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By J. D. T. Capocchi, M. B. Mourao

The rate of reaction between iron oxides and carbonaceous materials, agglomerated as pellets, was studied experimentally by measuring the weight loss as a function of time. The effects of temperature, carbon type, inert gas flow rate, pellet size and additions (sodium. carbonate and Portland cement) were determined. It was shown that the value of the apparent activation energy can display large deviations under different experimental conditions; in the present work it was found to be 226.6 kJ/mol. The reaction with coke is slower than with charcoal, and the rate increases as the flow of inert gas in the reaction vessel decreases. Comparison of the rates for pellets of different sizes has shown that for small pellets the initial rate is faster but that it slows down at high conversions owing to the penetration of inert gas into the pellet. Additions of sodium carbonate and Portland cement increase the rate; sodium. carbonate promotes the catalysis of the Boudouard reaction, which is the slowest of the partial reactions. The increase in the rate with Portland cement is attributed to the release of water vapour

Jun 18, 1905

By A. K. Tripathy, P. K. Pattnayak, H. S. Ray

The effects of water addition on the solid-state reaction between Cr2O3 and Na2CO3 at low temperatures (up to 873 K) were investigated to determine its possible influence on the reaction rate and the degree of conversion to soluble chromate. Experiments at high temperatures were conducted for comparison. It was found that adding water to the mixture before roasting enhanced both reaction rate and yield significantly. The reactions followed the Lesokhin-Tempelman equation at low temperature and the Ginstling-Brounshtein equation at above 973 K; the respective activation energies were 95 and 22 kJ/mol

Jun 19, 1905

By A. Berckmans

The key variables in the financial analysis of a mining project include the metal price and the quantities of ore and metal. In general, if the metal price drops, the cutoff grade is increased so as to increase the average grade. This causes recovered tonnages of ore and metal to drop. Discussion is presented of the development of a new method to evaluate the relationship between the cutoff grade, z, the ore tonnage above cutoff, T, and the metal quantity above cutoff, Q. Detailed information is provided on the QTz curves for lognormal and inverse gaussian (Sichel's) distributions. Both these distributions are used as models for the grades in different types of ore bodies, and they are both T-symmetric. The geometry of the QTz curves is simplified, making it easier to work out the impact of minor variation in the parameter values for each distribution

Dec 1, 1996

By C. S. Spirakis, A. V. Heyl

Paper presented at the conference Economic geology in Europe and beyond II, models for mineral deposits in sedimentary basins, held in Keyworth, UK, 13-14 April 1994. The modified basinal brines, containing partly oxidised sulphur species, scavenged metals from basement rocks and sediments and transported them through the host rock, which contained local concentrations of organic matter. Reacting in various ways with the mineralising solution as temperatures at the sites of mineralisation changed, organic matter caused the precipitation and dissolution of a variety of minerals in the ore zones; it was organic matter that caused all of these reactions to occur at the same sites. Thus all components of the mineralising fluid - salt, water, heat, sulphur and metals - were obtained within the ore district. The siting of the mineral districts was related to the locations of faults through U- and Th-enriched granites beneath sediments containing basinal brines, and the locations of ore deposits within the districts were controlled by local concentrations of organic matter

Apr 1, 1995

By R. A. Halatchev

A risk model for assessment of the uncertainty in the forecasts of the planned profit is developed. It is based on the selling price of the metal recovered from the ore and the production per shift of the excavators. These two critical variables characterise the economic and technical aspects of the mining venture. Time-series methodology is used to describe the behaviour of the economic variable, which improves the adequacy of the modelling. A hypothetical open-pit gold mine is used to illustrate the application of the model. Results obtained show that the model is a good alternative to sensitivity analysis in taking account of the stochastic character of the price of the metal recovered from the excavated ore and the production per shift of the excavators used. The model can be extended by the inclusion of new variables that have a probabilistic nature

Dec 1, 1996

By B. B. Dhar

Slope stability at the proposed mine in Rajasthan was analysed in two dimensions using a finite difference code. The properties of the rock material were determined in the laboratory and subsequently modified to approximate those of the in situ rock mass. Geotechnical mapping was undertaken to determine the critical orientation of structural discontinuities. The results of the work indicated that an open pit 148 m in depth would be stable with overall slope angles of 60 degrees

Aug 1, 1994

By W. R. Paterson, W. Morton, D. B. Cameron

The Massbal II computer simulation program has been used to develop a general framework for the building of thermochemical models of metallurgical processes. The framework allows the rapid, simple construction of complex models of process equipment for use in flowsheet design, planning and plant operation. Application of the program to model the iron-making blast furnace and a flash smelting process is described

Apr 1, 1991

By S. P. Godby, S. P. Sharples

Wind-tunnel tests were carried out of the conditions under which nuisance dust particles (100-1 000 micrometres) become entrained by wind. A laser entrainment monitoring system (LEMS) was used, and was found to provide an accurate means of assessing nuisance dust emissions from a surface. Accurate determination of the threshold entrainment velocity of dusts using the LEMS gives a baseline against which the performance of dust control techniques can be evaluated. Minerals tested included coal, petroleum coke, limestone, sand and pulverised fuel ash. Pilot field trials of a portable wind tunnel equipped with the LEMS have been successfully completed, providing a means of validating laboratory results in the field

Jun 19, 1905

By S Colak, M Tunc, C Celik, M. M. Kocakerim

The most important parameters affecting the solubility of ulexite (sodium calcium borate) in H2SO4 were found to be reaction temperature and solid:liquid ratio, in that order. Dissolution increased with increase in temperature and stirring speed and with decrease in solid:liquid ratio, particle size and acid concentration, the last effect as a result of decreased precipitation of CaSO4 on unreacted particles. Optimum conditions, in which around 99.5% of the ulexite could be dissolved, were a reaction temperature of 60 degrees C, a solid:liquid ratio of 1:8 g/ml, an acid concentration of 8 mol/l, particle size smaller than 425 micrometres, a stirring speed of 52.33/s, a reaction time of 1 800 s, a calcining time of 3 600 s and a calcining temperature of 170 degrees C. These conditions, determined by the Taguchi method, are reproducible in a commercial production environment

Jun 21, 1905

By M. M. Cole

An assessment of the combined application of remotely sensed satellite imagery, geobotany and biogeochemistry reveals the complementary value of these techniques in the Thalanga area. The SPOT imagery yields useful information on features of the terrain and discriminates the gossan over the ore zone. Geobotany differentiates geological units and the anomalous vegetation provides visual expression of the surface presence of the ore zone, while biogeochemistry effectively locates its concealed extension below Tertiary sediments and ferricrete

Jan 1, 1991

By P. A. Rossouw, G. A. Fourie

Several attempts have been made over the latter half of the twentieth century to devise a system for the classification of underground mining methods. None of these are found to be totally successful. A revised classification is suggested with three main categories being identified by reference to fill requirements, steep stopes and stratified geological environments. Methods always needing lasting mass or structure fill include methods with timber-structured stopes and those with mass-filled (or cut-and-fill) stopes. Methods associated with steep stopes are subdivided into steep-stope-specific caving and steep-stope-specific non-caving (or self-supporting) methods. Methods not in the first two categories, often used in stratified geological situations, are not necessarily restricted to stratified environments and include caving as well as non-caving varieties. This category is further divided into room-and-pillar mining, longwall and shortwall coal mining and the type of open stoping found in gold or platinum reefs comprising overhand, underhand and breast-stoping variations

Dec 1, 1996

By M. J. Scoble, L. M. Daneshmend, C. Hendricks

Paper presented at a meeting on: Artificial intelligence in the minerals sector, held in Nottingham, UK, 20 April 1993. An attempt is made to relate emerging technologies to education and training requirements by examining the nature of the Canadian mining industry's human resources. Particular attention is given to the trends evident in mine automation and their likely impact on instructional needs. The characteristics of "computer-aided instruction" systems are reviewed and related to the implementation and support of mine-wide monitoring and communication networks, which are seen as fundamental to the eventual automation of underground hardrock mines

Apr 1, 1994

To maximise recovery by highwall mining, pillars must be designed which are long, slender and of relatively low width-to-height ratios. The strength of pillars with width/height less than 2 depends primarily on the mechanical response of the coal, due to the reduced influence of frictional restraint between roof and floor. A suitable pillar design approach therefore requires a method of estimating coal-seam properties. Experimental studies were carried out to determine ways of reliably predicting the large-scale mechanical properties of coal seams from small-scale test data. The studies led to a method of practical, systematic assessment of coal-seam properties based on measurement of coal rank and seam brightness profiles. The criterion employs the parameters sigma(c), m and s of the generalised Hoek-Brown empirical strength criterion for rock masses. A novel design approach combines the flexibility of modern numerical modelling programs with simple hand calculation for rapid assessment

Jun 21, 1905

By R. A. Ixer, R. A. Lord, H. M. Prichard, A. J. Boyce, P. McConville, C. T. Pillinger, I. P. Wright, J. Maynard

Analysis of 62 samples show that the sulphides throughout the igneous stratigraphy have a magmatic signature, with the exception of the uppermost gabbros and the lowermost basal thrust talc-carbonate lithologies. Mean delta-34S values for whole-rock samples from harzburgites, dunite pods in harzburgite, crustal dunites and wehrlites, the main and high-level pyroxenites and gabbros suggest that the primary sulphides derived their sulphur from a magmatic source enriched in 34S. This finding is compatible with the proposed origin of the ophiolite above a subduction zone. Values for pyrite mineralisation in the uppermost part of the gabbros are thought to result from precipitation from a seawater-derived fluid, while isotopically light sulphur in the basal thrust could have been introduced from underlying metasediments. The replacement of pentlandite by heazlewoodite has not led to sulphur fractionation

Jun 19, 1905

By R. J. Gochin, M. A. Diaz

A modified Hallimond tube is described which allows the determination of the ultimate recovery R and the flotation rate constant k in a single, continuous experiment. The range of fine particles which can be satisfactorily floated with the modified apparatus can be extended by increasing the length of the bottom part of the tube. Findings suggest that pyrite and arsenopyrite can be separated in alkaline suspension using the so-called F series of collectors. Lime was found to act as a depressant. The collectors operate under pH and dosage control and do not require other depressants. Collectors used in the study were thio-amine (a cationic surfactant) and alkyl propionamide (a non-ionic surfactant)

Apr 1, 1995

By B. Tiryaki, O. Z. Hekimoglu

Shearer drums are a critical component in the overall performance of coal shearers, with the cutting performance depending very much on the disposition of cutter tools on the drums (the tool-lacing arrangement). A series of practical and theoretical studies has been undertaken to investigate aspects of shearer drum vibration in terms of circumferential pick spacing. A number of commercially available drums were redesigned and the lacing patterns compared with those of the original drums under near-uniform conditions. Mine trials were carried out at the Middle Anatolian lignite mine in Turkey with drums fitted on Eickhoff type EDW-230 double-ranging drum shearers. It was found that the performance of drums could be improved if the concept of circumferential pick spacing was taken into account in CAD packages along with the existing design parameters such as cutting rate, reduced dust, low pick consumption and low down-time

Jun 19, 1905

By G. Adachi, K. Machida, T. Ozaki, K. Murase

The chlorination rate with CCl4 was unexpectedly slower than carbochlorination using chlorine under the same reaction conditions. Chlorination with CCl4 was topochemical and the amount of monazite reacted after different periods suggested that the kinetic control step was the reaction between CCl4 and the monazite core at the interface. The kinetic order of the reaction was 0.5. The presence of a complex former, AlCl3, promoted the chemical vapour transport of rare-earth chlorides as complexes

Jun 18, 1905

By R. R. Tatiya

Data obtained from a copper mine were used in a comparative study of the reserve estimates generated by applying geostatistical methods to surface borehole data, underground core drilling results and assay values from chip sampling. Global estimation of the deposit performed by kriging of the low-density sampling data from the surface boreholes did not provide reliable results, but could identify the potentially mineralised zones. The reserve generated from core drilling results correlated well with that estimated from chip sample data and with that estimated by the conventional methods used at the mine. A satisfactory reserve evaluation could, therefore, be obtained by kriging of the data from the underground core drilling alone, provided that a systematic sampling procedure was adopted. Estimates based on chip sampling information could be used as a check, which could avoid the current practice of chip sampling of most of the mine workings. The aim should be to develop a semi-variogram for the deposit, which could be used to estimate the reserves by kriging

Jun 19, 1905

By M. K. Abd El-Rahman

A complete chemical analysis of the waste showed that it contains 15.64% P2O5; X-ray diffraction analysis revealed that it is composed mainly of francolite, calcite, pyrite, quartz and dolomite. The phosphate values were recovered and the settling rate of the wastes enhanced by the use of hydrocyclone and flocculation techniques. The hydrocyclone produced an underflow enriched in phosphate and an overflow enriched in clays. The former represented 39.8% by weight of the phosphatic clay waste and assayed 26% P2O5 at a recovery of 66.36%. The results of flocculation of the phosphatic clay waste showed that both the degree and rate of settling were increased and that the process water could be recycled. The settling rate was 37 times greater when anionic polyacrylamide A130 was used

Jun 21, 1905

By S. L. Gay

The conventional mass-balance equations used as constraints can lead to flow estimate values of zero even though the flow estimates should be some positive number. This is because many of the constraint equations are satisfied if the flow rates are zero. The way to overcome the problem is to use a slightly different form of the equations. For example, rather than use the conservation of flow of solids as a constraint it is better to use the constraint that the percentage of solids going into a unit equals the percentage of solids coming out of the unit. Examples are given using mineral processing data sets from Mount Isa, Queensland, and Red Dog, Alaska

Jun 21, 1905