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By V. Gaudreault

Rio Tinto Alcan (RTA) has three smelters that use the Alcoa P155 technology: two in Canada (Grande-Baie and Laterrière, Saguenay, QC) and one in the United States (Sebree, Kentucky). The oldest RTA P155 smelter was built in the 1970s (Sebree) and had an initial current intensity of 155 kA. In the 1990s, RTA installed an amperage booster in Grande-Baie smelter to increase cell productivity. Since then, RTA has continuously pushed the limit of this technology and the target amperage that was 195 kA in 2005 has been increased to 210 kA in 2010.This article describes the successful plant-scale trials to increase current intensity from 195 kA to 210 kA, and the key performance indicator results. It demonstrates RTA's technology leadership to undertake such a development with its Brownfield smelters.

Jan 1, 2011

By L. Yuan, J. Qin, J. Xie, Q. D. Qu, Y. P. Liang

"This paper presents key outcomes of a major Asia-Pacific Partnership project between the Commonwealth Scientific and Industrial Research Organisation and Huainan Mining Industry Group Co. Ltd. to develop and demonstrate advanced technologies at Pansan mine, Huainan, China. A comprehensive approach assessed fundamental strata and coal seam methane conditions during mining and optimized mining sequences and coal mine methane capture systems. The project demonstrated a practical approach and procedures for advanced coal and methane co-extraction systems, improved mining safety and efficiency, increased methane capture and use, and reduced fugitive methane emissions.RÉSUMÉ Le présent article donne les principaux résultats d’un grand projet de partenariat Asie- Pacifique entre le CSIRO (Commonwealth Scientific and Industrial Research Organisation) [Organisation de recherche scientifique et industrielle du Commonwealth australien] et le Huainan Mining Industry Group Co. Ltd.; ce projet cherche à développer et à démontrer des technologies avancées à la mine Pansan, à Huainan, en Chine. Une perspective globale a évalué les conditions fondamentales des strates et du méthane dans les couches de charbon durant l’exploitation et a optimisé les séquences d’extraction et les systèmes de captage du méthane dans les mines de charbon. Le projet a permis de démontrer une approche pratique et des procédures pour des systèmes avancés d’extraction conjointe du charbon et du méthane, pour améliorer la sécurité et l’efficacité minières, accroître le captage et l’utilisation du méthane et réduire les émissions fugitives de méthane."

Jan 1, 2015

By J-P. Rossetti, A. Guerin, M. Jaboyedoff, L. Baillet, A. Mariscal, J. D'Amato, D. Hantz

"The processes leading to the fall of rock compartments from rock walls are poorly known as well as their velocity. It ensues that quantitative prediction of the failure time for a rock compartment which is presently stable, is not possible by a purely geomechanical approach. However a quantitative probabilistic prediction of rockfalls at the scale of a rock wall is possible if the spatial-temporal rockfall frequency can be determined or estimated (Hantz, 2011). For a better knowledge of failure processes and frequency, rockfalls have been detected in several rock walls, using annual terrestrial laser scanning, allowing comparison of the frequencies in different geological conditions. For one of these rock walls, the spatial detection have been completed by a precise dating of the events, using a quasi-continuous photographic survey (one photo every 10 mn), allowing the study of the influence of meteorological factors.The precise dating of rockfalls has been carried out for the Saint-Eynard cliff which towers above a residential area of the town of Grenoble (French Alps). The South-East facing cliff consists in bedded limestone gently dipping North-West and located at an elevation between 850 m and 1100 m. The surveyed zone is about 750 m large and 250 m high. Between 01/02/2013 and 26/11/2013, 65 rockfalls ranging between 0.01 m3 and 20 m3, have been detected by diachronic comparison of laser scanner data and dated by comparison of photographic images. The temperature at the elevation of the cliff has been calculated from the temperature measured (every 5 mn) at a meteorological station located at an elevation of 245 m and 2.5 km away from the cliff, using a temperature gradient of 0.003°C/m (D’Amato et al., 2014). The precipitation were measured 900 m away from the cliff at an elevation of 469 m. Different meteorological conditions have been defined: (a) “freeze” qualifies days with negative mean temperature (but with a thaw period, except for two days); (b) “thaw” qualifies days with positive mean temperature, but following a freeze day; (c) “rain” qualifies days with precipitation.Table 1 shows the rockfall temporal frequency for the different meteorological conditions. It appears that the frequency is about 6 times higher the freeze days, 2.5 higher the thaw days and 3 times higher the rain days than days without freeze, thaw or rain."

Jan 1, 2015

By A. Mehinrad, F. Rafia

"The Dez River flows from the Zagros Mountains into the great Khuzestan plain, Southwest of Iran. The 203 m high Dez Dam is a double curvature thin concrete arch dam, with a Pulvino, founded on thick bedded to massive conglomerate of Bakhtiary Formation, mainly horizontal and very less jointed at the dam site. Construction work was completed in 1963, creating a reservoir with a total storage volume of 3’315 million m3. The dam body, with some 350’000 m3 volume and (W/H=1.1/1.0), is the dominant feature of the project.Geological and geotechnical studies at the dam site started in 1957 and continued during the whole period of dam construction. Simultaneously, two extensive programs of laboratory testing were carried out in New York and Milan.Most of the results were recorded in the project design documents and in two very well-known papers of Talobre et. al. (1964) and Dodds (1966), however, no detail results are available for most of tests.In order to estimate geomechanical parameters of the rock mass foundation for numerical modeling of the dam body and its foundation, reassessment of the in-situ and laboratory test results using the recent rock mechanics methods was required.This paper explains how the outcomes of those tests, performed more than 50 years ago, were reevaluated and how the definitions and parameters presented in the project reports were re-interpreted using the recent rock mechanics concepts and definitions. Also, the results of classification of Bakhtiary conglomerate using GSI system and application of Hoek & Brown failure criterion for estimating rock mass parameters have been described.INTRODUCTIONThe Dez River flows from its headwaters in the Zagros Mountains into the great Khuzestan plain. Just before entering the plane, the river passes through a narrow, steep gorge that is about 17 km long. The Dez Dam is located at the entrance to this gorge, some25-km upstream of the city of Dezful and 150-km upstream from the provincial capital Ahwaz (Figure 1)."

Jan 1, 2015

By T. S. Heah, S. T. Bishop

"The Lorraine property is located in the northern Intermontane Belt, north-central British Columbia. The property is underlain by intrusive rocks of the Duckling Creek Syenite Complex, an Early Jurassic, alkaline phase of the Late Triassic-Early Cretaceous Hogem Batholith. Two significant zones of copper-gold mineralization have been explored to date; the Main zone (historical Upper and Lower deposits) and the recently discovered Extension zone. A combined geological resource was estimated in 1975 for the Main zone deposits at 10 million tonnes averaging 0.7% Cu, and from 0.1 g/t Au to 0.34 g/t Au. The Extension zone, still at an exploration stage, is estimated to be considerably smaller than the Main zone.Copper-gold mineralization at Lorraine Mountain exhibits characteristics suggestive of both magmatic and hydrothermal origins, and may be related to orthomagmatic-hydrothermal fluid flow contemporaneous with magmatism and development of migmatitic fabrics. A depth greater than the depth of formation of classical porphyries may explain many of the variations displayed by mineralization at Lorraine. These characteristics distinguish Lorraine from other members of the alkalic suite of porphyry Cu-Au deposits in the Canadian Cordillera.IntroductionThe Lorraine prospect is located in the Omineca Mountains, at the headwaters of Duckling Creek, 56 km northwest of Germansen Landing (Fig. 1). The property is centred at latitude 55°55'N, longitude l25°26'W on NTS mapsheet 93N/14W. The area is typified by mountains of moderate relief, with elevations ranging from 1150 m in the valleys to peaks of 2000 m. Valleys are U-shaped and blanketed by glacial till which give way to steep, talus covered slopes and sharp ridges. Outcrop is generally limited to elevations above 1600 m (Fig. 2)."

Jan 1, 1995

By P. Müller, W. J. Przybylowicz, V. M. Prozesky, D. de Bruin

"Abstract -The common style of gold mineralization in the Basal Reef and other auriferous conglomerates of the Witwatersrand Supergroup comprises clusters of gold grains occurring interstitially to quartz and pyrite pebbles as well as gold accumulations attached to the surface of and infilling hairline cracks and fractures in round, compact, detrital pyrite. The latter textural association is generally interpreted as a result of remobilization of originally detrital gold during regional metamorphism and related hydrothermal fluid circulation. There is general agreement that, although gold solubility was Iow, ore modification occurred during the metahydrothermal event, but uncertainty exists about the magnitude and scale of gold remobilization .Micro-textural and chemical investigation of compact round pyrite and associated gold accumulation has established that gold is preferentially deposited on chemically heterogeneous pyrite surfaces. Combinations of alternating high- and low-As zones in pyrite result in mixed np-type conductivity accompanied by electron exchange and the reduction-driven deposition of gold at the cathode. This mode] does not explain gold accumulations which are not immediately linked to chemical heterogeneities and it is inferred that an additional control on the deposition of gold was exerted by physical defects which lead to zones of increased charge density and/or areas of focussed conductivity. The inferred precipitation mechanisms suggest that submicrocopic physical and chemical controls are the important factors that determined the sites of gold nucleation and that precipitation mechanisms based on physicochemical changes of the hydrothermal system were not involved. The Basal Reef contains on average close to 5% of round, detrital, chemically zoned pyrite which provides a large number of electrochemically active pyrite surfaces. The extremely effective electrochemical precipitation mechanism together with the low solubility of gold in Witwatersrand fluids is the main reason for the spatially restricted remobilization of gold in the conglomerate reefs."

Jan 1, 1994

By B. Tougas

Recycling of titanium represents an important economic activity due to high cost of the material and the amount of returns of machined parts which represent the bulk of finished titanium products (typical "buy to fly" of 10 in the aeronautic industry). In the present work, the metallurgical quality of 76 mm in diameter and 20 cm ingots poured in coated graphite mold will be assessed against the nature and condition of application of 4 coatings namely aluminum oxide, yttrium oxide, zirconium oxide and zirconium oxide with 4% aluminum oxide. The metallurgical quality has been evaluated in terms of alpha case thickness, microstructure and composition. Microhardness from surface will be assessed against casting conditions. Least square regression analysis have been use to optimize casting conditions.

Jan 1, 2011

By K. Halada

Current trend of the global flow of strategic metals are analyzed to discuss the strategy of the development of recycling technology and alternative technology. In many cases, each global flow of metal is changing from the trilateral structure of U.S., EU and Japan in the later 20th century into the convergence to China as the factory of the world. Scrap flows are also changing dynamically. A long term change of prices of metal has gotten changed since the entrance of this century. The estimation of metal consumption up to 2050, in which the author estimated that many kinds of metal will overshoot the reserve base line, is revised considering these change of current trends.

Jan 1, 2014

By A. Ehsani

"Seas and oceans constitute about 70% of the earth’s surface. They contain an enormous stock of various mineral resources such as sedimentary (marine placers), massive sulfide ore deposits, manganese nodules and cobalt-rich ferromanganese crusts. Sea and ocean floor ore deposits could well contribute to the meeting of ever-rising demand for raw materials in the metal industry. In this regard, more research and development in science and technology appear to be required to ensure maximum benefit from the mineral resources of seas and oceans. Since the 1960s, a variety of mineral and metallurgical processes have been studied and developed to deal with marine ores and to extract metals such as gold, nickel, copper, cobalt, manganese, tin, platinum group metals (PGM), zirconium, thorium, etc.In marine environments, there are many parameters which can affect the selection of the mineral and metallurgical processes. These include the extent and grade of the deposit, mineralogical and chemical properties of the deposit, and physical properties of minerals present with particular reference to particle size distribution and mineral liberation size.In this paper, we briefly review the latest trends in processing and extraction of marine mineral resources. Mineral processing technology is mostly applied for recovery of precious metals i.e. gold and PGM, in particular, from marine placers. In general, pre-treatment (sizing, classification, dewatering), gravity concentration techniques (shaking tables, spirals, jigs, etc.,), flotation, magnetic, and electrostatic separation are the options for enrichment of marine placer ore deposits. In the case of massive sulfides, manganese nodules/cobalt-rich crusts, hydrometallurgical and pyrometallurgical methods (as proven technological methods) can be exploited for extraction of metals from concentrates after physical separation or directly from marine ores. The hydrometallurgical treatments involve acid (e.g., sulfurichydrochloric) and alkaline (e.g., ammonia) leaching with different reducing agents and pre-treatments such as roasting. Alternatively, pyrometallurgical treatments involve mostly smelting, chlorination and segregation processes."

Jan 1, 2016

By K. Yamaguchi

To contribute highly efficient and environmentally conscious copper smelting process, several topics in chemistry of the continuous converting were discussed. Through the reviewing the authors' thermodynamic simulations, it is recognized that small amount and low copper content of the coexisting slag is preferable. Some discussions were added to the Takeda's diagram for Cu20-Fe0x-Ca0 ferrite slag, and the activity curves of the constituents were derived. Thermodynamic calculations were carried out on the copper contents of the slag during the blister copper formation. The dissolution of copper in slag decrease somewhat with increasing temperature, but the effects of increasing S02 pressure and decreasing %S in copper are considerable to increase in copper content of the slag. The optimum oxygen enrichment in the supplied air, and regulation of the oxidation degree for the blister copper are important in practice. The gypsum phase separation in the calcium ferrite slag was also evaluated thermodynamically, and concluded that decreasing temperature, increasing CaO content or S02 pressure, and extensive oxidation of the blister copper tend to separate CaS04. 0

Jan 1, 2007

By A. Quilodran, B. Jakovljevic, T. McCallum, P. Wong

"Rare earth separation by solvent extraction (SX) requires multiple separation plants each consisting of many extract, scrub, and strip stages to separate the individual metals. SX modeling advances have brought benefits to circuit design and process optimization by quickly narrowing test conditions without the need for exhaustive laboratory studies. Modeling can be used to optimize circuit configuration, O/A ratios, and acidities, which allows for CAPEX and OPEX savings. A comparison between pilot plant data and the results expected from modeling is presented for rare earth separations with CYANEX® 572.INTRODUCTIONRare earth separations can be difficult due to limited separation between the elements (Xie, Zhang, Dreisinger, & Doyle, 2014). This requires relatively complex solvent extraction circuits utilizing multiple extract, scrub, and strip stages as well as multiple SX configurations to achieve the desired metal purities. Designing rare earth circuits can be complex, and significant time and testing may be necessary to determine the required staging and optimal conditions.Circuit modeling for rare earth separations has been introduced to the industry using CYANEX® 572 extractant (Soderstrom, McCallum, Jakovljevic, & Quilodran, 2014). CYANEX® 572 is an acidic organophosphorus extractant formulation which has a weaker ligand-metal complex strength than that of the traditionally used phosphonic acid extractants. This allows efficient extraction while requiring a significantly lower acid concentration for stripping (Wang, Li, Zhao, Dong, & Sun, 2015). The reduced acid requirement in strip is expected to provide OPEX savings.The modeling can be utilized to quickly determine the required acidity and organic/aqueous (O/A) ratio for a given separation. It is also expected to reduce CAPEX requirements as optimal staging can be determined, and implemented.CYANEX® 572, combined with modeling, was utilized to produce a purified dysprosium (Dy) stream. To achieve this separation, multiple SX circuits were designed and operational conditions specified to separate Dy from the mixed rare earth chloride feed."

Jan 1, 2016

By W. A. Gow, H. H. McGreedy

It is believed that many of the problems encountered in the operation of gold cyanidation plants are difficult to resolve due to the lack of sufficient and reliable in-formation regarding the variations and actual values of operating variables at any given time. The application of instruments to monitor the more important variables in the cyanidation process should result in more efficient plant operation and a better understanding of the process. The use of pH and conductivity sensing devices for alkalinity measurements, a monitor to determine the dissolved oxygen content of plant solutions, a continuous cyanide titrator and sonic control of grinding circuits are discussed. Although the discussion is oriented toward the cyanide process, much of the paper is applicable to other ore treatment operations.

Jan 1, 1966

By Richard Simon

This paper presents an ongoing study on the use of borehole breakouts to estimate in situ stresses at depth in a Canadian underground mine. Breakouts were identified using an acoustic televiewer (ATV) probe. Rock samples were tested in a laboratory to determine their failure curve. Breakout analyses were performed using a 2D failure criterion and a multiaxial failure criterion. Analyses were carried out using both short-term (peak) and long-term strengths (the latter considered here as being represented by the damage initiation threshold DIT). The analyses have shown that the use of the longterm strength and a multiaxial failure criterion leads to results that are more consistent with stress measurements performed in the field, in the vicinity of the mine.

Jun 1, 2012

By A. H. Anderson

THE travelling grate coking process was developed by Shawinigan Chemicals, Limited, at their Shawinigan Falls plant. The first production unit went into operation a month prior to the outbreak of the war. Since then a substantial part of the coke used in the manufacture of calcium carbide has been produced by this process. In the following will be given a short account of the development work, a description of the process and the equipment, a discussion of the properties of the coke, the economics of the process and its future possibilities. EXPERIMENTAL WORK The carbide industry is a large consumer of coke, one ton of commercial carbide requiring for its production 1,200 lb. This coke must meet certain specifications in order to be acceptable. It should have a low ash content, preferably below 8 per cent, and the sulphur and phosphorus content must not be above specified limits. The size of the coke is also important. If it is too large it has to be crushed before it can be used in the furnaces, and if it is too fine it may have to be screened and briquetted. In addition, it must be dry. Although it was generally possible to purchase coke, including petroleum coke, and coke fines, in the quantities required, it became increasingly more difficult as time went on to obtain coke of a suitable quality at an attractive price. It was therefore natural for us to look to coal carbonization as a means of basing the supply of the fundamental raw material for carbide manufacture on something more solid than the shifting conditions of the coke market.

Jan 1, 1944

By Tassos Grammatikopoulos, Vladimiros Papangelakis, Douglass Duffy, Cheryl Washer, Srinath Garg

Flotation operations in Sudbury, Ontario, seeking to separate pentlandite and chalcopyrite from mixed sulphide deposits, produce pyrrhotite tailings that have been disposed of in tailings ponds for over 50 years. These reactive tailings are viewed as waste, despite containing ~0.8 wt% Ni, and represent an environmental liability because of their acid mine drainage (AMD) potential. Given the large quantities of pyrrhotite currently stored in Sudbury, and declining ore grades elsewhere, these tailings have shifted from being viewed as a waste to a potential resource. Recent advances in the bioleaching of low-grade sulphide ores have raised the prospect of bioleaching as a potential low-cost processing option. However optimization of this proposed process requires a thorough understanding of the mineralogy of the pyrrhotite tailings that would be leached. The work presented here addresses the characterization of two distinct Sudbury pyrrhotite tailings, namely from the Vale and Glencore operations, using electron microprobe, XRD and QEMSCAN analysis. Particular focus is given to how the mineralogy may affect bioleaching as a processing option, through the deportment of nickel and the various phases present

Jan 1, 2015

By W. de Klerk, M. B. Thorpe

Golden Star Resources Bogoso operates in Ghana’s Western Region. The gold recovery plant includes; a flotation circuit producing a concentrate for the BIOX® process that oxidizes sulphides before a CIL circuit; and a dedicated CIL circuit. BIOX® uses bacteria, therefore water from the BIOX® and CIL plants remained separated; CN water could not be introduced into the flotation / BIOX® circuit. The operation built a process water inventory with high TDS and installed a process water treatment plant (PWTP). Water was released in compliance the permits but containing some thiocyanate. The PWTP brine was returned to the TSF, further exacerbating the TDS. The operation experienced a drought removing the traditional water sources; the team evaluated the options to maintain production - various water streams were laboratory tested provided options for water use. The paper presents the story (treatment chemistry and process chemistry) of continued operations by treating stored water and PWTP discharge water with peroxide; brine usage within the CIL circuit, which increased gold recovery (laboratory testing) and reduced the TDS. Water flows were further modified to include hydraulic tailings re-mining to a CIL circuits. Details of the recovery, basic chemistry and costs savings are provided.

Jan 1, 2014

By Arnfinn Prugger

"The construction of the new Scissors Creek shaft at the Rocanville mine, the first potash shaft successfully completed in Saskatchewan Canada since 1979, is summarized here. Located 15km from the existing Rocanville surface plant, this new 6 m inside-diameter, 1121 m deep service shaft was built for fresh-air ventilation and access. Shaft construction in the Saskatchewan sedimentary basin involves sinking through five different rock-types: glacial tills, shales, sandstones, carbonates and salts. The first four rock- types are all water-bearing, and the salts will dissolve in water. This results in five different sinking challenges and requires five different shaft lining designs. The upper 580 m of rock (the till – shale – sands sequence) was frozen before sinking, and grouting methods were used for water control through deeper carbonate levels. Challenges that were faced and overcome during shaft sinking are reviewed, and ideas that future operators working in sedimentary basin environments might consider in order to avoid these difficulties are discussed.INTRODUCTIONThe Nutrien Inc. (formerly Potash Corporation of Saskatchewan Inc. / PotashCorp) Rocanville potash mine in southeast Saskatchewan, Canada has been in continuous production since 1971. Devonian potash, formed approximately 380 Mybp, is mined in a sedimentary basin environment at approximately 1000 m depth below surface in this area of Saskatchewan. The predominant use for finished potash products is fertilizer: potash fertilizer is concentrated and nearly pure KCl (i.e. greater than 95% pure KCl). Currently 10 potash mines are in operation in Canada, all in Saskatchewan. In 2018 Saskatchewan mines produced ˜ 23 million tonnes of finished potash products, which is approximately 35% of World demand of ˜ 66 million tonnes for the year (e.g. Nutrien Inc., 2019).In November, 2007 it was announced that the Rocanville potash mine would be expanded to increase production from 3.0 Million tonnes per year (Mtpy) to approximately 6.0 Mtpy of finished potash products, requiring an increase in hoisting capability from approximately 9.0 Mtpy to over 18.0 Mtpy. The Rocanville potash mine has historically been accessed through two shafts: a production and ventilation exhaust shaft, and a service and ventilation fresh-air shaft located approximately 200 m from each other. All surface offices, processing facilities, etc. are situated near these original shafts.A very important part of the recent Rocanville expansion involved the construction of a new service shaft (6 m diameter, 1121 m deep) for fresh-air ventilation and access, approximately 15km west of the existing surface plant. Once this third shaft was completed in 2015, the historical service shaft was converted to a second exhaust and production shaft. Three shafts are now available for mine access, ventilation and ore hoisting at Rocanville. As of December 31, 2017, annual nameplate capacity for Rocanville was 6.5 million"

Jan 1, 2019

By John A. Meech

"Oleic acid flotation of Mount Wright thickener underflow tailing material has been shown to be capable of increasing plant recovery by 3%. High levels of oleic acid addition (1.5 kg/t) are required, which limit the economic practicality of the system at this time. Nevertheless, from a technical viewpoint, the process is stable with respect to extreme fluctuations in oleic acid requirements, pulp pH and pulp temperature. Methods to reduce the average consumption of oleic acid need to be found. One technique that merits further testwork uses the ""piggy-back"" principle to float hematite fines with coarsegrained hematite particles.IntroductionWith most large-scale iron mining operations treating specular hematite ores, flotation is not often conside red a necessary processing step. The bulk of the iron minerals can be concentrated by gravity techniques and the generation of fines can be minimized because of the course- grained nature of the mineralization. Nevertheless, production of some fine material is unavoidable, and recovery of iron from this fraction by spirals is poor (10-30%).When the proportion of the iron in these fines becomes excessive, alternative methods to conventional spirals are considered(11), Many of the techniques that have been developed suffer from either poor recovery (e.g. the Reichert cones at 36010 recovery)(11) or low throughput rates (e.g. wet highintensity magnetic separation)(12), Flotation is often passed over because of excessive reagent costs, pollution problems and/or balling difficulties from the reagents used.However, of all the processes available, flotation can yield high recoveries (60-90%) at reasonable throughput rates with excellent process control features (reagent addition and/or cell level). The key parameter is reagent cost.This paper describes testwork on the use of oleic acid to float hematite from the fine fractions of the Mount Wright concentrator tailing. The concentrate product from this plant is directly shipped, so no balling problems exist. As well, oleic acid may be considered a lesser pollution hazard than many of the cationic collectors used in other iron ore flotation systems. A reduction in fine hematite slimes discharged as tailing into lakes may also reduce environmental damage."

Jan 1, 1981

By Long Han, Beijing General Research Institute of Mining and Metallurgy, Yu Xie, Yunhai Zhang, Yangge Zhu, University of Science and Technology Beijing, Yanbo Shang, Xingrong Zhang

"The first-principles method was employed to study the adsorption of hydroxyl calcium (CaOH+) and hydroxyl (OH-) on hematite and quartz surfaces. The calculation results suggested that OH- preferred to interact with the active Fe sites on the hematite surface, whereas OH- adsorbed on the quartz surface by weak hydrogen bond. Though CaOH+ could easily adsorb on the hematite and quartz surfaces by the formation of Ca-O bond, the covalence formed on the quartz surface was apparently stronger than that on the hematite surface, meaning a stronger and more stable adsorption. CaOH+ adsorbed on quartz surface was mainly through the interaction of O-2p and Ca-3d states, and this interaction on hematite surface was weaker.INTRODUCTIONIron Increase and Silicon Reduction Technology (Yu & Duan, 2002) of hematite is mainly through the reverse flotation (silica is floated away from the iron concentrate). There are two ways to achieve this (Houot, 1983). One is to collect quartz by cationic collector directly; the other is to activate quartz by lime and then collect it by anionic collector. There are two main different views with respect to the mechanism of quartz activation: mono-hydroxyl compound theory (Fuerstenau, Rice & Somasundaran, 1965; Fuerstenau & Palmer, 1976) and surface hydroxyl precipitation theory (Hu & Wang, 1988; Wang & Hu, 1990). The former indicated the formation of the mono-hydroxyl complex is one of the two criteria of quartz flotation. The later theory, on the other hand, suggested that surface precipitation is the adsorption of active species of metallic ion on quartz surface. However, most of those researches are based on the solution chemistry of flotation and little is done at the microscopic level.In this paper, by the help of first-principles calculations, the adsorption models, bonding conditions, Mulliken charge populations and adsorption energies of hydroxyl and calcium hydroxyl ions (OH- and CaOH+) on hematite (001) and quartz (100) surfaces were investigated to find out the lime activation of quartz at atomic level, which is significant for the researches of quartz activation theoretically and practically."

Jan 1, 2016

By E. Asselin, P. Sauve, H. Salomon-de-Friedberg

"Residues from the CESL Copper process were leached using the CESL Gold process. The kinetics of reaction were confirmed to be fast with over 50% of the gold consistently extracted within 2 minutes of leaching. Final gold extractions under the conditions tested here were between 80-90% obtained within 90 minutes. A model for the CESL Gold process was developed. This model is slightly different based on whether the copper concentrate leach residue was ground or unground prior to leaching: the gold leaching rate constant is approximately twice as fast for the ground samples. Unground residues had a P80 of 13 ?m whereas ground residues had a P80 of 10 ?m. The model predicts a 43% decrease in leaching time for ground residue versus unground residue to achieve the same extraction under otherwise identical conditions. The model was more accurate for the ground samples. INTRODUCTIONTeck's CESL Process (Jones, 1996) was developed to provide an economically attractive alternative to traditional copper smelting. It has since evolved to also deal with copper concentrates containing valuable impurities such as nickel and undesirable ones, such as arsenic, while reducing downstream costs. Effective recovery of gold and silver is essential to the economics of the CESL Process. The Brook Hunt 2007 copper concentrate assay data (Wood-Mackenzie, 2007) were examined to determine the ratio of gold plus silver value relative to the contained copper. As indicated in Figure 1 below, nearly two-thirds of concentrates have 10% or more of their total value tied up in their precious metals content.CESL has extensively examined the recovery of gold and silver at bench, pilot and demonstration scale, which has culminated in the present CESL Gold Process (Barr et al., 2007). The process targets the precious metal contained in the leach residues produced in the copper portion of the flowsheet. This residue has two primary components which influence downstream processing. The major iron-rich fraction (-75 wt%) of the residue is a mixture of various forms of iron oxide precipitates including hematite and jarosite (Sahu and Asselin, 2011). The iron fraction ranges from amorphous to crystalline in nature depending on the compound precipitated, upstream operating conditions and feed material composition. The lesser, but by no means less important, fraction is a mixture of elemental sulphur and unreacted sulphides (principally pyrite).Elemental sulphur formed during the oxidative leach of the copper concentrate reacts with cyanide to form thiocyanate (SCN-) making a traditional cyanide leach approach too costly. Since the SCN formation reaction strongly depends on contact time with the CESL residues (Po, 2007) short contact times were preferred. This factor guided the development work towards the eventual room temperature, pressure cyanidation process which results in near complete gold dissolution in 90 minutes. A recent CESL gold demonstration campaign treating 1.5 t/d of residue from the copper oxidation step achieved an average gold extraction of 91% (96% maximum)."

Jan 1, 2012