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THE assay of all metal ores is made by means of fusion and they are brought to their fineness in the same way as if they were a large quantity. However, I have told you of lead, tin, copper, and iron in their own places, that they are smelted in order to obtain a good assay so that one may know from its weight whether the quantity justifies the expense. This is their assay, for it does not matter whether it be done with great exactness. But the eye is turned with much more care to the assaying of silver and gold, since they are things of value, and one tries to have a more exact knowledge of them. Thus, when you have found the mountain and the vein of ore in it, and have also uncovered it or extracted it from the mine, it is necessary to make an assay of it, for though it is often apparent to the experts what kind of metal it contains, nevertheless they do not know for sure what virtues or evilness it may have unless the light of the assay itself shows them. Therefore it is necessary to extract a quantity in some way that is as free from rock and as good as possible. To a part of this, without any addition, a smelting fire must be applied in order to see whether it can be smelted easily. If it does not smelt by itself, you must consider and try to understand what causes this, for many times it comes from the rock which accompanies it and which contains much dryness and earthiness. I do not believe that one can know this with other judgment than by experiment with powerful and strong fires. Therefore, if the efforts of ordinary methods do not succeed, it is necessary to try to soften them by means of the company of fusible things-now with marble, now with ground glass, now with lead, galena,* or litharge from lead, or with iron scale, or else with the slag of other ores. With small operations even borax, saltpeter, or ochre is used and similar things, as I shall tell you in detail in the discussion of the preparation of ores for smelting. In short, try to see whether they can be overcome by adjustment of the fires or by virtue of the means

Jan 1, 1942

By Philip B. Bucky

[CONTENTS t. How Does One Determine WhetherPAGE an ore Body Will Block-cave?R. W. Hughes13 Sherman R. Burdick 13 PAGER. T. Gallagher 14 Mark A. Smith 2 C. F. B. Price, Jr.14 Harry A. Leidich2Benjamin F. Tillson 14 McHenry Mosier2C. F. Jackson14,17 R. W. Hughes2R. Taborelli15 Sherman R. Burdick3Frank A. Ayer16 R. T. Gallagher 3Philip B. Bucky16 Benjamin F. Tillson 3Rollin Farminr6 Lucien Eaton 3J. L. G. Weysser15, 0,17 C. F. Jackson 3George S. Rice17 Philip B. Bucky32. How Does One Determine the Block4. What Determines the Procedure in Dimensions and the DevelopmentRemoving Caved Ore? Work Necessary to Make an OreHarry A. Leidich17 Body Cave?McHenry Mosier17,21 Mark A. Smith 5,7,() R. W. Hughes17 Harry A. Leidich6Sherman R. Burdick 18 McHenry Mosier6,7,12 R. T. Gallagher 18 R. W. Hughes6Mark A. Smith I8 Sherman R. Burdick 7Philip B. Bucky20, 21, 23 R. T. Gallagher 7C. F. B. Price, Jr20 Benjamin F. Tillson 7,11R. H. Bennett21 L. E. Young7C. F. Jackson 21, 23 Robert D. Hoffman8, 1 2Gerald Sherman 3 . 21 Gerald Sherman8Tell Ertl21 Philip B. Bucky10, 11, 12G. K. Foster 23 R. S. McClellan 12C. H. Shoemaker23 Tell Ertl 12 3. How Do the Forces Act and What Are5. What Are the Criteria for Determining the Stresses Developed in a Blockthe Efficiency of a Block-caving That Cause It to Block-cave?Operation? Mark A. Smith 12, ISHarry A. Leidich23 Harry A. Leidich13McHenry Mosier24 McHenry Mosier13R. W. Hughes24 Sherman R. Burdick 24 R. T. Gallagher 24]

Jan 1, 1942

By R. F. Mehl, B. Lustman

THE formation of intermediate phase layers in cementation processes has been subjected to extensive qualitative investigation though to relatively little quantitative study; this work has recently been fully summarized by F. N. Rhines.1 It is necessary here only to enumerate the general conclusions drawn concerning the kinetic laws governing the growth of intermediate layers and to state what is known concerning the structural changes accompanying the generation of phase layers. I. When the intermediate phase is protective in type-i.e., when its density is less than that of the base metal, so that a continuous coating is formed and maintained-the isothermal growth of the phase follows a simple parabolic equation: [1 = ki [I]] where X is the thickness of the alloy layer, k the reaction rate constant, and [t] the time. The applicability of this equation to diffusion processes is tested by plotting the square of the thickness versus time, or by plotting the thickness versus the square root of time; the resultant achievement of a straight line in such a plot has been considered sufficient proof of the validity of this equation. Exceptions have been found where liquid phases are involved in the reaction, where the diffusion layer is cracked,2 and where thin semimetallic oxide and sulphide coatings are formed on metals.3 In the first two cases the thickness increases linearly with time, and in the latter it is a logarithmic function of time. 2. The rate of thickening varies with temperature according to the Arrhenius equation: [k = Ae-QIRT [2]] where k is the parabolic rate constant of Eq. I, or some other rate-descriptive function, A is the action constant, e the base of natural logarithms, Q the heat of activation, R the gas constant, and T absolute temperature. This equation has been found to be generally valid except when transformations occur during reaction in either the base metal or in the reaction layer; in such instances Eq. 2 is still applicable with different values for the constants A and Q above and below the transformation temperature. 3. All phases that are stable at the temperature at which diffusion occurs will appear in the interdiffusion of two components. In some cases certain of the phases may be too thin to be observed and identified easily. Nonequilibrium phases have never been noted in thick reaction layers; i.e., layers of a thickness that may be discerned microscopically. The relative thickness of each phase in a diffusion layer is proportional to the concentration gradient and to the rate of diffusion in that phase.4 The reaction layers tend to have a

Jan 1, 1942

The only definite information available is for the years 1875, 1878, and 1879 and 1880. The total figures in Table 48 are estimated. [ ]

Jan 1, 1942

By H. S. Rankin, E. C. Houston

Olivine is considered a valuable potential source of metallic magnesium in the chloride electrolytic process. Treatment of olivine with hydrochloric acid can be carried out under conditions that prevent the formation of gelatinous silicic acid, which would inhibit the reaction by forming a covering around the ore particles. It is our hypothesis that the formation of gelatinous silicic acid is avoided by the dehydrating action of the magnesium chloride, which takes up water to form a series of hydrates and leaves the silicic acid in granular condition. Leaching serves to separate the magnesium chloride from the silicic acid and unattacked ore, which can be treated with fresh acid in successive steps until extraction is essentially complete. The leach solution can be i purified by the addition of caustic magnesia and the precipitated impurities removed by decantation or filtration. The resulting magnesium chloride contains: Fe, less than 0.001 Per cent; Mn, 0.012 ; per cent; Ni, none. Chlorination† of olivine has two major defects: (1) a large part of the chlorine goes to form silicon and iron chlorides, (2) the anhydrous magnesium chloride is held by absorption in the finely divided silica. SupplY It is well known that olivine, a silicate of magnesium and iron, is present in large amounts in several localities in the United States. The largest deposits occur in the southeast and on the Pacific Coast.' The southeastern deposits were surveyed by Lewis2 in 1896 and by Hunter3 in the period 1933-1940 It is estimated that high-grade olivine, conveniently located with regard to transportation and power, is present in excess of 230 million tons above local drainage level in western North Carolina and north Georgia. Previous Technical Work In the past few years, olivine has attracted considerable attention in the refractory field. In the chemical processing industry, however, it has long been thought axiomatic that the cost of processing silicates is an economic barrier to their utilization, especially where more reactive minerals, such as carbonates, oxides or salts, are available. This attitude is not entirely justified in connection with olivine. unlike most silicates, olivine is readily attacked by acids, chlorine and other reagents without resorting to fusion to break down the silicate structure. Olivine has been suggested as a raw material for making epsom salt by roasting with pyrites.4 Other processes include acid treatment6 and digestion with calcium chloride.6 Recently a small plant was built near Webster, N. C., for making epsom salt from olivine by treatment with sulphuric acid. This plant is now in commercial operation, producing approximately two tons per day. Olivine is also receiving attention from the fertilizer industry as an inexpensive source of soluble magnesium.

Jan 1, 1942

No early records of coal in Iowa have been found, although it is very probable that coal along the Mississippi, in the northeastern corner of the state, was seen very early. The United States Census of 1840 showed a production of 400 tons, mined of course in 1839, and the earliest mining, was in Jefferson and Fairfield Counties where the coal was hauled by wagons to shops in the Mississippi River towns years before any railroad was built in the state. In 1840 mines were opened in Van Buren County, near Farmington and Douds, and in Scott County, near Jamestown, all of the product being used locally.' In 1844 D. D. Owen reported seeing mines in the tongue of land between the Rock and Mississippi Rivers, in one of them the coal being 5 to 6 ft. thick, and several other seams south of this locality? In the, late forties a number of small mines were opened in various parts of the state, and in following years in practically every county having coal. The Mystic seam was first opened in 1857 in Appanoose County, since then consistently one of the large producing areas in the state. Consumption was local until the Milwaukee Railroad was built through the county in 1887.1

Jan 1, 1942

By R. F. Mehl, J. K. Stanley

THE recrystallization of cold-worked metals is studied ordinarily by determining the temperatures required for complete recrystallization to occur within a given arbitrary time period, usually within 15 min. to 2 hr. The results obtained are conventionally assembled in a three-dimensional diagram relating this temperature to the amount of cold-work (percentage deformation) and the resultant grain size, though sometimes other modes of representation are employed.1 Such three-dimensional diagrams are not complete, for the number of variables exceeds the number represented. The process of recrystallization is characterized by a time-rate, a fact that is not portrayed upon ordinary recrystallization diagrams. It is known that recrystallization consists in the formation of new nuclei and the growth of these nuclei, a process that continues until the matrix is completely consumed and the original set of grains entirely replaced by the new. This knowledge is old.2 Truly heterogeneous reactions invariably proceed by nucleation and growth; the decomposition of eutectoid solid solutions provides an example about which much is known,3 and freezing, originally studied by Tammann, provides the classic example. Although recrystallization is not a heterogeneous reaction within the orthodox meaning of the term, the mechanism of the process is the same. As in eutectoid inversion and freezing, it should be possible to study the rate of isothermal recrystallization as a function of time, and it should also be possible to analyze the isothermal reaction curve into the component rates of nucleation and growth that determine them.* Other methods, not employing the rates of nucleation and growth, have been used to represent the rates of such reactions, but these in general have been artificial and have not led to progress .4,5† The theory of recrystallization is not in advanced state; if recrystallization data were obtained in terms of the rate of isothermal recrystallization, and in terms of the rate of nucleation and the rate of growth of recrystallized grains, and in particular if the temperature coefficients of these rates were measured accurately, an adequate theory should be more readily developed .27 Such an effort requires proper experimental technique, but especially requires suitable methods of mathematical analysis to convert measurements made upon a surface of polish into values for the rate of nucleation and the rate of growth and to combine these into a rate of isothermal recrystallization. These methods are now

Jan 1, 1942

EVERY intelligent and practical investigator of minerals says that copper ore is found in various regions of the world and that among others Italy is very rich in it. But very little is mined there, perhaps because of a cowardly Italian avarice which has the power to make us lazy and indolent in carrying out those lofty and fine designs which should reasonably make us proceed swiftly, or perhaps because we are not prone to attempt extraordinary profit but only undertake those enterprises in which we are certain of a return on our investment. The reason for this might also be found in the meager possibility of success, which, since these things are not easily attempted because they are enormous undertakings of doubtful outcome, cools the spirit of men and in place of enthusiasm introduces the fear of loss, the fear of having to sacrifice not only time but also the work and money invested; then they think of the difficulty [II] of discovery, of the impossibility of full ownership, and of the necessity of excavating the mineral marrow from the hardest bones of the mountains with the brawn and efforts of men. To this is added the fear common to many that in attempting such things they may be called fools by certain ignorant and dissolute persons, and it seems better to them to be praised for becoming rich through usury and by many other infamous and illicit methods than to lay themselves open to the danger of censure from such as these. But there are those who deserve still greater censure, particularly princes and all rich and powerful persons, and theirs is an even more useless error than that of those who refrain for the above reasons. If the occasion and means present themselves for both attempting and continuing such a profitable and laudable affair as mining ores and if they hesitate solely because of cowardice or because they give ear to the bayings of ignorant hounds, or if because of their own willfulness they wish to remain prisoners of a detestable and ugly avarice, then this is their own loss.

Jan 1, 1942

By G. E. Archie

The usefulness of the electrical resistivity log in determining reservoir characteristics is governed largely by: (I) the accuracy with which the true resistivity of the formation can be determined; (2) the scope of detailed data concerning the relation of resistivity measurements to formation characteristics; (3) the available information concerning the conductivity of connate or formation waters; (4) the extent of geologic knowledge regarding probable changes in facies within given horizons, both vertically and laterally, particularly in relation to the resultant effect on the electrical properties of the reservoir. Simple examples are given in the following pages to illustrate the use of resistivity logs in the solution of some problems dealing with oil and gas reservoirs. From the available information, it is apparent that much care must be exercised in applying to more complicated cases the methods suggested. It should be remembered that the equations given are not precise and represent only approximate relationships. It is believed, however, that under favorable conditions their application falls within useful limits of accuracy. Introduction The electrical log has been used extensively in a qualitative way to correlate formations penetrated by the drill in the exploitation of oil and gas reservoirs and to provide some indication of reservoir content. However, its use in a quantitative way has been limited because of various factors that tend to obscure the significance of the electrical readings obtained. Some of these factors are the borehole size, . the resistivity of the mud in the borehole, the effect of invasion of the mud filtrate into the formation, the relation of the recorded thickness of beds to electrode spacing, the heterogeneity of geologic formations, the salinity or conductivity of connate water, and, perhaps of greatest importance, the lack of data indicating the relationship of the resistivity of a formation in situ to its character and fluid content. On the Gulf Coast it is found that the effects of the size of the borehole and the mud resistivity are generally of little importance, except when dealing with high formational resistivities or extremely low mud resistivities. Fortunately, little practical significance need be attached to the exact values of the higher resistivities recorded. Low mud resistivities are not common, but when this condition is encountered it may be corrected by replacing the mud column. With the present advanced knowledge of mud control, invasion of mud filtrate into sands can be minimized, thereby increasing the dependability of the electrical log. The effect of electrode spacing on the recorded thickness of a bed is often subject to compensation or can be sufficiently accounted for to provide an acceptable approximation of the true resistivity of the formation. As development of a field or area progressively enhances the knowledge of the lithologic section, the resistivity values of the electrical log take on greater significance, ultimately affording acceptable interpretations. The salinity, and

Jan 1, 1942

By Reed W. Hyde

SOME information has been published on the sulphur dioxide concentration of gases from Dwight-Lloyd machines sintering lead ores but most of this relates to the customary practice in which the charge is relatively high in lead and is sintered in two passes over the machine. It is thought, therefore, that the following observations on sintering in one pass a low-lead, low-sulphur charge may be of interest. The data were obtained in sintering lead sulphide flotation concentrates mixed with minus 20-mesh oxide ore, the mixture carrying 16.8 per cent Pb and 5.3 per cent S. No returns were used because of the limited amount of sulphur available as fuel, but the mixture pelletized readily to make a satisfactorily permeable bed on the sintering machine. As there was a possibility that the SO2 might be utilized, a series of runs was made to determine the concentration of S02 in the gases at different points along the wind box, and the effect on this concentration of changes in the wind-box vacuum. Several runs each were made with vacuums (as measured in inches of water at the wind box) of (1) 2 to 1 1/3 in., (2) 4 to 3 1/2 in. and (3) 6 to 5 1/8 in. The averages of the determinations from each series are platted on the graph (Fig. I). The vertical scale shows the percentage by volume of SO2 (as determined by the Reich method), and the horizontal scale shows the time expressed as percentage of the total sintering time. Sintering was considered to be complete when no S02 could be detected in the gases. In all cases the depth of bed was 4 ½ in. and the weight of dry charge per square foot of hearth area was 45.2 lb. Other data are given in the table. The volume of gases corresponding to the several points along the wind box at which S02 determinations were made could not be measured, but has been calculated from the S02 content and sulphur elimination on the assumption that the volume is uniform throughout the sintering period. This is not strictly true, as with a given vacuum the volume will usually drop slightly toward the middle of the period and increase toward the end. However, this assumption is a reasonable approximation. Several interesting features are brought out by these data. In general, the published data on S02 concentration in sintering under ordinary conditions show a high S02 concentration in the early stages followed by a rapid decrease in concentration and with relatively little SO2 in the gases from the last half or third of the operation. In other words, the greater part of the sulphur elimination is obtained in the first third or half of the period. In these runs, the 6-in. vacuum, which approximates the usual operating condition, gives a curve that follows this customary pattern. Maximum S02 concentration is obtained 2 ½ min. after

Jan 1, 1942

By J. E. Armstrong

THE Pinchi Lake mercury belt is in central British Columbia, about fifty miles north of the Prince Rupert branch of the Canadian National railway (Figure 1). Until 1936 little was known about the geology of this area. Jn 19~6 and 1937, J. G. Gray and the writer mapped the Fort Fraser area (G.S.C. maps 630A and 631A) for the Geological Survey of Canada. During the field season of 1937, cinnabar was discovered by J. G. Gray in the Permian limestones on the north shore of Pinchi lake on what have since proved to be the main showings of the Pinchi Lake mercury mine. Claims were staked in the spring of 1938 and later that year were optioned to the Consolidated Mining and Smelting Company. Development work revealed cinnabar deposits of commercial size and grade, and a small reduction plant was erected, production of mercury commencing in June, 1940. Since 1940, this plant has been enlarged by additional units. The ore treated is reported to contain between 0.5 and 0.75 per cent mercury. The production of mercury from this deposit is now far in excess of Canadian requirements and this country is able to supply the United Kingdom with part of its needs. In 1940 and 1941, several other occurrences of cinnabar were found northwest of Pinchi lake. During 1941, the writer made a geological investigation of the known cinnabar occurrences and of the belt of country in which they are located. The present paper summarizes the results of this work. The writer is indebted to officials of the Consolidated Mining and Smelting Company, and to Mr. E. Bronlund of the Pinchi Lake mine in particular, for their generous co-operation in the work.

Jan 1, 1942

IT is necessary that all men who wish to bring things to a certain end should think of the agents needed to attain this. Now whichever one of the above processes you wish to use you must consider the nature of the material and see whether it is disposed to render what you wish to extract. Then you must see whether you have the other agents sufficiently powerful and proportioned to attain this result, for if the things were not in harmony your work would be vain and very laborious. Therefore, if you should wish to make waters or oils by way of distilla-

Jan 1, 1942

From the early part of the thirteenth century bituminous coal was called "sea coal" in England, from the fact that the coal seams in the Fife and Northumberland fields outcropped on the shores of the North Sea and wave action and erosion resulted in lumps of coal being found in large quantities along the shores. These were gathered by women and children and sold for fuel to replace wood. Coal first reached London by sea, and there was a "Secole Lane" in that city in 1228. The term was gradually applied to all coal and for some hundreds of years all coal in England was called "sea coal", and the term is not yet obsolete there. Another reason for the use of a defining word was the fact that from time immemorial, in England and elsewhere, the word coal meant char-coal, or coal made from wood, as this was the common fuel of those times when anything other than natural wood was burned. The biblical references to coal all mean wood-coals or charcoal, and one must be careful in writings prior to at least 1750, when "coal" is used to be sure that it means stone, or mineral coal, rather than wood or charcoal. "Sea-coal" was in common use along the Atlantic seaboard until after about 1780; the first map showing coal in Pennsylvania, Ohip and Kentucky, made as of 1750, used the term "sea-coal here."2 In the interior stone coal was used by the early writers almost entirely, partly to differentiate it from charcoal, but largely because it was found with stones and rocks, and in most places then had the same value. "Fossil" coal was used by Hamilton in 1790. Jefferson called it mineral coal and pit coal in 1781. The term mineral coal was usually used in the governmental references to it as late as 1850, but the present use of bituminous coal began as soon as anthracite came on the market in 1820. Both mineral and stone coal still survive in the laws of several states specifying the weight of a bushel of coal.

Jan 1, 1942

HAVING promised you to write concerning the nature of ores in particular, I must tell you some general facts, especially those concerning the places, kinds, and manner of their existence as well as the tools which are used. However, you must know that according to good investigators these ores are found in many parts of the world. They show themselves almost like the veins of blood in the bodies of animals, or the branches of trees spread out in different directions. Indeed, careful investigators of minerals, wishing to show by analogy how ores are located in mountains, have drawn a large tree with many branches, planted in the middle of the base of a mountain. From its principal trunk extend various branches, some thick, some slender, exactly like real trees in mature forests. They think that these grow and enlarge continually and draw themselves toward the sky, ever converting into their own nature the most disposed adjacent materials so that finally the tips arrive at the summit of the mountain and emerge with clear sign, sending forth, in place of leaves and blossoms, blue or green fumosities,* marcasites with small veins of heavy mineral, or other composition of tinctures. From these things, when they are found, it is possible to make certain inference that such a mountain contains ores, and as the signs are more or less, so are the minerals plentiful and rich or poor. For this reason the prospectors for these things take heart according to the manifestations that they find, and with hope and certainty of profit they take all possible pains to mine with skill and expense those things that the signs have indicated. Often there are ores of such a kind and quality that they raise a man in wealth to the skies. For this reason men penetrate with eyes of appraisal and judgment within the mountains and see almost exactly the places where there is ore and the

Jan 1, 1942

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Jan 1, 1942

There are references to the early and continuous production of coal since 1851, but few definite figures. Some data were obtained from Bancroft, but nearly all the tonnages in Table 80, prior to 1869, are estimated. [ ]

Jan 1, 1942

By F. A. Jones

Increased mechanization .of coal mines has emphasized the need for study of actual power requirements of the various machines employed in the production of coal and losses in the distribution of power to these machines. These studies are being made in order that hazards, excessive use of power, and high maintenance cost of equipment resulting from these losses may be analyzed and eliminated where possible. Research on the use of electric power in-coal mines was suggested by the Advisory Committee of the Bureau of Mines in 1937, and it was decided to begin with a study of individual machines of various types under operating conditions in modern coal mines. The transmission of power, particularly line losses and inadequate return circuits, should be a part of the investigation. This report presents some of the data of an initial study in commercial mines. ACKNOWLEDGMENTS The superintendents, engineers, and other officials of the two mines studied cooperated fully and aided in setting up and transporting the test equipment, giving such information as was requested.

Jan 1, 1942

By John D. Sullivan, Edwin J. Rogers, Chester R. Austin

THE problem of making a building unit combining the necessary physical and mechanical properties and good thermal insulation has been foremost in the minds of architects and ceramic and construction engineers for many years. This paper presents the results of studies on thermally expanding shales or clays to produce light-weight cellular products suitable for making building units. An expanded clay block suitable for building purposes should be large enough so that substantial savings may be effected in labor costs in laying the wall. The permeability should be low and it should have sufficiently good "dry-wall" characteristics to permit exposing the exterior surface to the elements, and to permit plastering directly the inside wall surface. The thermal conductivity should be low and the mechanical properties should be adequate. Obviously, a unit possessing satisfactory qualities for constructing an outside wall would be satisfactory for interior walls and for back-up purposes. The results of studies on bloating various shales or clays† and the properties of the expanded products are reported. In another paper1 basic factors involved in bloating of clays are discussed. Manufacturers of ceramic products, particularly structural clay, may encounter bloating of the ware during burning, and precautions must be followed to avoid this phenomenon. About 1927 the C. F. Burgess Laboratories, Madison, Wis., while carrying on an investigation for the American Face Brick Research Corporation, conceived the idea of intentionally bloating clay while holding it in a restrained condition, with the hope of producing a unitary cellular mass. Work was carried on until about 1931, when studies were terminated because of business conditions. These studies were continued later by The Western Brick Co., Danville, Ill., which developed a process of "inwardly expansive bloating." The major purpose of the latter investigation was to produce back-up tile to compete with concrete blocks made from Haydite or cinder aggregate. Haydite is a light-weight aggregate formed by heating certain clays or shales rapidly in a rotary kiln. While the investigations at the C. F. Burgess Laboratories or at Western Brick Co. were not carried far enough to lead to the commercial production of material for the construction of walls, particularly outside walls, they showed that certain clays could be thermally expanded and that it was possible to produce a material of low permeability with a large percentage of the total voids or cells closed. Commencing in 1939, the Ozark Chemical Co. sponsored a research program at Battelle Memorial Institute for the purpose of determining whether it is technically feasible to make thermally expanded building units, and specifically to get answers to the following questions:

Jan 1, 1942

The Howe Memorial Lecture, in memory of Henry Marion Howe, Past President of the Institute, was authorized in April, 1923, as an annual address to be delivered by invitation under the auspices of the Institute by an individual of recognized and outstanding attainment in the science and practice of iron and steel metallurgy or metallography, chosen by the Board of Directors

Jan 1, 1942

By C. J. Ramsburg

The construction and operation of by product coke-oven plants in America are essential to strong national defense and of the greatest importance to many widely diversified undertakings as well as to safety and health. Carbonization Process Coal used under a boiler or in a locomotive is consumed by combustion. Coal used in a by-product oven is distilled or carbonized, meaning that heat is applied to the coal, out of contact with air, causing a distillation that removes the volatile matter in the coal in the form of gas and vapor, leaving coke as a final product. From the gas and vapor distilled from the coal, many valuable substances can be secured, known as by-products. Hence the name "by-product oven." The simplest example of this principle can be shown by means of an ordinary clay pipe. If powdered coal is placed in the bowl of the pipe, the opening of the bowl is plugged with clay, and the bowl placed in a flame, the bowl will become hot, transferring the heat through the wall of the bowl to the coal within. When this coal attains a temperature of about 750°F., gas will begin to pour out of the pipe stem, and this gas may be lighted. A black liquid also will exude from the stem of the pipe, This is tar mixed with certain other products. What remains in the bowl after distillation is coke. A coke oven corresponds to the bowl of the pipe. A modern oven of the latest type is a refractory brick chamber approximately 42 ft. long and 14 ft. high, averaging 18 in. in width. The oven is filled with coal through closable charging holes in the oven top. Each end of the oven consists entirely of a self-sealing door, the removal of which permits the finished coke to be discharged by means of a power-operated pusher machine. The ovens are built in batteries, and the heating is effected by gas burned in vertical flues in the oven walls, each set of flues heating the walls of two adjacent ovens. Such ovens carbonize a charge of approximately 18 tons of coal in 18 hr., or have a daily throughput of 24 tons per oven, producing about 17 tons of coke. In times of need, the output may be increased by raising the temperature of flues, thus shortening the coking time. There is one great essential difference in principle between distillation in a clay pipe and in a coke oven. In the 18-in. oven, the distillation proceeds from two parallel walls held at a high temperature (over zooo°F.) and instead of all the coal being heated at once, the distillation is a progressive one creeping inward. The average travel of this heating is 35 in. per hour from each vertical wall, and as the volatile products are formed progressively they must push away from the interior toward the wall through the previously formed hot coke, then up the walls and Over the top of the coal charge, finally escaping through the outlet pipe. This results in a cracking of the components into many different and valuable substances not formed when the carbonizing temperature is low.

Jan 1, 1942