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By W. Miles

Introduction From a historical perspective, bentonite is the common rock term for various uses and applications. Its name originates from water-based muds near Fort Benton used for lubrication of wagon wheels during the 19th century migration to western territories (which are presently part of the United States) when the pioneers ran out of axle grease. From a clay mineralogy perspective, bentonite is composed primarily of montmorillonite, an expandable magnesium aluminum silicate clay mineral. When magnesium occupies an octahedral structural site that usually contains an aluminum atom, a negative charge is created. In order to neutralize negative charges, cations are drawn to the interlayer surfaces between clay mineral sheet structures. Modern applications for bentonite depend on the sodium or calcium cation populations and other characteristics of the clay mineral. When sodium is the dominant cation, the material is also called sodium bentonite, also known as swelling bentonite, western bentonite or Wyoming bentonite. When calcium or magnesium is the dominant cation, the material is called calcium bentonite, also known as nonswelling bentonite or southern bentonite. Swelling bentonite is recognized for its rapid hydration of interlayer sodium and subsequent dramatic expansion up to more than 20 times its original volume. Low shear can then disperse the hydrated sodium bentonite to form suspensions that increase viscosity and suspend solids. However, when shear is subsequently eliminated a sodium bentonite slurry gels. Characteristically, nonswelling calcium bentonite has relatively poor hydration properties and thus low expansion of the clay mineral. When subjected to low shear, calcium bentonite exhibits very little viscosity and poor suspension. Additionally, when shear is subsequently eliminated no more than minimal gelling takes place. The domestic and export markets related to both swelling and nonswelling bentonite are discussed below.

Jan 1, 2007

By William J. Miles

From a historical perspective, bentonite is the common rock term for various uses and applications. Its name originates from water-based muds near Fort Benton used for lubrication of wagon wheels during the 19th century migration to western territories (which are presently part of the United States) when the pioneers ran out of axle grease. From a clay mineralogy perspective, bentonite is composed primarily of montmorillonite, an expandable magnesium aluminum silicate clay mineral. When magnesium occupies an octahedral structural site that usually contains an aluminum atom, a negative charge is created. In order to neutralize negative charges, cations are drawn to the interlayer surfaces between clay mineral sheet structures. Modem applications for bentonite depend on the sodium or calcium cation populations and other characteristics of the clay mineral. When sodium is the dominant cation, the material is called sodium bentonite, also known as swelling bentonite, western bentonite or Wyoming bentonite. When calcium or magnesium is the dominant cation, the material is called calcium bentonite, also known as non-swelling bentonite w southern bentonite.

Jan 1, 2012

By Alan R. Johnson

Because of the competitive nature of the iron ore pelletizing industry, commodities required for the production of pellets are continually being scrutinized to minimize their usage and offset rapidly escalating costs. In the Tilden pellet plant, the usage of one commodity, bentonite, has been reduced from over twenty-four pounds per long ton of pellets to as low as eight pounds per long ton. The evolution of bentonite usage from plant start-up to the present time is described.

Jan 1, 1984

By Christopher R. Harris

"Considerations are presented for developing and implementing self-hardening slurry mix designs to be utilized in barrier seepage walls. Slag-cement-cement-bentonite (SCCB) slurries are the primary focus, with some comparisons referenced to the more traditional Portland-based cement-bentonite (CB) slurries. Field and laboratory mixing methods are reviewed, including 1) single sack – single mixer method; 2) bentonite slurry mixer – cementitious addition mixer method; 3) bentonite mixer – grout mixer – CB blending mixer method. Major phenomena associated with the dynamics of barrier wall excavation, such as loss of water from the in-trench slurry and consolidation of in-trench slurry are discussed. Other topics touched upon include sand content effects, fluidizers utilized, and chemical contaminants. The role of higher bentonite to water ratio is reviewed, with demonstration of improvement of filtration properties, and an increase of water retention of the final consolidated product.IntroductionSelf-hardening slurry has been utilized to construct barrier seepage walls for many decades. This is essentially a single-step slurry excavation and backfill process whereby the trench-supporting fluid gains strength over a short period during installation and maintains or develops low hydraulic conductivity. The resulting curing slurry becomes the actual barrier wall as the resultant cement-augmented clay slurry now fulfills the dual purpose of both temporary trench stabilization and final cured-in-place product. This eliminates the requirement and expense of subsequent backfill/slurry displacement operations required in traditional barrier wall installations.Self-hardening slurries have been fabricated using a number of various clays, most commonly sodium bentonite, calcium bentonite, attapulgite, and sepiolite. Perhaps due to plentiful high quality sodium bentonite deposits found domestically, the proven excavation stabilization properties imparted from sodium bentonite slurries, sodium bentonites are typically specified for formulating self-hardening slurries in the US. Cementitious materials utilized most commonly are Portland cement and slag (ground blast furnace slag or GBFS). For the purposes of this discussion, self-hardening slurry having a cementitious of Portland will be referred to as CB. Those having cementitious material of GBFS replacing Portland (partially or wholly) will be referred to as SCCB."

Jan 1, 2016

Although Canadian bentonite is competitive in quality for most uses, it has not been accepted for the pelletizing of iron ore concentrates. In 1962, Canada consumed about 10,000 tons of imported bentonite for this use. By the end of 1965, the planned domestic consumption for this purpose alone will probably be more than 100,000 tons a year, valued at about $3 million. Consequently, a challenge exists for the establishment of a Canadian source of high-quality bentonite for pelletizing. Such a bentonite would also be suitable for the two other major applications -well drilling and foundry use. Brief mention is made of such topics as the identification, 1noperties, occurrences, exploration, applications, technology and laboratory testing of this clay. In particular, the type of bentonite in demand, the geological horizons warranting exploration, and simple preliminary test methods are discussed.

Jan 1, 1964

By William J. Lang

In just over a generation, the United States bentonite industry has grown from almost a rake and shovel operation into one with a multimillion ton annual production rate and exports to all corners of the globe. Bentonite production, pressed to keep pace with the soaring demand, has increased more than 10 fold in the last 30 years. The worldwide demand for bentonite is expected to double during the next eight to ten years. It remains to be seen whether U.S. producers will be able to maintain the dominant position in the world market. It should be noted that accurate statistical information regarding production or market information is difficult or impossible to obtain abroad and also within the United States. Published information obtained in response to questionnaires of the Bureau of Mines tends to be on the conservative side. FOUNDRY It has only been in the last thirty or forty years that bentonite has become an indispensible part of the age old metal casting industry. The relationship has proven most beneficial to both industries and promises to be long lasting. The foundry market for bentonite was the least of the three major markets twenty years ago but now leads all others and consumes 1/3 or more of the

Jan 1, 1971

By E. J. Mayhew

Bentonite and newly discovered deposits of sepiolite, saponite, and hectorite are now being processed and marketed from the Amargosa Valley of Nevada. All of these deposits are large. The bentonite has been known for decades and is the whitest known. The only other sepiolite deposit is in Spain. The only other commercial hectorite deposit is at Hector, California. No other saponite deposit is known. All the components except bentonite are hydrous magnesium silicates. The bentonite is mixed layer Na-Ca. All the materials have characteristics unique to their locale and type, such as high yield point for drilling muds and liquid suspending agents. The sepiolite has geothermal stability. Figure 1.

Jan 1, 1979

By C. Erichsen

ABSTRACT: The Berg Bock Freeway Tunnel represents the southernmost link of the "Thuringian tunnel chain" of the new freeway A71 located in the eastern part of Germany. It comprises two tubes each 2700 m in length. From north to south, it passes through the Suhl granite, the base sediments and the porphyrite of the New Red as well as the layers of the Middle Bunter. The two tunnel tubes were driven by the shotcrete method within appr. 10 months. With four tunnel faces, maximum performances totalling appr. 30 m/d were attained. Additional, supplementary demands on the safety conception, resulting from the findings from and the analysis of fire accidents in tunnels in recent years, had to be fulfilled in the execution planning at short notice. The inner lining is largely constructed using non-reinforced concrete. Reinforcement is only installed in the portal zones, in tunnel sections in less stable rock and in areas with a special cross-section as for instance cross connections and niches. ZUSAMMENFASSUNG: Der Autobahntunnel Berg Bock stellt das südlichste Glied der "Thüringer Tunnelkette" auf der Autobahn A71 dar, die im Osten von Deutschland liegt. Er besteht aus zwei Röhren von je 2700 m Länge. Vom Norden nach Süden durchörtert er den Suhler Granit, die Basissedimente und den Porphyrit des Rotliegenden, sowie die Schichten des Mittleren Buntsandsteins. Die beiden Tunnelröhren wurden in Spritzbetonbauweise in einer Bauzeit von etwa zehn Monaten aufgefahren. An vier Vortriebsorten wurden Spitzenleistungen von insgesamt etwa 30 m/d erzielt. Ergänzende Anforderungen an das Sicherheitskonzept, die sich auf der Grundlage der Auswertung der in den letzten Jahren aufgetretenen Brandunfälle in Tunneln ergeben haben, wurden im Rahmen der Ausführungsplanung kurzfristig berücksichtigt. Die Tunnelinnenschale wurde weitgehend aus nicht bewehrtem Beton hergestellt. Nur in den Portalzonen, in Tunnelabschnitten mit weniger standsicherem Fels und in Bereichen mit speziellen Querschnitten, wie beispielsweise im Bereich von Querstollen und Nischen, wurde bewehrter Beton ausgeführt. RÉSUMÉ: Le tunnel d'autoroute de Berg Bock représente le plus méridional maillon de la "chaîne thuringienne de tunnels" sur l'autoroute A71 dans l'est de l'Allemagne. Il se compose de deux tubes d'une longueur de 2700 m chacun. Du nord vers le sud, il traverse le granit de Suhl, les sédiments de base et le porphyrite du Rotliegendes, aussi que les strates du grès bigarré intermédiaire. Les deux tubes étaient creusés en méthode de construction de béton projeté dans une période de construction d'environ dix mois. À quatre fronts de taille rendements maximaux collectifs d'environ 30 m par jour étaient obtenus. On a eu égard à court terme dans la conception d'exécution à des demandes supplémentaires vers la conception de sécurité, qui ont résulté sur la base de l'interprétation des accidents d'incendie dans des tunnels dans les années dernières. La paroi intérieure était construite largement de béton non armé.

Jan 1, 2003

COMPLYING with your frequently expressed wish and, your persistent request, I have decided to prepare a brief little book on metallic ores, based on ,the books of the ancient philosophers and on the experience of practicing miners, that will instruct you how to judge from promising indications which rock forma¬tions, which veins, stringers, or mineral matter are likely to bring. forth metallic ores so that it would be promising and gainful to work them. It explains according to the best of my ability, in separate chapters, as much as you need to :know for your, chosen profession or business, about such things as the favorable characteristics of the terrain, the strike, and dip* and outcrop of veins in general, and also about each metal in particular. Young Knappius: † Then it will be explained to me logically in. this little book and I shall be given a reasonable understanding which mines can be worked gainfully so that my investment will not be wasted but will show a profit. Daniel: Everybody should, of course, use his intelligence and should educate himself well and diligently to become able to understand, [2]‡ as far as that is. possible, from what matter, by what means, and where metals are generated by. Nature; and as a mere side issue he should not spurn the profit that ensues there from. But if his aim is solely and predominantly profit and gain rather

Jan 1, 1949

By Andy Schroeder

Located in Hamilton, Ontario Canada, Berminghammer Foundation Equipment, is a manufacturer of advanced foundation equipment with 30 years of experience. The company is represented in more than 20 countries world wide, maintains an extensive Research and Development team, and has earned a reputation for finding the most practical solutions to the most challenging projects. The vertical travel lead, referred to as "VTL" system, was first developed and patented by C.W. Bermingham in the 1970's. This lead system was developed in response to the fundamental limitations of either a fixed lead or hanging lead system. The fixed lead system is well suited to level job sites with few obstructions and has the advantage of faster positioning of the lead, the hanging lead is very adaptable to different elevations and batter piles but takes much longer to position. Therefore the Vertical Travel Lead was developed to combine the advantages of fixed leads, fast and accurate positioning, with the ability to adjust the height of the lead base up or down. The VTL lead is connected to the boom by a sliding connection which allows the lead to be elevated or lowered below grade. The advantages of the VTL system were recognized by many foundation specialists and they have become the Industry standard in Canada , US Railway Construction , and many parts of the USA.

Jan 1, 1997

By Lance Rasband, Richard Hanke

"Seattle Tunnel Partners (STP) started mining on Seattle’s SR99 tunnel on July 30, 2013, working slowly through a 15 ft (4.6 m) thick fiber-reinforced concrete headwall. Once through the headwall, the machine would move through roughly 400 lineal ft (122 m) of jet grout-improved soil at a rate slightly over 6 ft (1.8 m) per day. It was anticipated that once through the improved area, Bertha—the world’s largest tunnel boring machine—would move at a rate of 35 ft (10.7 m) per day. By the end of October 2013, Bertha had mined roughly 430 ft (131 m), averaging 4.73 ft (1.4 m) per day, and had begun mining within native soils. By the start of December 2013, tunneling reached the 800 ft (244 m) mark and Bertha averaged 12 ft (3.7 m) per day, achieving as much as 42 ft (12.8 m) of progress on some days. However, on December 6, 2013, Bertha began to stumble and all progress quickly came to a halt. Preliminary InvestigationInitial reports stated that an obstruction had stopped the machine in its tracks. Malcolm Drilling received an early morning call on Sunday, December 8, 2013, from STP to rapidly mobilize a Bauer BG-50 drill rig with crews to investigate what was hindering Bertha’s progress. Malcolm’s equipment and crews flew into action and were completely mobilized and operational by mid-week. The preliminary investigation involved installation of 10 deep dewatering wells to reduce the hydrostatic head within the ground around the machine and allow STP personnel to inspect the cutter head from within the shaft for presence of obstructions. By the close of December 2013, the wells were installed and the dewatering system was fully commissioned. STP crews were then able to inspect the cutter head and found small fragments of a steel pipe wrapped around the outside of the shield. The steel was apparently from an abandoned 10 in (0.25 m) diameter monitoring well casing previously installed by WSDOT (Washington State Department of Transportation) to monitor groundwater conditions for the design and planning of this very project. After the steel was cut out of the head and cleared from Bertha’s path, she attempted to move forward but was only able to manage a slow crawl"

Jan 1, 2015

By J. Piper

Markets and Production Beryllium (Be), an extremely light metal, is used in many specialty applications. It the lightest element in Group 2A of the periodic table, with a specific gravity of 1.85 gm/cc, and a high melting point of 12850C (Calvert, 2004). The functional properties of beryllium are stiffness, strength, dimensional stability, resistance to corrosion from acids, and electrical and thermal conductivity. The ability to reflect neutrons and transmit x-rays, makes beryllium irreplaceable in uses such as precision optical components, inertial guidance systems, and in nuclear reactors (Anon, 1993). Beryllium is used in Cu alloys to strengthen and reduce corrosion in copper wire, and in lightweight oxide ceramics that are used as heat sinks, and as electrical insulators. The market revenue of beryllium can be broken down into the seven major groups below, and are plotted on the pie chart in Figure 1 (Anon, 2005). 1.) Telecommunications & Computer 2.) Magnetic & Optical Data Storage 3.) Aerospace and Defense 4.) Automotive Electronics 5.) Industrial Components 6.) Appliance, and 7.) Other.

Jan 1, 2007

By G. B. Sazuyer

DEVELOPMENTS respecting beryllium during the past year have been sufficient to center attention on it as likely to be the most important of any of the chemical elements that have recently found a place for themselves in technical industry. This importance is only potential, however, largely because adequate supplies of beryllium ore will be necessary. The beryllium industry will be only as great as the mines which support it. To find and develop large mines will be the problem. Chief of the immediate commercial developments in the United States is beryllium-copper and its espousal by Anaconda and Riverside even at present high prices. According to the pamphlets of these companies, it ap¬pears that beryllium is to copper nearly what carbon is to iron. When one considers that the tensile strength of pure copper is about 33,000 lb. per sq. in., but that the addition of 1.5 to 2.5 per cent of beryllium produces a heat-treatable alloy with a maximum tensile strength of 220,000 lb. or over, the analogy to carbon and iron is made strikingly, clear. Striking among the properties of beryllium-copper is its resistance to fatigue, claimed to be equal or superior to that of spring steel. It needs little imagination to foresee a great industry for this alloy alone.

Jan 1, 1934

By Deborah A. Kramer

Although beryllium was initially discovered in 1797, it was not until 1916 that the first significant quantity of beryllium metal ingot was produced in the United States. Before 1940, most of the small quantity of beryllium metal used in the United States was supplied by Germany. Beryllium was not used in its metallic form; it was used as an alloying addition to other metals, mainly copper and nickel. World consumption of beryllium at that time was estimated to be a few hundred kilograms annually. Because of increased tensions in Europe before World War II, imports of metal from Germany ceased in 1940, and domestic production was required to meet the needs of the military. As a result, by 1946, the United States became the principal supplier of beryllium products for the world, a condition that prevails today. Because of beryllium's high strength, light weight, and high thermal conductivity, it has been used in a large number of industrial and defense applications as a metal, alloy, and oxide. The United States is the only country other than China and the former USSR currently producing beryllium products from beryllium ores and concentrates. Bertrandite, mined in Utah, is the principal ore source of domestically produced products. Imported ore, mainly from Brazil, supplements domestic ore supplies. Production and consumption data for the United States is shown in [Figs. 1 and 2]. Production data for 1969-1979 is withheld to avoid disclosing company proprietary data.

Jan 1, 1994

By W. H., Bassett

IN January, 1926, the writer began a study of the commercial value of beryllium in its relation to copper. The purpose of the investigation was not to make a mere laboratory study of the characteristics of beryllium-copper alloys, but to determine under mill conditions the behavior of copper when alloyed with beryllium and when other metals were added to such alloys; in other words, it was considered important to know whether the alloy bars could be hot-rolled or cold-worked, and what limits in composition would have to be established for these two methods of working. Consequently, more stress has been placed on the practical application of the alloys in engineering and commercial use than on a discussion of the metallography of the specimens examined, although this part of the matter has not been entirely neglected. Credit should be first given to G. Oesterheld,1 who, in 1916, published the copper-beryllium equilibrium diagram. Fig. 1 has been copied from the original article with the simple substitution of English words. It will be noted from Fig. 1 that alpha solid solutions are formed, up to about 1.5 per cent. Be (10.5 atom.). The freezing-point curve, after falling from 4.2 per cent. Be (23.5 atom.), enters into a very complicated form over the entire beta region. There is a possible compound, Cu2Be, at about 6.5 per cent. Be (32.3 atom.). The pure gamma range extends from 11.2 to 12.2 per cent. Be. (46.5 to 49 atom.), after which the liquidus rises rapidly to 30 per cent. Be. (75 atom.). The delta solution extends from 25 per cent. to an unknown percentage of beryllium. There is a eutectoid point at 575" C., extending from 1.5 to 11.2 per cent. Be., the maximum time interval of which occurs at 6 per cent. Be. Below this line the beta solution is described as breaking up into alpha and gamma. Microscopically, the eutectiferous alloy thus formed closely resembles pearlite, and requires a high magnification for its resolution.

Jan 1, 1927

By AIME AIME

BERYLLIUM is one of the most interesting of the minor metals and distinctly a modern development, for until the last two decades it had practically no commercial importance whatever. Then it was discovered that when small quantities of it were alloyed with copper, a copper alloy of unusual and valuable qualities resulted. This is by far its major use-in the manufacture of strong, heat-treated copper-base alloys in which the beryllium content varies from about 0.3 to 2.5 per cent. Its second most important use, though much smaller, is in the form of oxide or other nonmetallic products in the fluorescent lamp, X-ray, cathode ray, and television industries. Certain beryllium salts have the quality, in common with several other materials, of transforming short-wave radiation and cathode rays to visible radiation. Such materials are commonly known as phosphors, and the beryllium salts are the most important phosphors now in use. The third largest use for beryllium is for ceramics, including refractories. Beryllium is also used in small quantities in the form of the metal itself.

Jan 1, 1943

By W. H. Bassett

BERYLLIUM was discovered in 1798 by Vauquelin and the metal was first produced by Wohler in 1828 about a year later than his production of metallic aluminum. Beryllium remained dormant until about 1920 when the production of the metal by the electrolysis of a molten bath was carried out by Stock in Germany, closely followed by Dickinson in the United States and by Vivian in England. This may not have been the first time the electrolytic method was thus used but was the beginning of present-day methods. I believe the first commercial attempts in this country started with the Kemet Laboratories about 1924. Siemens & Halske in Germany were working on the same problem at about the same time. The work of the Kemet Laboratories was transferred to the Beryllium Company of America and later to the Beryllium Development Corporation. In 1926 1 made a considerable study of the beryllium¬copper alloys, using beryllium purchased from the Beryllium Company of America, and read a paper on this subject at the February, 1927, meeting of the A.I.M.E. However, I failed at that time to discover the properties of precipitation hardening which such alloys have in a very marked degree. After this publication the work on beryllium-copper alloys rested awhile. One cause for this was the difficulty of securing a supply of beryllium-at least at what might be considered a reasonable price. In 1926 the price was $200 per lb., a figure which held about the same both in this country and in Germany until the beginning of 1932, when it was offered here at $50 per lb. if taken in the form of a copper alloy which carried about 121/2 per cent beryllium. Somewhat later the 121/2 per cent alloy dropped to $25 per lb. of beryllium contained, which is the present price. Promise is made that with a greater consumption, production on a larger scale warrants a reduction in price to $10 per pound or less.

Jan 1, 1933

By Robert Forsyth

IN working the Bessemer process, the bottom of the converter has always been a source of trouble and annoyance, and the subject of more experiments, probably, than any other part of the complex mechanism called a Bessemer plant. This will not appear remark- able when the duties this important piece of refractory material has to perform are taken into consideration. In the first place, by means of the tuyeres, it delivers at a high pressure the air necessary for the conversion of the bath of metal, and has then to resist the intense

Jan 1, 1876

By J. S. Fox

"Besshi-type Cu-Zn (-Ag-A u ± Co) deposits are tabular, stratiform volcanogenic sulphide bodies which are usually associated with mafic volcanic rocks of oceanic or intra-plate geochemistry, but which can also be found locally with ultramafic volcanics or subvolcanic mafic intrusions. A thick sequence of continentally-derived clastic sediment usually encloses both the mafic volcanics and the ore. Besshi-type deposits form subaqueously, in epicratonic rifting environments, more-or-less proximally, and as a result of hydrothermal convection in their subjacent mafic volcanic - clastic sedimentary piles. They belong to a rift -related metallogenic spectrum that includes sediment-hosted and Cyprus-type base metal deposits, and may diller genetically from these mainly with respect to rate and degree of crustal extension. Modern analogues to these deposits are f ound in the submarine volcanogenic sinters of the Gulf of California rift system.The associated lithologies and tectonic selling of Besshi-type deposits clearly distinguish them from Kuroko-type ores. This difference also seems to be reflected in their lead isotopic character. For example, leads from Besshi-type deposits in the Sanbagawa belt of Japan and from the Blue Ridge belt of southeastern U.S.A. lie on extended anomalous lead lines and have lowslopes in 207Pb/204 Pb - 206Pb/ 204 Pbspace (Sato and Sasaki, 1980; Leriuray, 1982), wheras those from most Kurokotype mining districts exhibit only narrow isotopic ranges and lie near or on the orogene growth curve (e.g. , Franklin et a I., 1981). More over, where Besshi- and Kuroko-type deposits are found in the same orogene, the former often occur earlier in the tectonic cycle than the tatter (e.g., Japan, the Norwegian Caledonides, the southern Appalachians and south-central Finland).Besshi-type deposits are not confined to any particular part of the world, or to any geological epoch. Moreover, in many mineralized belts, Besshi-type deposits are the predominant volcanogenic ore type. On a world-wide scale, deposits of this type therefore constitute an important base metal resource."

Jan 1, 1984

By D. J. Zuliani

A mass and energy balance for a modern electric arc furnace ("EAF") indicates that about 70% of the process energy losses are contained in the off-gas as chemical energy in the form of uncombusted CO and H2 and as thermal energy. Given the magnitude of the off-gas energy losses, improved EAF energy efficiency needs to focus first on controlling furnace practice to maximize "in-EAF" energy utilization and second, on recovering residual energy in the off-gas existing in the fume system. This paper focuses on the application of off-gas analyzers, sensors and process models to control and optimize "in-EAF" energy utilization efficiency. The paper will also discuss the application of heat recovery technology to EAF steelmaking.

Jan 1, 2015