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By James Dickson

Brief History of Discovery and Early Development In the first half of the nineteenth century, the only authority on the Pacific coast between the Columbia river and Alaska was exercised by the Hudson's Bay Company, who had established a series of forts and trading stations on the coast from the Columbia north to Millbank sound. The Hudson's Bay Company were chiefly interested in the fur industry, and the large influx of settlers from the eastern United States into the territory now known as the States of Oregon and Washington, about 1840, not only interfered with the fur business but involved the question whether the territory should be under the British or the American flag. Anticipating the possibility, later realized, of losing control of this area, the Company, in 1845, established their main fort and trading centre on the southern end of Vancouver island under the name of Fort Camosun; shortly afterwards changing the name to Fort Victoria. Realizing that their former policy of discouraging all attempts to develop any other business than the fur industry had lost them several hundred thousand square miles, the Hudson's Bay Company now set about encouraging settlers in the vicinity of Fort Victoria by disposing of lands to suitable parties and also to those in the employ of the Company. The usual pioneering stage was passed through with the starting of small sawmills, grain mills, etc., and the incidental work accompanying such efforts. Any coal required for blacksmithing or other purposes was brought from England around Cape Horn by the few ships that visited the Pacific Coast. About 1849, an Indian who was having his gun repaired by a blacksmith in Fort Victoria asked about the "black stones" used in the fire and, on being told that the "black stones" had to be brought a great distance, he informed the blacksmith that there was plenty of the same stone where his people lived. This information was immediately given to an official of the Hudson's Bay Company who talked with the Indian and told him that if he would bring some of the "black stones" he would get his gun repaired free and a present of a bottle of rum. Nothing more was heard of this coal until April of the following year, when the Indian came into Fort Victoria with his canoe loaded with coal, which was tested and found to be of good quality. It is reported that the Indian got his bottle of rum.

Jan 1, 1935

By E. T. Turner

Introduction 1n assembling material for this paper on Wood Refuse Burning 1 turned first to the records of our early studies of the problem in order to learn how and why certain basic decisions were arrived at and also how it came about that the completed central steam plant differed so much from the original plans. It may be of interest, therefore, to outline the engineering problems as they presented themselves in the early part of 1948, and to indicate the economies involved. Although the principle of using wood refuse as boiler fuel instead of burning it to waste was quite sound, and in fact the practice had been in use for a long time in the boilers of many lumber companies, there was some guesswork as far as Hollinger was concerned in deciding how best to handle the large quantities of wood refuse involved and as to the type of boiler equipment necessary to .burn it efficiently. These problems will be examined first. Hollinger Boiler Equipment in 1948 Hollinger had four separate boiler houses, at Main, No. II, and No. 19 shafts, and a small unit at the compressor plant for heating purposes. Main and No. Il boiler houses operated all the year round; No. 19 and the compressor plant only in the winter. At Main there were four 36-year-old HRT boilers with total available h.p. of 500, at No. II, three 30-year-old HRT boilers with 195 available h.p., and at No. 19 two old field-type locomotive boilers capable of producing 95 h.p.

Jan 1, 1951

By Matthew Novak, J. Brent Hiskey

It is well known that when chalcopyrite is put in direct contact with copper in an acidic medium a galvanic cell is created. Chalcopyrite is reduced to iron and sulfur deficient defect phases such as bornite, chalcocite, and at very low potentials to elemental copper. Galvanic conversion experiments were performed using three chalcopyrite concentrates. The first chalcopyrite contained less than 10% impurity phases. The second concentrate had a high concentration of pyrite, and the third concentrate had a high concentration of pyrrhotite. The effect of temperature, acid concentration, chalcopyrite grain size, copper grain size, and agitation on the rate of chalcopyrite conversion was studied.

Jan 1, 2014

By T. Takayama Filho

Votorantim Metais Zinco is a smelting facility which produces SHG zinc, zinc alloys, sulfuric acid, liquid SO2, copper sulfate, cadmium metal and silver concentrate. It is located at Juiz de Fora, Minas Gerais State, Brazil. This facility has been operating since 1980 and its current capacity is 95,000 tonnes of zinc per year, using mostly imported sulfide concentrates.The plant uses the conventional roast-leach electrowinning (RLE) process, in which iron is removed from the circuit as jarosite. The residues generated by the RLE process, which amount to about 200 t/day (dry weight), were until 10 years ago, deposited in tailing ponds having no impervious lining. More recently, jarosite and other wastes have been deposited in a properly built reservoir, but this is reaching its maximum capacity. In order to decommission these disposal operations and to reclaim the sites in an environmentally acceptable manner, Votorantim Metais concluded in 2004 a rehabilitation project for the old tailings pond and prepared detailed plans for managing the current and future disposal of jarosite-bearing residues. This paper describes the procedure for removing iron from the hydrometallurgical circuit and discusses the past and current status of the residue disposal sites, as well as the future challenges related to the environmentally acceptable handling of iron residues.

Jan 1, 2006

By C. R. Julian

THE large pyrites ore-bodies, the underground mining of which is to be described, are situated at Rio Tinto in the Province of Huelva in Southern Spain. The situation of the different ore-bodies with relation to one another is shown in Figure 1. It will be seen on the plan that the strike of the ore-bodies is approximately east and west. The geology of the district has been very fully described by Dr. D. Williams (1), so that for the purposes of this paper it will be sufficient to give briefly the salient features o each of the two larger ore-bodies which are being mined by underground methods at the present time. (a) San Dionisio.-This ore-body is the largest single deposit in Rio Tinto, having on its upper levels a length of 3,500 ft. On the upper levels the average width is approximately 200ft. but in places on the lower levels there is a width of 900ft. of un broken pyrites. Diamond-drill holes, without running out of ore, show the ore-body to persist to a depth of at least 1,600 ft. The ore-body in the upper part lies between slate and porphyry walls, but in depth is enclosed in porphyry walls. (b) South Lode.-Faulting is considered to be responsible for the break in the solid ore between South Lode and San Dionisio. On the upper levels, the South Lode ore-body has an unbroken length of 4,000 ft. The massive pyrites has a maximum width of 300ft. and an average of about 100 ft. Ore has been proved to a depth of 1,000 ft., at which depth the ore-body is much reduced both in length and breadth. This ore-body, to the depth at which it has been proved, lies entirely between slate and porphyry walls. The South Lode and the San Dionisio ore-bodies are mined both by open-cast and by underground methods. There is evidence that these mines have been exploited intermittently during the last 3,000 years; but, as is to be expected, no records are available of the tonnage mined prior to the time of purchase by the present company.

Jan 1, 1940

By A. Anderko, R. D. Springer, R. D. Young

A thermodynamic model has been developed for calculating phase equilibria and other properties of multicomponent electrolyte systems. The model has been designed to reproduce the properties of both aqueous and mixed-solvent electrolyte systems ranging from infinite dilution to solid saturation or pure solute limit. The model incorporates formulations for the excess Gibbs energy and standard-state properties coupled with an algorithm for detailed speciation calculations. The excess Gibbs energy model consists of a long-range interaction contribution represented by the Pitzer-Debye-Hiickel expression, a second virial coefficient-type term for specific ionic interactions and a short-range interaction term expressed by the UNIQUAC equation. The accuracy of the model has been demonstrated for common acids and bases and for multicomponent systems containing aluminum species in various environments.

Jan 1, 2005

By G. R. Webber

CHEMICAL AN AL YSIS by x-ray emission spectrometry has become increasingly important during the past few years. The method is analogous to optical spectrography ?with x-rays being used instead of light and should not be confused with methods of x-ray diffraction used? for identification of minerals and chemical compounds. X-ray emission spectrometry has many advantages for both qualitative and quantitative analysis. Its optimum concentration range is higher than that of the optical spectrograph, and the group of elements which can be detected is not identical to that which can be detected by the optical spectrograph. Elements which can be detected by the x-ray spectrometer are those elements from magnesium (atomic number 12) to uranium (atomic number 92) in the periodic table. The lightest elements in this range have low sensitivities and more specialized equipment is necessary for their detection than for the heavier elements. A large number of applications of x-ray analysis have been directed toward the analysis of ores, metallurgical products, and related materials (see References at end of paper). A more complete bibliography is presented in the Norelco Reporter, Vol. 3, 1956, pp. 37-39. The periodicals Analytical Chemistry and Applied Spectroscopy are a good source of current articles and references.

Jan 1, 1957

By M. Tanaka, T. Oishi, K. Koyama, S. Alam

"A novel hydrometallurgical process for copper recovery from waste printed circuit boards has been proposed, which consists of selective leaching of copper metal as Cu(I) by Cu(II) in ammoniacal alkaline solution, purification, and electrowinning. The distinct feature of this process is much lower power consumption during the electrowinning than that during the conventional one from acidic copper sulfate media, because the deposition of copper metal from Cu(I) at the cathode and the oxidation of Cu(I) to Cu(II) at the anode take place in the present method. In the laboratory-scale tests using waste printed circuit boards, high purity copper which contains 1.1ppm of impurities was obtained in a chloride system. INTRODUCTIONThe recovery of various metals from waste materials is an important issue in order to conserve the environment and metal resources. Copper is used for cables, electric appliances, etc., and is currently a very important material for industries and will continue to be in the future. Among the wastes that contain copper, one of the most complex recycling materials is electronic scrap like printed circuit boards (PCB), which generally contain 10-30% copper as well as plastics, fibreglass and other metals. There are two ways to recover copper, either pyrometallurgical or hydrometallurgical. Hydrometallurgical treatments generally have more flexibilities in the process scale and control. The separation processes tend to become complicated because of the poor selectivity during the leaching in the sulphuric and hydrochloric acid media. On the other hand, the use of ammonia as a complexing agent, gave a higher selectivity for copper leaching (Nigo, Majima, Hirato, Awakura, & Iwai, 1993; Majima, Nigo, Hirato, Awakura, & Iwai, 1993; Zhou, Shinme, & Anezaki, 1995; Koyama, Tanaka, & Lee, 2006) .In this study, recycling process containing leaching, copper deposition at a cathode and oxidation of copper(I) at an anode from ammoniacal alkaline solutions containing Cu(I) or Cu(II) is introduced. Furthermore, copper recovery from a waste printed circuit boards and impurity behaviour was examined in ammonia-ammonium sulfate (sulfate system) and ammonia-ammonium chloride (chloride system) systems."

Jan 1, 2012

By J. E. Udd

A core sample for this study was taken from the sulphide ore of the Geco Mine. The subsequent research was based on the assumption that a part of the scattering of strength-grade data could be correlated with variations in the chemical and/or mineralogical compositions of the samples. The results demonstrate clear relationships between strengths in tension and compression and the zinc-iron contents of the rocks.

Jan 1, 1977

By L. D. van Dyk, G. S. Tshofu

Iron ore fines are by-products of iron ore mining operations. Unlike iron ore lumps, fines cannot directly be used in conventional iron making processes, and consequently large quantities accumulate around the world. Pelletizing and sintering can be used to convert iron ore fines into agglomerates or briquettes for processing with lump ore, but these techniques are energy intensive and produce greenhouse gases. This research investigated the extraction of iron from iron ore fines using acetylacetone (a ß-diketone) as an environmentally friendly alternative process for fines utilization. A 2k factorial experiment design was used to identify the significant extraction variables. It was found that the reaction temperature and solid to liquid ratio had significant effects on the extraction process. The extraction kinetics were studied at different temperatures and the highest iron extraction (97 %) was obtained after 48 hours at 413 K and 0.025:1 (g:mL) solid to liquid ratio for a particle size range of +106 to -150 µm. The extraction products were easily separated from the unreacted acetylacetone by flash distillation and iron(III) acetylacetonate crystals were recovered. An economic evaluation showed that selling the crystals was profitable. Alternatively, the crystals can be reduced with hydrogen to iron particles and acetylacetone (for reuse).

Jan 1, 2015

By Mingxia Liu, Hao Li, Qi Liu

"Laboratory batch flotation tests were carried out on fine (-20 µm) hematite to investigate the non-polar oil’s influences when sodium oleate, octyl hydroxamic acid, or oleyl hydroxamic acid were used as a collector. Batch flotation tests were performed with artificial mixed minerals (hematite:quartz = 1:1) under natural pH condition and kerosene was utilized as the model oil. The experimental results showed that kerosene emulsion behaved differently when used in conjunction with the three collectors. Kerosene helped improve the flotation when sodium oleate or oleyl hydroxamic acid was used as a collector. Nevertheless, it reduced concentrate weight yield, grade and recovery to a noticeable extent when octyl hydroxamic acid was used as a collector, especially at low dosages. In addition, single hematite batch flotation kinetics tests coupled with water recovery measurement were carried out to study the role of kerosene at different collector dosages. It was observed that water drainage and the resulting froth destabilization by kerosene was dominant at low collector dosages, especially in the flotation using octyl hydroxamic acid. At higher collector dosages, the water drainage and froth destabilization effect by kerosene was possibly counter-balanced by the higher hematite hydrophobicity and bubble surface tension gradient, which led to more stable froth layer.INTRODUCTION The minerals industry is facing a steady decline in ore grade, compounded by increasing complexity of mineral dissemination. As a result, the ore has to be ground sufficiently fine to have a suitable degree of mineral liberation, which produces large percentages of fine and ultrafine particles outside of optimal size range for ore dressing. Due to the unique characteristics of fine particles, i.e., small mass, high specific surface area, and problems such as increased solubility of complex minerals (Finkelstein, 1997; Finkelstein & Allison, 1976; Fornasiero & Ralston, 2005), high reagent consumption, fast surface oxidation in the case of sulfides (Collins & Read, 1971; Klassen & Mokrousov, 1963), severe particle entrainment (Subrahmanyam & Forssberg, 1988; Warren, 1984), low flotation rates (Glembotsky, 1953; Philippoff, 1952; Ye & Miller, 1988), slime coating (T. K. Mitchell et al., 2005; Parsonage, 1984), etc., flotation performance of these finely ground ores is very poor in terms of low concentrate grade and recovery."

Jan 1, 2017

By The Staff

THE property of McKenzie Red Lake Gold Mines, Limited, consists of eleven claims located on McKenzie island in Red lake. The mine is about 4,Y:l miles by water from the Howey townsite on the same lake, and about 95 miles north of Kenora, Ont. (see Figure 4). Mail and express are flown-in daily, winter and summer, from Sioux Lookout, Hudson, Kenora, and Winnipeg. All heavy supplies are freighted-in during the summer over a water route, using four marine railway portages, from Hudson, Ont., a distance of about 180 miles. During the winter, freighting over the same route is clone by tractor if necessary, but costs are three to four rimes the summer rate. Due to these conditions, large inventories of supplies must be kept on hand, varying from a spring minimum of $45,000 to a peak of $110,000 early in November. The average cost of all freight brought in from steel during 1937 was $0.01 per pound.

Jan 1, 1938

By T. Krumins, L. Zunti, R. Frischmuth

Mercury is known to occur in sulphide-bearing refractory gold deposits in the form of sulphide minerals or elemental inclusions. These deposits typically require an oxidative pre-treatment process, such as pressure oxidation or roasting, to achieve economic gold recovery. However, these processes also have the potential to liberate mercury, a portion of which may then be released to the environment through gaseous emissions. Mercury emissions from mine processing operations have been of particular interest in recent years, as governments impose lower emission targets and organizations adopt better industry practices to reduce the environmental and health aspects of releasing mercury into the environment. This paper describes various mercury removal technologies with respect to pressure oxidation gas handling circuits, with a focus on key design variables and technology selection criteria.

Jan 1, 2014

By Paul R. Terry

This paper presents a brief picture of the quality of coal produced in Eastern Canada for use in thermal generating stations. It describes, in particular, the characteristics of coals burned in six power plants -two in New Brunswick and four in Nova Scotia. Each station is dis-cussed in turn, and comments are made on the coals used therein with regards to origin and physical and chemical properties affecting station operation. A table of coal data shows, at a glance, the wide variation in the quality of coals received by these stations from producers in New Brunswick and Nova Scotia. "The promotion of improved coal quality for thermal generation can benefit our national economy." T HIS is the opening statement in a paper which was presented by Mr. D. A. Pirttinen at the Coal Division's Toronto meeting in April, 1960. In bringing the power engineer's viewpoint to the coal producers' attention, Mr. Pirttinen made a survey of utility steam plants operating in Canada, and the results of this survey formed the basis for his paper, which he titled: "Generating Station Coal Quality.

Jan 1, 1965

By D. Lascelles, J. A. Finch, E. El-Ammouri

Flotation separation is expected to be related to the degree of dispersion of the pulp. For instance, highly aggregated systems may show reduced selectivity, reduced entrainment and increased flotation rate. In an attempt to test the impact of aggregation on flotation, we have taken advantage of the effect of Mg ions. Using combinations of Mg2+ and pH gave a wide variation in aggregation of several Cu-Zn ores (measured by settling rate) and corresponding flotation response was determined by batch tests. The trials were conducted on-site at Louvicourt and Agnico-Eagle. In a majority of cases a similar trend in aggregation and flotation selectivity (grade at given recovery) was observed. At Louvicourt, improved selectivity with increasing aggregation at pH 10.5 was found. At Agnico-Eagle, an analogous association between aggregation and selectivity was observed at pH 11.5. It is suggested that aggregation influences particle entrainment, the increased effective particle size reducing gangue recovery and hence improving selectivity.

Jan 1, 2004

The use of QemSCAN in providing mineralogical input to detailed ore and product characterization has proved of immense value in recent years. In this paper, a brief review of selected Cu-case studies is presented to demonstrate the versatility of automated, quantitative mineralogy by QemSCAN. This versatility ranges from measurement and analysis strategies through to data processing and presentation. As a rapid diagnostic service, it is common to find that only grain size, the degrees of liberation and/or ore mineral modal mineralogy are of interest. By contrast, the detail afforded by the simultaneous determination of both gangue and ore minerals can alert mineral engineers to fatal flaws and attributes deleterious to processing that are directly a function of silicate and other gangue mineralogy. Examples of the latter effects include the influence of micaceous minerals and acid consuming species, while the former include fluorine minerals, which can provide both processing and environmental challenges.

Jan 1, 2007

By Mark Sherman, M. Dennis, Raj Rajamani

"The two Alumbrera 36ft (10.97m)dia. SAG mills were sized, using the FDW ""Grindpower 'I program, to treat an average of 1852 tph each. This paper describes how modelling of the shell lifter design, using the Millsoft program, identified milling inefficiencies caused by poor charge motion. This explained the ""as built"" circuit's inability to achieve the throughput rates predcted by the circuit's designer. Use of the Millsoft program to design a new, dramatically different lifter configuration, in conjunction with a different approach to variable speed drive utilization, has resulted in an improved charge motion and a 30% increase in hard ore milling rates. The new lifter design has allowed the designer's predicted average throughput rates to be achieved.IntroductionThe Alumbrera project grinding circuit consists of two 36ft dia. X 17ft EGL, 13 500 kW, variable speed, gearless drive SAG mills coupled to four 20ft dia. X 30ft EGL, 6 000 kW fixed speed, gear driven, ball mills. The circuit is configured as two identical grinding aisles, each consisting of one SAG mill and two ball mills. No pebble crushing circuit was installed due to the expected absence of a critical size fraction in the first years of production. However, the grinding circuit layout does incorporate space for a pebble crushing retrofit. At present, only about 5% - 10% of the new mill feed reports as trommel oversize and is recycled back to each SAG mill using a water cannon.The circuit was designed to be ball mill limited and to treat the four major Alumbrera ore types at rates varying between 68 000 tpd, and 89 750 tpd, depending on ore hardness. Average throughput rate, and hence nominal design rate, for the grinding circuit was 80 000 tpd (1 852tph per line at 90% availability)."

Jan 1, 1999

By Charles J. Zablocki, Robert J. Kamilli

"Abstract - Buried, possibly mineralized granite cupolas at the Silsilah tin deposit in Saudi Arabia (lat. 26°06' N, long. 42°40' E) have been successfully located using a closely spaced electric-field-ratio profiling technique. In this study, electrical fields at 27 and 270 Hz across grounded electrodes spaced 50 m apart were measured along six traverses. This method is interpretable by inspection, unlike the dipole-dipole technique, which requires mathematical modeling for interpretation.In the study area, the technique allowed the authors to identify and distinguish among unroofed granite cupolas, cupolas with their aplite-pegmatite apical contact zones intact, strong (quartz-rich) and weak (relatively quartz-poor) greisens, dikes, faults, and pervasively argillized rocks.This method should be useful in the valuation of other shallow mineral prospects in similar settings in other parts of the world, especially deposits for which the location of vertical contrasts is important, such as veins or mineralized zones associated with the apexes of small igneous cupolas."

Jan 1, 1993

By Chris M. Healey

"Abstract- The Jasper Gold mine in northern Saskatchewan produced a total mill feed of 140 127 tonnes at an average grade of 19.0 g/t Au. Both diamond drilling and chip samples from under­ ground workings returned extremely high values, up to 12 851 g/t (375 oz/I) Au over 0.10 meter from a chip sample. In the presence of such extremely high grades, the accurate estimation of reserves is a major problem.ln the first part of this study, production data from the mine were used to evaluate the results of a variety of reserve estimation techniques in this environment. In two out of three cases studied, indicator kriging with assays cut to 342.9 g/t (10 oz/I) gave extremely good results. In the third case, however , indicator kriging gave unacceptable results. Instead, lognormal kriging of uncut data gave the best results.Secondly, from the same database, a number of drill-hole spacings were simulated, and reserves estimated from the simulations. As may be expected, the results of this analysis show increasingly better results with tighter drill-hole spacing. However, even with a 5 m by 5 m spacing the variation from actual grade was quite large. This is not a systematic under- or over-estimation of grade, rather a random scatter of results .The results of this study show very clearly the problems of deriving good estimates of reserves when extremely high-grade samples are encountered. There is a high degree of randomness to this database, so reserve estimation in this situation will remain a high-risk operation."

Jan 1, 1993

By K. R. Brown, P. L. Krawchuk

In-situ recovery (ISR) is under increased investigation as a viable methodology for the extraction of minerals in ore bodies that may be uneconomic to mine by traditional methods or for resources situated in locations where underground and surface mining operations are not feasible. Although the concept of ISR is relatively new with respect to hard rock applications, it is not a new technology; it has been used successfully in potash and uranium mining and also in heavy oil extraction for years where it has been proven to be both technically and commercially viable. ISR allows for the extraction of metals and minerals without the need to mine large amounts of ore that need to be processed at surface. The ore stays in-situ and only the valuable metals and minerals are produced to surface in a process that produces very little to no waste rock or tailings. This paper aims to discuss the geological conditions that make ISR amenable to an ore body as well as the application of maturing technologies such as advanced directional drilling and the creation of artificial permeability that will help to access deep ore bodies and enhance or create favorable recovery conditions for ISR in the ore body. INTRODUCTION In-situ recovery (ISR), also referred to as in-situ leaching, is a potentially disruptive technology for the mining industry. ISR is under increased investigation as a viable methodology for the extraction of valuable minerals that may be uneconomic to mine by traditional methods or for deposits situated in locations where underground and surface mining operations are not feasible. Although the concept of ISR is relatively new with respect to hard rock applications, it is not a new technology; it has been used successfully in potash mining, uranium mining and also in heavy oil extraction for years where it has been proven to be both technically and commercially viable. Recently there has been increased interest in deploying ISR in hard rock applications due to a number of factors: the drive for environmental stewardship is stronger than ever, technological advances in drilling, blasting, and leaching are strengthening ISR economics, and a large inventory of ore bodies exists that are not feasible to mine or extract using conventional open pit or underground mining techniques. ISR allows for the extraction of valuable metals and minerals without the need to mine large amounts of ore that need to be processed at surface. The ore stays in-situ and only the valuable metals and minerals are produced to surface in solution via a recovery process that produces very little to no waste rock or tailings. Where the right conditions exist, the ISR process has a much smaller environmental footprint (Hiam-Galvez, 2018) and potentially much lower capital and operating costs than using conventional mining techniques.

Jan 1, 2019