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Jan 1, 1955

Jan 1, 1955

E. A. Peretti (University of Notre Dame, Notre Dame, Ind.)—Mr. Deitz and Professor Halpern are to be congratulated on a fine piece of work which adds to our knowledge of precious metal—cyanide-solution reactions. I should like to offer the following comments: The authors state, "the rate plots were always linear, indicating a zero order reaction rate." This appears to conflict with the data of Fig. 6 which clearly show the rate to vary with the NaCN concentration. It seems to me that the rate curves are linear because of the experimental setup. The volume of solution is so large that over a three-hour period the change in NaCN concentration is very small. A rough calculation for the experiments of Table I where the initial NaCN strength was 0.0096 mol per liter show a change of NaCN concentration of about 0.0009 mol per liter at the end of three hours. In short, over the period of time that the experiment was in progress, the NaCN strength was practically constant; hence the rate of dissolution remained practically constant. Eq. 10, as written, specifies that 1 mol of H202 and 2 mol of hydroxyl ion are formed when 2 mol of silver react. Is this true? The effect of H,O2 on the rate was made in solutions having an oxygen pressure of 4.8 atm. Were any tests made in solutions containing hydrogen peroxide, but no oxygen? G. M. Willis (University of Melbourne, Melbourne, Australia)—The authors have shown that, under their experimental conditions of high O2 concentrations, the rate of solution of silver in aqueous cyanide solutions is controlled by diffusion of O2 or CN- to the metal surface. With diffusion control, it is generally not possible to obtain further information about the mechanism of a process.

Jan 1, 1955

By C. Arthur Carlson

"It now becomes my privilege and duty to call to order this fifty-first meeting of the Rocky Mountain Coal Mining Institute. "I bid you a hearty welcome and I know by your attendance at these meetings you will gain a great deal of valuable information, as well as have a wonderful time. "We have been very ably represented by Mr. John H. Emrick as General Chairman, assisted by our good friend Mr. Fred W. Whiteside, our secretary and treasurer. I know they have worked very hard in selecting the various committees, who in turn - by the looks of our program have gone all out to prepare material that should be of great interest to us. I trust we will be attentive to the subjects presented and freely enter into the discussions, also relating our problems and experiences. I am sure this will prove both profitable and beneficial to all present. "The main purpose of these conventions is to become acquainted with each other, renew old acquaintances, talk over our problems, and have a little fun and relaxation from our every day routine. "Let us not forget the manufacturers, the distributors, the operators, or the press because it is through their splendid support that this organization is successful. "Since our last meeting we have gained many new members, whom we especially welcome. We are sorry to have lost a few. I am mindful, at this time, of two very good members from my home state who have passed away, Walter Wetzel, a former president of this institute, and Lee Alger, at the time of his death, Vice-President from Utah. We also lost very recently our assistant Secretary-Treasurer, Everret Davis. These men contributed a great deal to the institute and the coal industry in general. I am sure they are greatly missed by all who knew them."

Jan 1, 1955

The ores described in this paper are from the two principal orebodies at Wiseman's Creek, a small village about 22 miles south-east of Bathurst in central-western New South Wales.The first official reference to mining at Wiseman's Creek is in "Mineral Statistics of New South Wales" of 1875, which reported that the Wiseman's Creek Copper Mining Company had proved a lode-later known as "North Wiseman's"-to a depth of 120 ft., where it was found to be 20 ft. wide. By 1876 the erection of a mill and smelting works had commenced, and the sulphide ore found to contain copper lead, zinc, silver and gold. Some oxidised ore was also being worked. Operations were, however, generally unsuccessful, and sporadic work up until 1907 produced only about 5,000 tons of ore. The other more important orebody of the locality-the Phoenix-was not opened until about 1895. By 1908, as reported by J. E. Carne, the shaft had been sunk 340 ft., with the extraction of both oxidised and primary ore. At the time of the slump in copper, pric'es in 1907 approximately 3,000 tons of, ore had been produced.Several smaller orebodies were discovered and worked during the same period as the North Wiseman's and Phoenix, but their output was more or less insignficant. THE OREBODIES AND THEIR GEOLOGICAL SETTINGIt is now impossible to examine the orebodies underground, but they appear to have formed a series of flat lenses, whose major axes were parallel to ,the foliation of the enclosing quartz-chlorite-muscovite schists. The largest ,of these lenses was worked as the North Wiseman's orebody, which was reported by Carne to vary in width from 1 ft. to 20 ft., and which probably extended discontinuously over a strike length of about 1,000 ft. The Phoenix orebody is stated to have varied from 1 ft. 6 in. to 3 ft. in width...

Jan 1, 1955

By M. E. Nicholson

IN order to understand how alloying elements influence hardenability through their effect on the rate of pearlite nucleation, it is advantageous to use a model to describe the mechanism of pearlite nucleation. The model which currently is most widely accepted has been described, among others, by Mehl et a1.1-3 and by Hultgren.4 Pearlite nucleation involves both the nucleation of ferrite and cementite.4,5 Cementite nucleates first, followed rapidly by the formation of ferrite at the cementite-austenite interface. The conclusion that cementite is the first phase to form during the process of pearlite nucleation is based, in part, on the observation that proeutectoid cementite is continuous with pearlitic cementite and that the orientation relationship between proeutectoid ferrite and austenite is not the same as that between pearlitic: ferrite and austenite.6,7 Recently, Smith" has suggested that the dissimilarity in orientation relations, instead of indicating the pearlite nucleation sequence, may be evidence that pearlite is nucleated in a grain adjacent to the one in which it is growing. Also, Modin9 as shown that ferrite in pearlite may be continuous with proeutectoid ferrite, and he has also shown that proeutectoid cementite is not always continuous with pearlitic cementite. Thus, it appears that the conclusion that cementite always initiates the pearlite nucleation process is open to serious question. The author believes that important evidence on the question of how pearlite is nucleated exists in the rates of pearlite nucleation of different steels. The following is a review and analysis of this evidence. If the nucleation of pearlite is considered as requiring the nucleation of both cementite and ferrite, then the time to nucleate pearlite consists of the time to nucleate the first phase to form, plus the time to nucleate the second phase at the advancing interface of the first. In the absence of a visible proeutectoid constituent, the second phase must be nucleated very soon after the first. If cementite is the first phase to form, the time to nucleate pearlite will be approximately equal to the time to nucleate cementite. Since the nucleation rate of a phase precipitating from solid solution increases with the degree of supersaturation, it would be expected that the rate of pearlite nucleation should increase with increasing carbon content. Digges10 has shown that the reverse is true. He determined the quenching velocity necessary to suppress pearlite formation in plain carbon steels as a function of carbon content. His results showed that pearlite formation could be suppressed with lower quenching velocities as the carbon content of the steel increased, at least up to 1.25 pct C, the highest carbon content he studied. Thus, it would appear that in plain carbon steels, in which pearlite is formed at the nose of the C-curve, the hypothesis that cementite nucleates first does not predict the observed change in nucleation rate. The validity of the current model of pearlite nucleation may be tested also by determining whether or not it predicts the relative influence of alloying elements on the nucleation of ferrite and pearlite. This can be done best by a consideration of the changes in a TTT diagram produced by a change in alloy content. Hultgren4 suggests that the general shape of a TTT diagram, as well as what constituents will form from austenite, can be predicted from the relative nucleation rates of ferrite and cementite. This is illustrated in the schematic diagram for a hypoeutectoid low alloy or plain carbon steel shown in Fig. 1. The C-curves for ferrite nucleation and for cementite nucleation are represented by AA' and CC', respectively, and the start of ferrite formation and pearlite formation are represented by AX and BC respectively. Adopting the current theory, Hultgren suggests that between X and C pearlite forms directly from austenite, since cementite nucleates more rapidly than ferrite in this temperature range. Conversely, at temperatures above Tx, ferrite is the first to nucleate and proeutectoid ferrite is formed. As proeutectoid ferrite grows, austenite becomes enriched in carbon, so that the cementite nucleation rate is increased. As a result, pearlite nucleation above temperature Tx is accelerated, beginning along BX and not along C'X. Temperature T, represents the temperature at which the nucleation rate of ferrite equals that of cementite. By extending this type of reasoning, using the principle that the nucleation rates of ferrite and cementite increase with increasing supersaturation of austenite with respect to these phases, it should be possible to predict the influence of carbon content on the shape of the isothermal transformation diagram. For a slightly higher carbon content than that of Fig. 1, the curve A A' representing the beginning of ferrite formation should be moved to the right, whereas the curve CC' representing the beginning of cementite formation should be moved to the left. For hypoeutectoid plain carbon and low alloy steels, this prediction does not agree with existing data. Instead, as the carbon content is increased, the pearlite curve moves to the right along with the ferrite curve and always appears to join it tangen-tially. This behavior is demonstrated by the TTT-curves of a series of manganese steels" shown in Fig. 2. In this figure, TTT-curves for four alloys containing 0.20, 0.40, 0.60, and 1.20 pct C are superimposed. The curves are identified in the figure legend. The letters F, P, and C are used to indicate the start of ferrite, pearlite, and cementite formation, respectively. In these steels, it appears that the nucleation of ferrite and of pearlite are related processes. As a result of the foregoing evidence, it is proposed that the formation of pearlite be considered as follows: Either ferrite or cementite may nucleate from austenite, then grow until the remaining phase is nucleated at the interface between the growing phase and austenite. (The growth of the first phase to form is assumed to be accompanied by a composition change in the adjoining austenite.) According to this model there are two modes of nucleating pearlite: 1—where cementite initiates the succession

Jan 1, 1955

By C. P. Haller, S. J. Aresco, R. F. Abernethy

The Bureau of Mines has been active in promoting the purchase of coal for Government use under specifications that define the requirements in terms of heating value of the coal, expressed in British thermal units, and the composition as shown by proximate analyses. To these, when required, are added the ash- softening temperature of ash, the free-swelling index, and the hardgrove grind- ability index. Under most of these specification contracts the bidders guarantee the quality of the coal, and that guaranteed by the successful bidder becomes the standard of his contract. The deliveries are sampled in accordance with instruc- tions issued by the Bureau of Mines; the samples are analyzed in the Bureau laboratory to determine whether the coal is of the quality guaranteed by the con- tractor and, if it is not, a price adjustment is made. Analyses of the delivered coal and tipple samples (samples collected at mine tipples as coal is being loaded into railroad cars or trucks) provide valuable data for use in evaluating future bids. In addition, the continuous sampling of coal as delivered is a check on the practical results obtained in burning the coal. The Government purchased approximately 5-1/4 million tons of coal in fiscal year 1953. In connection with these purchases, the Bureau analyzed 11,435 samples. These are published for the use of Government officials and the public. A series of publications has been completed on coal analyses by States, or, where production is small in any one State, by groups of adjacent States. In addition to analytical data showing composition and quality of coals of the States, the publications con- tain brief descriptions of the geological structure of the coal basins, typical mining conditions in the various districts, the principal economic data of the industry, and the relationship of mine or channel samples to delivered and tipple samples. The present publication covers many States but deals only with the analytical data of the coals. Previous publications in this series are: Bulletin 516, Analyses of Tipple and Delivered Samples of Coal (Collected During the Fiscal Years 1948 to 1950 Inclusive); Report of Investigations 4934, Analyses of Tipple and Delivered Samples of Coal (Collected During the Fiscal Year 1951); Report of In- vestigations 4972, Analyses of Tipple and Delivered Samples of Coal (Collected During the Fiscal Year 1952). Following are the Bureau of Mines technical papers published by States, with their numbers: Alabama, 347; Alaska, 682; Arizona, California, Idaho, Nevada, and Oregon, 696; Arkansas, 416; Colorado, 574; Illinois, 641; Indiana, 417; Iowa, 269 and 706; Kansas, 455; Kentucky, 308 and 652; Maryland, 465; Michigan, North Dakota, South Dakota, and Texas, 700; Missouri, 366; Montana, 529; New Mexico, 569; Ohio 344 (and Bulletin 499); Oklahoma, 411; Pennsylvania Bituminous, 590 (Supplement 645); Pennsylvania Anthracite, 659; Tennessee, 356 and 671; Utah, 345; Virginia, 365 and 656; Washington, 491 (Supplement 618); West Virginia, 405 and 626; and Wyoming, 484.

Jan 1, 1955

By B. K. Shibler, I. S. Solet, H. W. St. Clair

"This study was undertaken to provide a more adequate knowledge of the chemistry of the sulfide volatilization process for recovery of tin from low-grade Bolivian ores. The investigation was partly supported by the Department of State under its program for scientific cooperation with South American republics.The results of this investigation demonstrate the conditions under which cassiterite (Sn02) may be converted to stannous sulfide by reaction with pyrite or sulfur vapor. Quantitative data are given on the rate of sulfidization and on the vapor pressure of stannous sulfide.INTRODUCTIONAlthough the United States is the world's largest consumer of tin, virtually no tin ores occur within our national borders. Most of the world's tin supply comes from alluvial deposits in the Far East and in Africa, The major sources of tin ores are Malaya, Indochina, Bolivia, Belgian Congo, Nigeria, Thailand, Burma, China, and the United Kingdom. Bolivia is the only important source of tin in the western hemisphere. It was the chief source of tin f or the United States during World War II. The Government-owned tin smelter at Texas City, Tex., was built primarily for smelting Bolivian ores and depends largely on Bolivian ores for its operation. Bolivia is the only major tin-producing country in which the tin ores occur as vein or lode deposits requiring underground mining. Most of the tin from the Far East and Africa is mined by dredges from alluvial or placer depos its. It is recovered as a high-grade concentrate of cassiterite relatively free from impurities. The tin minerals in the lode deposits are more intimately associated with other minerals and more difficult to separate into a clean concentrate. Furthermore, a large part of the tin in the original ore is lost during concentration. The ores as mined contain only a few percent of tin, so they must be milled to separate the gangue minerals and produce a concentrate containing 30 to 40 percent tin before they are shipped to the smelter. The losses of tin that occur during milling vary from 18 to 65 percent. The average recovery of tin from Bolivian ores is probably 50 to 60 percent."

Dec 1, 1954

By Agustín Arias

El presente artículo describe brevemente la historia, métodos de explotación, mecanización, energía eléctrica, las plantas de preconcentración y flotación y el consumo de reactivos de la compañía minera Milpo.

Nov 1, 1954

By Hugo Vásquez Rosas

El presente texto señala la composición química de un mineral de cobre a través de un estudio microscópico. El estudio consiste en establecer los componentes químicos del mineral por medio de las microfotografías con luz reflejada normal. Estos componentes son la bornita, chalcopirita, chalcocita, hematita y cuarzo. De acuerdo a los estudios efectuados por Schwartz, la bornita y la chalcopirita forman extensas pero no continuas soluciones sólidas a temperaturas elevadas -por encima de 475°C. dado que tienen como componentes los mismos elementos y la estructura cristalina es parecida.

Nov 1, 1954

By S. Haapala

El presente artículo describe la geología general, formaciones, plegamientos y fracturación, geología económica, mineralogía y la mineralización (alteración, zoneamiento, controles de mineralización) de la mina Colquijirca.

Nov 1, 1954

By Mario Samamé Boggio

El presente texto describe las condiciones en que se desarrollaba la industria extractiva antes de la dación del Código. Asimismo se revisa la política económica y social en sus aspectos económicos de la minería.

Nov 1, 1954

By Silvio Hernández Aquije

"El presente texto señala las instrucciones para el trazado de los sondajes diamantinos, así como se describen las siguientes fuentes vanadíferas: Checoeslovaquia, Inglaterra, Francia, Alemania, España, Méjico, Estados Unidos,Argentina Sud Africa y Rhodesia del Norte y Minasragra. En ese sentido, se recomienda que se realicen investigaciones en la parte oxigenada de todos los filones de plomo, zinc y cobre de la Cordillera de los Andes con el fin de identificar una nueva fuente vanadífera. Asimismo, de los tres grupos de filones asfalto-vanadíferos que comprende la región Central del Perú, el que más interés ha tenido por su valor en vanadio es el primer grupo, pese que las asfaltitas que lo constituyen pertenecen a la clase de las llamadas secas. A este grupo de filones, pertenecen Minasragra y Sillapata."

Jul 1, 1954

By Pedro Dominguéz S

La exposición apunta al doble tratamiento metalúrgico para la recuperación del oro, cobre y plata contenidos en los minerales de la mina Calpas. Para ello, el conjunto de vetas de las minas,muestra las zonas en las que predomina el cuarzo y la pirita con oro y algunas trazas de cobre. En este punto, surge la cianuración como tratamiento para beneficiar aquellos minerales con cobre, como aquellos que no lo tienen y en el que las instalaciones de plantas de beneficio permitirá una producción mayor a su tonelada.

Jun 20, 1954

By Pengle C. H.

El presente trabajo señala los beneficios de la explotación del mineral encontrado en las minas de Carahuara, Junín, de la Compañía volcán Mines S. A. El tratamiento del mineral logra superar las dificultades de separación cobre- plomo mediante la planta concentradora del Marh Tunel, Cerro de Pasco Corporation y permite recuperar el valor principal de la plata-dentro de los concentrados de zinc-, así como del plomo.

Jun 20, 1954

By Alfonso Rizo-Patrón Remy

El objetivo del siguiente trabajo es señalar un método que permita la recuperación económica de metales preciosos como el oro, plata y otros metales básicos (tales como plomo y cobre) de sus respectivas menas naturales y de los concentrados o relaves que los contengan. Para ello, se utlizará dos formas de aplicación: La primera se da en el tratamiento por cianuración de las menas, donde el carbón mineral es el medio precipitante de los metales disueltos. Mientras que la segunda ocurre cuando el carbón ha sido separado de las pulpas cianuradas, conviertiéndose en un agente reductor de los metales de fundición. De forma tal que se logra una recuperación integral de los metales preciosos y básicos en las barras de fundición.

Jun 20, 1954

By Silvio Hernández A

La siguiente investigación refiere dos aspectos de la metalurgia del vanadio, en tanto se relaciona con el desarrollo de la industria minera nacional. El primero indica el modo de aumento de la producción de dicho metal, a través de un método adecuado que aligere el proceso de calcinación y del tratamiento metalúrgico de las cenizas vanaderas. Mientras que el segundo aspecto,muestra las causasdel déficit (causas mecánicas, temperatura, composición de la mena), en la planta de Lixiviación N. 2 de la Vanadium Corporation of America en Jumasha, Cerro de Pasco. Para ello, se propone aplicar el tostado clorurante, seguido de una lixiviación con ácido sulfúrico en hornos de reverbero, que mantenga una recuperación aceptable y permita una mejor producción del metal.

Jun 20, 1954

By Tage Jepsen

El presente análisis muestra el proceso de lixiviación y precipitación en la extracción del cobre en el Perú utilizando las aguas de la mina Quiruvilca. La alimentación de las mismas permitirá transformar el mineral en sales secundarias de cobre, fácilmente solubles y por ende, dar una mejor distribución del mismo hacia los canales de precipitación.

Jun 20, 1954

By I. Girón

El siguiente estudio revela la importancia del cultivo del selenio, propiedades, combinaciones y distintos usos en la industria y sistema de comunicación telefónica. Asi también describr el proceso de purificación y obtención de este compuesto mineral en Cerro de Pasco Corporation, destacando al Perú como uno de los países productores a nivel mundial, pese a su reducida proporción.

Jun 20, 1954

By Alfonso Ballón

Dado que las aguas pertolantes crean problemas en las operaciones de concentración de menas, se buscó un tratamiento selectivo de flotación por el cual pase la blenda(obtenida de yacimientos de cobre y zinc) separada del cobre. Empero, este proceso tiene dificultades porque no hay diferenciación de sus superficies cristalinas y los sulfuros de cobre son confundidos con los de zinc. Por ello, el objetivo del presente trabajo es mostrar las pruebas realizadas que permitan asegurar una perfecta activación de la blenda contenida en la mixtura, asi como una mejor separación del cobre y el zinc, entre otras, reuniendo las condiciones necesarias para su aplicación con el sulfato de cobre.

Jun 20, 1954