compared to physical liberation. The findings from these investigations will form guidelines for developing economically viable flow sheets for improved uranium recovery, at least in a South African (Witwatersrand) context.

Jan 1, 2014

By X. Xu

This paper presents the research on comprehensive recovery of copper, gold, silver and iron from tailings from high-intensity magnetic separation in Tonglushan Mine. By comparison of experimental results of three flowsheets?regrinding of tailings-conventional sulphidizing flotation, water heating enhanced sulphidizing flotation and acid leaching-sulphidizing precipitation flotation, it is concluded that regrinding of tailings-conventional sulphidizing flotation flowsheet has the best economical and technical performance and practicability. Regrinding and using the mixture of sodium hydroxamate and sodium xanthate are two of the notable technical characteristics of this best flowsheet. The system for comprehensive recovery of tailings has been put into production. It not only can recover the valuable minerals from tailings in Tonglushan Mine, but also can reduce the environmental pollution, resulting great economic and social benefit.

Jan 1, 2014

By L. M. Wang

Chengmenshan Copper Mine Concentrator adopts the new process of preferential?bulk stage floatation and utilize reground, largely increase the mineral processing index of the copper and the sulphide concentrates. In addition, the paper describes the remarkable economic benefit of the new process through the comparison of the new and the old processes.

Jan 1, 2014

By D. Chen

The experiment adopted magnetic separation-priority flotation (first to float copper,then float lead) combined technology to deal with a complex Cu,Pb ,Zn multi-metals ore which has high sulphur content, difficult to separate Cu, Pb ,Zn minerals from sulphur and separate Cu from Pb. Floatable pyrrhotite was separated through magnetic separation which could eliminate the adverse effect on the flotation followed up. And then adopting the priority flotation process to recover the Cu, Pb ,Zn from the magnetic tailings. In priority, flotation Cu, BP(a kind of ethionine ester collector ) and ethyl xanthogenate were used as the collector, LD-1 and sodium sulphite were used as the depressant.The depressants combined with humic acid sodium and lime were used for chalcopyrite ? pyrite separation to further improve the copper concentrate grade. Considering the raw ore that contain 0.32% copper, 0.54% lead and 25.54% sulfur. The copper concentrate grade is 23.61%. The lead content of copper concentrate is only 0.85% . The recovery of copper is 75.03%,and the lead concentrate grade is 54.58%, the copper content of lead concentrate is only 0.81% and the recovery of lead concentrate is 62.24%. The mineral processing indexes were excellent, finally realizing the high effective separation of Cu, Pb , Zn and pyrite. This technique provides a new approach to highly utilize complex copper-lead-zinc ore.

Sep 1, 2012

By G. Demi

Chromium ore exploitation has commenced in 1948 in Albania and there are produced about 24.3 million tons up to the end of 2006. Last years the prices and need were increased notably. Main export of chromium ores and concentrates was accomplished respectively 114 500 ton and 13 000 ton in People Republic of China during 2006 year. Location, status, reserves and grade of chromium deposits of Albania are presented in the paper. Chromium ore enrichment is related with their composition and Cr2O3 content, as well as with market requests. Actually, high grade chromium ores with Cr2O3 content over 38% ~ 40% are directly exported or treated in metallurgy, but last time have been exported and chromium ores with 28% ~ 30% Cr2O3 content for the reason that dressing plants can not be operated for investment lack. High grade chromium ores have been treated in heavy media separation plant before 1990. It is presented flow sheet, figures and necessity to put in operation HMS plant in the paper. Actually, low grade chromium ores with content 16% ~ 20% Cr2O3 are not enriched for the lack of investments, but before 1990 they have been concentrated in dressing plants producing chromium concentrates grade 48% ~ 50% Cr2O3. In the paper are shown technological schemes and industrial figures during more than 20 years operation and possibilities to reconstruct these mineral processing plants. Only chromium mineral processing plant of Bulqiza is in operation using as raw material its old existing tailings. The flow sheet and figures show that are possibilities to increase recovery and grade of concentrate in the plant. Separation and concentration of slimes in suitable equipment gives visible improvement of Cr2O3 recovery. Several tests have been carried out with flotation and magnetic separation methods for enrichment of low grade chromium ores. Flow sheet and figures of mineral processing ores content olivine as gangue mineral are interesting, because combination of gravimetric with magnetic methods is necessary in this case. In the paper are presented the tests and good results of low chromium ore pre concentration. Metallurgical treatment of chromium ores to produce Ferro chrome, as well as technological process, figures, consume of electrical power and materials in Elbasani and Burreli furnaces are shown and necessary investments to treat in metallurgy all produced chromium ores in Albania are considered.

Jan 1, 2014

By Pramila Misra, Jibardhan Meher, Debadutta Das

The concentrated coal-water slurry has been receiving considerable attention recently due its ability to replace fossil fuels. Attainment of stable and concentrated slurry has been succeeded so far through several physical and chemical techniques. The present article reports the formulation and stabilization of a highly concentrated coal-water slurry formed from five varieties of non-coking coals with variable ash contents obtained from Eastern part of India, employing three varieties of starch esters, such as starch benzoate, starch formate, and starch carbamate as dispersant. The apparent viscosity of the modified coal-water slurry has been measured by varying coal loading, dispersant percentage, pH, temperature, etc. The apparent viscosity of the slurry has been found to be decreased substantially on addition of 0.8% of adsorbate in the slurry. The particle-particle interaction has been considerably decreased and stable concentrated coal-water slurry containing high weight fraction of coal (61.5-63.5%) has been achieved in each case. The slurries stay in a non-settling form for about a month with viscosity in a permissible low range. The coal-water slurry has been found to behave as a non-Newtonian liquid. Comparison of the zeta potentials of the naked and modified coals evidences that adsorption of the dispersants at coal-water interface results in inhibition of the agglomeration of coal particles through mostly steric repulsions.

Jan 1, 2014

By Kamalendu Bhunia

With the progressive depletion of known resources of good quality coal and minerals as well as the increasing demand of these minerals by different user industries, the emphasis has been shifted all over the world from selective mining to bulk mining followed by up- gradation to obtain the required quality of concentrate. The column flotation cell is one of the alternatives to reduce the gangue content of fines because of its inherent characteristics viz. easier to operate, low space required, no moving parts etc. A laboratory flotation column is used to conduct experiment. Present work has been undertaken to observe the effect of process variables (gas flow rate, feed/slurry flow rate, and frother concentration) on gas dispersion parameters (gas holdup, bubble surface area flux) in collection zone and to explore the effect of feed (slurry) inlet orientations and gas flow rate on column?s metallurgical performance. The effects of solid particle concentration, size and type (hydrophobic and hydrophilic) of solid on gas dispersion parameters have also been investigated. Test work has been performed in a continuously operating Perspex column (10 cm in diameter and 168 cm in height) using coal, sphalerite and dolomite as solid. Gas hold-up has been measured by phase separation method and mean bubble sizes are estimated from a drift flux analysis. The influence of operating parameters on bubble surface area flux has been discussed. It is observed that gas holdup in collection zone is affected by air as well as feed flow rates and also solid?s type. It is also found that addition of solid decreases the gas holdup and rate of decrease in gas holdup increases when solid concentration increases and particle size increases. Increase in gas flow rate increases recovery in collection zone due to increase in number of bubbles per unit volume of the column. From the experimental results it is evident that cross-current orientation of feed inlet shows slightly better metallurgical performance compared to other orientations. Keywords: column flotation, gas holdup, drifts flux, bubble size, bubble surface area flux, hydrophobicity, and recovery

Sep 1, 2012

By Linghu Changjin

Based on the characteristics of typical marine sedimentary phosphate rock in Guizhou, Southwest China, together with the research findings made on the surface electric properties of pure collophanites taken from different areas in pure water and under the action of collectors, a pure minerals flotation test of collophanite was conducted in this research. The differences of collophanite flotation behavior and the effects of the different pH values, varieties, and dosage of collector on flotation separation of collophanite were studied. It is suggested that that in pure water, collophanite had a negative charge within a wide pH range. The electro negativity values of collophanite increased with the addition of collectors GJBW and WF-01. When GJBW and WF-01 were used as collectors, the collophanite was depressed in acid medium, but had a good flotability in basic medium.

Sep 1, 2012

By Ofra Damm, v du Preez, D. van Vuuren, L. Simpson, H. Chikwanda

"South Africa is the world?s second largest producer of titanium bearing minerals, but apart from producing titanium mineral concentrate to form TiO2 slag, little further value is added in South Africa to mined minerals. Various studies were undertaken by both government and the private sector in an un-coordinated manner until 2007 when the South African Department of Science and Technology (DST) planned and adopted a national strategy to establish a local titanium metal industry through the research and development of key technologies that would provide a competitive advantage to such a local industry. The strategy entailed a two-pronged approach in the development of this capability, viz. simultaneous investments in the development of high-level human capital and technology in the fields of titanium metal powder production and downstream titanium metal powder processing technologies. To date significant progress has been made to establish research and/or pilot scale facilities in the following technical areas: TiCl4 production technology, titanium powder production technology, high energy milling of titanium powder, metal injection moulding facilities, rapid production of large components using laser additive manufacturing technology, investment casting of titanium, resource efficient machining of titanium and friction stir welding of titanium. Supporting technologies are also at an advanced stage through investments in titanium powder spheroidization and direct rolling of titanium powder. The intent with investment in some of these areas is not to develop new technology per se, but rather to establish local capability that will position South Africa to collaborate with other organisations in the world so that technologies can be acquired and transferred when needed in the future."

Jan 1, 2014

By A. K. Suri

India plans to increase the nuclear power share in overall energy-mix to about 30% by 2032 using both indigenous and imported reactor technologies. In the immediate time-frame, it is envisaged to generate 10000 MW electricity by PHWR technology by 2020 using indigenous uranium resources. This necessitates setting-up of new uranium mills and augmenting the existing resource, mining and milling capacities. This paper describes the current status and future R & D needs towards achieving the targeted demand of yellow-cake. Keywords: uranium, hydrometallurgy, leaching, yellow cake

Sep 1, 2012

By J. E. Gebhardt, D. McBride, T. N. Croft, M. Cross

"Heap leaching is well-established as a relatively low-cost and low-energy method of extracting metals from low grade ores. However, the design methodology, attention to the engineering details during heap construction and the long time scale in metal recovery makes the process susceptible to significant variation in the success of a heap leach operation. Often the laboratory predicted recovery rates are not achieved on site due to poor understanding of the complex physics of flow and coupled solid-liquid-thermal reactions within the multi-dimensional heterogeneous ore body. Given the large scale of commercial operations, small changes in metal recovery can substantially change the operating profitability. While there are a variety of approaches to heap leach modeling, computational fluid dynamics (CFD) modeling coupled with leach kinetic models offers a methodology to describe and understand the complexities of heap leaching. The CFD model uses leach kinetics specific for the mineralogy of the ore, including gangue chemistry, and provides an energy balance to calculate and predict temperature. Coupled with the CFD model’s inherent capability for modeling complex fluid flow, the physics and the chemistry of the heap can be simulated. This provides a tool for engineering design, as well as forecasting heap production under different scenarios. The calibrated model is used to simulate a three-dimensional test heap under fluctuating meteorological data, such as precipitation events, periodic solution application, and notably temperature. These simulations provide support for a methodology to design and engineer heap leaching of low grade copper sulfide ore. INTRODUCTION Worldwide copper ore reserves are faced with decreasing head grades with copper sulfides, particularly chalcopyrite being the predominant mineralogy (Nesse, 2000). Heap leaching offers an economical way to recover copper from low grade ore. The ore is stacked and a leach solution is applied and allowed to trickle though the porous bed of ore to extract target metals. The heap can be built with run of mine material or crushed ore and is constructed in order to achieve percolation of the leach solution to all regions. Bartlett (1998) provides an authoritative overview of the solution mining process where the leach solution interacts with the solid, the lixiviant dissolves the target minerals from the solid into the solution, and the dissolved species are transported out of the heap for subsequent recovery. Petersen (2016) provides a recent review of heap leach technology and emerging and potential future applications, and Ghorbani et al. (2016) summarizes the current state and challenges of the technology. Early applications of heap leaching offered a low cost technique to achieve high recoveries from oxide ores, typically greater than 70% depending upon the kinetics of reaction. As world copper resources transition to mainly copper sulfide mineralogy, such as chalcopyrite based ores, achieving high recovery from these copper sulfide deposits is proving more difficult due to the complexity of the leach kinetics, which leads to low leaching efficiency."

Jan 1, 2018

By T. Kumaresan

The Bayer process used for refining bauxite to smelting grade Alumina serves as the linchpin of the Aluminum production industry worldwide. Even though the process is well established, the presence of impurities in the liquor affects the quality of product and imposes a major economic cost on the industry. This review article focuses on the issues pertaining to Gibbsitic (Al2O3.3H2O) precipitation circuit. The comprehensive review provides a basic understanding of the aluminum trihydrate precipitation and agglomeration phenomena. Crystal growth rate and agglomeration play a significant role in determining the output PSD of agglomerates. Hence, the effect of certain thermodynamic and hydrodynamic parameters along with the impact of impurities (oxalates, aldols, acids etc.) and additives on hydrate growth has been reviewed.

Sep 1, 2012

By S. K. Dutta

Enormous amount of iron ore fines is generated, due to partly soft and friable nature, during mining. Coal fines are also produced during their processing. These fines cannot be used directly in ironmaking reactors. Utilization of these fines for extracting metal is of vital concern for resource conservation and pollution control, and therefore, a novel concept of agglomeration by cold-bonding is developed. Composite briquettes/pellets of iron ore fines with coal fines were prepared in the laboratory by cold-bonding technique. Various binders such as lime, Ca(OH)2, slaked lime, dextrin, molasses, fly ash etc were employed either alone or in combination in different proportions for making composite briquettes/pellets. It was possible to obtain dry strength of composite briquettes more than 300 N/briquette in some cases and more than 200 N/briquette in many trials. The combination of fly ash with slaked lime and molasses produced the highest strength, more than 400 N/briquette. Drop strength and shatter index values of composite briquettes/pellets were also measured. In briquettes, best compressive strength (978 N/briquette) is observed by using polyvinyl alcohol (PVA) binder. In pellet, best compressive strength (362 N/pellet) is achieved by PVA; shatter index (0.1%) and dry drop strength (158 numbers) are also good. Compressive strength above 200 N/pellet is obtained by fly ash, slaked lime and molasses combination.

Sep 1, 2012

By W. Kobal

The extraction of nickel (Ni) and cobalt (Co) from the laterite deposit of Ramu nickel-cobalt Project in Papua New Guinea was performed in this study. Chemical analysis by Inductively Coupled Plasma (ICP-AES) atomic emission spectrometer, SPS-3000 (Seiko Instruments (Inc.), shows the ore contains 48% Fe, 1% Ni, 0.1% Co, 1.8% Al, 0.14% Mg, and 0.8% Mn. Characterization by X-ray diffraction (XRD) analysis of the laterite ore obtained from the mine site shows the ore contains 70 to 80% goethite (FeOOH), assuming Fe content of 48% is mainly from geothite. The main leaching parameters investigated include; slurry temperature, leaching time and sulphuric acid (H2SO4) concentration to evaluate nickel and cobalt extraction. For all experiments, 10g batch samples are put into 300 ml beaker containing 100 ml of sulphuric acid of varying concentrations (1M, 2M, 4M). During the leaching period, 5 ml slurry samples are withdrawn at different times and filtered to obtain filtrate for ICP analysis to monitor nickel and cobalt extraction. Solid samples at the end of all tests are also obtained by filtration and after drying, XRD and ICP tests are performed to monitor nickel and cobalt contents. According to the test results performed at normal atmospheric pressure, over 99% of nickel and over 50% cobalt were extracted into solution within 120 min at 95ºC in 2M H2SO4 solution. Similar results were obtained when only temperature was reduced to 90ºC, but cobalt extraction increased to over 70% when leaching time was increased to 240 min. Further reduction in temperature to 80 and 60ºC resulted in reduction of nickel and cobalt extraction. At the end of each leaching test, magnetite was seen to attach to magnetic stirrer. The study showed nickel can be completely leached into solution but cobalt only up to 70%. Keywords: atmospheric pressure, sulphuric acid leaching, nickel laterite

Sep 1, 2012

By T. Tsurata

The accumulation of thorium and/or uranium by various microorganisms from a solution containing thorium and/or uranium at pH 3.5 was examined. Among the species tested, a high accumulation ability for thorium was exhibited by strains of gram-positive bacteria, such as Bacillus megaterium, B. subtilis, Micrococcus luteus, Rhodococcus erythropolis, and actinomycetes, such as Streptomyces levoris. On the other hand, though uranium was accumulated in small amounts from the solution containing both elements by all these microorganisms, actinomycetes, such as S. flavoviridis and S. levoris had relatively high uranium accumulation abilities. In these high performance thorium- and uranium- accumulating microorganisms, S.levoris, which accumulated the largest amount of uranium from the solution containing only uranium at pH 3.5, could accumulate about 300 µmol thorium and 133 µmol uranium per gram dry wt. of microbial cells from a solution containing both thorium and uranium at pH 3.5. After this screening, uranium accumulation using microorganisms isolated from uranium mines, among which some strains of bacteria were found to possess an extremely high uranium accumulating ability. The microbial biomass may thus be considered for use as an accumulating agent for the removal and recovery of uranium that may be present in metallurgical effluents, mine tailings, seawater and other sources. Recently, hundreds of micro-organisms existing in uranium deposits located in North America, Australia, and Japan for their ability to accumulate large amounts of uranium, and found some new strains which accumulated large amounts of uranium, such as Lactobacillus and Bacillus sp. from Japanese and Arthrobacter and Bacillus sp. from the United States uranium deposits. These bacterial strains can accumulate about 2500 µmol uranium per gram dry wt. of microbial cells within one hour. These microbial cells can remove uranium from the uranium refining wastewater with a high efficiency. The accumulation of uranium from a solution (pH 5.8) by microorganisms contained Arthrobacter nicotianee, which is a similar strain mentioned above Arthrobacter sp., was examined. Among the 76 strains of 69 species tested (23 bacteria, 20 actinomycetes, 18 fungi, and 15 yeasts), high uranium accumulation ability was exhibited by strains of the bacteria, A. nicotianae, B. subtilis, and M. luteus. A. nicotianae cells, which showed the best performance, could accumulate about 698 mg uranium (2.58 mmol) per gram dry wt. of microbial cells.

Jan 1, 2014