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By J. R. Allsup

Air pollutants in exhaust gas produced from LP-gas (propane) were studied using both laboratory engines and vehicles. The objective of the study was to evaluate engine parameters relating to the advantageous use of propane as a low-pollution fuel. Some comparisons are made between gasoline, natural gas, and propane. Results show that engines can operate over a wider range of A/F with minimum carbon monoxide and hydrocarbon emission when using propane than when using gasoline. Mixture enrichment using propane is unnecessary during cold starts, thereby eliminating the emission penalty during warmup. Carbon monoxide and hydrocarbon emission using propane are unaffected by ambient temperature. The photochemical reactivity of hydrocarbon emission is considerably lower with propane than with gasoline.

Jan 1, 1972

Control of flotation processes is mostly managed by plant operators, who assess the performance of the plant based on their own experience and other heuristic rules. These rules tend to be subjective or ill-defined, since most of them are concerned with the structure of the flotation froth, such as colour, bubble size and shape distributions, froth mobility and froth stability. These phenomena are very difficult to quantify objectively, and inexperience on the part of the operators, human error, etc., can lead to significant inefficiencies in plant operation. In this paper the development of a fuzzy system to support the control decisions of plant operators is described, which leads to significantly smoother control action and more stable plant operation than could be obtained with crisp sets of rules or manual control strategies. Keywords: flotation, fuzzy logic, image analysis, genetic algorithms, rule induction

Jan 1, 2000

By John T. Norton

N order to attempt to arrive at a better under-Jl standing of the whole basic problem of sintering, these remarks will serve as an introduction for discussion that is included and will, perhaps, help to isolate specific questions which need to be answered or to suggest some definite avenues of investigation which should be followed. To bring some sort of logical order into the presentation, I will consider the various types of interaction between the metal to be sintered and the atmosphere which surrounds it, depending upon whether the phenomena are essentially chemical or physical in nature. For example, when the only necessary criterion for the satisfactory sintering of a certain powder is the removal of an oxide skin, then the problem of choosing a suitable atmosphere is primarily chemical; however, if a special surface condition as a consequence of the oxide skin removal is necessary for particularly effective sintering, then the problem becomes a physical one. Of course, the two aspects overlap considerably, but it may be possible to make a distinction in principle if not in practice. The chemical characteristics of the phenomena will be emphasized, since these are the better known. Metal-gas reactions involved in sintering are controlled primarily by the thermodynamics of the processes involved. In which direction will a reaction go and how far before it stops? The answer is to be found in the magnitude of the free energy change associated with the reaction. If a constituent is to be removed from the specimen as completely as possible or if a constituent is to be formed in the specimen as completely as possible, then one chooses conditions which are far from equilibrium so that the reaction is driven toward completion. On the other hand, if the composition is to be maintained at a desired value, then conditions are adjusted as closely as possible to the equilibrium point. This aspect of the problem is susceptible to quite precise analysis, provided, of course, that the significant reactions can be recognized and the required thermodynamic data are available. Conversely, if one asks how fast the reaction goes or how far it proceeds in a given time, the answer is frequently much more difficult to answer in quantitative terms. Yet the rate-con trolling factors of the reactions may be of primary importance in the success of a particular operation, especially where competing processes are at work. Both equilibrium and rate factors must be understood if a clear picture is to be obtained. For instance, in a process for carburizing titanium dioxide, is the difficulty of obtaining a stoichiometric Tic due to a true limitation of the equilibrium or simply to a very slow rate of reaction? An example of this appears in the work of Kalish and Mazza.' They showed that the oxygen content of sintered iron compacts was lower when sintered in pure hydrogen than in the case where the hydrogen was diluted with either argon or nitrogen. The equilibrium oxygen content of the iron would be the same in the two cases, since it is determined by the ratio of the partial pressures of water vapor and hydrogen and this pressure ratio is unchanged by dilution. The rate of oxygen removal, however, under the conditions of a constantly replaced furnace atmosphere, depends upon diffusion and thus upon the concentration of hydrogen in the furnace atmosphere. Possibly the clearest way to illustrate the interplay of these two factors is to consider in more detail some of the typical metal-gas reactions. Adsorbed Gases It is common experience that fine metal powders with their very large surface areas often contain large quantities of gas. This gas, which results from exposure to air or perhaps from some step in the

Jan 1, 1957

By Steven R. Munts

The U.S. Bureau of Mines investigated mines, prospects, and mineralized areas in the South Providence Wilderness Study Area (WSA) in 1982. No mines are currently operating in the WSA, however, the Golden Gift Mine in the southeastern part of the WSA produced $6,800 1/ worth of gold and silver and five mines adjacent to the east boundary of the WSA had a total production of about $3,500,000 1/ in gold, silver, lead, and copper. There is no recorded placer gold production. Over 350 lode and placer mining claims are in and immediately adjacent to the WSA. Of these, 74 were actively held (1982) and at least one area, which is partly within the northeast portion of the WSA, was being actively explored by private industry in 1982. Adjacent to the southeastern border of the WSA the Big Horn Mine contains an estimated 200,000 tons of indicated and inferred marginal reserves averaging 0.25 oz/ton gold; and the Hidden Hill Mine has 550 tons of subeconomic resources averaging 0.60 oz/ton gold. An additional 11,000 tons of marginally economic gold-bearing dump reserves average 0.17 oz/ton gold at the Bighorn, Hidden Hill, and the Buena Vista Mines and the Midas Touch Prospect. Sample analyses indicate eight mines and prospects in, and five adjacent to the WSA may have additional gold-silver-lead-copper vein-type resources. Five of these prospect areas may have a disseminated gold resource and one may have gold resources in a skarn. One prospect may have a porphyry-type copper-molybdenum resource. Although gold placer claims were filed sporadically throughout the WSA, none appears to have placer gold resources. Likelihood for mining is greatest at the Big Horn Mine; if a mill is built there, it could process Big Horn Mine ore, ore from the Hidden Hill Mine, and gold-bearing dumps at the Big Horn, Hidden Hill, and Buena Vista Mines and the Midas Touch Prospect. All of these resources are adjacent to the WSA; however, their development would increase likelihood for development of resources in the WSA. Two major fault zones (the Hidden Hill, and the Big Horn) appear to have controlled the mineralization at many of the prospects and mines. All of the prospects or mines with vein-type occurrences and resources are on or adjacent to one of these fault zones. Veins throughout the eastern half of the WSA contain various amounts of gold, silver, and copper; only veins near the Big Horn Mine and in the northeastern corner of the WSA contain lead. Some veins are as thick as 6 ft, are traceable intermittently for over 2 mi along strike, are sporadically mineralized, are encased in prophylitic, argillic, and phyllic altered host rock, contain pyrite, chalcopyrite, galena, specularite, barite, or fluorite, and display multiple stages of quartz veining and (or) brecciation. Sample analyses at five prospects (map nos. 3, 18, 23, 24, and 31) indicate they may have disseminated gold resources. To date no oil or gas has been discovered within the WSA. However, some oil and gas leases are currently (August 1982) held within this study area.

Jan 1, 1984

Under contract from U. S. Bureau of Mines, Harza Engineering Company in cooperation with Eastern Associated Coal Corporation, conducted a ground control study of two mechanized longwall panels at the Federal Number 2 Mine. The mine is located in Northern West Virginia, and the coal is mined from the Pittsburgh Coal Seam. The prime objective of the study was to collect data which will aid in the proper selection of the longwall supports system and to control the entry caving problem. Instruments installed in the mine were borehole pressure cells, convergence recorders, roof sag recorders, horizontal roof strain indicators, differential floor movement systems, and lateral roof and floor movement systems. Instruments installed on the surface, above the instrumented longwall panels, consisted of slope indicator system, vertical bed settlement probe system and shear displacement detecting system. A comprehensive surface subsidence study was conducted in conjunction with the instrumentation. In addition to the instrumentation and monitoring, special tests were conducted to determine the bearing capacity of the roof and floor rocks, in situ modulus of coal, roof and floor rocks, and response of borehole pressure cells to ground stress. Cores of coal measure rocks were collected for the physical property tests. Face observations were made to detect various roof behavior parameters under the different jack setting pressures. This report essentially describes the instrumentation work, special tests and presents the data collected.

Jan 1, 1976

The occlusion of unliberated gold particles in silicates and sulfides in crushed/milled ore dictates the recovery that can be expected. The grade of this occluded gold in cyanide leach residues shows a consistent, general relationship to the head grade of the ore, irrespective of mineralogy or geographical location. The residue grade almost invariably increases with the head grade, but not in proportion to it. This phenomenon appears to stem from the nature of the geological events originally responsible for creating the ore deposits. A statistically-based technique for determining the true head grade-tail grade relationship from gold plant operating data is described. The effect is illustrated with results from several worldwide gold milling operations analyzed over the last 35 years.

Jan 1, 2008

By N. Mulaudzi, S. Archer

"Direct cobalt electrowinning was developed to produce unrefined cobalt metal as an alternative to producing a mixed hydroxide product (MHP), which is the common cobalt intermediate product in African Copperbelt operations. MHP is preferred due to the high cost of producing high-grade cobalt cathode. Direct cobalt electrowinning test work results have shown that the purity of the unrefined cobalt metal produced from a low-grade copper solvent-extraction raffinate stream was ~97% (w/w), which is significantly higher than the MHP purity (up to 45% (w/w) Co). The current study investigates whether direct cobalt electrowinning would increase the profitability of African Copperbelt copper–cobalt oxide operations, when compared with the MHP flowsheet. An order-of-magnitude economic evaluation was conducted using dynamic differential discounted cash flow models on a “bare-bones” basis, using a 10% discount rate. Three variables were evaluated, namely; reagent utilisation extents, precipitation extents and filter-press wash efficiency. Multivariable risk analysis was also conducted using the Monte Carlo simulation technique to understand the impact of key project drivers. The financial study results indicated that a direct cobalt electrowinning flowsheet could potentially result in a higher mean net present value (NPV) compared with the MHP flowsheet. Cobalt recovery was found to have the most significant impact on the NPV. In addition to increased profitability of African Copperbelt operations, direct cobalt electrowinning has the potential to reduce the environmental footprint of operations as well as addressing the Democratic Republic of Congo government’s drive towards export of higher value metal products instead of low-grade intermediates."

Jan 1, 2015

The Rosebery and Hercules mines, situated in the Rosebery-Williamsford district in western Tasmania, have a history of production dating back to 1896-7, although full scale production did not commence until 1936, following the development of a satisfactory process of selective flotation (Hall, Cottle, Rosenhain and McGhie, 1953). The mineral composition of the Rosebery zinc-lead ores was first described in detail by Stillwell (1934). The Hercules ore is generally similar, but as yet no descriptions of it have beenpublished.Since Dr. Stillwell's paper appeared, the management of the Rosebery and Hercules mines has from time to time submitted a number of interesting mineral specimens to C.S.I.R.O. Mineragraphie Investigations. Examination of these specimens brought to light eight minerals, some relatively uncommon, not previously recognized in these ores.They are cassiterite, molybdenite, stannite, electrum, meneghinite, boulangerite, pyrargyrite and pyrrhotite. Some of the specimens are also rich in tetrahedrite and gold. In addition each of the other ore minerals described by Stillwell, viz. pyrite, sphalerite, galena, bournonite, chaleopyrite and arsenopyrite, was detected in one or more of the specimens examined during the present study. The principal gangue minerals were found to be quartz, manganiferous carbonate, sericite and barite, agreeing closely with the observations of Stillwell.The present study was based on the examination of the following eight specimens.

Jan 1, 1960

The proper selection of a coal for a particular use depends on knowledge of fundamental data concerning the coals that offer, particularly their type and rank. Type of coal depends on the nature of the original plants and the environment in which they accumulated.Rank reflects the subsequent metamorphism of the coal, and is of two kinds-physical rank and chemical rank.INTRODUCTIONIn the different coalfields of the Commonwealth of Australia there occur many different kinds of coal which provide the coal-research worker with a wide range of material, but to the fuel technologist they represent complex problems in utilization.In the past it has been common practice to instal coal-using equipment of a design based on plant used in large industrial centres of other countries and then search for supplies of suitable coal. This has led to the transportation of coal mainly from New South Wales to other States, which have inadequate supplies of coal suitable for use in the equipment they have installed. However, modern economy and industrial practice demand local resources of coal for the development of industry, transport and domestic services, and a change in the old order is rapidly taking place. Technologists and engineers are now faced with the problem of designing and installing equipment to use whatever kind of coal is available in local coalfields.Much has been accomplished in this direction and important investigations are at present being carried out, but there still remains a wide field of problems for research.In planning and carrying out investigations into coal utilization it is essential that fundamental data and knowledge should be available and that its significance should be appreciated.

Jan 1, 1955

By Robert M. Baker

This document details the method whereby Allen Corporation of America gathered and analyzed data and developed an annotated bibliography of metal and nonmetal mine fire reports (1950-1979). The primary objective of this program was to develop the annotated bibliography which included MSHA accident reports and periodicals. Two additional objectives were to gather data on non-reportable fires and to conduct statistical analyses on the data to delineate trends. Data was acquired from three major areas: periodicals, MSHA fire reports, and mine safety directors. Data was separated into reportable fires (at least ½ - hour duration or injury), non-reportable fires, and opinion data. The data was then analyzed by time trends, state, ore, ignition source, burning substance, location, equipment, detection, duration, injuries, fatalities, and successful extinguishing agent. The authors make a number of recommendations: (1) improved stationary electrical equipment design and fire protection, (2) improved design of mobile equipment to separate combustibles from ignition sources, (3) improved maintenance, (4) improved housekeeping, and (5) improved training. The document is divided into two volumes and an appendix. Volume I contains data acquisition procedures, data analysis procedures, and conclusions and recommendations. Volume II contains a chronological list of mine fires and fifteen indexes to assist the reader in locating fire incident report of interest. The Appendix contains the annotated bibliography of over 300 metal and nonmetal mine fire reports and journal articles and a list of non-reportable fires.

Jan 1, 1980

By G. E. Geiger

The purpose of this research was to develop a computer simulator fur predicting the air quality in existing coal mines as well as a design aid for developing new mines. In addition to the air quantity flow, the other variables of tempera Lure, moisture, methane and respirable dust are necessary to determine the air quality. An additional feature of this simulator is that it allows parametric studies of these variables to explore the effect that these variables have on the air quality of an operating mine system. The research has also pointed out arias where more research is needed, and promote better and more systematic data taking techniques. Wang and Hartman (see Reference 9, on page 1-98 of Section 1) had already published a computer program to determine the ventilation of large mines, and Wang and Saperstein (see Reference 10 on page 1-98 of Section 1) later published a refinement of the work in the previous reference. These references were the starting point of the simulator developed by this present research effort, and Section 1 of this report is a slightly modified version of the original vent elation program. The modifications were necessary to permit the additional programs of temperature-moisture, methane and dust to be

Jan 1, 1972

By Taylor G. H

The Triassic Ipswich (SE. Queensland) coals are of bituminous rank. The more exact rank of individual samples was determined by measuring the reflectance of the vitrinite. While in general the rank of the coals increases with stratigraphic depth, minor reversals, probably related to igneous intrusions, occur.The Ipswich coals form a coherent group so far as petrographic type is concerned. All are comparatively rich in vitrite and clarite, cutinite being the common maceral of the exinite group. The mineral contents of all the coals are comparatively high, clay and quartz being most abundant. The coals appear to be of essentially autochthonous origin, and to have been formed under conditions of fairly rapid subsidence.While the use of the coals is at present restricted to combustion, most have pronounced coking properties, as would be predicted from their petrographic composition and reflectance. However, the high mineral content of the coals would be a limiting factor in their use for coke-making.INTRODUCTIONDuring the last ten years, the Division of Coal Research, Commonwealth Scientific and Industrial Research Organization has carried out an extensive investigation of Australian coals, providing a wide range of analyses of most of the important of them. Special attention has been given in recent years to Queensland coals.Most seams were sampled as a number of subsections, enabling the internal variations, as well as the overall properties, to be assessed. The lenticularity of many of the mineralrich layers may tend to limit the significance of the samples, particularly in respect of ash yield, but although the vertical distribution of mineral matter may vary considerably from one sampling position to another, the lateral variation of the total mineral matter in the whole seam may not be great.Apart from extensive chemical analyses and utilization...

Jan 1, 1963

By Georgene Renner, William R. Yernberg, Steve Kral

ABB offers complete electrical revamps of mining shovels with ac or dc drives, drive control, frequency converters with insular gate bi-polar transistor technology, intelligent control packages and visualization. Many of the world’s shovel excavators and draglines (walking excavators) were built in the1980s. After 15 to 20 years of round-the clock operation in openpit mines, these machines start to feel their age. Electrical parts are particularly vulnerable. Their performance deteriorates and availability and productivity fall. Even with regular ser-vice and maintenance, a machine of this age will accumulate 400 hours of unscheduled downtime a year. The need for a replacement becomes pressing, but the expense is often prohibitive.

Jan 1, 2005

By R. A. Cummings

Certain roof shales in coal mines deteriorate upon exposure to the atmosphere, causing difficulties in the mining operations and adding to the cost. This report presents the results of both field investigations, in a West Virginia mine, and laboratory studies on the effects of atmospheric moisture on roof shales. Based on these observations, a conceptual procedure is presented on how shale deterioration might be predicted during exploration, and guidelines are given as to how air tempering or conditioning chambers may be designed to reduce moisture effects. Recommendations for further studies are included. An annotated bibliography of the literature constitutes the second volume.

Jan 1, 1981

By John V. Simmons, Peter J. Simpson

Excavated slopes in open pit coal mines are designed to be as steep as possible consistent with stability and safety requirements. Slope failures occur for many reasons, including oversteepening. This paper is concerned with slope design and excavation experience in the Bowen Basin coalfields of central Queensland (Figure 1), [ ]

Jan 1, 2006

concentrations) and physical nature of receiving streams, which in turn affects the stream ecosystem. Benthic macroinvertebrates are used to illustrate these impacts, and to investigate natural recovery in affected streams. In Charming Creek, a severely impacted stream in the Buller District, the macroinvertebrate community recovers diversity and the proportion of sensitive species (EPT) in the community is more significant with increasing downstream distance from the source of AMD. This is most likely due to dilution of AMD contaminated water by tributaries to the Charming Creek mainstream. Other impacted systems with less dilution from tributaries did not display similar levels of recovery. The effectiveness of remediation products BauxsolÖ and Zeolite was investigated using laboratory trials. Both products mitigated the toxicity of AMD and enhanced the survival of mayflies exposed to AMD contaminated water. Such products may be of use in the New Zealand environment but are likely to be most effective in conjunction with other systems (eg wetlands). Mitigating the impacts of AMD on stream ecosystems needs to include systems to directly address water chemistry issues (low pH, high metal concentrations) as a component of a holistic approach to restoring environmental conditions.

Jan 1, 2003

By Brigitte Lacouture, Yeen Shien Hwang, David Lin

"A baseline survey of the partially open lead regrind circuit at Red Dog Mine indicated poor regrind efficiencies for the three parallel 450 HP tower mills. Driven by the high energy cost and the potential metallurgical gain brought by improved mineral liberation, the Red Dog lead regrind circuit was optimized in two stages.In the first optimization stage, different circuit layouts were evaluated in two plant trials. In June 2003, the regrind circuit was changed to a fully closed circuit. This reduced the tower mill requirement from three to two mills. The circuit modification payback was 11 days through power savings alone.The second stage of optimization was the evaluation of reagent addition. To improve pyrite depression, sodium cyanide was added to the feed of the lead regrind tower mills and tested in a series of plant trials over several mill feed stockpiles. Galena selectivity against pyrite was found to improve in these plant trials. Due to environmental sensitivities, no net increase in cyanide addition to the plant occurred and thus no increase in the cyanide concentrations in the tailings pond or the environment will result.The lead regrind optimization work improved the overall lead metallurgical performance and reduced energy and reagent costs. Economic analysis showed that annual profit increased by as much as US$3.0 M."

Jan 1, 2005

By J. Shang, P. Howarth, B. Morris

Tailings from the nickel refinery in Copper Cliff, Ontario, consist of fine silicates mixed with a variable amount of conductive and magnetic minerals mainly associated with sulphides and iron oxides. Subsequent oxidation of sulphide- rich phases within the tailings results in the formation of an acidic leachate that may contain significant concentrations of trace metals. Mapping the spatial distribution of regions of higher sulphide concentration therefore provides insight into the distribution of the acidgenerating potential within the tailings. Electrical conductivity is constrained by two parameters — the concentration of metallic sulphides and the ionic concentration of acid in groundwater. Magnetic susceptibility is directly related to the pyrrhotite and magnetite content. It is proposed that combining information derived from airborne electromagnetic and magnetic surveys can provide an indication of metallic sulphide distribution. Preliminary investigations of airborne electromagnetic and magnetic data acquired concurrently over the sulphide-rich Copper Cliff tailings site reveal that these parameters can provide information on mine tailing extent and permit separation of tailings with varying compositional and alteration levels. Airborne geophysical data provide information about the subsurface while a digital elevation model (DEM) and hyperspectral imagery record surface conditions. Integration of the two data sets can reduce ambiguity when interpreting mine tailing distributions and their subsequent alterations.

Jan 1, 2001

By J. C. Bokros, A. S. Schwartz

The irradiation-induced densification of pyrolytic carbon has been shown to take place by a simple first-order rate process. The values of the densification constant, kd, for isotropic carbons are 1.0 x 10-22, 1.4 X 10-22 and 2.8 X 10-22 (nut)-1 at irradiation temperatures of 520o, 670°, and 1000oC, respectively. The apparent activation energy obtained from the temperature dependence of kd for isotropic carbons is about 0.2 ev. Estimates of the maximum stresses that develop in isotropic carbons owing to shrinkage onto an unyielding support show that stresses in excess of 15,000 psi may be avoided during irradiatian at 600" and 1000°C if the initial coating density is kept above 1.5 and 1.9 g per cu cw, respectively. If a carbon coating on an unyielding support is not completely isotropic, stresses may continue to build up at high neutron exposures after densification is complete because of continued anisotropic distortion. Stresses in excess of 15,000 psi from this source may be avoided during irradiation at 1000°C if' the Bacon anisotropy factor is kept below 1.3. A variety of applications of carbon and graphite in nuclear technology has stimulated numerous studies of the effect of neutron irradiation on these materials One of the most interesting problems associated with the use of carbons and graphites in the high fast neutron fluxes of nuclear reactors arises as a consequence of the neutron-induced dimensional changes that occur during irradiation. Energetic neutrons displace car- bon atoms from their lattice positions; and, depending on the temperature, the interstitials and vacancies produced migrate to form clusters, recombine, or are annihilated at dislocations or crystallite boundaries. The competition of various sinks for the point defects results in structure-sensitive bulk-dimensional changes that vary with temperature in a complicated way. This paper deals with the neutron-induced dimensional changes in turbostratic carbons that are being used as coatings on nuclear fuel particles. Details of the structure of these carbons and the variations of their structure with deposition conditions have been reported.'-3 It has been shown in previous work that the neutron-

Jan 1, 1968

By Everson P. T, Moyle F. J

Magnesite-rich and dolomite-rich ores from the Savage River region of Tasmania are being considered as potential feed material for a commercial process for production of magnesia.Two selected samples have been characterized by chemical analysis, X-ray diffraction, and differential thermal and thermogravimetric analysis. The materials differ in calcination behaviour, with magnesite decomposing at a significantly lower temperature than dolomite. Calcination conditions have a marked effect on the rate and percentage of magnesium dissolved as the bicarbonate when slurries of the calcine are leached with carbon dioxide. From a process point of view, the feed should have the highest possible magnesite/dolomite ratio, while the optimum calcination conditions are determined by the behaviour of the magnesite component of the feed.From batch calcination tests, it is apparent that the optimum calcination conditions for magnesite-rich ore are a temperature in the vicinity of 700°C and a calcination time of one hour.

Jan 1, 1981