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By C. Q. Cupps

Rate of gas diffusion in reservoir oil has been investigated in an effort to explain the variation in oil characteristics observed in the Weber Sandstone reservoir, Rangely field, Colorado. Coefficients of gas diffusion were determined experimentally for the Rangely oil system and used in a mathematical simulation of gas diffusion during the probable life of the Rangely reservoir, estimated at 65 million years. The simulator involved solution of Fick's law for diffusion in two dimensions by the method of finite difference and successive over-relaxation. The results show that continuing gas diffusion is a logical explanation for the variation in oil characteristics at Rangely and that the pattern of gas distribution by diffusion in an asymmetrical reservoir will not conform to structural contours as originally proposed.

Jan 1, 1971

A number of small copper deposits occur in the Pernatty Lagoon-Mt. Gunson area. Textural and mineralogical differences distinguished the lagoon sulphide deposits, which occur in a water filled basin of permeable bedrock immediately under the lagoon floor, from the largely oxidized deposits which occur in the low hills adjacent to the lagoon deposits.Groundwaters are carrying copper, and to a lesser extent zinc, downstream to the lagoon. Several species of sulphate-reducing bacteria are widespread in the groundwaters and lagoon muds.It is suggested that copper sulphides were first deposited at the same time as, or soon after, the host Proterozoic sediments, and that during the present cycle of erosion the lagoon deposits may have been enriched, or largely formed, by bacterial precipitation of copper sulphides from laterally migrating cupriferous groundwaters.

Jan 1, 1971

By Jack Parker, Bert Caverson

More than 6000 resin-anchored bolts have been installed at the White Pine mine, and their performance has proven excellent in both pull tests and "beam" building. With its improved reliability, resin anchorage will permit a more scientific approach to the design of roof bolting systems, and this should ultimately result in both better support and reduced costs. The White Pine mine lies five miles south of Lake Superior in Ontonagon County. Mich. The orebody occurs in gently dipping upper Keweenawan sediments midway between the Porcupine Mountains and the Bergland Hills, both of which are ranges of steeply dipping Keweenawan extrusives and intrusives.

Jan 1, 1971

By F. L. Holderreed

A choosy in what they would smelt. The furnace charge had to be coarse, and it had to be rich. They discarded fines in excess of about 1/10 the total weight. They wanted 10% copper content and fussed about anything with as low as 5%. They concentrated the copper content of the charge as much as they could by prior selection. They roasted off enough sulfur to further enrich the copper content of the succeeding fall of matte (a melt of cuprous and ferrous sulfides or Cu2S.FeS). Then they desulfurized the iron and fluxed it by carefully adding silica (quartz, not silicates) for a slag of lower density than the cuprous sulfide (Cu2S or white metal). After skimming off the slag, they further desulfurized the white metal by blowing the molten bath with compressed air. The result was blister copper. Yesterday Their techniques and furnaces? Some experimented with mechanically rabbled roasters, but their standard roasting practice was burning coarse sulfide ore in 250-ton heaps. These heaps, approximately 24 x 24 x 6 ft, were burned for about 75 days down to 6-10% sulfur. The turnaround time for a given roasting position was 100 days. Assuming the base was a hearth, the calculated rate of treatment was on the order of 0.004 tpd per sq ft.

Jan 1, 1971

By M. L. Whisman

The Bureau of Mines developed a radiotracer method for detecting the contribution of selected components and additives to thermally induce deposits of turbine aircraft fuels. Fuels were examined before and after 52 weeks of storage at 130° F. Of particular concern was the influence of aromatic hydrocarbon fuel constituents on thermal-stability quality of jet fuels during storage. A microfuel coker test apparatus was used to thermally stress the test fuels and blends, and the resultant contribution to deposits of selected fuel components, labeled with carbon-14, was determined by radioactive-counting techniques. Ninety-one blends of five test fuels with carbon-14-labeled fuel additives or components were prepared, tested, stored for 52 weeks at 130° F, and reanalyzed for deposit-forming tendency. These additives included two anti-oxidants, a metal deactivator, and a corrosion inhibitor. Of the labeled hydrocarbon fuel systems studied, the greatest reaction was observed in blends containing methyl-and ethyl-substituted indenes. Other aromatic types also showed some contribution to the deposits. Three of the additives showed a marked tendency to degrade and react during storage and thermal stress. A cresol antioxidant, however, barely contributed to deposit formation. Oleic acid interacted with cadmium present in aircraft fuel systems and produced deleterious effects upon the thermal-stability quality of the fuel.

Jan 1, 1971

By H. Tetu, F. Pells

"The copper-molybdenum property of Brenda Mines Limited is located in the Okanagan district of British Columbia, approximately 25 miles west of Kelowna. The Okanagan Valley is a resort and fruit-growing area, and therefore pollution control measures are more stringent than in some remote areas.The Brenda plant began production in April 1970 and is operated at a rate of 24,000 tons per day. The plant site is located at an elevation of 4,800 feet, which is approximately 3,600 feet above the level of Okanagan Lake. The site is in the Okanagan drainage basin.The major consideration in the design of the system was the prohibition of any downstream discharge. It was therefore necessary to redaim as much water as possible and to minimize the addition of fresh water to the system. The maintenance of a water balance is of critical importance.This paper will outline the major design criteria for the systems and the site investigations which were carried out. The design and construction of the facilities will be de-scribed and current operating experience will be outlined."

Jan 1, 1971

By John V. Beall

They let the whole world know again that not only could we do it, but we make it look easy. The great crews before Scott, Irwin and Worden of Apollo 15 have all blended warm humor, informality and dexterity to put on a good show: but it keeps getting better and the last one was the best. Scott's rendition of Galileo's experiment using a hammer and a feather--not just any feather, but a falcon feather after the name of the LEM-was priceless. One generation of school kids will never forget that lesson. The final touch was in the "would-you-believe''" category, Now if English astronauts had been performing the mission, the sign-off would have been typically low key. Something like; "well its tea time, chaps; we'll have to toddle along." Apollo 15 surprised and thrilled spectators by blasting off to the Air Force song "Off we go into the wild blue yonder" and leaving a camera behind to photograph their own ascent. Now that is what we call showmanship. There is another aspect to our space show and that is that it cost billions of dollars to put on. With that kind of backing, the world for an audience and in the face of grave personal risk, one would expect the space explorers to be all business. Instead they did their jobs with limpid buoyancy. Our older readers will recall and contrast a movie of the thirties and the tense atmosphere when they had to talk that kid up there (Franchot Tone) down through the zero ceiling. A feat of considerably less difficulty than docking LEM. but nevertheless the gut tightening drama was absent in the latter event. In another example, few of us can visualize reporting back after a business mission to one of the old barons such as J. P. Morgan in any but the most sedate and business-like terms. In fact we don't have to go that far back, as we can think of a few pepper-pot bosses we have had to whom one always played it straight.

Jan 1, 1971

The 67th Regular Meeting of the Rocky Mountain Coal Mining Institute convened in the C'est Bon Hotel, Park City, Utah, and was in session at 10:00 a.m. The meeting was called to order by Past President John A. Reeves, Vice President, Mid-Continent Coal & Coke Company, Carbondale, Colorado. Mr. Reeves introduced President Max A. Robb and read a brief biography as follows: A Westerner by birth, he has chosen to pursue his mining career with United States Fuel Company, a subsidiary of United States Smelting, Refining and Mining Company. United States Fuel Company is the largest underground producer of commercial and utility coal in the Intermountain West. Max attended Utah schools and has kept his education current through correspondence courses in mining technology and business education, and through attendance at various university-sponsored development seminars.

Jan 1, 1971

By F. E. Senftle

Preliminary geophysical surveys for nickel deposits are usually carried out by airborne magnetometer and surface electrical methods. Once an anomaly is discovered by these techniques, one must resort to chemistry to identify nickel and determine its concentration. Consequently, a method to determine nickel quickly and quantitatively at the exploration site could help guide detailed sampling and provide analytical data that might otherwise be delayed at distant laboratories. In addition, borehole probes capable of indicating nickel in the rock adjacent to the hole, should prove attractive to the exploration geologist. With these needs in mind, preliminary investigations have been made to demonstrate an in situ analytical technique which appears feasible for nickel exploration. The method depends on the very high energy gamma rays emitted when nickel absorbs a thermal or low energy neutron. These neutron capture gamma rays should be distinguished from the lower energy gamma rays emitted during decay of radioactive nuclides as in conventional activation analysis.

Jan 1, 1971

By John J. Henn

An evaluation is presented of the Bureau of Mines process for the recovery of metal and mineral values from municipal incinerator residues. This process employs standard mineral beneficiation techniques and is operating on a pilot-plant scale of 1,000 pounds of incinerator residue feed per hour. Products from this separation process include ferrous, aluminum, and copper-zinc scrap, and colorless and colored glass. Cost estimates were prepared for four plant sizes. The estimated capital and operating costs For the four plants follow: [ ] It is assumed that the separation plant is located adjacent to a municipal incinerator. Provision is made, however, for part of the residue feed to be delivered by truck so that one large separation plant can be used for residue from more than one incinerator.

Jan 1, 1971

By E. E. Malouf

Rapid depletion of the world's mineral deposits combined with the expanding demand for metals places great pressure on our ability to provide technologically and economically feasible processes to recover greater amounts of metals from progressively lower grade sources. Chemical mining is one area in which expanding research and development can provide new processes or refinements to existing ones. These new techniques could result in increased production of metals from materials now considered uneconomic to process by current technology. To mine by chemicals requires the interaction of such disciplines as hydrometallurgy, microbiology, chemistry (both organic and inorganic), fluid flow, mineralogy, geology, and of course, economics. One of the least understood areas but one which may end up being an essential part of any chemical mining process is microbiology, i.e., the role of microorganisms in altering minerals and metals in solution.

Jan 1, 1971

By J. K. Gustafson

Since prehistoric times, gold has been sought for its beauty and its unusual physical and chemical properties. Early in the dawn of civilization it became the ultimate unit of value, and for at least 6000 years it has been used to barter for other commodities. It has been prospected for, treasured and made into works of art and personal adornment. From time to time, it has even been the object of conquest. Because of its predominant role as a basis for money in recent centuries, economists have come to think of gold solely in these terms. Gold, however, has physical and chemical properties that make it one of the most useful metals in the modern world. It is the most ductile metal known. An ounce of it can be drawn into a continuous wire over 35 miles long. It is also so malleable that an ounce of it can be beaten into films 0.00001 in. thick covering 68 sq ft of surface. It has a density of 19.3 and is so heavy that 1 cu ft of it weighs more than half a ton. Gold is nonmagnetic and has a high electric conductivity that is only slightly less than that of silver and copper. Gold is so inert to all the chemicals found in nature that gold coins and jewelry buried beneath the soil or at the bottom of the sea for thousands of years appear to be as bright and perfect as when they were first immersed. Finally, gold has an extremely high reflectivity of both light and infrared rays.

Jan 1, 1971

By A. Chakravarti, C. C. Harris

First-order kinetics adequately describe the recovery of a single floatable species. The conditions under which cell behazior can be simulated by a single-phase model are discussed; deviations from the multiphase model are accountable. The rate coefficient depends upon operating conditions besides particle size and mineralogy and the physicochemical properties of the pulp constituents. The model for a real flotation system combines the first -order, single-phase model with a distribution of noninteracting species. Methods for determining the distributions are discussed. Applications of the procedure to flotation studies are outlined. The mathematical description of flotation as a rate process can be traced to Garcia1 who reported cases in which the fraction of solid remaining in a cell in semi-batch operation, F (for Notation used throughout, see Table l), decays exponentially with experimental time T. F = e-k>r. (1 The differential equation leading to Eq. 1 is dF ----= -k,F (2) dT which is recognized as the algebraic analog of the chemical kinetics first-order reaction equation.' This has led to suggested mechanisms for flotation and mathematical relationships other than first order: with very little foundation other than analogy. The flotation rate coefficient kl can be accounted for as the product of several probabilities concerning bub-ble-particle attachment and detachment, aggregate entry from pulp into froth and return from froth to pulp, and removal from froth as concentrate. These factors clearly contribute to the magnitude of the overall flotation rate, and there are others also, but describing flotation merely as the overall probability of consecutive gross events hardly appears a significant advance in understanding. More recently, it has been described in terms of a stochastic process, which promises to provide a more satisfactory approach? The present paper will be more concerned with a phenomeno-logical description of the flotation process than with an account of the internal mechanics of the process. This is not a statement of priorities, or a judgement of the relative importance of these options but rather an assessment of what is presently possible. Previous investigators'" have developed methods for interpreting semi-batch flotation data in terms of species distribution. These methods have been used in an attempt to explain flotation behavior in response to changes in operating conditions." Inspection of examples given in the literature" reveals discrepancies between theory and experiment, and data obtained in the Colum-

Jan 1, 1971

By Thomas V. Falkie, Robert Stefanko

Higher education is in serious trouble in the United States. With increasing costs threatening to create a taxpayer's revolt, serious thought must be given to determining whether or not we can continue to afford our present educational policies. Disinterested students with little aptitude are pushed into over- crowded universities by well-meaning parents, but they lack real objectives beyond achieving that great status symbol-the degree. Advanced degrees are heaped upon the baccalaureate degree, and the pursuit of the pure and social sciences continues at the expense of engineering and technology.

Jan 1, 1971

By James J. Scott

I welcome this opportunity to speak before the Coal Division of the AIME in such an attractive setting as the Pacific Northwest. With the development of the Centralia project, the Pacific Northwest will have its first major coal-fired thermal electric generating plant. This State has a long history of coal mining that diminished with the passage of coal-fired steamships and locomotives but is now reviving with the growth of electrical power demand. Because this 1,400 row plant is to be supplied with surface-mined coal, it is particularly appropriate that this area be the setting for a talk on factors influencing the growth of surface coal mining in the West. During the course of my talk, I will touch on a number of factors including electric power demand, coal resources, production trends, environmental considerations and trends in State and Federal activities that I feel will influence surface coal mining in the West. Total electric power consumption by the year 2000 is expected to reach 9.4 trillion kilowatt-hours. Predictions of total coal consumption for electric power generation by that year range from a low of 845 million tons to a high of 1,520 million tons, or 2.6 to 4.7 times the amount used for this purpose in 1970.

Jan 1, 1971

By Donald T. Mylar

It is axiomatic that in designing a bulk material handling system the primary consideration is the functioning of the machines. The structure is secondary -its reasons for being are to support, enclose and provide access to the machine, for servicing. This results in a wide variety of supporting structures. Other considerations are: plant layout, local soil conditions, climate, local laws and codes, and last, but by no means least, the Customer's wishes.

Jan 1, 1971

By Robert B. Fulton

It is a pleasure to talk to you about the world economics of industrial minerals on this occasion of AIME's 100th anniversary. In order to fit this topic into the time and tenor of such a session as this where you are hearing subjects equally broad in scope one after the other, I will deal with the subject through the medium of eight minerals selected to illustrate import- ant economic factors. I must admit to some bias in the selection, since I picked personally familiar ones to elucidate facts of life in the industrial minerals business. It is a very interesting field, different in many respects from metals and certainly far different from petroleum. The minerals chosen are celestite, diamond, fluorspar, salt, sulfur, ilmenite, rutile and zircon. Celestite The market for celestite is mainly in the U. S. where it is consumed in the manufacture of strontium compounds for red-colored flares and other pyrotechnics, for the production of electrolytic zinc, for glass manufacture, and for the manufacture of ceramic ferrites. Smaller markets exist in Europe and Japan. Production comes from England, Mexico and Spain, and a new mining operation is being started in Nova Scotia. There is no significant production in the U. S. nor in the other principal consuming countries, except England; so it is mainly an international commodity. Celestite illustrates many of the factors important in the economics of industrial minerals. To have a marketable product, grade and freedom from deleterious elements are important for materials used by the chemical industry. In the celestite used to make strontium nitrate, calcium is the most objectionable of the commonly associated cations. Selling price is adversely affected because nitrate manufacturing costs are greatly increased if calcium is pre sent, hence less can be paid for the raw material. Meeting specifications can add significantly to the vendor's cost; hence a balance must be struck between the producer's capability and the consumer's requirements, permitting a reasonable profit for both. Sizing of industrial mineral products is often important to the consum-

Jan 1, 1971

By F. E. Armstrong

Tritiated water has been used as a tracer to follow the path of leach liquids as they flow through a copper-mine dump. Semipermeable layers, produced within the dump by compaction and "stratification" of deposized dump material, restrict the vertical movement of water. Knowledge of this restriction would aid in the optimization of the leaching process. The portion of the dump of particular interest was approximately 2,000 feet long, 800 feet wide, and 200 feet high. A total of 94 curies of tritiated water was injected into the dump at the rate of 650 gpm over a period of 39 hours. The leach liquid was sampled at natural surface outflows and through a series of wells, some drilled to the bottom of the dump and others to intermediate levels. More than 3,300 samples were analyzed, most by liquid scintillation counting, but a few hundred by gas counting. Data obtained permitted calculation of flow paths, recycle times, total fluid volume, and estimates of retention times in various portions of the dump.

Jan 1, 1971

By Charles B. Kenahan

A summary of Bureau of Mines research on utilization and disposal of solid wastes is presented, accompanied by an extensive bibliography of related publications. The Bureau's Solid Waste and Materials Recycling Program is directed toward four main areas of research, development, and demonstration: (1) extraction of mineral, metal, and energy values from urban refuse; (2) upgrading and recycling of automotive and related ferrous and nonferrous scrap; (3) utilization and stabilization of mine, mill, and smelter wastes; and (4) recovery and reuse of values from industrial waste products. A contract and grant program that supplements the in-house research and aids in the training of manpower in management of mineral-, metal-, and energy -based solid wastes is also discussed. This publication is an updating of Bureau of Mines Information Circular 8460 issued March 1970.

Jan 1, 1971

By T. E. Schmieman, J. E. Miller, M. L. Rizzone

Both centrifugal and reciprocating-type pumps have been widely used in the transport of slurries. Although with some limitations, centrifugal pumps may be used, especially for short-haul systems, however, for the long pipelines the reciprocating pumps are better suited. A state-of-the-art review is presented in which a discussion of applications is made and some of the problems associated with meeting the proper design conditions for satisfactory service are discussed. Several developments underway give considerable promise of better pumps in the future, although the current level of development provides for an economical means to move slurries. The movement of liquids in pipelines necessarily occasions the use of pumps. The petroleum industry is familiar with the transport of solids through mud pumps and cementing and fracturing pumps where the movement of slurries is an everyday matter. In the drilling of an oil well, the circulating fluid utilized to remove drill cuttings is called drilling mud. This substance is usually a fairly sophisticated material designed to develop certain characteristics desirable in the drilling process. The cuttings are suspended in a moving column of this fluid and brought to the surface. The separation of the cuttings from the drilling fluids is accomplished by the use of shaker screens and settling pits; however, it is impractical to remove the cuttings completely and as a result they are pumped through the mud pumps back into the circulating stream. Over the years, mud pumps have been improved so that rather long life can be obtained from liquid end parts subject to the attritional effects of the abrasive-laden fluid. It is from this background that reciprocating-type slurry pumps have been developed. Centrifugal Pumps Centrifugal pumps have also been used to transport solids, where low heads are required, typically up to 200 ft or so, and for short hauls. The centrifugal pump is a hydrokinetic device wherein the increase in velocity of a fluid stream is converted to head, and to achieve high heads a large change in velocity is necessary. Abrasive laden fluids cause wear on impellers and casings as a result of erosion by the fluid and the suspended particles. Centrifugal pumps, therefore, can only be used where the internal velocity of flow is rela- tively low. The advantage of centrifugal pumps is their high capacity at relatively low capital cost and usually relatively small space requirement. One of the disadvantages of the centrifugal pump when used in slurry pipelining can be seen in its typical pressure-volume performance relationship, which tends to work against the application (see Fig. I). If an increase in pressure (head) is occasioned by flow restrictions in the pipeline, say by the dropping out of solids, a desirable characteristic of a slurry pump would be that it develop increased pressure to overcome the restriction. The centrifugal pump provides the increased pressure only at the expense of considerably reduced volume which then results in a lower flow velocity. With the reduced flow rate, adequate velocity to hold the material in suspension and keep it flowing in the line might not be achieved. If centrifugal pumps are considerd for the movement of solids in a long line, a series of pumps must be staged in order to provide the necessary motivating force. A large number of pumps in the line would be required, since each of the pumps could provide only a small pressure increment. An equal number of standby pumps

Jan 1, 1971