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By Enzo Palumbo, Joël P. T. Kapusta, François Larouche

In light of the rapid deployment of bottom blowing smelting in China over the last ten years, one has to wonder why it has taken the copper industry so long to adopt ultra-high oxygen enrichment via Savard-Lee type injectors. As early as 1976, Kellogg and Henderson suggested, in their landmark paper on energy usage in the copper industry, that ‘maximum use of oxygen enrichment of process air’ was one of seven ‘energy saving features’ for copper matte smelting and converting. Yet today, shrouded injection and high oxygen enrichment has not been implemented in copper bath smelting outside China and Vietnam. In this paper, the authors explore the reasons why bath smelting processes such as the Noranda Reactor and the Teniente Converter still operate around 40% oxygen enrichment, while the bottom blowing SKS/BBS process typically runs at 65 to 75% oxygen, with all three processes producing white metal. Are there fundamental metallurgical explanations for this striking difference beyond the long-standing skepticism towards high oxygen shrouded injection and its perceived high implementation cost?

Jan 1, 2015

By Ricardo Boullosa R.

De acuerdo a la ley de presupuesto, aquellas empresas mineras donde el Estado participa, están obligadas a adquirir bienes a través de licitaciones. En este sentido, si anteriormente la decisión se limitaba a evaluaciones técnico económicas, las cuales optimizaban la relación costo-beneficio, ahora se rige por dispositivos legales que se relacionaban con ciertas adquisiciones. Por tal motivo, el presente texto señala los posibles inconvenientes que genera la adquisición de equipos por el proceso de licitaciones, dado que estas se delimitan a la producción y no son aptas por el Gobierno para su habilitación, pese a estar avalados por estudios técnicos.

Nov 8, 1984

By Dwayne D. Tannant

The Adra tunnel near Naramata BC experienced a fire in 2010 that burned timber sets within the tunnel and caused severe spalling of rock from the roof and tunnel walls. The nature of the damage is documented and efforts completed to rehabilitate and open a portion of this tunnel to the public are described. The use of shortcrete and rock bolts is a technically and economically superior support system to timber sets as well as being far more fire resistant.

Jun 1, 2012

By Saul Escalara

Data on sulfonate adsorption by silicate minerals are very scarce in the literatures. Perhaps the only comprehensive paper written on the topic was done by Fuerstenau and Bhappu (1); this work dealt exclusively with quartz but included many important suggestions as to the form and nature of the hydroxy-sulfonate species of some cations formed during the conditioning step and their effect on the flotation response of quartz. Another paper by the same authors (2) contains additional data on the role of hydrolysis in sulfonate flotation of beryl. As postulated by Fuerstenau and Bhappu, a solid form of cationic sulfonate functions as the collecting species to produce flotation of quartz and beryl. According to the authors, the solid compound is a hydroxy-sulfonate of a given cation, where the hydrogen of the hydroxyl part provides a means for bonding of the species to the mineral surface; thus, the presence of hydroxyl in the neutral precipitated compound is of primary importance to produce flotation. Although the preceding examples illustrate the effect of a sulfonate collector in silicate systems other than plagioclases, they are important as examples of processes of hydroxy-sulfonate complex formation. Since the plagioclase minerals con¬tain Ca(II) and Al(III) cations, which are very reactive in sulfonate media (1), the formation of hydroxy-sulfonate compounds with these cations released from the solid phase may well prove to be the cause for their flotation.

Jan 1, 1973

By W. M. Cross

The hydrophobic character of sapphire surfaces in SDS solutions was examined with respect to the aggregative nature of the adsorbed surfactant phase. It was found that, at equilibrium, sapphire surfaces having adsorbed SDS bi-layers exhibited no contact angle. Conversely, when the adsorbed SDS was found to be mi-cellar in nature, sapphire surfaces developed significant hydrophobic character. The surface states as detected by Fr -IRIIRS conformational analysis were found to be reversible with temperature. The variation in adsorption density with temperature was studied by in situ Fr-IRIIRS. The isosteric heat of adsorption was calculated to be -1.6 kcal/mole. Although the adsorbed SDS was found to undergo a reversible phase change between 25 and 32°C, similar to SDS in solution, the extent of adsorption was not reversible with temperature.

Jan 1, 1993

By M. K. Aydogan

Today, arsenic has become a much greater problem than before because of the limitations introduced by WHO and USEPA that are lowered from 0.05 ppm to 0.01 ppm. In the nature Arsenic is mostly found as inorganic compounds in the forms of arsenite (As+3) and arsenate (As+5) in aqueous solutions. Arsenic contamination in ground and surface waters has been encountered in almost every country. This element has a carcinogenic effect and can occur in natural sources and anthropogenic sources such as metal mining, groundwater usage and industrial activities. In this study adsorbing colloid flotation was applied in the presence of aluminum sulfates. In the experiments SDS and K-Oleate were used as collectors while MIBC was the frother employed. The effects of collectors and aluminum/arsenic ratios on the removal of arsenic were examined under various pH values. It was found that arsenic removal enhanced with increasing aluminum concentration. Furthermore, it was observed that pH was a very critical parameter in all experiments. The best results were obtained when initial As: SDS: Al concentrations were 10:40:40 ppm at pH 5.5. At this concentration, the efficiency of arsenic removal found to be 99.9%. Keywords: arsenic, adsorbing colloid flotation, aluminum sulfate

Sep 1, 2012

By Fathi Habashi

THE UNIT process of adsorption involves two steps: 1) Loading of the adsorbent. 2) Recovery of metal values from the adsorbent. Charcoal is the adsorbent commonly used in extractive metallurgy. The discovery of the adsorptive power of charcoal from solutions is generally accredited to Lowitz (1785), who observed that several dissolved organic substances were precipitated on charcoal. Graham was the first to demonstrate that inorganic substances were also adsorbed on charcoal. In 1830, he reported that iodine dissolved in KI solution was adsorbed on charcoal. Also calcium ions were adsorbed from limewater, as were lead ions from lead nitrate solution. The use of charcoal in metallurgy was first applied

Jan 1, 1970

Results of investigations on adsorption and desorption of CO M CH and a mixture of the two gases are described.4 Results showed that even when the equilibrium conditions contains 50% Co and 50% CH4, the gas emission in the initia' stages will contain as much as 80% CH . 4 The temperature has a small effect and so also particle size for 1.4-11.2mm. The ratio of CO2/CH gases adsorbed in coal samples depends upon t4he equilibrium pressure and this ratio decreases with pressure. Results of field tests support laboratory studies.

Jan 1, 1988

The paper describes the studies conducted to date on the short term adsorption/desorption of gases in coal from the point of view of developing techniques to predict imminent outbursting conditions in coal mines. A number of different parameters such as'dP express, K' and AV 0/60 etc. which have been effectively used overseas were studied on samples of coal from Westcliff and Leichhardt Colliery. Results indicate that these do not seem to be valid indices for predicting an outbursting condition. Based upon desorption isotherms, a new index defined as "L" has been developed which shows promising results. This index is in a position to differentiate the changes in the structures of coal and its proness to outbursts. The "LZ value determinations and its usefulness opens a new field where it would be possible to determine outbursting conditions from existing drill cores obtained during exploration studies or from long holes drilled in advance from underground workings. The index is more or less independent of the time elapsed between the extraction of a sample and the conduct of the test. The test for "L" can be conducted'on site or in the laboratory. The test is simple, easy to carry out and the "L" value for a sample can be calculated in less than 20 minutes. It could be adapted as a routine test for monitoring outburst conditions in mines.

Jan 1, 1980

By E. Szelag

The adsorption and stabilization of mineral dispersed systems by using Pluronic copolymers with different molecular weights and EO content has been studied. The role of sequential adsorption of EO-PO copolymers and cationic surfactant (CTAB) on the carbonate particle properties and in determining the stability of their suspension was studied with particular attention to the conformation of the polymer at the solid-liquid interface. The purpose of this work was to investigate the flocculation phenomena, influence of polymer molecular size on stability of suspensions of magnesite and dolomite and the effect of addition mode of polymer and surfactant. The suspension stability measurements and the determination of sedimentation speed were carried out using an optical analyser (Turbiscan). In most of investigated cases, the biggest floccs and the fastest sedimentation were found for low concentrations of copolymers.

Jan 1, 2014

By Fazel G. Jahromi, Ahmad Ghahreman

"Several studies were performed on the atmospheric leaching of copper sulfide minerals in the presence of activated carbon and a new catalyst, AF 5. AF 5 is a carbon based catalyst with similar properties to those of activated carbon however much better mechanical properties. The activated carbon surface chemistry has been investigated in various studies; however the connection of the surface chemistry of activated carbon and AF 5 with the sulfide minerals during the atmospheric leaching process is not well-understood yet. Based on the surface analysis, AF 5 showed higher surface area than activated carbon (AC). Adsorption and oxidation of copper, arsenic and iron ions in the presence of different activated carbon were investigated. Adsorption properties of both catalysts were similar and 18-24% of iron, 12-18% of copper and 10% of arsenic adsorbed on the catalysts surface form 5 g/L Fe(III) and Cu(II) and 2 g/L As(III) at 80°C. In oxidation experiments, both catalysts reduced Fe(III) and Cu(II) ions and re-oxidized the reduced species in the presence of oxygen and oxidized As(III) ions. The addition of oxidizing ions can enhance the oxidation process kinetics and increase the catalytic capability of carbon.INTRODUCTION Hydrometallurgical processes of copper sulfide concentrates are under development and various different methods have been proposed to increase the atmospheric leaching rate of copper sulfide minerals. These methods include using different media, reagents, and catalysts. Among different methods, leaching of the copper sulfide minerals in the chloride media has some advantages over sulfate media. Smaller scale of operation, increased leaching rates, and lower sulfate formation are some of the benefits of the chloride leaching media over other similar media. Moreover, using ferric and cupric ions as oxidants and utilizing activated carbon as a catalyst has been proven to enhance the leaching rate of copper sulfide minerals effectively. Activated carbon (AC) and AF 5 (micro porous carbon based catalyst) are two of the most efficient and practical catalysts in copper sulfide leaching processes. AC can enhance the copper recovery of enargite in chloride media from 69% to 92% after 96 hours of leaching under the similar conditions (Jahromi & Ghahreman, 2016). It has been shown that AC at acidic pH can generate hydrogen peroxide in the presence of oxygen which can leach copper minerals (Ahmumada et al., 2002)."

Jan 1, 2017

By Qingzhu Li

The brewing industry byproduct, spent grain (SG), was evaluated for its ability to adsorb Ag(I) from aqueous solutions. Ag(I) adsorption was dependent on solution pH, contact time, adsorbent dose, initial Ag(I) concentration and temperature. The kinetic data were well described by pseudo-second-order kinetic model, indicating that chemical adsorption was the rate-controlling step. The equilibrium data followed Freundlich isotherm rather than Langmuir isotherm, suggesting heterogenity of the adsorption sites on spent grain. Ag(I) desorbed from Ag(I)-loaded spent grain was also evaluated in this study. HCl, NaOH, Na2S2O3 and ultrapure water were chosen as eluants and desorbed Ag(I)-loaded spent grain for 30min, Ag(I)-loaded spent grain desorbed in 0.1M Na2S2O3 exhibited higher elution efficiency as compared with other eluants. The results indicated that application of spent grain for adsorption and recovery of silver from aqueous solutions was feasible.

Jan 1, 2009

By A. M. Raichur, K. Keltner, M. Misra

The removal of oxyanions of arsenic present in mine process water and drinking water to a regulatory level (i.e. below 50 ppb) is a challenging problem. Conventional water treatment methods presently used for controlling arsenic have several drawbacks and limited success. A new adsorbent (LS™) developed at the University of Nevada, Reno, has strong specificity for both arsenate and arsenite species present in process waters. The adsorbent in very selective to oxyanions of arsenic and competition of other indifferent ions is minimum. Water samples from different sources were tested and arsenic was successfully removed to below 50 ppb. This paper describes both batch and packed column tests conducted in the laboratory as well as at the plant sites using LS™.

Jan 1, 1997

By A. W. Wensel

The adsorption behavior of sodium oleate on brucite, Mg (OH)2, has been studied by Fourier transform infrared spectroscopy. Both internal reflection and diffuse reflection (DRIFT) methods were used to characterize the adsorbed oleate on brucite. DRIFT measurements were shown to be quantitative, and an equilibrium adsorption isotherm was obtained. The conformational behavior of the adsorbed oleate was investigated as a function of adsorption density. It was found that at sub-monolayer coverage the alkyl chains of the adsorbed oleate had more ?gauche? character than at multi-layer coverages. Also, DRIFT spectra revealed that the adsorbed species were magnesium dioleate. For internal reflection measurements single crystals of MgO were hydrolyzed to form a thin Mg (OH)2 layer.

Jan 1, 1994

By D. Kang, K. N. Han

The adsorption behavior of silver in ammoniacal solutions on activated carbon was studied. In addition to the concentration of ammonia, the parameters that affect adsorption include temperature, degree of agitation and anion and cation concentrations. In the study, it was found that the adsorption of silver from ammoniacal solutions is dependent on the initial silver concentration in the solution. It was also found that the recovery of silver from ammoniacal solutions is not as effective us gold. The adsorption rate was relatively slow overall, despite a rapid initial adsorption. The apparent activation energy ,for the adsorption was measured at 30.2 kJ/mol. It was believed that the kinetics of the silver adsorption on activated carbon was limited by a mixed control mechanism.

Jan 1, 1999

By Y. Guan

The adsorption of zinc species onto silica in ammonical solutions has been studied. Adsorption isotherms reveal that increasing adsorption occurs as the solution pH is made more alkaline. Fr-IR spectroscopy revealed that the adsorbed species is a zinc ammine complex.

Jan 1, 1993

By S. Sheng, Y. G. Huang, W. Chai

"Polyacrylamide (PAM) is a typically synthetic depressant and may be used as a depressor of pyrite. The modification of polyacrylamide may improve its physicochemical properties and performances. Sulfonated polyacrylamides (SPAM) with different sulfonation degree (SD) were prepared using sodium sulfite as the sulfonating agent, and the interactions of SPAM and pyrite were investigated by the adsorption experiment in this work. The adsorption tests of SPAM on pyrite were conducted as a function of sulfonation degree, pH value and contact time. Pyrite and SPAM were constructed and optimized through MS software. The interaction mechanisms of sulfonated polyacrylamide and pyrite were simulated by molecular dynamics simulations. The results show that the adsorption capacities of SPAM at neutral and weak alkaline conditions are higher than that at acidic and strong basic conditions. The high sulfonation degree favors the adsorption of SPAM on pyrite surface. The adsorption process can be described best by the pseudo-second order kinetic model. Molecular dynamics simulations show that the adsorption of sulfonated polyacrylamide on pyrite is better than that of polyacrylamide. Sulfonated polyacrylamide can be used as a potential depressant of pyrite with the main interacting mechanism of hydrogenbond force.INTRODUCTIONPyrite is the most abundant sulfide mineral and often associated with valuable minerals such as galena, chalcopyrite, sphalerite, molybdenite, gold, diaspore as well as coal (Forrest et al., 2001; Jaiswal et al., 2015; Maier and Dobiáš, 1997; Qiu et al., 2017; Xin and Liye, 2010). Froth flotation is the most popular method to remove pyrite from valuable minerals. Pyrite could be floated as the flotation concentrate either by its hydrophobicity or activation by metal ions (Chandra and Gerson, 2009). What is more, pyrite could be seperated as flotation tailing by adding highly selective depressants including inorganic and organic modifiers. Polysaccharides polymers and lignosulfonate-based biopolymers are common natural organic depressants (Deng et al., 2017; Mu et al., 2016). While the synthetic organic products have proved to be particularly versatile in terms of molecule tailing capability and controlled structures (Boulton et al., 2001a; Raffa et al., 2015)."

Jan 1, 2018

Adsorption Behaviours of Humic Substances onto Iron Ore Particle Surface Humic substances extracted from lignite mainly consist of fulvic acids (FA) and humic acids (HA), which have been successfully used as good composite binders for iron ore pellets in laboratory tests and industrial production. However, there exists a general lack of understanding of the interaction between humic substances and iron ore particles surfaces. In this research, by means of zeta potential measurements, Fourier Transform Infrared (FTIR) spectrum, colorimetric method and Environmental Scanning Electron Micrograph (ESEM) imaging, the adsorption behaviours of FA and HA onto the surfaces of iron ore particles are investigated. The zeta potential results indicate that adsorption of FA on the iron ore particles can be characterised by specific and electrostatic interactions, while adsorption of HA is by electrostatic and chemical adsorption interactions. FTIR spectrum results show that adsorption force of FA on the iron ore particle surfaces is stronger than that of HA. From results of colorimetric method, compared with HA, adsorption amount and adsorption rate of FA is more and faster, respectively. FA molecule presents on the surface of magnetite in the shape of an araneose network structure according to the ESEM images, while HA molecule appears on the surface of magnetite in the form of small flocs or microclusters. Humic substances are effective to iron ore pelletisation. Comparsion of agglomeration results show that the different mechanisms of adsorption result in varied agglomeration behaviours. Theses findings above would be beneficial to the implications of composite binder for agglomeration.  

Sep 13, 2010

By A. M. L. Cushing, S. Kelebek

Presently, adsorption is one of the effective methods of removing toxic contaminants from waste waters. The contaminants from metal mining industrial operations include an effluent water containing various types of heavy metal species at concentrations beyond the maximum allowable limits, which are 0.5 ppm and 0.3 ppm for nickel and copper species, respectively. Adsorption behavior of copper ions pre-chelated with diethylenetriamine (DETA) and triethylenetetramine (TETA) onto natural bentonite and peat has been investigated. Both natural bentonite and peat was found to be capable of removing these copper-polyamine complexes from aqueous solutions relevant to process water effluents. However, the adsorption capacity of bentonite was significantly higher than that of peat. Two models were used to study the adsorption kinetics: a pseudo-first-order rate expression and a pseudo-second-order rate expression. For both adsorbents, the data conformed best to the pseudo-second-order rate expression. Representation of the experimental data through adsorption models was also investigated. Out of the four cases considered, namely, Langmuir, Freundlich, Temkin and Dubinin-Radushkevich isotherms, it was found that for both bentonite and peat, the copper polyamine adsorption data conformed best to the Dubinin-Radushkevich adsorption model. The Langmuir model also represents the bentonite-copper polyamine adsorption system reasonably well as the second best case, suggesting that the amount adsorbed on bentonite might be a monolayer with strong affinity.

Jan 1, 2015

By Cheng Wei

Fly-ash was used as adsorbent to remove butyl xanthate from aqueous solution in this study. Adsorption kinetics investigation reveals that the adsorption process abides by the Lagergren-second-order Kinetic Model, and fine fly-ash prepared by grinding has a higher second-order adsorption rate as 1.25 g/mg?min and a higher saturated adsorption amount as 10.92mg/g. Four influencing factors as adsorption temperature, solution pH, consumption of fly-ash and adsorption time were investigated. Testing results indicate that butyl xanthate removal rates declines slightly with the temperature increase within the range of 15-50?, increases slightly when pH rises from 7.27 to 8.01 and then declines from 99.65% to 98.25% when pH rises from 8.01 to 11.10. An enhancement of removal rates can be observed by increasing the consumption of the adsorbing agent or prolonging the adsorption time. Thermal desorption was adopted to regenerate the used fly-ash, and test results show that fly-ash possess good regeneration performance and could be used as adsorbent repeatedly with little influence on the adsorption capacity.

Sep 1, 2012