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By L. D. Wyant

[A convenient method for the, analysis of oil-wax mixtures has bean developed in the petroleum laboratory of the Bureau of Mines. This method has been found useful in studying the characteristics of the products obtained in petroleum refineries during the manufacture of ?wax distillate?, "foots oil", ?intermediate wax", and commercial paraffin. In this method ac-to-au is used as a selective solvent.]

Jan 1, 1924

By C. V. Corless

1. Introductory Some members may recall that at the Annual Meeting two years ago I read a paper, 'The Future of the Mining Industry in Canada." Discussing this large subject it was possible only to outline the facts and inferences leading to ?the conclusion that Canada is a country endowed with enormous mineral wealth, of which the fringes are yet scarcely touched. In the present paper, I wish to examine in somewhat fuller detail the evidence, both direct and inferential, concerning the mineral wealth of the greatest physical and geological feature of Canada-the Precambrian Shield. Many, if not most, of these facts are already familiar to you. But, since they will form the basis of the reasoning employed, they will be recalled for explicit reference. First, let us review very briefly the position and extent of the Shield. The area of the entire Shield is given in textbooks as 2,000,000 square miles, of which perhaps 10 or 12 per cent. is exposed in the south-easterly part of Canada's Arctic islands. The remainder occupies roughly two-thirds of the North-west Territory; the north-east corner of Alberta; one-third of Saskatchewan ;two-thirds of Manitoba; three-fourths of Ontario; and nearly ninety-five per cent. of Quebec.

Jan 1, 1924

By A. W. Fahrenwald

The physics and chemistry of the flotation process are not well understood. Many papers dealing with the theory of flotation have been published but most have been narrow in their viewpoint. No theory advanced has done more than explain, more or less satisfactorily, various isolated phenomena. Scientists have done little with the problem, doubtless because they have not seen sufficient of the practical side of the subject to have their interest aroused. Any attempt to explain the mechanism of flotation that considers only contact angles, surface tension, adsorption, the floating of needles, flocculation, or any other single and narrow phase of the question is sure to be disappointing. Flotation is a problem of colloid chemistry and must be studied as such. In a broad general way, flotation is a process involving and operating by virtue of surface reactions. The term "surface reactions" may be open to criticisms. Many chemists give the term "reactions" a definite and restricted meaning and to such the term may connote change in atomic grouping in strict stoichiometric ratios. While Langmuir looks upon adsorption as a reaction, and there is much evidence in support of this view, we may look on adsorption as a physcial process as far as this paper is concerned. The term seems well suited to the work in general. Presumably these reactions are reactions between the same kinds of forces (electrical) and differ only in degree and in the surface manifestations produced. This premise seems logical if we accept the theory that the atoms of dl elements are made up of grains of electricity, having mass and charge, called electrons; and that atoms differ from one another only in the number and arrangement of the electrons about a positive nuclear

Jan 1, 1924

By Bradley Stoughton

The magnetic oxide of iron, F eO4 , contains a theoretically larger amount of iron ( 72.4 per cent.) than any other commercial ore. It is probable that it has originated in many cases by the prolonged exposure of the hydrated oxide, ZF e20 a + 3H20 to heat and pressure which converts it first into hematite, F e20 3, and then into magnetite. It would thus appear as if nature had already done part of the work of removing all the oxygen and that magnetite should be relatively easy to reduce. That it is, in fact, less reducible than either limonite or hematite, is due chiefly to its dense and compact physical structure, which makes it less pervious to the furnace gases, and also to its characteristic action in resisting crushing to a uniform size, with consequent irregularity in reducing conditions within the furnace. The net result is that the magnetic oxide requires more fuel and more time for its reduction in the blast-furnace than any other iron ore of similar iron content and physical condition. There is another very important reason why the smelting of magnetite is more costly than that of hematite, and its treatment viewed with a great deal of adverse prejudice by blast furnace operators, namely, that magnetite decreases the proportion of heat developed by the fuel in the stack of the furnace, and increases the already excessive heat requirements of the heart.

Jan 1, 1924

The Committee, appointed early in May, met and organized in Washington, May 9, 1923, and were then advised that such data as they required would as far as obtainable be submitted to them in tabulations, and that they could not be allowed to see the individual reports nor know the identity of the operators on whose reports the figures submitted were based, therefore the Committee's valuation is based on data received from your statisticians, and on tonnages estimated by your staff and by the United States Geological Survey. Various methods of valuation for mining properties have been suggested, but all authorities seem to agree in accepting, as the fairest and most practicable and logical, a capitalization of the estimated future earnings, when such estimate can reasonably be made. Hoover and Finlay both emphasize this. The United States Supreme Court says in Cleveland, Cincinnati, Chicago & St. Louis Railway Co., v. Backus, 154 U. S. 439: But the value of the property results from the use to which it is put and varies with the profitableness of that use, present and prospective, actual and anticipated. There is no pecuniary value outside of that which results from such use. The amount and profitable character of such use determines the value. The Committee on Federal Taxation of the American Institute of Mining and Metallurgical Engineers, appointed in 1919, in its report states: A proper value of a mining property is the present value of the prospective net earnings, taking into account probable variations in output and value. Ingalls ("Wealth and Income of the American People," p. 97) says: The fundamental principle of mine valuation is the present worth of an annual dividend accruing during the period of years corresponding with the lie of the mine. It is a convention that the estimated period shall not be more than 30 years.

Jan 1, 1924

By H. B. Cooke

In connection with its researches on the crude petroleums of the United States, the Bureau of Mines has made a particular study of apparatus for the distillation of hydrocarbon mixtures. While this study is still incomplete it has already resulted in the development of considerable laboratory and semi-plant equipment, motet of which has been described in various publications of the Bureau. The laboratory apparatus (Hempel distillation) and method gives satisfactory comparative results in the laboratory examination of crudes and have been found applicable to crudes of all types, but the agreement of laboratory and plant distillations is not as close as might be desired. This is due, in part, to limitations in size and construction of the laboratory apparatus. Some refiners claim that the Bureau of Mines' laboratory method (Hempel distillation3) for distilling crude petroleum, does not show the full gasoline content of the oil, while others have stated that it indicates more gasoline than can be obtained from the crude commercially. This difference of opinion among refiners results largely from the great variation in stills used and methods of operating them. The Bureau's experience has shown that crude oils from different fields vary widely in character; in fact, that it is not yet possible to classify crude's adequately on the basis of their Down chemical and physical characteristics. As a result of the differences that exist among crudes, and of the difficulty of designing refinery equipment, no standard practice has yet been adopted for the commercial distillation of petroleum, and ma" types of stills are used in the refineries of this country. Although many factors enter into the design of equipment and the development of commercial practice in refining of crude oil, there

Jan 1, 1924

By F. E. Lee

The following outline gives a brief account of some of the ways in which microscopy is applied to the problems arising from the various operations of the Tadanac reduction works, at Trail, B. C. The Sullivan ore is a very fine-grained mixture of galena, marmatite, pyrite and pyrrhotite. The separation of minerals associated so intimately is a difficult task and requires careful control. Various oils and reagents are used in the process as developed, and it is essential that the operators have a means of control which shall be rapid, and at the same time, approximately correct. This result is obtained by microscopic analysis in the following manner: The operator places a quantity of the material upon a slide, a drop of water is added, and it is covered with a cover glass. Upon examination with transmitted light, the zinc mineral particles appear reddish, the ordinary gangue colorless, the lead and iron sulphides opaque. This method has proved of great assistance both in the development and in the operation of the present method for concentrating Sullivan ore. The miscroscope has thus become as much a part of the metallurgical equipment as the balance and burette. The microscope used in the laboratory is a Fuess "petrographic" with a specially-made vertical "illuminator" by Bausch & Lomb, with the usual accessories.

Jan 1, 1924

Jan 1, 1924

By G. A. Bole, F. W. Davis

The purpose of this paper is not to report, to the Institute, the results so far obtained in the survey, by the Bureau of Mines, of the metallurgical requirements for open-hearth refractories, but to present an outline that we hope will serve as a basis for discussion. The systematic survey that the Bureau proposes to make has not been outlined, although considerable preliminary work has been done in the way of interviewing open-hearth superintendents in several of the larger steel plants from the Chicago district eastward. At the several conferences so many of the opinions were diametrically oppoeite, when considering the same point, that it was thought that such an opportunity as the Institute offers in the way of a clearing house for moot metallurgical topics should not be overlooked. For this reason, the paper has been prepared as a basis for a discussion which, it is believed, will be of value in outlining the program of the Bureau. D. A. LYoN, Assistant Director. The importance of securing suitable refractories for metallurgical operations is daily becoming more universally recognized; particularly in the manufacture of open-hearth steel, where the life and earning power of the furnace depends largely on the judgment and care exercised in the selection of the correct quality of refractory for each of the parts. Any innovation that would make available to the steel manufacturers refractories with longer life or better suited to their needs than those now employed, and at a cost that would permit of their use, would be of enormous value to the industry at large. It is quite probable that revolutionary changes would not be necessary. Material now used in some parts of the furnace might, by more suitable preparation, be made of much greater service; in other parts, possibly entirely different material would be necessary in order to effect much improvement. Inasmuch as different parts of the furnace structure perform different functions and are subjected to different service conditions, a refractory suitable for one part will be entirely unsuited for another. For this reason, to make a comprehensive study of the refractory requirements of the processes, we should consider the furnace as built up of a number

Jan 1, 1924

By Mayo D. Hercey, Edward W. Butzler

"Purpose and Origin of Investigation.For many investigations of mineral products such as metallic and ceramic materials, especially refractories, a knowledge of thermal conductivity and specific heat at high temperature is required. Such data have been needed by the Bureau of Mines for checking heat balances in kilns, and computing heat loss through furnace walls.Design of apparatus for thermal conductivity tests was undertaken by the Bureau early in 1922, an industry at that time indicated that no equipment intended for extreme high-temperature observations was elsewhere available or likely to be in the immediate future.The Bureau's investigation was begun by C. R. Greenslade, assisted by F. A. Hartgen, and temporarily discontinued owing to their resignations in the summer of 1922. The work was later turned over to the writers of this report, and has been carried forward at intervals, along with other problems."

Jan 1, 1924

By Ernest E. Fairbanks

[Microscopic methods have proved to be valuable assets in the study of low-grade ores. While the chemical assay u a ally discloses tine total content of valuable metals in such an ore, a thorough knowledge of the nature of the ore should form the from which to prepare an efficient means of recovery. In the treatment of low-grade ores, inefficient recovery, as indicated bay the amount of valuable mineral permitted to go to waste in the tailings, is too frequently the rule rather than the exception, As methods of recovery become more efficient, many low-grade 10 mineral A posits suddenly assume o commercial significance, In much of this material the minerals are so finely disseminated and intermixed that identification even by microscopic methods is a difficult matter. The application of microchemical qualitative analysis with the aid of new device described in this paper, will solve many of the problems of identification encountered in the study of low-grade potential ores. In these ores, especially, the limitations of ordinary microscopic methods are liable to become very great. The microchemical tests obtained by applying a standard set of reagents to a polished knoting whether or not a tarnishing action develops, have considerable value but arc far from being infallible. It is well-known that electrolytic effects are apt to affect seriously the diagnostic value of the tests, end this effect is encountered much more frequently in dealing with finely desseminated minerals. resort to microchemical qualitative analysis, therefore, becomes indispensable.]

Jan 1, 1924

By E. Thomson

This type of microscopic investigation, although still in its infancy, has already found practical applications in several different phases of mining activity. The study of the transparent minerals in rocks, by means of the ordinary petrographic microscope, has for long been a very useful supplement to observations in the field, but the opaque minerals, until recently, have had to rest content with a more or less superficial determination with the hand-lens or the blow-pipe. In a great many cases, particularly where the association of metallics has been somewhat complex, this has been entirely inadequate, and the determination of these opaque minerals under the micro- scope, has opened up a new field of scientific investigation that bids fair to surpass, in practical value at least, the micro-scopic determination of the rock-forming minerals. As the details of this kind of microscopy are possibly not entirely familiar to all mining men, it might be well to outline them very briefly before dealing with the practical directions in which this method may be applied. The ordinary petro-graphic microscope, with but one extra attachment, will serve for this work. A small reflecting device, called a vertical illuminator, is inserted immediately above the objective lens. This reflects the light down to the surface of the specimen and from here the light is directed up the middle of the microscope tube to the eye. As it is desirable that the maximum amount of reflection should be secured from the surface of the section, it is first polished and set in a position perpendicular to the vertical axis of the microscope.

Jan 1, 1924

By R. H. Watson

A paper read by J. A. H. Church before the Northern Alberta Branch last February described a method of working thick inclined coal-seams from the dip upwards, with the view to preventing fire risk by using water for the stowage of waste workings, and extinguishing a conflagration should such break out, was favorably received; but there was some doubt as to the cost of such a method, as it involves a retreating system, which might prove too expensive for practical adoption. Let us consider a typical leasehold such as we are familiar with in the Rocky Mountains. The leasehold is crossed at one end by a mountain river, which is cut by the outcrop of a seam of coal, 30 feet in thickness, pitching as shown on the drawing herewith, which also shows the general line of the outcrop in elevation through the leasehold, which is two and a half miles long and contains 1,500 acres. The average lift is about 600 feet above river level and drilling has proved that the coalseam can be tapped at a depth of 1,500 feet, 2,000 feet down the pitch from the outcrop in the river, all as shown in the illustration, which is typical enough of our mountain conditions to serve the purposes of comparison of methods. We take up the leasehold and invest $30,000 to pay for drilling and prospecting; $30,000 more for the price of the lease to locator or holder, and say $100,000 to pay for a railway spur (it might cost twice this sum, but we are only comparing two methods in the same location) and "now we are ready to consider equipment and the cost of development.

Jan 1, 1924

By Robert Drummond

Away back in the eighties of the last century, when Sir Charles, then Doctor, Tupper, was not only a prominent but a dominant figure in the political life of Nova Scotia, his opponents brought the railing accusation against him that he was the foremost of egotists because of his frequent use of the personal pronoun. I heard Tupper speak and had no sympathy with the railers, because I could not well see how the pronoun could be dispensed with without laying himself open to a charge of affectation. I shall make reference in what follows to incidents in which I have taken part, and shall be at no pains to dispense with the pronoun, even though thereby I lay my-self open to the charge of being a pupil of the deceased states-man. EVENTS LEADING UP TO THE ORGANIZATION OF THE PROVINCIAL WORKMEN'S ASSOCIATION The Springhill Mining Company began development work at Springhill in the early seventies of last century. So vigorously was the work prosecuted that in 18 7 4 two slopes, the east and the west, were in active operation, with a considerable. output, the east slope on occasional days producing 800 tons. The President of the Company, the late Senator McFarlane, was a Nova Scotian, the other directors were mainly merchants from St. John, N.B. From the first the enterprise was an .astonishing success, due in the greatest part to its geographical position, and in large part to the untiring vigilance of the directors, a majority of whom visited the collieries at short intervals, thereby keeping the manager, much of the time, on tenter hooks.

Jan 1, 1924

By P. H. Royster, T. L. Joseph

In a study of the blast-furnace process, the Bureau of Mines has made many experiments for the purpose of determining the exact nature of the combustion of coke in the neighborhood of the tuyeres. Two papers1 presented at a meeting of this Institute discussed somewhat the practical aspects of coke combustibility in its relation to the operation of the blast furnace. In a later paper,2 Sherman and Kinney discussed the possible effect of variations in the combustibility of cokes on the furnace operation, and find that the "reoxidation theory" of Koppers and the "heat concentration theory" of Brassert³ are insuffcient to explain the variation in the conduct of different cokes that has been observed by furnace operators. In their report to the D-5 Committee of the American Society for Testing Materials, with which the Bureau of Mines has been cooperating, Perrott and Fieldner4 seem to agree with Sherman and Kinney that, for practical purposes, the nature of the combustion of coke at the tuyeres of any furnace is constant and is affected neither by the physical properties of the coke nor by the nature of the furnace operation. They omit as unimportant any tests on the combustibility of coke from their proposed methods for standard tests on coke. In the last two papers, it is pointed out that performance tests, in which all other factors except coke quality are kept constant, are to be desired and

Jan 1, 1924

By Stephen Birch

LATOUCHE, or the Beatson plant of the Kennecott Copper Corpn., is located in the Prince William Sound district of Alaska about 80 miles west of Cordova and 60 miles from Seward. Ore was discovered and claims located on Latouche Island in July, 1897. The mines were worked in a desultory manner until 1910, when the property was acquired by the Kennecott Copper interests. The first shipment of ore was made in 1904; only the higher grade ore was mined and no attempt was made to treat the ore until it was taken over by the Kennecott, company. Since that time the mine has been developed to produce 1500 tons a day and a mill has been erected for treating this tonnage, using flotation entirely. The orebody is more or less lenticular in shape with a maximum width of about 280 ft. and a length of about 800 ft. The southern end of the lens is split by a horse of waste for about 400 ft. The hanging-wall limit is a well-defined fault associated with a band of pyrrhotite, having an average dip of 60°. There is no defined foot wall, the value of the ore governing the limits of the mining; in one part of the mine, however, it is defined by a minor fault. The orebody is located in a shear zone of the country rock of graywacke and slate. The principal mineral is chalcopyrite associated with pyrite and quartz. The mine is located a few hundred feet from tidewater; the mill is located on the beach and the ore is hoisted direct from the mine through a vertical shaft into the mill bins. Until the past year practically all the mining had been conducted in open pits. During the past two years, the ore above the 200-ft. level has been developed and a system of stoping devised to recover this ore; however, this system has not been in use long enough to give any definite results as to costs or efficiency. It consists, principally, of dividing the orebody into stopes, across the full width of the orebody, 70 ft. wide with a pillar 30 ft. wide between the stopes. Raises are driven through the stopes at intervals of about 60 ft. and all the ore is broken by drilling from these raises; in other words, similar to a shrinkage stope, doing the drilling from the raises instead of setting up on the broken ore as is customary. The ground is very much broken up by clay slips and seams running in every direction. Shrinkage stoping had been

Jan 1, 1924

By George Brien, O&apos

The history of the lighting of mine workings dates back to the early part of the 18th century, when small candles known as tallow dips, were used. These were set or held in a lump of wet clay. When looking for gas the flame of. the candle was reduced to a mere glimmer by surrounding the wick below the flame with clay. The candle was then very cautiously raised from the floor toward the roof, the observer screening the brighter portion of the flame with his hand and watching for the first appearance of the pale blue cap above the flame, even at that time, known to indicate the presence of gas. When this appeared the candle was lowered quietly and its flame extinguished before attempting to drive out the gas. A very common and dangerous practice adopted at that time was to get rid of the gas by firing it. This was done by a person selected for his nerve rather than for his caution. Dressed in a? suit of dampened sackcloth or leather, this man well termed a "fireman", would lie prone on the floor of the roadway and light the gas above him by raising his candle fastened to the end of a long stick. If he survived, which was not always the case, he would withdraw promptly to fresh air after the flame had passed over him.

Jan 1, 1924

By A. J. Kraemer

This report on the physical and chemical properties of typical crude oils of California is the 'eighth in a series on the producing districts of the United States. It includes discussion of results, tabulated data, and individual analyses of typical California crudes. Additional analyses of crude oils from the fields of Fresno, Kern, Los Angeles, Orange, end Ventura Counties will be published later in another Serial of the Bureau, but the summary tabulations are presented here. The samples represented in this report were collected over a rather wide interval of tine, the early samples having been obtained during the fall of 1919, and the most recent ones dating from the summer of 1923. It is thought that the samples are fairly representative, both of the older settled production and of the new flush production of the southern California fields.

Jan 1, 1924

By G. W. Jones

Among its investigations into the prevention of waste in production and use of oil and gas, the Bureau of dines has made considerable study of the efficient utilization of gasoline and by-product distillates in motors, this being done chiefly by measuring and analyzing the exhaust gases therefrom. A number of reports3 of a highly practical nature have been published and are available on this subject. The results of these tests have shown that the average motor vehicle wastes approximately 30 per cent of the heat value of the fuel used, as incomplete combustion products - carbon monoxide, hydrogen, and methane, These unnecessary large heat losses are mainly due to improper carburetor adjustment, and by proper¬ly adjusting the carburetors for maximum power and efficiency a large part of this heat loss can be eliminated. This in turn results in an increased mileage per gallon of fuel used.4

Jan 1, 1924

By WM. G. Heeley

This paper will describe the experience gained and explain the deductions made from the phenomenon of the great squeeze which occurred at Brule Mines. The first indication of the commencement of the squeeze was the breaking of posts on the high-side rib of the slope. At first we thought this was due to a lateral pressure only, and we renewed the broken posts with new ones, the result being that the new posts also were soon broken. A noticeable bending and breaking of the collars occurred, with a corresponding reduction in the height of the haulage slope. These symptoms were also evident on the counter above the slope, indicating that the trouble was of an exceptional nature. In the meantime, we had concentrated a large force of repair men, renewing broken timbers and brushing the roof and floor, but in spite of all our efforts we could not overtake the damage being done. Our next problem was to find the cause of this trouble. We were in a new basin of coal (No. 2) which had only been opened a few months, as we had worked the previous four years in another basin (No. 3) where no such trouble as this had ever been encountered. Naturally our first thought concerned the adequacy of the size of the pillars. We had worked in the No. 3 south basin for the previous four years. without any such experience, with 60-feet pillars between slope and counters; whereas we had established 100-foot pillars in the No. 2 south basin between the slopes and counters with an 80-foot pillar between counter and first line of cross-cuts, and 100-foot pillars between the breasts.

Jan 1, 1924