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By C. O. Campbell

THE recognition by C. W. McKee, field engineer for Springer Sturgeon Gold Mines, Limited, in the fall of 1940, of the economic possibilities of a small outcrop of baryres near Pembroke, in Hants county, Nova Scotia, followed by aggressive exploration and development by the Company, has placed Canada for the first time in its history in the position of becoming a major producer of barytes and its products. In past years, production of this mineral in Canada has been unimportant. Thus the coral output from 1885 ro 1933, inclusive, amounted to only 41,027 short tons, following which there was no production until 1939. Deposits in Nova Scotia, and particularly in the Lake Ainslie district, Cape Breton, have been the main source of supply, with a production between 1866 and 1925 of 31,689 tons. Following the examination of the outcrop of baryres near Pembroke by Mr. C. W. McKee in October, 1940, the area surrounding it was trenched, and, as this work gave encouraging results, a diamond drilling programme was commenced. A grid system was laid our and sixteen holes aggregating 2809.3 feet were put down, spaced at 100-foot intervals, the deepest hole being 300 feet. This drilling outlined a body of high-grade baryres over 600 feet long and 200 to 250 feet wide, with an average depth of 120 feet and estimated to contain well over one million tons of ore. The limits of the body were reached on the west, north, and southwest, but the drilling was suspended before the eastern limit was determined. Quarrying operations, and construction of a 100-ton mill, were commenced in February, 1941. The mill was placed in operation on May 29th, and on June 15th, eight months after the initial discovery, the first shipment of 2,500 long rons of milled baryres was made to Trinidad, British West Indies.

Jan 1, 1942

By Geo. A. Wells

Abstract The consumption of barytes in certain paints polyurethane foams, seamless, flooring, glass, brake linings, plastisol caskets for food containers and in fluids used for gastrointestinal X-ray examinations rely on tie unique properties of barium sulfate, There are no readily available mineral substitutes. Barytes are also the essential raw material for the manufacture of industrially important barium chemicals. High quality barite ore has become scarce throughout the world. Processing ore into quality end products is both capital and energy intensive. These factors have tended to limit availability and increase prices which have encouraged the use of alternates and restricted market growth.

Jan 1, 1980

By G. A. Wells

The consumption of barytes in certain paints, polyurethane foams, seamless flooring, glass, brake linings, plastisol gaskets for food containers, and in fluids used for gastrointestinal X-ray examinations relies on the unique properties of barium sulfate. There are no readily available mineral substitutes. Barytes are also the essential raw material for the manufacture of industrially important barium chemicals. High quality barite ore has become scarce throughout the world. Processing ore into quality end products is both capital and energy intensive. These factors have tended to limit availability and increase Prices which have encouraged the use of alternative or competitive materials and restricted market growth.

Jan 1, 1981

By John H. Fowler

"Barytes is one of the major components of drilling fluids used in oil and gas well-drilling. This mineral's close association with the petroleum industry bestows it with a commodity status not enjoyed by many other industrial minerals. Approximately 85% of world barytes production is used as a weighting agent in oil and gas well drilling while the remaining 15% is consumed mainly in the manufacture of barium chemicals, glass and as a pigment, filler or extender.Barytes mining began in Nova Scotia around 1865 and has continued until the present. Currently there are three barytes producers in the province one exporting pharmaceutical-grade barium sulphate and the other two supplying drilling mud-grade barytes to the offshore. Several barytes exploration and development programs are underway with excellent possibilities that Nova Scotia deposits will supply a significantly larger share of the drilling mud-grade barytes used in east coast drilling programs.Currently there is renewed interest in barytes activities in Nova Scotia because of its use as a weighting agent in drilling flu ids used in offshore oil and gas drilling programs.This paper reviews the use of barytes by the well drilling industry; outlines the history of barytes mining in the province, progressing to present-day exploration, development and production activities underway in Nova Scotia; and concludes with the market potential for Nova Scotia barytes."

Jan 1, 1986

By D. R. Boyle

"The basal type uranium deposits in south central British Columbia occur within unconsolidated, late Miocene fluvial paleochannel sediments that overlie major fault zones within the Okanagan Highlands Intrusive Complex. Prior to the formation of mineralization, paleovalleys containing host sediments were flooded by Pliocene valley basalts of the Plateau Basalt Formation. Five uranium deposits have been outlined to date, of which the Blizzard (4020 tonnes U) and TYee (650 tonnes U) are the largest. The basement intrusive complex underlying the deposits varies in age from early Cretaceous to Eocene and is comprised of quartz monzonite, granodiorite, Coryell monzonite, porphyritic granite and pegmatite.The mineralized host sediments comprise a complex sequence of interfingering conglomerates, arkosic sandstones and mudstones. Organic material is abundant in many, but not all, mineralized beds. Uranium mineralization is present in the form of uranous (ningyoite) or uranyl (saleeite, autunite) phosphates coating clastic grains and filling voids. Because of very strong reducing conditions related to large concentrations of marcasite and organic material, ningyoite is the only uranium mineral in the Tyee deposit, whereas the Blizzard deposit contains a more complex assemblage of minerals (saleeite, autunite, ningyoite). The observed paragenetic sequence of mineral precipitation in the Blizzard deposit (autunite-saleeite-ningyoite) indicates that the uranyl minerals, saleeite and autunite, are primary. Small amounts of Zn, Ni, Co and Mo have been introduced into the Blizzard deposit whereas Mo is the only non ore-forming element enriched in the Tyee deposit. Mn is the only depleted element in both deposits."

Jan 1, 1986

By Mark D. Hannington

Seafloor polymetallic sulfides have been found in diverse volcanic and tectonic settings on the ocean floor at water depths ranging from 3700 meters to <1500 meters. More than 100 occurrences of hydrothermal mineralization have been documented (including Fe-oxide deposits, Mn-crusts, metalliferous sediments, and massive sulfides), but high-temperature hydrothermal activity and large accumulations of polymetallic sulfides are known at fewer than 20 different sites. Chemical analyses of samples from these deposits indicate that they contain important concentrations of Cu, Zn, Ag, and Au, comparable to those of massive sulfide deposits on land. However, the lack of sufficient data concerning the distribution, size, and bulk composition of seafloor deposits precludes a meaningful assessment of their resource potential.

Jan 1, 1994

By W. J. Kingwell

My comments and questions are addressed to Mr. Troughton. It seems to me that the tests were very well tailored to determine long term effects on performance of bearing piles as groundwater pressures rise in the London Basin. This rise is being simulated by means of a groundwater recharge system but it would be informative to have further details of the controls of conditions simulated. Ideally the porewater pressure in Standpipes 1, 2 and 3 should be the same throughout the test. Under test conditions are there not practical dif­ficulties? Recharge Well C2 is a lesser dis­tance from the pile than the other wells. Was the rate of recharge to C2 regulated to a lesser rate than the other three? In my experience the rate of acceptance usually varies from well to well. Under a common feed pressure were mea­sures taken to compensate for this? Since the problem does not only affect London, but also Liverpool, Nottingham, Birmingham and to a lesser extent, Manchester, I question whether an ideal procedure is being used. It is well known that rates of acceptance decrease with time and often recharge wells need to be flushed out at regular intervals. Other pro­cedures may need to be adopted to accurately simulate the effect of groundwater rise, if tests of longer duration are to be considered.

Jan 1, 1991

By D. E. Sherwood

Twelve toe grouted, and eleven ungrouted piles, founded in very dense sands have been analysed to establish how toe grouting enhances pile performance. It is shown that pile stiffness is greatly increased, and that pile bases work effectively. This is in contrast to ungrouted piles, where some milli­meters of base movement may be required before the base is mobilised. Grouting appears to recover most of the disturbance caused during construc­tion, but in general does not enhance the ultimate bearing capacity of undisturbed ground.

Jan 1, 1989

By Jochen Petersen, Caroline Muzawazi

The technical feasibility of ammonia leaching of PGM bearing Platreef flotation concentrates was investigated as an alternative method for the recovery of base metals prior to precious metal recovery. The composition of the concentrates includes 2.02% Cu and 3.17% Ni, and the major base metal minerals are chalcopyrite and pentlandite. Optimal leaching conditions were initially established in shake flask experiments to be a solution containing 4 M NH4OH, 4 M (NH4)2CO3 and a pH range between 9 and 10. These were used as base case conditions in column and batch stirred tank reactor tests, where the effects of total ammonia concentration and operating temperature were explored further. At optimal conditions nearly 100% Cu and Ni extraction were obtained in the batch stirred tank reactor, and 95% Cu and 60% Ni extraction was obtained in columns. The activation energy for chalcopyrite and pentlandite was 36 kJ/mol and 16 kJ/mol, respectively, in both reactors, indicating different reaction pathways for the two minerals. Gas-liquid mass transfer appears to be the limiting reaction step in columns much more than in tanks, and the degree of ammonia loss to air is significant. This initial test work indicates the feasibility of using ammonia leaching for this and similar materials as an alternative route to conventional smelting and refining prior to PGM recovery, but a number of technical challenges still need to be overcome.

Jan 1, 2014

By M Fewings

This paper casts a light on the sometimes murky world that lies between base metals product æout the gateÆ, and money in the bank. Whether your base metals are leaving the mine as a refined product, or as an ore or concentrate, the generally accepted method of value determination is a London Metal Exchange price, usually measured at some point after the material has left your control. In this paper, the structure and operation, regulation and the reasons for the use of the London Metal Exchange are explored. In addition, the risks and opportunities that terminal market pricing provides to mine managers are explained, with particular reference to hedging. The paper also deals with the structure of the sales contract, including management of shipping issues, agreement of delivered quality, documentation and administrative issues. The selection of counterparties, the role of traders in the market and the growing influence of China and India as base metal consumers and competitors are also addressed.

Jan 1, 2006

By D. H. C. Wilton, W. A. Sears

"Abstract-The 682.8 ± 1.6 Ma Tickle Point Group consists mainly of rhyolite flows and tuffs with- in the Avalon Zone of the Appalachian Orogen in Newfoundland. Stratabound massive sulfide mineralization, consisting of pyrite, sphalerite, chalcopyrite and galena, occurs at the Winter Hill prospect, where a lower pyritic, Cu-rich zone and an upper Zn-Pb-rich zone are hosted by a carbonate-calc-silicate lens. At the Frenchman Head prospect, stringers of pyrite, minor sphalerite, chalcopyrite and rare galena are hosted by felsic volcanic rocks of the Tickle Point Group .Base metal ratios, metal zonations and the overall stratigraphic framework suggest that these sulfide occurrences represent volcanogenic massive to semi-massive sulfide mineralization (stringer type at Frenchman Head). As such these prospects represent the only known VMS occurrences within the Avalon Zone of Newfoundland. Pb isotope data indicate that galena from the Winter Hill prospect is less radiogenic and older than galena from Dunnage Zone occurrences, and suggest that the Winter Hill mineralization formed in an environment tectonically distinct (exotic) from the Dunnage Zone."

Jan 1, 1996

Base metal sulphide mineralisation on the northern end of Great Barrier Island is spatially associated with hypabyssal intermediate to acidic intrusives, in transgressive structures in indurated, complexly deformed greywackes and argillites. Copper predominates in the mineralisation, with minor accompanying lead and zinc and also some gold and silver. However, in some cases lead or zinc may be the dominant constituent. The mineralisation is generally characterised by only narrow envelopes of weak alteration (propyliticassemblages dominated by chlorite and epidote) and with only minor amounts of quartz accompanying the sulphides, which form a cement in zones of hydraulic fracturing. There are two distinct structural settings to the mineralisation: at MinerÆs Head, in a structurally complex situation in a shell-like zone of crackling in hornfelsed greywacke, in association with both north- and east-striking fractures and rubble breccias associated with the apical part of a large intrusive; and in very narrow, but very strike-persistent, 1inear steeply-dipping fracture zones, exposed on the north coast and inland areas near Tataweka.

Jan 1, 1984

By A. E. Aho

"The material presented in this paper will be subject to modification as new data become available, but it is presented in the hope that it will inspire more intensive mineral exploration and geologic studies of what appears to be one of Canada's richest mineral provinces. A metallogenic province 400 by 150 miles in extent, lying mostly northeast of Tintina trench, encompasses most of the base metal deposits of Yukon, as well as deposits of other metals. Its main features are northwesterly trending arcuate fold belts, with several orogenic axes, which include most of the metamorphosed rocks, granitic intrusives and mineralization; and which are modified by regional uplifts, northwest-striking fault trenches, and lesser transverse folding and faulting.The main base metal occurrences and their regional controls are summarized briefly. Most of the replacement-type deposits are localized in late Proterozoic to early Paleozoic rocks, particularly Lower Cambrian -probably because these are the most physically and chemically favourable hosts encountered in an appropriate temperature and pressure environment; perhaps because of early age of deposition. Most of the deposits also occur near heat sources or intrusives with associated structural uplift, which has, moreover, served to expose the older rocks. They also tend to occur near known or suspected regional fault trenches, such as Tintina, Macmillan and Hess, although this relationship may be fortuitous. In detail, they may be localized in fold axes, flat-lying beds or other appropriate structural traps. Vein-type deposits are fracture-controlled and localized by dilational localfties, the competence of wall rocks and ""damming"" effects.In the Anvil district, large stratiform iron-zinc-lead replacement deposits lie parallel to gently plunging flex-ures in phyllite in a zone parallel to the Tintina trench, along the southwest flank of the arch-like Anvil batholith. About 80 million tons of massive sulphide ore probably existed before erosion of the Faro orebody, the Vangorda deposit could have been of similar magnitude before erosion and much more tonnage probably remains to be discovered in the district. The Anvil deposits may differ from others found to date in Yukon, but resemble the Sullivan orebody of southeastern British Columbia in their large size, localization in essentially non-limy peptic to arena-ceous host rocks of Proterozoic or early Paleozoic age and proximity to the Rocky Mountain -Tintina trench sys-tem. These features suggest an origin from primordial subcrustal sources.More major ore deposits, not only of lead, zinc and copper but probably of other metals as well, will no doubt be found in similar environments in Yukon or Alaska. Thus, the base metal province of Yukon offers challenging opportunities for prospecting, development, field studies and basic research."

Jan 1, 1969

By M. Pelegrin Rodríguez, J. Castellanos Suarez, R. Causse Miyares, A. Mosqueda Martínez, Rubén Aja

"This paper will describe the methods and the results of studies to integrate polymetallic nodule extractive metallurgy methods into existing and operating technologies or plants with the aim of reducing the capital cost of deep-sea mining challenges and to streamline the supply chain of raw materials where such opportunities exist (Moa Bay and others). It will also assess the possibility to carry out pre-industrial processing operations with productivity corresponding to pilot mining operation in the Clarion Clipperton Fracture Zone (5–10% of assumed annual production) with the use of existing facilities. The present study shows the results of high pressure acid leaching of polymetallic nodules (PN) mixed with laterite non-commercial ore. It also presents PN processing in the presence of ammoniacal tailings obtained from the Caron process. The experiments were carried out according to 24 full factorial design. The regression equations were determined for extractions of Ni, Co, Cu, Zn, Fe and Mn. The obtained results show that increasing temperature, the acid/ mineral ratio and the leaching time have a positive and significant effect on extraction of all the studied metals. However, increasing the tailings addition favors the extraction of the Co, Zn and Mn. The extraction of Fe diminishes, while the extraction of Ni is not affected. In the following conditions; 180 min, 260°C, 0.5 kg acid /kg minerals and 2.5 kg PN/kg tailing; the following extractions were achieved; 96% Ni, 90% Co, 97% Cu, 99.9% Zn, 43% Mn and 26% Fe."

Jan 1, 2017

Base metal skarns have provided most of South KoreaÆs Pb-Zn production since the end of the Korean War, with the bulk of production coming from the Yeonwha group of mines. Currently only the Kumho Zn-Pb mine remains in production, while magnetite skarns are mined as iron ore at the old Yomisan and Ulsan base metal deposits. Base metal skarns within Korea fall into two groups; those hosted in Cambro-Ordovician limestone sequences, situated mainly in sub-basins in the northeast of the peninsula and those hosted within carbonate volcaniclastics of the Cretaceous Gyeongsang Basin, in the southeast. Sulphide mineralisation is dominated by sphalerite, lesser galena, arsenopyrite and pyrrhotite, with subordinate chalcopyrite and molybdenite with Ag-Co credits. Skarns are composed of pyroxene-clinopyroxene-garnet-carbonate-quartz and magnetite, grading into silica-chlorite hornfels. Most of the significant deposits display both pipe-like and stratabound morphology. In the Hwanggang district, a zoned distribution of Ordovician carbonate hosted, polymetallic Mo-W and Zn-Pb-Cu-Ag base metal deposits is observed around the margin of a Cretaceous granite intrusion. Similar polymetallic zoning is recognised in the Sangdong district, where deposits include Sangdong (W), Abisan (Au-As) and Yomisan Northwest (Zn-Mo) and Yomisan Southeast (Zn-Cu-Co), hosted in Ordovician carbonates in proximity to Cretaceous quartz porphyry intrusives. The Taebaeksan district hosts the largest deposits at the Yeonwha group of mines. Although production ceased in 1993, significant resources remain, hosted in Ordovician limestone and dolomite that have been intruded by Cretaceous quartz porphyry dykes. Deposits in the Cretaceous Gyeongsang Basin consist of bedding concordant, vertically stacked base metal skarn mineralisation at several stratigraphic horizons, connected by carbonate-base metal veins with a pipe-like geometry. Evidence such as massive sulphide layers and restricted proximal carbonates suggest mineralisation was initially partly syn-depositional, with both base metals and carbonate venting onto a lake floor, being reconstituted to skarns by later magmatic activity. Skarn mineralisation is universally closely associated with the Cretaceous Bulgugsa Series acid intrusive activity. A common intrusive-structural relationship is recognised at some deposits, with bedding plane and imbricate thrust faulting, introducing felsic intrusives as sills. These intrusions probably introduced the base metals, carbonate, boron, heat and silica, which metasomatically reconstituted the carbonate lithologies to form skarn assemblages. The Korean base metal skarn deposits are regarded as Zn-Pb chimney-manto skarns and display similarities to the Mexican manto type deposits.

Jan 1, 1999

By J. M. Gregg, C. J. Persellin, I. D. Somerville, E. A. Atekwana, K. L. Shelton

"Zn-Pb sulfide mineralization at Abbeytown mine and Twigspark quarry comprise the only known car¬bonate-hosted base metal sulfide deposits in the Sligo syncline, northwest Ireland. Limestone sedimentation occurred uniformly throughout the region during the Early Carboniferous (Mississippian) as observed by field relationships and lithofacies; however, petrographic and stable isotope evidence indicate that host-rock dolomitization occurred under different conditions at localities to the west and east of the Ox Mountains inlier, suggesting significant uplift and geologic isolation of these areas prior to dolomitization. Localized fluid flow systems are thought to be responsible for sulfide mineralization and associated epigenetic carbonate cements. West of the Ox Mountains inlier at Abbeytown, evidence of three geochemically distinct fluids are observed: (1) a lower-temperature, lower-salinity fluid (70°-130-°C, 4-9 wt.% equiv. NaCl); (2) a lower-temperature, higher-salinity fluid (70°-140°C, 15-24 wt.% equiv. NaCl); and (3) a higher-temperature, moderate-salinity fluid (165°-220°C, 8-14 wt.% equiv. NaCl). Similar fluid types were observed at the Twigspark deposit. The source of the higher-salinity fluid is likely seawater evaporated to near the point of halite precipitation. The higher-temperature fluid is thought to have been derived from deep circulation of basinal brines. It is speculated that mixing of the higher-salinity fluid with the high-temperature fluid was vital for ore formation at Abbeytown because fluid inclusions in sphalerite have homogenization temperatures and salinity values that fall along a mixing trajectory of these end member fluids. Also, areas where the high-salinity end member fluid is absent are barren of sulfides. Less complex fluid systems are indicated for sites east of the Ox Mountains inlier where no sulfide mineralization was observed. Data from base metal sulfide prospects in northwest Ireland indicate no connection with the regionally extensive flow system thought to be responsible for Zn-Pb deposits throughout the Irish Midlands.Les minéralisations en sulfures de Zn-Pb de la mine Abbeytown et de la carrière Twigspark sont les seules gîtes de métaux usuels à encaissant carbonaté connus dans le synclinal de Sligo, au nord-ouest de l’Irlande. Ces carbonates se sont déposés d’une manière uniforme dans la région au Carbonifère inférieur (Mississippien) tel que l’indiquent les relations de terrain et les lithofaçiès; les données pétrographiques et d’isotopes stables indiquent toutefois que la dolomitisation de l’encaissant s’est faite sous des conditions différentes aux localités situées à l’ouest ou à l’est de la boutonnière des Ox Mountains, ce qui suggère un soulèvement et une isolation géologique significative de ces secteurs avant la dolomitisation. L’action de systèmes de circulation locaux sont considérés être à l’origine de la minéralisation sulfurée et des ciments carbonatés épigénétiques qui leur sont associés. À Abbeytown, à l’ouest de la boutonnière des Ox Mountains, on note les effets de trois fluides géochimiquement distincts: (1) un fluide à basse température peu salin (70°-130°C, 4-9% poids équivalent NaCl); (2) un fluide à basse température fortement salin (70°-140°C, 15-24% poids équivalent NaCl); and (3) un fluide formé à plus haute température et salinité modérée (165°-220°C, 8-14% poids équivalent NaCl). Des fluides similaires ont été observés au gîte Twigspark. La source présumée du fluide le plus salin est de l’eau de mer amenée par évaporation près du point de précipitation de la halite. Le fluide à plus haute température est probablement dérivé de la circulation profonde de saumures dérivées d’un bas¬sin sédimentaire. Il est possible que le mélange du fluide à haute salinité avec celui à haute température ait joué un rôle central dans la genèse de la minéralisation d’Abbeytown parce que les températures d’homogénéisation et les valeurs de salinité des inclusions fluide"

Jan 1, 2009

By S E. Munro, P D. Munro

The commonly traded base metals concentrates of copper, lead, tin and zinc are sold by miners to custom smelters using contracts whose terms were generally established at the beginning of the 20th century or even earlier. Technical clauses in these concentrates for items such as payable metals and penalty elements do not reflect current realities of extractive metallurgical technologies and hygiene/environmental issues.It is an axiom that the miners and smelters have a symbiotic relationship. While the existing antique and arcane commercial arrangements serve the purpose of transferring money from the buyer to the seller, they are not likely to result in the industry achieving better overall technical and economic outcomes. By examining the cases for copper concentrates and zinc concentrates in particular, it will be shown that the practical application of these antiquated technical clauses does not drive the miners to produce the better quality concentrates that should be desired by the smelters. This is despite development of mineral beneficiation and hydrometallurgical technologies that would allow the miners to make better products.The adage that any extractive metallurgical problem in the smelter is cheaper to solve in the concentrator still generally holds.While nickel concentrates are only touched on lightly in this discussion because sales terms are more opaque than those for the other base metals, it is expected that the same conclusions will apply.CITATION:Munro, P D and Munro, S E, 2015. Base metals concentrate sales contracts – change Pavlov and the dog, in Proceedings MetPlant 2015, pp 46–60 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 7, 2015

Flue dust from the sintering of base metal sulphides was leached to remove cadmium and arsenic. Leach liquor contained cadmium, zinc and small amounts of other base metals as chlorides. Results are reported of the use of a cation exchange resin Zeocarb 225 to separate the base metals from the arsenic. The resin was eluted with sodium chloride or sulphate to give a solution of relatively concentrated cadmium suitable for recovery by zinc cementation. The limited solubility of sodium sulphate presented some practical problems which were investigated. Another problem was the precipitation of lead sulphate in the resin during elution.INTRODUCTIONWhen lead-zinc sulphides are sintered prior to smelting, the gases passing to the flue are mainly uncondensable but contain a certain proportion of sublimates and dust particles which deposit in the flue or are carried, after condensation in the gas stream, to some form of dust extraction equipment.The recovered dust is a complex mixture of base metal sulphates, sulphites, sulphides, chlorides and oxides, the composition depending on the original concentrates. A large proportion of the cadmium and some of the arsenic originally in the concentrates finds its way to this flue dust, the treatment of which can be a convenient means of removing these elements and controlling their concentrations in the main lead-zinc smelter circuit. However, disposing of this material represents an appreciable waste of base metals as well as a serious toxicity hazard.Sulphide Corporation Pty. Ltd. was faced with this problem in planning the flow sheet of the new lead-zinc smelter at Cockle Creek, N.S.W. From a test run carried out on a pilot plant at Avonmouth, U.K., using a mixture of lead and zinc concentrates, a sample of dust was obtained for...

Jan 1, 1960

The heap leaching of base metal ores can be applied within a number of different scenarios, each requiring its own set of parameters to be determined during the metallurgical testwork programme. The occurrence of acid-gangue reactions and its concomitant precipitation reactions is a factor common to all cases, and requires that the optimal irrigation acid strength be found that optimises the combination of extraction kinetics, acid consumption and possible premature blinding of the heap due to precipitation reactions. For the heap bioleaching of base metal sulphide ores the oxygen requirement needs to be determined for the design of the aeration system, and the operating conditions employed need to also facilitate bacterial growth over and above the acid strength optimisation mentioned above. For the heap bioleaching of chalcopyrite, the need to preserve heat in the heap becomes yet a further parameter of critical importance. For the heap leaching of uranium ore a choice is required between either chemical or bacterial oxidation, based on economic and processing factors. Frequently the operating parameters need to be determined for a circuit in which heap leaching is combined with tank leaching and/or pressure leaching. The processing implications and metallurgical testwork approach for each case is discussed.

Jan 1, 2007

By Yannick Beaudoin

The source of base metals in modern seafloor hydrothermal systems can be attributed to leaching of host rocks by hydrothermal fluids and/or potentially by direct degassing of magma. From an economic perspective, metal grade is the most important consideration for seafloor deposits. Tectonic setting appears to be a key factor influencing the development of high grade seafloor base metal sulfide deposits. Back-arcs have a clear advantage over other settings in producing large and rich polymetallic sulfide ores. Microinclusions of magma or so-called melt inclusions trapped in phenocrysts of lavas have contributed to our understanding of the ore-forming process. n this study, we present data from 103 melt inclusions mainly in plagioclase crystals hosted in basaltic to rhyolitic lavas from 9 modern seafloor tectonic settings: oceanic back-arcs (Manus Basin including an ODP Leg 193 drill hole, Bransfield Straits), continental back-arc (Okinawa Trough), mid-ocean ridges (Explorer, MAR), seamounts (Foundation, Axial, Pito), and a transform (Garrett). Most sites host active hydrothermal systems that are producing polymetallic sulfides.

Jan 1, 2005