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By Claudio L. Schneider

Um flogopitito originário de um garimpo de exploração de esmeralda, na Bahia, está sendo estudado para utilização como fonte de potássio em técnicas de rochagem. Para este fim, é necessário cominuir a rocha até um tamanho apropriado. Estudos de cinética de dessorção e casa de vegetação estão sendo realizados com a finalidade de determinar o tamanho ideal de partícula para aplicações práticas. O custo associado à cominuição da rocha é um fator determinante na viabilidade econômica do uso da rocha como insumo na agricultura. Sendo assim, um programa de caracterização completo foi realizado para determinar rotas de britagem e moagem econômicas para esta rocha. Os resultados são apresentados de forma aplicada, com exemplos de circuitos e demanda energética.

Aug 8, 2018

By Daniele Perondi

Diferentes resíduos são gerados pelas indústrias siderúrgicas, dentre eles o resíduo dos trituradores de sucatas (RTS). O RTS gerado pelas siderúrgicas brasileiras se difere dos demais países devido aos materiais que são alimentados no triturador. Assim, o objetivo deste trabalho foi avaliar as características do RTS gerado por uma siderúrgica brasileira. As seguintes técnicas foram utilizadas: identificação e quantificação dos principais constituintes, análise termogravimétrica, imediata, elementar, poder calorífico superior e teor de cloro e metais. Os principais polímeros presentes no RTS foram o poliestireno e o polietileno. A partir dos resultados de análise imediata, elementar e de poder calorífico superior do RTS, verificou-se uma elevada quantidade de matéria volátil (76,22% ± 6,90). Os altos teores de carbono (72,92%) e hidrogênio (9,86%), foram atribuídos à elevada quantidade de polímeros e borrachas presentes no resíduo. O teor de enxofre (0,21%) pode ser atribuído a presença de borracha no resíduo, enquanto o teor de cloro (1,33% ± 0,13) pode ser atribuído a presença do PVC no resíduo. O poder calorífico superior do RTS foi de 30,01 ± 1,22 MJ/kg, de forma que uma avaliação termoquímica mostra-se como uma técnica atrativa para a sua destinação final.

Oct 30, 2017

By Mike Treffy

El presente texto describe las características geoquímicas de las rocas ígneas del tipo HHPG (High Heat Producing Granites) en los Andes peruanos. Dichas rocas tienen diferentes edades geológicas y están relacionadas a los depósitos minerales como estaño, plata, cobre, zinc, plomo, uranio, etc y están ubicadas al extremo sur de la Cordillera Oriental y norte del Batolito de la Cordillera Blanca. Asímismo, en base al procesamiento geoquímico de la de ANDESDATA, se demuestra que estos granitos y rocas volcánicas félsicas corresponden a diferentes series magmáticas y que este tipo de rocas pueden relacionarse a altas concentraciones de plata, oro, cobre, zinc, molibdeno, uranio, favoreciendo la circulación de fluidos hidrotermales a grandes distancias de las intrusiones y rocas volcánicas bastante diferenciadas.

Sep 21, 2013

By Tiago Nunes Lima

Novas ligas de Ti estão sendo desenvolvidas como uma alternativa para aplicação em implantes cirúrgicos e em componentes estruturais por possuírem propriedades atraentes em comparação à liga Ti6Al4V, com destaque ao menor módulo de elasticidade, menor citotoxicidade, maior resistência à corrosão e propriedades mecânicas similares, alta resiliência e elevada formabilidade. Este estudo tem como objetivo observar as características mecânicas de ligas Ti35Nb2Sn deformadas a frio e seguidas de envelhecimento. A liga foi laminada a frio com 80% de redução e envelhecida a 400 ºC por 48 horas. Foram realizados ensaios de tração, dureza, metalografia e análise das superfícies de fratura. A liga laminada apresentou uma maior relação de resistência à tração pelo módulo de elasticidade e maior ductilidade do que a liga envelhecida.

Aug 16, 2017

By Juliana Mesquita de Andrade

Em sistemas cerâmicos policristalinos as homojunções e heterojunções podem apresentar comportamento elétrico desde completamente ôhmico até com elevada característica retificadora, que no limite é a base do comportamento varistor, o qual é o dispositivo de proteção de sistemas e equipamentos eletro-eletrônicos contra sobretensões mais utilizado. Os óxidos de zinco (ZnO) e de estanho (SnO2) são, individualmente, base dos varistores com melhores comportamentos elétricos. Este trabalho, com base nas caracterizações estruturais por técnicas de microscopia eletrônica de varredura e análises termodilatométricas, e na caracterização elétrica e dielétrica, avalia as propriedades varistoras de cerâmicas à base do sistema misto ZnO-SnO2. Verifica-se a formação de um sistema polifásico apresentando homojunções e heterojunções com diferentes características morfológicas e graus de densificação, exibindo ainda comportamento eletrotérmico com predomínio de características varistoras em função da dopagem da matriz mista ZnO-SnO2. Os resultados obtidos evidenciam a tendência da formação de espinélio (Zn2SnO4) em presença de grãos de SnO2 e do estabelecimento de comportamento varistor (coeficiente de não-linearidade > 10), que pode ser aperfeiçoado por dopagem adicional e por tratamentos térmicos, principalmente quanto à redução da corrente de fuga e da ampliação e estabilização da região não-linear da curva tensão x corrente elétrica.

Aug 7, 2018

By Jean-François Dorion

La corrosivité des environnements miniers souterrains est un phénomène peu étudié au Canada. En plus de détériorer les systèmes de soutènement, la corrosion s?attaque aussi à divers installations et équipements souterrains. Cette étude, débutée en janvier 2007, est l?établissement d?une banque de données afin de caractériser les environnements miniers souterrains selon leur potentiel de corrosivité pour les systèmes de support de terrains. Pour ce faire, cinq (5) mines ont été sélectionnées afin de comparer les environnements : Laronde, Géant-Dormant, Niobec, Mouska et Doyon. À chacune des mines, trois (3) endroits ont été étudiés. Les résultats préliminaires démontrent une grande variabilité des conditions d?une mine à l?autre ainsi qu?à l?intérieur même d?une mine. La minéralogie des roches et du gisement influence la composition des eaux souterraines et la présence des sulfures joue un rôle important sur l?agressivité de l?eau et de l?air des mines de l?étude. Afin de déterminer le potentiel de corrosivité, plusieurs paramètres doivent être considérés et la mine doit être zonée selon l?agressivité des endroits.

Feb 1, 2008

By Michel Aubertin

Les activités minières peuvent produire de grandes quantités de roches stériles, qui sont typiquement entreposées dans des empilements de surface, au dessus la nappe phréatique. Ces haldes peuvent occuper une superficie de plusieurs dizaines d?hectares, et s?élever à plus de cent mètres. Pour des exploitations en roches dures, les roches stériles ont usuellement une granulométrie qui contient des particules de la taille d?un sol silteux jusqu?à des cailloux et blocs de taille métrique. La structure interne d?une halde construite sur une surface relativement plane comprend généralement deux zones principales. La première zone se trouve au coeur de l?empilement, et elle est formée par la présence de plusieurs stratifications subhorizontales (avec des couches denses et lâches) due à l?effet des équipements lourds qui compactent et brisent les grains. La deuxième zone se trouve aux endroits où les stériles ont été déversés en crête, par des camions ou des butoirs, ce qui induit une ségrégation des particules sur les flancs, le long de la pente. Selon la séquence de mise en place, la distribution granulométrique et la hauteur des bancs, un grano-classement plus ou moins développé se produit, avec les particules les plus grosses au bas de la pente et les particules plus fines au sommet ; on observe aussi une stratification inclinée due à l?avancement latéral du front de déposition. Ces éléments de la structure interne d?une halde influencent la distribution et le mouvement de l?eau (et de l?air). Pour évaluer la distribution des propriétés des matériaux dans une halde, on doit usuellement avoir recours à une combinaison de techniques qui fournissent des informations sur les caractéristiques hydrogéologiques et géochimiques des roches stériles. A cet égard, certaines techniques géophysiques sont particulièrement intéressantes car elles permettent une cartographie tridimensionnelle des variations des propriétés. Les informations obtenues de diverses techniques de mesures utilisées conjointement peuvent alors être employées afin de construire un modèle numérique qui permet d?analyser les écoulements non saturés de l?eau et le transport réactif des contaminants. De telles simulations aident à mieux comprendre la réponse de la halde dans son état actuel et futur, ce qui fournit des arguments pour ajuster la séquence de déposition pour élaborer le plan de fermeture et pour sélectionner la stratégie d?instrumentation et de suivi de l?empilement. La présentation inclura un survol des diverses techniques qui ont été développées afin de caractériser les propriétés des matériaux en laboratoire et sur le terrain, et pour obtenir un portrait global de la structure interne d?une halde. Des résultats additionnels sur la modélisation du transport réactif seront aussi montrés afin d?illustrer l?influence de la structure interne d?un empilement sur sa réponse hydro-géochimique et environnementale.

Nov 1, 2008

By Réal Tanguay, Mathieu Piché, Jacques Carignan, Charles Beaudry, André Bonenfant

"Le gisement Isle-Dieu est situé sur le flanc sud de l'anticlinal de Galinée. La stratigraphie locale comprend, de bas en haut, la rhyolite du Groupe du Lac Watson surmontée par le basalte du Groupe de Wabassee. Un horizon repère, siliceux et sulfure, d'origine sédimentaire, appelé ""Tuffite Clef', est présent au sommet du Groupe du Lac Watson et pend à 45° vers le sud.Le gisement Isle-Dieu est constitué par une lentille qui recoupe, en partie, la ""Tuffite Clef"". Elle est séparée en deux trorçons par un dyke de tonalite. Les données obtenues à partir des forages effectues à travers la rhyolite sous-jacente permettent de définir les zonations chimiques et pétrographiques de la cheminée d’altération.Ces transformation minéralogiques et chimiques sont caractérisées par un enrichissement en MgO, Fe2O3, MnO et un appauvrissement en CaO, SiO2 et Na2O. La zonation spatiale de ces altérations permet de mettre en évidence la géométrie et l'extension des conduits hydrothermaux. L'épaisseur maximale des sulfures massifs au sein de la lentille est en étroite relation avec l’importance des zones d'altération. Les patrons de variations chimiques dénotent une orientation préférentielle WNW des conduits hydrothermaux. Les parties les plus altérées et les plus déformées présentent localement de fortes variations positives en Zr, Nb, et terres-rares; ces concentrations sont vraisemblablement imputables a /' enrichissement résultant de la diminution du volume lors de l'altération.L'étude pétrographique montre que la porosité et la perméabilité du milieu ont joué un rôle important dans la circulation des fluides car les roches de la cheminée présentent des phénomènes de dévitrification, de bréchification et de microfracturation très prononces. La nature magnésienne de certaines chlorites et la perméabilité accrue du milieu semblent en accord avec le modelé propose par Roberts et Reardon, ( 1978 )"

Jan 1, 1990

By P. Soros

Rich iron ore deposits were discovered during the 1960's in the mountain range of Serra dos Carajas, State of Para, Brazil, near the headwaters of the Tocantins River some 400 miles southwest from the state capital of Belem. (See Fig. 1 and 2). The key to the successful exploitation of this deposit was the development of an efficient an economical transportation system. The rugged terrain, and the dense tropical vegetation of the Amazonian jungle and the irregular coastline with its high tidal range presented severe obstacles to the planning and building of such system. Starting in 1972 extensive surveys and studies were carried out by Soros Associates on behalf of CVRD to determine the optimum way of transporting the ore from the mine site to the markets, most of which are located overseas. Overland transportation to the coast, loading into seagoing vessels and the ocean voyage to the ports of destination was treated as an integrated system in these studies.

Jan 1, 1986

By Gabriel Gonçalves Pessoa de Castro

O trabalho teve por objetivo produzir uma liga Al AA1070 com microestrutura ultrafina via prensagem por canais equiangulares. O processo empregou a rota C com 2 passes consecutivos a frio e acumulou uma deformação ?2 = 2,38. O material de partida é proveniente de um processo de laminação a quente na qual a microestrutura resultante era composta de grãos grosseiros com tamanho de grão de 14,5 ± 19,1 ?m e dureza de 31,1 ± 1,9 Vickers. Foi realizada a caracterização microestrutural com o auxílio das técnicas de microscopia eletrônica de varredura (MEV) e de difração de elétrons retroespalhados. O comportamento mecânico das amostras foi avaliado por ensaios de dureza Vickers, a fim de se determinar a energia armazenada durante os passes. Os resultados obtidos mostraram que o material de partida apresentou estrutura parcialmente recristalizada, decorrente do processo termomecânico de laminação. A deformação cisalhante severa que ocorre na interseção entre os canais durante o processamento via ECAP permitiu um intenso refinamento de grãos. O tamanho de grão após o 2° passe foi da ordem de 1,6 ± 1,7 µm. A dureza após o 1° passe quase dobrou em relação ao material de partida, mas praticamente se manteve no passe seguinte, sugerindo uma possível estabilidade. Pode-se concluir que ocorreu um considerável refinamento do tamanho de grão em função da elevada fragmentação e rotação da subestrutura após os passes de deformação.

Aug 8, 2018

By Mark Cadzow, Rodney Lamb

CARBAD is a recently developed Australian process for the recovery of gold and platinum group metals (PGM). The process relies on the selective agglomeration phenomena of the gold and PGM to capture the mineral in a carbon-hydrocarbon media. The precious minerals are then extracted from the loaded media by a solvent gold room process producing a relatively pure concentrate. The media is then reformed and recycled. The process development from batch test work to a 5 t/h commercial scale CARBAD plant is discussed. The operation and results of processing a variety of ore types at several alluvial and hardrock gold mines is examined. The operating and capital costs for the CARBAD process shows that it is significantly less than that the conventional CIP/CIL. The environmental safety of the process is a major feature where precious metal deposits are located within urban environments or within wilderness areas.

Jan 1, 1989

By Maria José Santos Lima

A pesquisa e o desenvolvimento de Materiais nanoestruturados vêm crescendo significativamente nos últimos anos. Estes materiais apresentam propriedades significativamente modificadas em comparação às dos materiais convencionais, devido às dimensões extremamente reduzidas dos cristalitos. O carbeto de Tântalo (TaC) é um material extremamente duro, apresentando elevada dureza, elevado ponto de fusão, elevada estabilidade química, boa resistência ao ataque químico e choque térmico e excelente resistência à oxidação e corrosão. Desta forma este trabalho teve como objetivo a obtenção de TaC nanoestruturado a partir do precursor tris(oxalato)oxitantalato de amônio hidratado, através de reação gás-sólido a baixa temperatura (1.000°C) e curto tempo de reação. Os materiais obtidos foram caracterizados através de difração de Raios-X (DRX), Refinamento Rietveld, Microscopia Eletrônica de Varredura (MEV), Espectroscopia de Infravermelho (espectroscopia IV), Termogravimétrica (TG). Através das analises de DRX e do refinamento Reitiveld para o TaC com S = 1,1584 observou-se a formação do carbeto de tântalo puro com estrutura cúbica e tamanho médio de cristalitos na ordem de 12,5 nanômetros.

Aug 7, 2018

By Sander Mul, Michael Brandner, Armin Paar

Graphitic HSS roll grades such as ESW’s brand VANIMO can be considered as the latest developments for the last finishing stands in hot strip mills. These roll grades are developed on the basis of the alloying concept of (Carbide Enhanced) Indefinite Chill work roll materials. During the development of VANIMO, the amounts and types of carbide forming elements were increased and adjusted into the direction of cast HSS roll grades. The microstructure of graphitic HSS roll grades therefore consists of tempered martensite, cementite and several different carbide types as well as a well-defined amount of free graphite. The main purpose of graphitic HSS roll grades is to combine the high surface quality of Indefinite Chill alloys as well as the high wear resistance of HSS roll grades. Several systematic steps were taken to increase the wear performance from Carbide-Enhanced Indefinite Chill grades to the more advanced VANIC grade and further on to the highest alloyed roll grade VANIMO. In every development step, the surface quality of the roll grades was carefully monitored. The decision to invest in new testing equipment at ESW’s plant was driven by the wish to see microstructural effects of different alloys in a macroscopic dimension. Usually samples are taken from cast rolls and investigation is done in comparably small areas compared to the total surface of a roll. Rolling of strip is done with the entire barrel, so effects of alloy and microstructure can appear anywhere on the barrel surface. To ensure better understanding and deeper knowledge about influences of alloying trials we decided to install the last version of LRI (Lismar Roll Inspection). LRI includes the latest technology of Eddy Current with an enormous resolution. Depending on the formation of carbide precipitations, carbide network as well as matrix and free graphite, the EC test can detect smallest differences. The possibility to analyze the different results of EC and UT surface wave inspection will be discussed. A few examples of surface effects in the mill application will be discussed and improvement strategies explained.

Oct 1, 2019

By Walter Crafts, C. M. Offenhauer

IN a previous study' of the carbide phase of chromium steels, it was shown that chromium carbide (Cr7C3) is a more stable carbide than cementite (Fe3C) at tempering temperatures above about 500°C. in quenched steels containing from about r1to 7.5 per cent chromium. Below this temperature the carbide phase was found to consist of cementite in all of the steels examined. In the present investigation it was found that a similar change in the carbide phase takes place in molybdenum and in chromium-molybdenum steels at approximately the same tempering temperatures. The approximate ranges of occurrence of the alloy carbides Cr7C3, Cr4C, and Mo2C have been determined in steels containing up to 5 per cent chromium, 1 per cent molybdenum and 0.60 per cent carbon. The experimental steels were made in small high-frequency furnaces from Armco ingot iron, low-carbon ferrochromium and calcium molybdate and were poured into 2-in. ingots, which were forged to 1-in. round bars. Sections of the bars were heated to the carbide-solution temperature and cooled rapidly to induce austenite transformation at relatively low temperatures. The steels were subject to some segregation, therefore comparatively high temperatures were necessary to dissolve all of the carbides. The microstructure of the quenched specimens was examined to verify the belief that the carbides had been dissolved, and also to determine the nature of the nonmartensitic structure of incompletely hardened steels. Ferrite and pseudomartensite were present in some of the specimens, but all specimens were quenched at such a rate that pearlite was not formed, in order to ensure the formation of the carbides at temperatures lower than about 500°C. It had been found previously' that in chromium steels the chromium carbide could be produced by transformation of austenite in the pearlite range above 500°C., and, in order to start the tempering treatment with the carbide present as cementite, the absence of pearlite was considered to be essential. The specimens were tempered for 64 hr. to permit the formation of the stable carbide. After tempering, the specimens were submitted to microscopic and X-ray examination. The carbides were separated either electrolytically in a 5 per cent HCl electrolyte or with an acidified copper-potassium chloride solution. The crystal structure of the carbide phases was determined by the Debye-Scherrer type of X-ray patterns. The X-ray patterns obtained from specimens near the boundaries between two types of carbides were generally weak and diffuse as compared with the other patterns. For this reason, and because the more soluble components may be masked, the boundaries between the phases could not be determined precisely. However, the X-ray analysis of electrolytically separated carbides has given consistently reproducible results

Jan 1, 1943

By Walter Crafts, C. M. Offenhauer

IN the course of study of the heat-treatment of low-alloy steels, the behavior of alloy carbides at subcritical temperatures was found to vary from that indicated by published investigations. In order to establish the ranges of formation of carbides in low-chromium steels, a series of steels containing up to 0.60 per cent carbon and 7.5 per cent chromium has been investigated with respect to the type of carbide formed after quenching and tempering at subcritical temperatures. The types of carbide formed as products of austenite transformation to pearlitic and pseudomartensitic structures have also been determined. There have been numerous investigations of the carbides in chromium steels and diagrams of the iron-chromium-carbon system.1 Westgren, Phragmén and Negresco2 identified the following carbides in chromium steels: [Cementite Fe3C (containing up to about 15 per cent Cr) Trigonal carbide Cr7C3 (containing up to about 55 per cent Fe) Cubic carbide Cr4C (or Cr23C3) (containing up to about 25 per cent Fe) Orthorhombic carbide . Cr3C2 (containing only a few per cent Fe)] The most complete information on the iron-chromium-carbon system was supplied by Tofaute, Sponheuer and Bennek3 and by Tofaute, Küttner and Büttinghaus.4 By means of dilatometric and microscopic studies, sections of the diagram were established. This diagram showed the presence of the special carbide Cr7Ca in steels containing about 2.5 per cent to 12 per cent chromium in low-carbon steels and from about 5 to 20 per cent chromium in r per cent carbon alloys from A1 to room temperature. The present investigation has shown that a carbide inversion from Fe3C to Cr7Ca occurs in chromium steels containing more than about 1 per cent chromium after hardening and tempering at subcritical temperatures above about 500°C. The type of carbide observed to be more stable in quenched and tempered specimens was also found to be produced by direct austenite transformation in corresponding ranges of temperature and composition. EXPERIMENTAL PROCEDURE The steels used in these experiments were made in magnesia-lined crucibles in high-frequency furnaces and were poured into 2-in. ingots. The ingots were forged into 1-in. round bars, and all heat-treatments were conducted on specimens of this section .size. Sections of the bar stock 8 in. long were hardened in air, oil or water depending on the composition, after heating to a temperature sufficiently high to dissolve the carbides. The low-carbon and low-chromium steels were not entirely martensitic after quenching, and contained some ferrite and pseudomartensite. No pearlite was observed in the microstructures after auenchine. The quenched bars were cut into

Jan 1, 1942

By M. R. Rosen

CARBINDER Polymer 498 is a liquid organic taconite binder which significantly improves fired compression in both fluxed and acid pellets. It has been used commercially in both shaft and straight grate furnaces. This new binder produces an unusual wicking phenomenon during balling wherein the rate of movement of interstitial water is accelerated to the surface of the balls. The phenomenon is proposed to be responsible for the significant improvement seen in fired compression. This paper presents information as to the effect of CARBINDER Polymer 498 on green ball and fired pellet properties. It also describes the wicking phenomenon and discusses a reversal in the normal balling operation procedures required for successful agglomeration.

Jan 1, 1988

By Liang Li

Thermodynamic analysis and experiments were conducted in order to verify the feasibility of preparing crude titanium tetrachloride (TiCl4) via the carbochlorination of low-grade titanium slag in molten salt. Titanium slag, assaying 74.6 wt% TiO2 with high calcium and magnesium oxide impurities, was treated by an optimized carbochlorination process in NaCl molten salt. These impurities in the titanium slag were chloridized simultaneously, and chlorination products FeCl2, MnCl2, MgCl2, CaCl2 and CrCl3 were collected in the furnace slag. XRD and SEM/ EDS analysis of residue shown that SiO2 and Al2O3 in titanium slag were difficult to chlorinate completely. Theoretical calculations and industrial-scale experimental studies reveal the content of TiCl4 in the products was more than 98.8 wt% and thus proved the feasibility of utilizing low-grade titanium slag for TiCl4 preparation by molten salt chlorination technology.

By John Nell, Paul den Hoed

Carbochlorination tests were conducted with matched particle-size fractions of rutile, ilmenite and high-titania slag in a small bubbling fluidized-bed reactor. The effects of temperature, the type and proportion of solid reductant in the charge, and the fraction of Cl2 in the fluidizing gas were investigated. Tests confirm the need for solid carbon in the bed if chlorination is to run at high rates. With solid carbon in the bed, CO supplied with the fluidizing gas does not increase significantly the degree of chlorination after 75 minutes. Ilmenite is chlorinated more quickly than titania slag, which in turn is chlorinated more quickly than rutile. Rates of chlorination at 1100°C and 1000°C are much the same and significantly higher than at 900°C. Chlorination is associated with significant increases in particle porosity (even for rutile), which is brought about by the rapid initial chlorination of FeO and MnO (in ilmenite and slag) and (it is argued) by the chlorination of Ti2O3 which forms at high-energy surface sites. A reaction mechanism is presented; where possible, its validity is demonstrated by the support of empirical observations.

Jan 1, 2003

By Johan Nell, Paul den Hoed

"Carbochlorination tests were conducted with matched particle-size fractions of rutile, ilmenite and hightitania slag in a small bubbling fluidized-bed reactor. The effects of temperature, the type and proportion of solid reductant in the charge, and the fraction of Cl2 in the fluidizing gas were investigated. Tests confirm the need for solid carbon in the bed if chlorination is to run at high rates. With solid carbon in the bed, CO supplied with the fluidizing gas does not increase significantly the degree of chlorination after 75 minutes.When large proportions (30 wt%) of carbon are added to the charge, then the reactionTiO2 + 2C + 2Cl2 = TiCl4 + 2COis favoured overTiO2 + C + 2Cl2 = TiCl4 + CO2Ilmenite is chlorinated more quickly than titania slag, which in turn is chlorinated more quickly than rutile. Rates of chlorination at 1100°C and 1000°C are much the same and significantly higher than at 900°C. Chlorination is associated with significant increases in particle porosity (even for rutile), which is brought about by the rapid initial chlorination of FeO and MnO (in ilmenite and slag) and (it is argued) by the chlorination of Ti2O3 which forms at high-energy surface sites."

Jan 1, 2003

. F. W. SPERR, JR.,* Pittsburgh, Pa.--Mr. Malcolmson states that the Carbocoal process produces ammonium sulfate in excess of that normally recovered in the ordinary byproduct coke process. Table 3 indicates that 20,000 to 25,000 lb. of sulfate of ammonia are obtained in carbonizing 1000 tons of Clinchfield coal. This is a high-grade coal and yields from 26 to 28 lb. of ammonium sulfate per ton in a modern byproduct coke oven. On the next page, 21 lb. is stated as the yield of ammonium sulfate per short ton of raw coal; this is less than the average production from any well operated byproduct coke-oven plant treating coal of the character usually coked, in Pennsylvania and Ohio. The statement as to the comparative yields of light oil is somewhat misleading in view of the results obtained during the past year or two by the more modern byproduct coke plants. The plants put in operation by the H. Koppers Co., during the past two years, are producing about 3.5 gal. of light oil per short ton of coal, and several of these plants are producing more than 4 gal. per ton. The yield of pure toluene runs from 0.45 gal. to 0.55 gal. per ton. .The quality of the light oil .obtained from the Carbocoal process is of much greater importance than would be inferred by one not closely familiar with the subject. The presence of paraffins in the benzol and toluol fractions seriously detracts from their commercial value; the benzol and toluol fractions derived fro in the Carbocoal process contain about 50 per cent, of paraffins. It should be thoroughly understood what these paraffins are. They are simply hydrocarbons that go to make up ordinary petroleum, and if a successful method for the removal of paraffins from benzol and toluol has been developed, this can at once be applied to several well known processes by which benzol and toluol can be made directly from petroleum, which have as yet been total failures on account of the contamination of these products by paraffins.

Jan 11, 1918