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By George M. Douglas

The southeastern shores of Great Slave lake present a curious anomaly in geographical and geological exploration, in that an area so large and important, and withal so comparatively accessible, should nevertheless have remained unexplored, unmapped, and indeed almost unknown, until quite recent" times On their return from the famous journey to the mouth of the Coppermine, the band of Indians with whom he travelled led Samuel Hearne across Slave lake. He was the first white man to see that great body of water and it is rather curious that it should have been seen first from the north rather than from the south. Hearne's account of the lake is vague, and he made no attempt ?to map the part through which he travelled. About 30 years later John Franklin, on his first journey to the Arctic, crossed the lake from the mouth of the Slave river to the Yellow Knife river. Franklin's maps show all of his route in accurate detail, except that part of it which lay through Slave lake. In 1833-34, Captain, afterwards Sir George, Back made the first exploration of the eastern end of the lake. Captain Back was then on his way to the Arctic coast by way of the Great Fish river, and his Indian guides led him through Great Slave lake by the route they had followed from time immemorial. This route, partly because of its directness, and partly because of its sheltered character, lay through the great mass of islands in the middle of the lake to the Talthei narrows, and thence along the sheltered north shore with its many coves and harbours. Pere Petitot made extensive journeys in Slave lake as well as other parts of the far north.

Jan 1, 1929

Under the sponsorship of the U.S. Department of Energy, a project was completed in 2005, which studied the use of a special pneumatic capsule pipeline (PCP) system, driven by linear induction motor (LIM), for transporting minerals and/or mine wastes. In this study, the pipeline is a rectangular tube of 1m × 1m cross section. The capsules are similar to railroad cars running on small rails imbedded in the tube. A LIM is placed AT the entrance of the tube to transfer power electro-magnetically from the LIM to capsules. The capsules going through the LIM, propelled by the electromagnetic field generated by the LIM, move faster than the air and hence impart energy into the airflow. This in turn pushes the capsules in the tube forward. When the tube is long (say longer than 10 km), additional LIMs may be needed along the tube to serve as booster pumps. An advantage of using LIMs instead of blowers as used in ordinary PCPs is that capsules can pass through the LIMs unhindered. This enables the use of booster pumps for long tubes. It also enables PCP to achieve much higher cargo throughput than that of PCPs using blowers, thereby reducing unit cost ($ per ton-km). Advantages of using capsules with steel wheels running on steel rails in the tubes including: (1) contact friction is only about one-fifth of that using rubber tires, thereby conserving energy, (2) capsules can run at a much higher speed than those using rubber tires without overheating and damaging the tires, and (3) rails make capsule motion control simple; they restrict lateral movement of capsules, and make branching easy-by using standard rail crossing equipment. This advanced PCP system combines the advantages of LIM with the advantages of rails, resulting in a super-efficient tube system having throughputs an order of magnitude greater than that of conventional PCPs, and having an energy efficiency better than railroad transport. Analysis shows that the system is highly cost-effective when throughput is high-at least 5 million tons per year. The system is most suitable for long-distance transportation of minerals (including coal and flyash) and wastes (including both mine wastes and municipal solid waste).

Jan 1, 2014

By R. A. Ynchausti

In January 1993, Pyramid Resources began implementation of a supervisory expert control system at a U.S Cu concentrator. The objective of this control system was to improve plant profitability through unit operation optimization and integration. This paper documents the key aspects of the project, including: economic and associated benefits, system architecture, concepts of implementation, process control strategies, practical aspects of implementation and conclusions. The implementation of expert control at this concentrator has resulted in an estimated benefit of $50,500 per day. This is a net result of improved tonnage, reduced reagent consumption, improved concentrate grade and reduced energy per ton produced.

Jan 1, 1995

By E. G. Bazeley

The paper reviews the scope, timing and financial impact of this significant project, which involves the supply and transportation of nearly 4 million tons per year of bituminous coal and lignite from sources in British Columbia. Alberta and Saskatchewan to Ontario Hydro's generating stations. The critical factors involved in the selection and utilization of these coals are discussed in relation to the three types of coal to be utilized initially. The paper then deals with each of the significant project elements to be undertaken by the various companies involved in the mining and movement of the coal, beginning with production at the mine through rail shipment to Thunder Bay, train-to-ship terminalling, shipment by lake vessel from there to the generating station, and finally blending the bituminous coal with United States coal prior to combustion. The review discusses the key features of the facilities involved in each case and the status and timing of the project elements , which are phased for the start of coal shipment by mid-1978. The paper concludes with some observations on the capability of the project to handle increased tonnage s and the challenges facing the movement in terms of quality , quantity and cost.

Jan 1, 1978

By Russell J. Sheets

Reactivation of highwall slope failures during adverse weather had intermittently impacted haul road access into a previously mined open pit. These impacts ranged from limited access to full closures; however, the greater impact was to an underground mine that was developed within the open pit. Following several significant precipitation events, a rapid snow melts greatly accelerated movements finally closing the haul road and destabilizing other past failures. In addition to re-designing the overall pit access, the decision was made to relocate the primary portal to a more stable highwall. An accelerated surface geotechnical review was required to advance the portal relocation; however, only existing information from past investigation, existing geology model, visual inspections, and slope monitoring data were available for the assessment - no new investigations or data collection could be completed within the allowable timeframe. The evaluation included a review of the geology, an assessment of the current highwall condition and previously observed performance, and a rockfall analysis to evaluate existing catchment above the proposed new portal location.

Feb 1, 2024

By C. Musingwini, A. S. Nhleko, M. J. Mahase

"In an environment like the mining industry, which is characterized by different stakeholders with multiple objectives, multi-criteria decision analysis (MCDA) is a useful approach for optimal decision-making. The application of MCDA techniques in the mining industry has predominantly been in mine planning and related problems, although no comprehensive survey has previously been undertaken to establish the application trends. A survey of the use of MCDA techniques was therefore conducted using case studies from the literature. It was noted that often two or more methods are applied to the same problem in order to increase confidence in the solution derived. As the number of criteria and alternatives increases, some methods become inefficient. A combination of the analytic hierarchy process (AHP) method with other MCDA techniques was the most frequently used approach, indicating the efficiency of the AHP method, especially when evaluating problems with more criteria and fewer alternatives. A combination of fuzzy theory with AHP or other methods incorporates uncertainty. The findings from the survey will benefit users applying MCDA techniques to solve mine planning and related problems.IntroductionA country’s natural resources serve the needs of different groups of people within the country. These different groups are collectively known as stakeholders (Herath and Prato, 2006). Stakeholders have different needs, preferences, and expectations, which describe and define the criteria to be considered in decision-making. The options available as solutions describe the alternatives in decisionmaking theory. The criteria and alternatives have to be evaluated simultaneously when making decisions, and this is when multicriteria decision analysis (MCDA) techniques become invaluable (Herath and Prato, 2006) because the human mind is considered to be limited when solving complex and intangible problems with several criteria and alternatives (Saaty, 2007). MCDA techniques belong to a broad group of techniques called multi-criteria decision-making (MCDM) techniques. The other group of techniques within MCDM comprises the multi-objective decision-making (MODM) techniques. MODM techniques are generally used to solve problems with an infinite number of alternatives, while MCDA techniques are generally used to solve problems with a finite number of alternatives (Musingwini, 2010)."

Jan 1, 2016

By L. Yuan, J. H. Rowland

"In 1995 and 2003, the U.S. Mine Safety and Health Administration (MSHA) conducted surveys to determine the number of atmospheric monitoring systems (AMS) that were being used in underground coal mines in the United States. The survey reports gave data for the different AMS manufacturers, the different types of equipment monitored, and the different types of gas sensors and their locations. Since the last survey in 2003, MSHA has changed the regulation requirements for early fire detection along belt haulage entries. As of Dec. 31, 2009, point-type heat sensors are prohibited for use for an early fire detection system. Instead, carbon monoxide (CO) sensors are now required. This report presents results from a new survey and examines how the regulation changes have had an impact on the use of CO sensors in underground coal mines in the United States. The locations and parameters monitored by AMS and CO systems are also discussed.IntroductionThe last survey conducted by the U.S. Mine Safety and Health Administration (MSHA) on atmospheric monitoring systems used in underground coal mines in the United States was in 2003 (Francart, 2005). A total of 146 active mines were surveyed. The survey report states that since 1995 there had been a steady increase in the use of atmospheric monitoring systems in underground coal mines as the technology of carbon monoxide (CO) sensors was improved by manufacturers. Atmospheric monitoring systems had become more reliable, and some CO sensors could be purchased with the capability to discriminate between the CO produced by a fire versus CO produced by diesel equipment. This increase in reliability had reduced the number of false alarms and the response time. The faster response time to a developing fire allowed miners to take the necessary action to put out the fire or exit the mine.At the time of the last MSHA survey, some mines still used point-type heat sensors to detect the presence of a fire on conveyor belts. This detection method works by measuring the temperature of the air around the sensor. As a fire starts to develop, smoke and hot gases are produced from the combustion process, and the air is heated up. Once the air and gases reach a designated temperature detected by the point-type heat sensor, a fire alarm signal is generated. Studies have shown that the response times for detecting the presence of a fire using CO sensors are much shorter than when using point-type heat sensors (Conti and Litton, 1995)."

Jan 2, 2018

By Caelli T, Robey M

Most research into planning of open pit mines has been based on evaluation of volume-element block models in terms of their net present value. The major issues revolve around two interdependent problems the optimum ultimate pit and time-based scheduling. Despite feedback between the two problems, they are usually treated as separate tasks.The ultimate open pit is defined by the removal of whole blocks so that their net present value is maximised. This gives planners an estimate of the total worth of the venture in present terms, and is crucial to obtaining funding. All cost and profit values are assumed to be static throughout the mine life, and the only physical constraint usually taken into account is that of safe, average, wall slopes, which must be approximated by the removal of whole blocks. Modelling of any further constraints (for example, access roads and true wall slopes) is usually achieved by adding them to the optimal pit by hand. Typically this degrades the model by between five and 20 per cent of its value - which then brings into question whether it is still the true optimum.This paper reviews the dominant methods in use for this first task the ultimate open-pit planning problem. Some new optimisations are given, and the algorithms are examined in terms of their efficiency and accuracy. Finally, suggestions are made for improvement of model accuracy and eventual expansion into solutions of the more complete dual problem - that of simultaneously finding the optimum ultimate pits and dynamic schedules for the venture.

Jan 1, 1996

By R. F. Tylecote

"The closure of the iron and steel making plant at Consett in Durham in 1980 marked the end of an era-a long era in the world's iron and steel making history. Iron had been smelted in the Tyne-Wear area of the United Kingdom since before the Roman period, but apart from evidence of smithing in the Roman period, the historical evidence for iron production on a large scale dates from the 14th century.The paper describes sites in the area that first worked the bloomery process and then, in the 16th century, as did most of Europe, graduated to the blast furnace process. The main emphasis is on the early introduction of coal to iron making at the end of the 18th century and the use of the steam engine to render integrated sites possible.IntroductionIron has been smelted in the Tyne-Wear area of the United Kingdom since before the Roman period, but apart from clear evidence of smithing in the Roman period, the historical evidence for iron production on a large scale dates from the 14th century. Like many other countries, the United Kingdom benefitted from the visits of foreign observers, such as Jars, Svedenstierna, de la Houliere and Dufrenoy, who left detailed records. In modern times, information gained from excavations of iron and steel making sites has supplemented the historical record.Natural ResourcesUp to the end of the 19th century, the industry was wholly dependent on its own resources. Iron ore, limestone, wood, coal and water power were all found a short distance away from the main valleys of the Tyne and Wear. The main sources of iron ore were the coal measures, with rider ores from the lead vein s in Alston and Weardale, and carbonate ores from shale horizons in the Carboniferous limestone. Good coking coal was available from West Durham and reasonable coal from the Tyne valley and Northumberland limestone. Limestone was plentiful."

Jan 1, 1983

By Edward M. Weiss

THE emphasis in some political quarters on hemispheric unity and defense indicates Latin American mineral resources should be more extensively developed. However, United States mining companies have, in many instances, been discouraged by the laws of southern neighbors. At the same time, some of the countries have liberalized their mining laws in an effort to attract investments from the United States. The resultant confusion has been detrimental to all concerned. Ownership of Mineral Deposits Examination of the mining codes of Latin American countries shows that, without exception, governments reserve the right of direct ownership of all mineral resources. Ownership can be divided between the Feredal Government and the states or among the Federal Government, the states, and private individuals. However, in the majority of the nations constitutional authority vests all mineral rights solely in the Federal Government. Mexico is the only country that has expressed Federal ownership as imprescriptible; the other republics have not defined the exact significance of government ownership. The implication derived from the general economic and political climate is that all mineral resources are ultimately to be regarded as a national heritage. Whether a concession granted to an individual or corporation carries any right of private property is shaded with a variety of meanings. The exceptions at one extreme are Argentina and Bolivia, whose laws state explicitly that a concession granted to a juridical person is an act of the state, and the land becomes the private property of the individual, and the concessions constitute real property. However, in Mexico mining concessions or grants do not create rights of fee-simple ownership. The concession only conveys the exclusive right to explore, develop, and work the deposits. The mining property remains the property of the state. In some instances exploitation concessions represent a compromise between private and government ownership. In Honduras the period granted to a mining enterprise is fixed at 90 years. At the end of that time, the enterprise and all installations revert to the state without compensation.

Jan 1, 1952

By Pierre Mousset-Jones

A questionnaire was sent out to three classes of mines to determine the extent of the heat problem in U.S. and Foreign underground mines. The following list shows the replies received from this questionnaire, however not all the known hot mines in the US replied. A complete listing of the results can be seen in Appendix I. 1) US coal mines - 37 replies 2) US non coal mines - 23 replies 3) Foreign non coal mines - 36 replies. At the present time there are approximately eleven non coal and one coal mine in the US experiencing heat problems which require special efforts to maintain an acceptable working place climate. However since the survey was completed some of them have been placed on standby. The Mine Safety & Health Administration (MSHA) does not have any specific regulations relating to heat stress. Informally the American Conference of Governmental Industrial Hygienists guidelines are followed which use wet bulb globe temperature (WBGT) with values ranging from 26.7°C to 31.1°C for a moderate workload, and different rest regimes. An MSHA report (Misaqi 1976) recommended that conditions should not exceed 26.1°C WBGT for men and 24.4°C WBGT for women. However, quite recently the organizations involved with planning two of the proposed nuclear waste repositories in the United States, have opted for the criteria of an air cooling power of 300 w/m2, and a WBGT of 27'C respectively.

Jan 1, 1986

By E. Topuz, C. Duan

"INTRODUCTIONOperations research (OR) applications have experienced a substantial growth within the mining industry during the last three decades. The purpose of this paper is to present a summary of the results of a comprehensive survey of the application of various OR techniques to the major mining activities. It is hoped. through this sur vey , that the most widely used OR approaches, the important areas of application, and future trends have been identified.This survey included more than 500 articles published in this field in English since the late 1950s. Most of the relevant literature was found in mining publications, but, in terms of quality and originality, important applications were also found in literature not related to the mining industry. The sources constituted periodicals, proceedings research reports, and a few books. A listing of selected publications from which three or more articles reviewed in this survey appear is given at the end. Operations Research MethodologiesOperations research is concerned with optimal decision making in, and modeling of, deterministic and probabilistic systems that originate in real-life situation s. One basic feature of the OR methodologies is the attempt to optimize certain design parameters, subject to a set of constraints. This distinction has been employed in the survey as a guideline for selection of the techniques covered under the title "" OR methodologies"". The methodologies thus encountered in the literature are listed below. In a few cases, simulation has not been considered because it is not an optimization method per se."

Jan 1, 1989

By C. D. Anderson, C. G. Anderson, P. R. Taylor

"Rare Earths have become critical for our energy and materials driven society. While primary production must ramp up to fill growing demands, the recycle of these strategic elements must also be initiated. This paper will outline the potentials of and metallurgical technologies employed for Rare Earths recycle from various secondary sources.INTRODUCTIONWhen investigating the recovery of rare earths from secondary sources it is necessary to understand the nature of the sources to be processed. As of 2009, the USGS reports the distribution of rare earths by end use, in decreasing order, was: chemical catalysts 22%, metallurgical applications and alloys 21%, petroleum refining catalysts 14%, automotive catalytic converters 13%, glass polishing and ceramics 9%, rare earth phosphors for computer monitors, lighting, televisions 8%, permanent magnets 7%, electronics 3%, and others 3% (USGS, 2011). Additionally, it is reported that the amount of recycling was quite small and consisted primarily of rare earth magnet scrap, although with the sharp increase in the price of rare earths, and the potential shortage in supply, focus in this area is continually growing. Thus, the opportunities, whether realistic or not, are extremely vast in the recycling of rare earth containing materials. The following subsections will present methods proposed for the recycling of rare earths based on the feed material type.RECYCLING OF RARE EARTH MAGNETSCurrently, investigations are ongoing in the area of recycling production scrap and end-of-life materials in the rare earth magnet industry. The following techniques illustrate potential methods for the recovery of rare earths from secondary RE magnet sources.Recycling of Rare Earth Magnet Sludge by Selective ChlorinationDuring the production of neodymium magnets, a by-product of production is the so called “magnetic sludge”. This by-product contains high amounts of neodymium, thus a process for the recovery of Nd has been proposed. In this process the Nd present is selectively chlorinated/distilled by the addition FeCl2 via the following reactions."

Jan 1, 2012

By Khaled M. Mohamed, Michael M. Murphy, Ted M. Klemetti, Heather E. Lawson

"The design of rib support systems in U.S. coal mines is based primarily on local practices and experience. A better understanding of current rib support practices in U.S. coal mines is crucial for developing a sound engineering rib support design tool.The objective of this paper is to analyze the current practices of rib control in US coal mines. Twenty (20) underground coal mines were studied representing various coal basins, coal seams, geology, loading conditions, and rib control strategies.The key findings are: (1) any rib design guideline or tool should take into account external rib support as well as internal bolting; (2) rib bolts on their own cannot contain rib spall, especially in soft ribs subjected to significant load—external rib control devices such as mesh are required in such cases to contain rib sloughing; (3) the majority of the studied mines follow the overburden depth and entry height thresholds recommended by the Program Information Bulletin (PIB) 11-29; (4) potential rib instability occurred when certain geological features prevailed—these include draw slate and/or bone coal near the rib/roof line, claystone partings, and soft coal bench overlain by rock strata; (5) 47% of the studied rib spall was classified as blocky—this could indicate a high potential of rib hazards; and (6) rib injury rates of the studied mines for the last three years emphasize the need for more rib control management for mines operating at overburden depths between 500 ft and 1,000 ft.IntroductionEfforts to improve the stability of underground mine ribs have continued for decades. These efforts by mining professionals around the world persisted throughout the 1990s and 2000s as well, though much of this work focused on rib support methodology and selection of proper support for a specific location. Despite these efforts, it is unfortunate that there has been a continual occurrence of rib-related fatalities in underground coal mines. While overall improvements in rib safety have been achieved, the average fatality rate is still about 1.3 fatalities per year over the last 18 years (Jones, 2014).To manage and control the rib hazard, rib support is used in U.S. coal mines. The current rib support methods for U.S. mines fall into two main categories: rib control based on intrinsic support systems and those based on external support systems. Intrinsic or rib-bolt support requires a roof bolting machine that can install a bolt fixture into the rib. Furthermore, the appropriate level of support needed to control the ribs with an intrinsic-based support system as well as the design parameters for those support systems for various mine conditions have not been established in U.S. coal mines. Furthermore, surface control systems are often an integral part of these support systems and must be considered in the system design."

Jan 1, 2015

By Paul Sainato

Recruiting and retaining students in the explosives industry is becoming increasingly important each year. With no undergraduate degree in explosives engineering currently available in the United States, it is from other industries and degree disciplines we must recruit. The 2014 annual ISEE conference saw the first anonymous online survey distributed to members of SEE student chapters of the International Society of Explosives Engineers. The survey contained questions about future job and career plans, ideal job placement, expectations of salary and current academic degrees. The purpose of the survey was to determine what these students expect or require from a career in the explosives industry, and their current path to pursue this. This information can help steer recruitment activities and job offers for graduating students. The success for both student response rates and interest from the industry has allowed space for a yearly update of this survey. A second survey was distributed in 2015 and included international students. This paper provides the data from a third online survey distributed to all student members of the International Society of Explosives Engineers, globally. Understanding the main incentives for a student to accept a graduate position as an explosives engineer can help us, as an industry; position ourselves to remain competitive in recruiting against other major degree disciplines.

Jan 1, 2016

By Jim Petrie, Mary Stewart, Damien Giurco

This paper describes a generic approach to analysing the environmental and economic performance of a global mineral/metal value chain, with the express view of improving the quality of prospective decision-making within the industry in order to ensure more sustainable outcomes. The starting point for this analysis is the development of a global stocks flows and transformations model, for the metal of interest. Any aspect of the value chain, e.g. “metals refining, “goods manufacture”, “use and disposal”, can be assessed, either relative to other stages in the value chain, or in more detail by focusing on the technologies used within that stage. The use of this model as a decision support tool is explored here for the case of copper. Both primary and secondary production routes are enumerated, covering a range of processes, for seven distinct geographic regions round the globe. The value of the modelling approach is explored for different energy mixes. In particular, the case study examines the impact of increased recycling on the (re) distribution of global and regional environmental impacts for technologies-in-place in these different regions.

Jan 1, 2003

By Jim Petrie, Mary Stewart, Damien Giurco

This paper describes a generic approach to analysing the environmental and economic performance of a generic global mineral/metal value chain, with the express view of improving the quality of prospective decision-making within the industry in order to ensure more sustainable outcomes. As a point of departure we propose that it is not possible to place metals in the context of the sustainable development of society without paying due regard to the entire metals value chain. Thus, the starting point for this analysis is the development of a global stocks flows and transformations model, for the metal of interest. Any aspect of the value chain, e.g. “metals refining, “goods manufacture”, “use and disposal”, can be assessed, either relative to other stages in the value chain, or in more detail by focusing on the technologies used within that stage. The use of this model as a decision support tool is explored here for the case of copper. Both primary and secondary production routes are enumerated, covering a range of processes, for seven distinct geographic regions around the globe. The value of the modelling approach is explored for different energy mixes. In particular, the case study examines the impact of increased recycling on the (re) distribution of global and regional environmental impacts for technologies-in-place in these different regions. The aim of these case studies is to highlight to the minerals processing and metals refining industries their potential role in a more sustainable global society.

Jan 1, 2003

The use of mining by-products for beneficial use may face approval, and acceptance barriers. This paper described the use of a sustainability framework to assess the safety, effectiveness and economic value of modified bauxite residue (Alkaloam«) for use on agricultural land in the Peel-Harvey region of Western Australia. The results indicate the merit associated with using this by-product from a safety and, private, community and environmental value perspective. They may be used to indicate the worth of pursuing any future community acceptance and agency approval process.   The use of Alkaloam« for beneficial use on agricultural land in Western Australia was first investigated over 25 years ago. Efforts to gain regulatory approval and community acceptance of Alkaloam« have had a complicated and enduring history. Understanding and assessing the value of a by-product using social and economic considerations, in conjunction with an environmental assessment, provided a more complete evaluation to that previously used.

Jun 1, 2010

By S. Mudau, P. Mohasoa, M. J. Cole

Derelict and ownerless (D&O) mines in South Africa have been an ongoing concern for over a decade. While some progress has been made to rehabilitate D&O asbestos sites, significant work remains, exacerbated by the growth in illegal mining. There are concerns regarding the accuracy and transparency of the D&O database, lack of oversight, and constrained funding, and the government is increasingly looking to the private sector to fund rehabilitation. Given these challenges, a new, sustainable approach to D&O sites in South Africa is needed to bring clarity and transparency to the process, recognise responsibilities and promote partnerships, and explore economic opportunities at D&O sites to reduce the financial liability and respond to the growing demand for critical minerals. This article has three components: i) reviews of international D&O good practices; ii) it analyses South Africa’s current approach and the D&O sites; and iii) proposes a D&O framework that addresses data, risk ratings, responsibilities and rehabilitation, economic opportunities, and stakeholder engagement. The study finds that the majority of the 6,100 so-called abandoned D&O mines are quarries and mine site features, 16% are operational, at least 11% have owners, and only 752 (12%) require rehabilitation. The framework aims to bring clarity and fairness to decision-making and to assign risk and responsibility for rehabilitation and seeks to incorporate economic opportunities to reduce the financial burden of rehabilitation, create jobs for local communities, and respond to the growing demand for critical minerals for the clean energy transition.

Apr 25, 2025

By Jaeheon Lee, Junmo Ahn, Jiajia Wu

To reduce the environmental footprint of hydrometallurgical processing of black mass from spent lithium-ion batteries (LIBs), a green leaching system based on glycine and sodium metabisulfite (Gly-SMS) was proposed. The leaching study demonstrated that the highest cobalt and lithium recoveries of 100 percent and 99.8 percent were achieved under optimal conditions. The leaching mechanism revealed that the dissolution of LiCoO2 in the Gly-SMS solution followed the shrinking core model. The apparent activation energies for cobalt and lithium were determined as 48.05 and 41.51 kJ/mol, respectively, indicating a surface chemical reaction controlling mechanism. The leachate was then processed by an acidification- precipitation technique with oxalic acid as the precipitant to remove cobalt. Glycine complexes with metal ions by zwitterionic ligand and recycles in the leaching-precipitation circuit, reducing the reagent cost. Compared to other studies, this leaching system has near-neutral operating conditions and is cost-effective, making it an economically viable alternative for treating cathode materials from spent LIBs.

Dec 1, 2024