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By J. C. Griffiths

There are two kinds of problems concerning the elements of a population : the first is to estimate the proportion of some specific kind of element in the population, e.g. the amount of gold in a block of ground (equals population) or the proportion of mercury in a sample; the second is to estimate the length, breadth, volume, etc., of a specific kind of element, e.g. the grain size of quartz grains in a beach sand or the size, shape and arrangement of lenses of ore in an ore deposit. Given a specific objective, a bounded population, identified elements and the element characteristics of interest, it is then necessary to select a sample of the elements from the population and the problem of sampling requires a decision on how to select the sample. It is also necessary to establish, either by heuristic analysis or empirically, based on long experience, the model frequency distribution of the desired element characteristics: in general, constant-probability models are used as models, the binomial or Poisson for count data and the normal distribution for measurements (or their transformed equivalents). The objective of sampling then becomes to obtain an appropriate statistical estimate of the desired population parameter: for example, the estimators may be the mean (X) and variance (a2): these should be unbiased sufficient estimators of their corresponding parameters (u, a2, respectively). Statistical tests are performed in order to determine that the estimators are of the appropriate kind: all statistical tests are designed to test against bias of a specific kind, although they are stated as tests against randomness. Given a random sample of some population, the estimators are usually stable and adequate to solve the sampling problem. Random samples are simple to define but exceedingly difficult to achieve in practice: in selecting a sample, if every element in the population has an equal chance of occurring, then the sample is a random sample. Interaction between the arrangement of elements in a population, i.e. its structure, and the sample selection process frequently introduces bias—that is, some elements have more chance than others of appearing in the sample and, hence, the sample is not random. An algorithm for dealing pragmatically with this aspect of the sampling problem offers one way of achieving random samples and, therefore, adequate estimators. Examples of the use of this algorithm on various kinds of geological populations, in both field and laboratory, illustrate the requirements for solving sampling problems and the achievement of appropriate estimators.

Dec 1, 1971

By G. Mellgren, O. Mellgren

The conductivity of a solution is often used industrially to control the salt concentrations of reacting systems, normally using electrodes made of glass fitted with platinised platinum electrodes. When a standard platinum conductivity electrode was used to control the acid fed to the leaching circuit for an ilmenite flotation concentrate at Titania, Norway, a deposit of calcium sulphate (containing some calcium phosphate) covered both the platinum electrode and the external glass fitting, rendering the electrode inefficient in the course of a few minutes. A new electrode consisting of a casing, two measuring tubes and an electrode stem is described and illustrated. A significant advantage of its design is that the useful range of conductivity measurement can be adjusted by adjusting the concentration of the electrolyte in the electrode. It has been in use at Titania for about four years with an electrolyte consisting of 0-1 n HCI. It is robust and demands little maintenance.

Dec 1, 1971

By J. H. E. Jeffes, K. T. Jacob

The activity coefficients of oxygen in liquid Pb-Sn alloys have been measured between 550 and 1100°C by use of solid oxide galvanic cells: Pt, Ni-NiO | Zr02 Solid electrolyte | O (Pb + Sn), Cermet, Pt; and Pt, Fe-FeO | Zr02 Solid electrolyte | 0(Pb + Sn), Cermet, Pt. Alcock and Richardson's quasi-chemical equation, with the coordination number of atoms set to 2, is found to predict successfully the activity coefficients of oxygen in these alloys. The relative partial molar enthalpy and entropy of oxygen at 1 atom per cent in the alloys have been calculated from the variation of the activity coefficient with temperature. The addition of Sn to an unsaturated solution of O in Pb is shown to decrease significantly both the partial molar enthalpy and entropy of O. As the measurements were restricted to a narrow range between 750 and 1100°C in Pb-rich alloys, however, the pronounced variation of the partial molar enthalpy of O with temperature at constant alloy composition predicted by the quasi-chemical model could not be verified.

Dec 1, 1971

By R. J. Howarth, P. L. Llowenstein

The errors resulting from field sampling, sample preparation and analysis are investigated for drainage sediments derived from homogeneous sandstone, shale, limestone, basic igneous and granite lithologies as a background to a primary reconnaissance survey of England and Wales. Emission spectrographic analyses of approximately 350 samples for Al, Ca, Fe, K, Si, Ba, Co, Cr, Cu, Ga, Li, Mn, Ni, Pb, Sc, Sn, Sr and V and atomic absorption analyses for Cu, Ni, Mn, Co, Zn and Pb have been treated statistically. For routine broad-scale surveys analysis of the unground -80-mesh sediment fraction proves satisfactory. Sampling error between localities in a stream is shown to be less than spectrographic analytical error for many of the elements considered here, except where mineralisation (contamination) occurs, but exceeds the atomic absorption analytical errors in most cases. Unless it it critical to reduce the amount of between-site variability (having regard to analytical errors) in the regional survey, there appears to be no advantage in the use of a more sophisticated sampling technique. The utility of moving-average maps in reducing the width of the confidence belt around the regional 'geochemical surface', and thus compensating to some extent for the sampling errors, is also demonstrated.

Dec 1, 1971

By J. Laskowski, J. Lekki

"The mechanism of joint action of a frother (alpha-terpineol) and a collector (ethyl xanthate) in the flotation of chalcocite has been examined. In order to study the dynamic effects of frother and collector in bubble-particle collisions, the following aspects were investigated : determination of zeta-potential. Measurements of the thickness of fluid film on the surface of chalcocite and adsorption of xanthate, as influenced by alpha-terpineol, induction time and flotation versus concentration of alpha-terpineol and ethyl xanthate.The mechanism of the adsorption-desorption phenomenon on chalcocite with regard to non-ionic molecules, e.g. a-terpineol, has been considered, and the influence of this on the stage and thickness of the intervening wet layer between a bubble and a particle, changing the probability of collision and attachment, is suggested."

Dec 1, 1971

By C. P. Summerhayes, J. W. G. Gilbey, S. Henley, G. P. Glasby, J. J. T. Harvey, J. Larsson, O. Akiman, A. G. Brown

Abstracts are presented from six University of London, one University of Nottingham and one University of Durham PhD theses

Dec 1, 1971

By R. W. Schultz

Mineral exploration carried out in Ireland since the mid-1950s has resulted in the discovery of ore deposits that are now in production atTynagh (Pb-Zn-Cu-Ag), Silvermines (Zn-Pb) and nearby Ballynoe (barite), and Gortdrum (Cu-Ag-Hg); a major Zn-Pb deposit at Navan that is now being drilled prior to development; potentially productive deposits at Keel (Zn-Cd-Pb), Ballinalack (Zn-Pb) and Aherlow (Cu-Ag); and a number of interesting prospects, including one of spodumene. Underground exploration of a formerly extensively mined copper deposit at Allihies has outlined new, albeit currently uneconomic, reserves at depth. The copper and pyrite deposits at Avoca have in recent years been re-explored and are now again being worked. Most Irish ore deposits are in the lower half of the Lower Carboniferous succession of limestones and subordinate shales and sandstones, and this stratigraphic zone is being most intensively explored at present. Other geological units under active exploration are Ordovician sediments-volcanics belts, Caledonian granites, and parts of the Old Red Sandstone and Dalradian series. Surface prospecting is made difficult in many places by glacial and other superficial deposits, including peat and alluvium. Geochemical prospecting methods have been outstandingly successful and primarily responsible for most new discoveries. Boulder hunting and outcrop prospecting have proved effective in detailed investigations of geochemically anomalous areas. Some parts of the country have been covered by three separate airborne geophysical surveys, albeit without success so far. The induced polarisation technique, the most widely used ground geophysical method, has contributed to several discoveries. The scope of application of electromagnetic surveys is more restricted than that of induced polarisation, but the method has been effective in a few cases and has contributed to the Tynagh discovery. To date, the resistivity and self-potential methods have found little application. Magnetic surveys are not applicable directly in the search for ore deposits of the various known types, but can be helpful in outlining geological structures in some areas. The gravity method has been used successfully in a survey over the Zn—Pb deposit at Navan ; it has also proved effective in trials over a blind sulphide deposit at Tynagh that cannot be detected with geoelectrical methods. An appendix lists summary descriptions of 15 Irish deposits and occurrences

Dec 1, 1971

By J. K. Brimacombe, F. D. Richardson

Studies have been made of interfacial turbulence occurring in reactions in which indium, zinc and cadmium, dissolved in amalgams, are oxidised into aqueous phases by ferric or mercurous ions. It has been found that this turbulence occurs when the concentrations of oxidising ions in the aqueous phase become sufficiently great. These concentrations are the same as those at which the mass-transfer coefficients in the aqueous phase increase sharply when both phases are stirred by gas bubbles rising through them. The effects of gas flow rate on the mass-transfer coefficients for zinc in mercury have been established, and the oxidation of pure mercury has been investigated. The relevance of the work to processes involving liquid metals is discussed

Dec 1, 1971

By S. V. Shiraishi, H. B. Bell

Report of discussion at February, 1971, IMM general meeting (Chairman: M. J. Cahalan, President) of a paper published in Transactions/Section C (Mineral Processing & Extractive Metallurgy), vol. 79, June, 1970, pp. C120-C127, with a contribution by Wright P.A. on the miscibility gap

Dec 1, 1971

By J. H. E. Jeffes, C. Diaz

The heat balance and chemical equilibria involved in the production of blister copper from a chalcopyrite concentrate in a single operation are examined. It appears that two stages—one oxidising and one reducing—will be required. The analysis indicates that on thermal grounds the process is possible with a dry, high-grade chalcopyrite concentrate, if oxygen enrichment to about 30 per cent is used, but that copper losses in the slag will be serious and will require a secondary recovery operation. More extensive data on the activities of copper oxide in slags are required to elucidate this point more effectively

Dec 1, 1971

By M. J. O'Hara

El presente texto describe el programa "Apolo" dentro de la geología lunar. Dicho programa revisa los comienzos del sistema solar y estudia los desconocidos procesos de "erosión" y "evolución" de las rocas que han tenido lugar en la Luna. Asi también se describe el origen de la luna, procesos de superficie, las montañas lunares, formación de mares lunares, concentraciones de masa y el interior de la luna.

Nov 1, 1971

By S. H. Boshlov

Los problemas del diseño estructural de minas se basan en numerosas complejidades como el de una incapacidad para definir explícitamente los parámetros, físicos in situ del medio rocoso y sus materiales asociados, el comportamiento del sistema bajo alguna descripción bosquejada de la aplicación de la carga; otras proceden de la incapacidad para especificar con precisión el estado inicial de la tensión en el medio. En ese sentido, el presente texto señala un modelo de diseño estructural manipulable donde se refleje el comportamiento del prototipo que representa. Así, el análisis por elementos finitos, en el cual la estructura se considera como una reunión de numerosos elementos, cuyas propiedades individuales pueden señalarse a voluntad, indica la posibilidad de un problema de diseño de una estructura minera como un ejercicio de análisis de sistemas. Tal sistema rocoso podría incluir todos los factores naturales y los medios ambientes artificales que afectan la resistencia de las estructuras mineras de superficie interior.

Nov 1, 1971

By Jorgen Damgaard

El proceso de deshidratación de los minerales comprende espesamiento, filtración y secado y una operación típica. En ese sentido, el presente texto señala el secado por atomización donde se busca eliminar el agua de las pulpas espesas para producir concentrados de forma directa y así mostrar el impacto que este tiene en el manejo, permitiendo operaciones de sistemas de transportes integrados en recipientes a granel que van desde la mina a la fundición, a través de sistemas de transportes neumáticos totalmente cerrados.

Nov 1, 1971

By K. H. Hofer

La mecánica de rocas se basa en el descubrimiento de las leyes que siguen las perturbaciones del estado natural de la corteza terrestre provocadas por la actividad minera. En ese sentido, el presente texto señala la importancia de este proceso en la ciencia de la minería -en tanto revisa el comportamiento de la resistencia de la roca, determina el estado de las tensiones primarias de la corteza terrestre y analiza la repartición secundaria de tensiones provocadas por la formación de huecos y sus consecuencias sobre la roca en el espacio y tiempo.

Nov 1, 1971

This report describes the investigational work on the development of a fire-assay method capable of concentrating, in a button of nickel sulphide, all six of the platinum-group metals present in samples of ores, concentrates, and mattes. In the method adopted, the sample is fused with a mixture of sodium carbonate, sodium tetraborate, nickel carbonate, and sulphur. The nickel sulphide formed during fusion collects the noble metals and carries them to the bottom of the crucible. The nickel sulphide button is dissolved, and the noble metals are isolated and determined. The coefficients of variation range between 1,0 and 4,9 per cent for the various platinum-group metals when they are present in concentrations between 0,3 and 75 p.p.m.

Oct 15, 1971

By Vicente Gonzáles Otoya

El presente texto describe el descubrimiento, cubicación y evaluación del fosfato de Bu -Craa en la provincia de Sahara. Para ello, se realizó campañas donde se hizo el reconocimiento exhaustivo del límite de afloramiento del Paleoceno en toda la provincia, que va desde Hasi Melehes hasta Villa Cisneros, así como se determinó que las capas fosfatadas importantes estaban localizadas en este tramo geológico. Así también se revela la geografía, sondeos, testificaciones, pozos y calicatas y la organización del trabajo de evaluación de dicho sector.

Sep 1, 1971

By Mario A. Espinoza

"El presente texto señala la función del médico en la prevención de las enfermedades ocupacionales. La Salud Ocupacional, no solo concierne a la prevención de las enfermedades ocupacionales, debidas a la inhalaciónde ciertas sustancias químicas como el plomo, benzol, polvos de sílice u otras, sino que estudia los efectos fisiológicos del trabajo y ambiente físico y psicosocial del trabajador. En ese sentido, es importante la participación de profesionales en los programas de salud ocupacional como la del médico quien se encarga de aceptar a los postuiantes que física y mentalmente están capacitados para realizar trabajos sin ninguna limitación, clasificar a los postulantes que no demuestren aptitud para el trabajo que solicitan, asignándoles otras colocaciones y los proteje de los riesgos inherentes al trabajo a través de una distribución adecuada de sus funciones. "

Sep 1, 1971

By R. Duval

El presente texto señala el muestreo de lotes de mineral a granel a través de la selección de individuos que componen la población a muestrear, la selección de masas iguales, la selección de individuos con volúmenes iguales y la selección de individuos que se proyectan verticalmente sobre un plano horizontal, así como el muestreo de yacimientos (muestreo de métodos clásicos, el muestreo de individuos con volumen constante y de acumulación).

Jul 1, 1971

By L. M. Kaas

El presente artículo señala el uso de la computadora desde 1950 y sus avances a lo largo de la historia industrial y de producción. En este sentido, anteriormente ninguna fase de los procesos de minería y de molienda ha quedado sin investigar para encontrar nuevas aplicaciones de este aparato. Hoy, los problemas de geología, minería, preparación de minerales y gestion -muchos hasta hace tiempo imposibles de tratarse han resuelto satisfactoriamente con el empleo del computador.

Jul 1, 1971

By R. Duval

El presente texto se basa en la estadística clásica del muestreo que indica los lotes de materiales minerales al granel y de yacimientos mineros a los ingenieros. Este sistema describe las fallas que afectan los resultados de los muestreos cuando se emplea métodos, sin las debidas precauciones. Así también se muestran los tres principios esenciales que son la base del muestreo simple al azar, donde se funda toda la teoría estadistíca del muestreo

Jul 1, 1971