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By James CH

For drainage sediment to be used as a successful sampling medium in reconnaissance geochemical surveys, the length of any dispersion train from a typical target must be great enough for it to be detected by a widely spaced sampling pattern, and must also be homogeneous enough to avoid it being missed by the unfortunate selection of a random low value sample. Elements which occur in stream sediments in the form of discrete heavy minerals present two special problems in this regard. Since the element is concentrated into a few particles, the medium is extremely heterogeneous, which makes representative sampling impossible unless very large samples are taken, while the high specific gravity of such grains leads to their being concentrated in traps along the stream bed. Several ways of overcoming these difficulties have been suggested. Among these the "schlich" test, in which heavy material obtained by panning is taken for analysis is among the most popular. However, the results of the present study indicate that while this method improves the nature of the patterns obtained, they are still far from satisfactory. Alternative methods of sample preparation, including the taking of light material for analysis, appear to provide better answers to the problem. In the area studied this approach eliminated most of the "noise" associated with the data obtained by other methods, as well as giving an extended dispersion pattern.

Jan 1, 1986

By E. Dendy Sloan

An overview of hydrate properties is given, with emphasis on unusual deviations from ice, the most common solid water form. Reliable sample preparation and reproduction of in situ hydrates provide the foundation for all hydrate science and engineering. Relations are given to connect the three domains in the title: (1) micro-scopic properties measured with Raman, NMR, and diffraction spectroscopy, (2) meso-scopic properties measured with single crystals, and (3) macro-scopic properties measured with pressures, temperatures, volumes, etc. A principal illustration relates micro-scopic and macro-scopic domains. Experiments provides the basis for improving statistical thermodynamics model for these compounds. To date, this model is one of the most commonly used industrial statistical thermodynamics applications, based upon the classical model of van der Waals and Platteeuw (1959). Microscopic measurements and simulations indicate model assumption improvements, resulting in the next generation of the statistical thermodynamics for improved macroscopic property prediction.

Jan 1, 2002

By H. Ries

THE term "clay" is applied usually to certain earthy rocks whose most prominent property is that of plasticity when wet. This permits them to be molded into almost any shape, which they retain when dry. Furthermore, they harden under fire. Clays contain hydrous aluminum silicates-the clay minerals-in appreciable amounts, but aside from this a number of other mineral grains, particularly quartz, may be present. Texturally clays are fine grained, and the so-called true clay particles are usually under 2µ in diameter. MINERALS IN CLAY Certain hydrous aluminum silicates that predominate in many clays are known as the clay minerals"." and are grouped by Kerr41 as follows: [ ] The kaolin group has been found to consist of a number of minerals with the same chemical composition but different crystalline structures .83 Kaolinite is commonly formed by the weathering of other mineral particles, particularly feldspar, but some deposits, like those in Cornwall, England,36 and others in the Washington-Idaho district, are thought by some to be of hydrothermal origin. Dickite and nacrite are thought to be due usually to waters of

Jan 1, 1949

By Booth GW, Robertson IG

The Paddington Gold Mine ties within the Norseman-Wiluna greenstone belt, in the celebrated Eastern Goldfields province of the Yilgarn Block, Western Australia. Regionally, tropical to subtropical weathering has effected development of a prominent regolith and a deep lateritic profile. Detailed examination of the clay mineralogy, largely from a single drill hole which traversed the original Paddington I deposit, outlined three separate, vertically gradational assemblages, which are, in part, rock-type dependant. These include; 1. kaolinite with minur to trace quantities of sericite/illite (0-22m), 2. smectite and/or interstratified clay minerals, together with variable amounts of kaolinite, relic chlorite and illite/sericite (22-81m), and 3. chlorite and sericite (> 81m). Near surface, kaolinitic assemblages may be directly correlated with the intensity of lateritization, whereas smectite and interstratified clays from intermediate zones appear in association

Jan 1, 1989

By R. O. Heckroodt

After a brief review of the characteristics of clay minerals and their origin, a summary is given of the industrial uses of different types of clay materials. The mining and beneficiation of clays are discussed, with special reference to the upgrading of certain types of materials. The occurrence and resources of the more important varieties of clays are dealt with in some detail, viz residual kaolin derived from granite and sediments, brickmaking clays, refractory clays, bentonite, and palygorskite. The Republic of South Africa is well endowed with a wide spectrum of clay materials, with one important exception. Kaolin suitable for paper coating is not known to occur in the Republic, and efforts to beneficiate and treat local materials to achieve the desired properties have so far been unsuccessful.

Jan 1, 1991

A clay binding agent has been investigated to enhance flotation recovery of bitumen from Canadian high fines oil sand in the Clark Hot Water Extraction (CHWE) process. Selective adsorption on fine particles and subsequent agglomeration are critical for the success of clay binder enhanced oil sand flotation. A number of flotation tests have been performed at different reagent dosages under different operating conditions such as pulp pH to evaluate the reagent performance. Dissipative Quartz Crystal Microbalance (QCM-D) analyses of clay binder adsorption on quartz were carried out to better understand process mechanisms. It has been found that use of clay binder in flotation resulted in an absolute bitumen recovery increase of 18%, 25%, and 11% for the high-, medium-, and low-grade oil sand samples, respectively. The QCM-D analyses have revealed that the clay binder was strongly adsorbed on the SiO2 surface.

Jan 1, 2012

By H. H. Murray

Industrial usage of clays for current and new applications will continue to grow into the next century. The rate of growth will be highest in the less developed areas of the world. Transportation costs are a significant part of the delivered price, so the location of reserves and processing facilities for kaolin, bentonite, and palygorskite (attapulgite) are reviewed relative to serving these emerging markets. New value added applications will increase in the more developed areas which will require high quality raw materials, more sophisticated processing, and rigorous quality control.

Jan 1, 1998

By I. E. Odom

An electron optical and microprobe study was made to determine the physical and chemical nature of the silica minerals that occur as natural impurities in bentonite and montmorillonitic fuller&apos;s earth clay products (both granular and powder) and that occur in <10-µm dusts from plants that process these products. The purpose of the study was to determine if discrete "free" silica minerals, such as quartz, could be observed using SEM and EDS methods. No “free" silica minerals could be observed in the SEM images of the granular and powdered products, either among or on the surfaces of the particles. Also, no “free" silica could be identified by either SEM or EDS analyses of the dusts, even though quantitative X-ray diffraction analysis indicated that trace amounts of quartz occurred in all samples. It was determined that these quartz and other silica minerals were encapsulated or coated by montmorillonite. Vigorous washing, however, removed some of the clay coatings, so that small amounts of silica minerals could be seen by SEM and EDS analysis. It was found that all primary crystalline quartz grains in the bentonites have diagenetic overgrowths consisting of a mixture of montmorillonite, opaline silica and possibly microcrystalline quartz. Detrital quartz grains in the fuller&apos;s earth have thin diagenetic overgrowths of opaline silica, also containing montmorillonite. The clay encapsulation of the silica minerals in the products studied, as well as in the potentially respirable (<10-µm) dust produced during manufacturing of bentonite and montmorillonitic fuller&apos;s earth clay products, is considered to be an important factor influencing the potential health effects (e.g.. silicosis) of the contained silica. Even if clay dust containing silica should be inhaled, the montmorillonite encapsulating the quartz and other silica minerals would prevent direct contact of the silica with lung tissue. The clay encapsulation of quartz, as well as the highly hydroscopic nature of montmorillonite, may explain why not a single confirmed case of silicosis has ever been reported among plant workers in more than 65 years of production.

Jan 1, 1998

By I. E. Odom

A study was made of the physical and chemical nature of silica minerals found as natural impurities in bentonites and montmorillonitic Fuller&apos;s earth clay products as well as in <10 micron dust from eight processing plants. The results show that the silica minerals present in these clay materials are totally encapsulated or encased in clay. No "free" silica minerals could be observed in SEM images of either granular or powder products or in dust samples collected for MSHA crystalline silica analysis. Silica minerals, such as quartz, are identifiable by SEM and EDS analysis only after removing the clay coatings by vigorous washing. After washing it can be observed that all crystalline quartz grains also have diagenetic overgrowths of what is probably opaline silica. The clay and opaline silica encapsulation of quartz plus the strongly hydro scopic nature of montmorillonite are believed to be responsible for there not being a single confirmed case of silicosis among workers in the subject plants after more than 65 years of production.

Jan 1, 1996

By Edward J. Sterne

Several shale-hosted Pb-Zn-Ag deposits have been discovered in the northwestern Brooks Range, Alaska. Best known among these are the Red Dog, Drenchwater Creek, Lik, Ferric Creek, Hot Dog Creek, and Competition Creek deposits. They occur in a tectonically disturbed sequence of of Mississippian to Triassic shales, argillites, and cherts, and most are spatially associated with volcanic rocks. The sulfides are hosted in shales as disseminations, banded layers, massive lenses, and crosscutting veins. Detailed geologic descriptions of sulfide prospects in the Brooks Range were given by Tailleur (1970), Nokleberg and Winkler (1978), and Plahuta and Robinson (1979). Lange et al. (1980) discussed the formation of the deposits, the nature of the mineralizing solutions, and the temperature of formation on the basis of sulfur isotope studies. More recently, Harrover et al. (1982) detected a correlation between sulfide mineralization and high-temperature formation of charts associated with the sulfides by oxygen Isotope and chert crystallite size determinations.

Jan 1, 2013

By K. Donahue

Clay minerals play an important role in the gravitational stability of man-made rock piles by affecting geotechnical and hydrological characteristics of the material. The Goathill North rock pile at the Questa Mine in northern New Mexico has been the focus of a multi-disciplinary study to determine the effect of weathering on rock pile stability and in particular to determine if clay minerals are forming in the rock pile due to surface weathering. The results of x-ray diffraction (XRD) and scanning electron microscopy (SEM) analyses indicate the clay minerals found within the fine-grained soil matrix of the rock pile are of hydrothermal origins and did not detect any neoformation of clay minerals. The foremost mechanism for an increase in clay minerals within the rock pile is the physical break down of hydrothermally altered rock fragments to release hydrothermal clay minerals. The hydrothermal clay minerals within the rock pile show evidence of weathering by the dehydration of smectite from 2-water to 1-water interlayers within the clay mineral structure. This dehydration is most likely due to higher temperatures and low relative humidities in the Goathill north rock pile during surface exposure.

Jan 1, 2009

By Robert Linton

SPECIFICATIONS for clays serving raw materials in the ceramic industry usually contain the following items: (1) Chemical analysis, sometimes with mineralogical structure determined by microscopic investigation. (2) Maturing temperature and firing range, usually expressed in terms of pyrometric cone equivalent. (3) Shrinkage (drying and firing shrinkage separately). (4) Degree of plasticity. (5) Color after firing. Clays may be classified, according to the purpose of the classification, in several different ways, based on (1) Geological occurrence-transported, altered An place, indurated (shales). (2) Physical properties-plastic (bonding clays, ball clays) and nonplastic (flint clays, kaolins or china clays, bone clays). (3) Color. (4) Use. A common classification of clays for commercial designation, and one fol-

Jan 1, 1936

By Phoebe L. Hauff, Jeffrey P. Kurtz, Paul D. Chamberlin

Clay minerals can be a source of problems in heap leaching operations. The ore for many heap leach operations is commonly acid-sulfate alteration zone rocks which may be found in hot springs deposits as well as the supergene zone of other near- surface gold deposits. Clays can be important constituents of these ores. Swelling clays, such as smectite, can come loose from the agglomerated ore, migrate within the heap, concentrate in pore spaces and often plug up flow channels in the heap Cement is often added to the ore as a binder during the agglomeration process. Lime is added for pH control. Their presence, combined with the sodium cyanide commonly used to leach, can raise the pH of the leach solution to 10 or even 12. This very alkaline solution can cause dissolution of some mineral Some clays, such as kaolinite, are not very stable in high pH solutions. They can be dissolved and reprecipitated as other clay species if sufficient silica and the appropriate cations are available in solution. Silica gels and amorphous materials can also be created from the dissolved kaolinite and other minerals and act as retardants to the flow of leach solutions in the heap. Therefore, before a heap leach operation is built, the operator should evaluate the clays in the ore and test the agglomeration procedure. It is important to know not only the mineralogy and the chemistry of the leach environment but how the minerals and solutions interact and what the products of this interaction are. A hypothesis is presented in this paper that expanding smectite- bearing clays can be generated within the heap. How and why this happens will be explained.

Jan 1, 1987

By W. F., Dietrich

THIS paper deals with the- methods of mining the high-grade clays of California. Although the majority of the clay pits in the state are operated on a scale that is small by comparison with most metal mines, this very fact results in a diversity of methods and gives rise to problems of selection of the method best suited to given conditions. Two or three operators in California produce approximately 500 tons per day of a single kind of clay from a single pit. About five varieties of clay are mined on a scale of 200 to 400 tons per day; not over fifteen varieties are mined on a? scale of 50 to 200 tons per day; and more than 50 varieties are mined at a rate of less than 50 tons per day. It is the aim of this paper to delimit, insofar as the data at hand permit, the conditions and scale of operations that favor the selection of each dominant method of mining that is actually being applied at California properties. Details of the occurrence and utilization of the clays of California have been given in a recent bulletin and are not considered here.

Sep 1, 1928

By Haydn H. Murray

The area from Ohio on the east, Tennessee on the south, and Minnesota on the west: contains some very unique and useful clay deposits. Included are fireclays and plastic clays in Ohio, Kentucky, Indiana, Illinois, and Missouri; flint clays in Kentucky and Missouri; ball clays in Kentuckv and Tennessee; adsorbent clays (fuller&apos;s earth) in Missouri, southern Illinois, and Tennessee; and alluvial clays and shales for structural clay products from every state. Unique kaolin clays are known in Minnesota, Missouri, and southern Illinois and halloy-site localities are known in southern Indiana. The geology, physical properties, and uses or potential uses of these midwestern clays are described.

Jan 1, 1980

By D. Steele, B. Ndlovu

"Adequate characterisation of clays is becoming increasingly important as operating mines move into areas of more complex ores. The processing therefore needs better mineralogical characterisation to identify problematic ores for better planning before issues arise. While a number of instrumental mineral characterisation methods are available, X-ray Diffraction (XRD) is widely recognised as perhaps the best technique for the identification and quantification of minerals, particularly clays. When an appropriate sequential and systematic sample preparation and treatment protocol is employed with instrumental XRD analysis individual clays can be uniquely identified, and the proportions of interstratified clays can also be quantified. The effect of sample preparation on the XRD analysis and identification of clays was investigated in this study. The results showed that sample preparation protocol is indeed critical to accurately analysis and characterisation of clays. For example, both dry grinding and micronizing affected the degree of crystallinity of kaolinite leading to the formation of reactive surfaces or changes in the physicochemical behavior. It was also found that the apparent degree of preferred orientation in platy minerals correlates directly with the amount of force/pressure applied during the preparation of backfilled powder samples. This work showed that manual preparation can produce highly variable peak intensities especially with minerals that show any preferred orientation. KEYWORDS Clay; XRD; kaolinite INTRODUCTION Clays are important in our life and they have numerous applications in modern world from cosmetics to environmental remediation. Therefore, clays have been extensively investigated for many years. Adequate characterisation of clays is becoming increasingly important as the mineral processing industry faces more complex mineralogy with the need for better mineralogical characterisation to identify problematic ores and plan accordingly. In most studies, X-ray diffraction (XRD) method has shown the unique capability to characterise mineralogy, especially for the fine grained size materials. The XRD technique is particularly diagnostic for clays. It is known that under ideal conditions, the peak intensities of an XRD diffractogram are proportional to the concentrations of individual minerals present in the sample. Hence, the qualitative mineralogical data obtained from XRD can be quantified, using either the internal or external standard methods. However, it is also known that clays are particularly sensitive to the influences of sample preparation method due to their physical characteristics (e.g. fine grain size, morphology, relative physical softness, crystallinity, thermal sensitivity) that could be destroyed by inappropriate preparation prior to the analysis. Thermal and mechanical treatment and grinding of clays can change their crystalline structure, and consequently, their characterisation results by XRD analysis. The behaviour of clays in grinding has been widely studied, especially for kaolinite (Miller and Oulton, 1970, Milocevic et al., 1992, Tomasevic-Canovic et al., 1992). With prolonged grinding time, the crystallinity of the clays can decrease (Filipovic-Petrovic et al., 2002). It has been shown that grinding may gradually cause the loss of hydroxyl ions of kaolinite (Gonzalez Garcia et al., 1991)."

Jan 1, 2018

By M. A. Kessick

Current treatment and disposal procedures are compared for clay slimes resulting from the extraction of Alberta oil sands, the extraction of Florida phosphate matrix, the recovery of diamonds from kimberlite deposits in South Africa, the recovery of kaolin from clay deposits in southwest England and the upgrading of bauxite ore. Published research in the area is reviewed, and common trends which are emerging in the disposal of clay slimes are discussed.

Jan 1, 1978

By T. McCallum, C. Cooper, B. Hutzler

"In copper solvent extraction, managing the quality of the organic phase is a key parameter to ensure optimal physical and metallurgical performance in the plant. Increased throughput as a result of declining ore grades coupled with advances in plant design and practice, resulting in reduced organic losses, has pushed the limits of the status quo with respect to organic quality. Clay treatment of plant and recovered organic at the optimal dosage is critical in maintaining quality, however, achieving the optimal dosage through existing filtration capacity and practice can be difficult. Cytec has developed a process aid that increases efficiency of existing filtration equipment that has been successfully implemented at two commercial SX operations. ACORGA® CB1000 enables higher dosages of clay while allowing for more efficient use of existing filtration capacity. This study analyzes results from commercial trials and demonstrates that improved organic quality and clarity is achievable through optimization of current treatment practices. INTRODUCTION Decreasing ore grades have prompted copper solvent extraction operations to raise PLS flow rates, increasing plant throughput to maintain production1. The ability to process higher flow rates through existing mixer-settlers historically came at the expense of increased entrainments2. However, advances in mixer-settler design, practices and improvements in organic recovery processes have enabled operations to maintain, and in some cases reduce organic losses while achieving higher flow rates through existing equipment. Based on the increased demand on the SX equipment and reduced losses (or more efficient recovery) maintenance of the circuit organic quality through efficient clay treatment is now more important than ever. This paper discusses common industry practices and related issues in organic clay treatment, and presents benefits achieved in commercial operations through the use of ACORGA® CB1000 Clay Binder. IMPROVEMENTS IN DESIGN AND PLANT PRACTICE Mixer-settler design has improved since the first commercial copper SX operation in the late 1960s. Advanced designs in mixer, settler, and settler internals have contributed to reductions in entrainments. For example, improved impeller designs have been reported to decrease organic in aqueous entrainment from the ‘old designs’ of 50-200 ppm3 to as low as 4 – 10 ppm confirmed via diluent and reagent consumptions . Similarly, operations are reporting a 20-50% decrease in reagent consumption when compared to the original design criteria3. Operations have optimized settler internals to increase coalescence and have improved settler operating practices which have been shown to reduce entrainments7. Comparison of the SX world operating data from 1999 and 2007 shows reductions in organic entrainment losses with increases in flow rates."

Jan 1, 2015

By Frank E. Chase

Clay veins, also referred to as clay elastic dikes, have been responsible for numerous underground injuries and fatalities. These hazardous structures are also responsible for increased production costs during all phases of mining. For these reasons, the Bureau of Nines has investigated the physical characteristics of and roof instability problems associated with clay veins in order to make support and other mining recommendations. In addition the occurrence and origins of clay veins were examined to determine whether or not the structures could be projected into unmined portions of the coalbed. This investigation included portions of the Arkoma, Illinois, Northern Appalachian, Southern Appalachian, and Uarrior Coal Basins. Virtually a11 clay veins observed or documented occurred in the Illinois and Northern Appalachian Basins. Observed clay veins ranged in sire from 1 inch to 16 feet In cross-section and were found under shale, siltstone, sandstone, and limestone roof rock. Individual clay veins were predominantly composed of claystone; however, limestone. siltstone. and sandstone infilled clay veins do occur. Clay vein formation has been associated with the infilling of fissures which result from compressive, tensile, or shear ground failures. These gaping fissures were propagated by compactional processes and/or tectonic stresses active during and subsequent to coal iff cation. Associated fault, fracture, and slickenside planes commonly parallel clay veins and disrupt the lateral continuity of the immediate and, sometimes, main roof. When clay veins parallel or subparallel the direction of face advance the roof is segmented into cantilever beams causing unstable conditions. Therefore, the strata on either side of the clay vein must be bolted and strapped together to form a beam.

Jan 1, 1984

By J. Darlington, A. K. SenGupta

Water-swellable layered silicates, namely, the smectite clays can remove suspended materials (called herein as debris) and metal ions from aqueous streams. The present study shows that the flocculating and metal extracting abilities of smectite clay-based flocculants can be enhanced when these clays are used in conjunction with a specific anionic polymer. Such performance enhancement is attributed to the following: i) the clay-dispersing ability of the polymeric additive, that would translate into an increase in the clay-surface area available for the attachment of the debris particles onto the clay particles; ii) the possibility of dispersant-to-coagulant transition of the polymer during the later instants of the treatment process, as a result of reduction in solvency of the wastewater for the polymer due to the release of cationic species from the clay-based flocculant solids; iii) metal-complexing ability and adsorption properties of the polymer.

Jan 1, 2002