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By E. G. Davis

The Bureau of Mines investigated gaseous direct reduction of low-grade iron ore concentrates in a continuous fluid-bed reactor. These studies were made in a 4-inch diameter fluid-bed reactor using hydrogen alone, and oxygen-or air-reformed natural gas as the reductants. The percent reduction is directly dependent on the mole ratio of hydrogen in the reducing gas to the oxygen associated with the iron oxide in the ore. Two-and three-stage fluid bed tests were simulated by repeated continuous tests. The results showed that percent reduction of the final product was dependent on the mole ratio of the quantity of hydrogen in the gas of each stage to oxygen in the iron oxide of the initial ore feed. Reduction as high as 87 percent in the single stages and as high as 94 percent in the multistages was obtained when either hydrogen or reformed natural gas was used as the reducing gas. Magnetic separation and concentration of the highly reduced fluid-bed product yielded a high metallic iron concentrate analyzing 85 percent total iron and 80 percent metallic iron with total iron recovery as great as 90 percent. Agglomeration of the high-grade metallized concentrate produced hard pellets analyzing 85 percent total iron and 78 percent metallic iron. Green pellets, with good strength, were made without any binder in a drum pelletizer. Direct melting of the high-metallic fluid-bed product in a basic lined arc furnace produced a nearly pure iron which contained 0.09 C and 0.01 P with 95 percent recovery of the metallic iron in the metal.

Jan 1, 1972

By J. D. Vincent

The Henderson mine site is located at Red Mountain on the eastern slope of the Rocky Mountains, approximately 50 miles west of Denver, Colorado. The mill site is on the west slope of the Rockies and mine and mill will be connected by an underground railroad. All designs were for a 30,000 ton per day molybdenite processing plant with provisions for future expansion up to 50,000 ton per day if required. This plan did not just happen, but slowly evolved over the course of about three and one-half years. Many plants cannot afford such a delay, but the Henderson project will take about 10 years from the time it was first discovered until production starts, and these 3 !1 years were well spent in determining the best possible plant site and flowsheet. This paper describes some of the problems and the decisions made in arriving at the final location and flowsheet. The paper does not go into the specific details of how protection of the environment went hand-in-hand with all other project considerations. This particular aspect of the planning has been well-reported on other occasions and considerable information on it is readily available.

Jan 1, 1972

By B. F. Buie

In South Carolina and Georgia an area about 20 miles wide situated near the inner margin of the Coastal Plain and extending from the vicinity of Columbia, S.C. southwestward about 180 miles to the vicinity of Macon, Georgia is the principal kaolin-producing area of the world. It is especially important as the world's major source of clay used for paper coating. Essentially all of the land known or likely to be productive of quality kaolin in this area is now owned or controlled by producing companies. The least-fully developed portion is that in the vicinity of Wrens, Georgia which has been explored and developed since 1961. For the two decades following the end of world war II, demand for kaolin increased at approximately twice the rate for other industrial minerals. From 1945 to 1965 production increased four-fold. Since 1965 the rate of increase has been less, but the outlook now is that production and demand will double at least once again before the year 2000. A substantial part of this increased demand has come, and will continue to come, from industrial development, especially in the paper industry, outside the United States. The general effect, in addition to a continuing increase in production in the U.S., will be to cause: 1. Intensive research for development of more effective and more economical methods of beneficiation; 2. Concerted research effort to find an economical way of modifying high-viscosity kaolin so that it can be used for paper coating; 3. More active exploration in the U.S. and overseas, especially for deposits to supply the foreign markets; 4. More intensive study of the geological factors responsible for the accumulation of commercial deposits of kaolin; 5. Some modest rise in price, relative to the cost of other industrial minerals. The effect on kaolin producing region of Georgia and South Carolina will be to cause: 1. Working of progressively lower-grade deposits; 2. An increase in the acceptable thickness of overburden; 3. Mining of deposits farther down-dip, the use of which is now inhibited by large volumes of groundwater; 4. Increased threat of invasion of the kaolin in industry's market by substitute materials; 5. A substantial increase in concern over environmental factors; 6. More attention to be paid to the large opportunity offered for mining of silica sand and other co-products.

Jan 1, 1972

By R. H. Smith

The total energy demand in the United States increased about 4 per cent annually during the 1960's 1 and is expected to increase at the same rate during this decade. Z Fuel oil growth in the 1960's was only Z per cent per year until 1968, but it increased to 8 per cent in 1969 and 11 per cent in 1970. Fuel oil demand is expected to grow at a 6 per cent rate through the 1970's. Part of this rapid increase in demand has been caused by restrictions placed on the sulfur content of fuels. High sulfur coal can no longer be burned in many parts of the country and has been replaced by low sulfur fuel oil. An insufficient supply of natural gas has also contributed to fuel oil demand. Air pollution regulations have not only caused an increase in fuel oil consumption, but they have also caused a reduction of sulfur content in residual fuel oils. Current regulations call for 1 per cent maximum sulfur content fuels over much of the country. Sulfur contents of fuels are limited to 0. 3 per cent in certain areas on the east and west coasts. Sulfur in residual fuel oils from high sulfur imported crude oil is reduced to 1 per cent currently. However, sulfur reduction to 0. 3 per cent is difficult and expensive.4 As a result, refiners may be hard pressed to supply the market for low sulfur fuel oil. The oil shale deposits in Colorado and Wyoming potentially are a huge source of low sulfur fuel oil. It will be shown that the low sulfur content and more importantly the sulfur

Jan 1, 1972

By T. W. White

One of the objectives of today's mine superintendent is to increase his equipment availability. To this end we have seen improved scheduling procedures, preventive maintenance programs and extensive drive training and operating procedures. However, until recently, one area that has changed little in the past twenty years is the method of refueling and servicing mine equipment. In looking at mines across the country continually one encounters the hazardous oil soaked ground, the hand held fuel nozzle and the maze of hoses of the "traditional" fuel stop. By adapting technology developed in the construction and aircraft industry, current fueling and servicing practices can be easily improved. The result will be less nonproductive time, less downtime from engine failures and increased security from major refueling fires. The time saved almost amounts to having another truck in the fleet! One feature of the improved servicing practice is the implementation of high flow fueling. For trucks now on the market, a flow rate between 120 and 150 gam is feasible, about 90 gam greater than current practice. This flow rate could be increased even further as larger trucks come into use. A second idea borrowed from the aircraft industry is the use of positive lock type connection nozzles that automatically shut off when flow stops. These may be used for fuel, water, oil and hydraulic systems to eliminate spillage and assure that clean fuel, oils, and water are delivered to the vehicles. The reduction of fuel spillage lessens the threat of major fires resulting: in equipment damage and loss. Eliminating fire hazards will become even more important as the turbine engine with its lighter, more volatile fuels come into common use.

Jan 1, 1972

By William G., Pariseau

There are important phenomena in rock and soil mechanics that cannot be explained in terms of theories of homogeneous, isotropic materials. Subsidence of strata about mine openings is an example. In-situ stress measurements in nonisotropic sedimentary, and metamorphic rocks is another. Patterns of joints, faults, fractures, and similar geologic features impart directional mechanical properties to rock masses that are locally isotropic or anisotropic. On the geologic scale, the non-homogeneity of composite rock masses may, in certain instances, be dealt with as homogeneous anisotropy. The mechanics of large rock masses can, therefore, be expected to involve considerations of anisotropy. The source of the anisotropy is not relevant. Once the scale of observation is selected and the material is defined accordingly, the analysis of stress and deformation proceeds without regard to the numerical values of the material constants. There are also important phenomena in rock and soil mechanics that cannot be explained in terms of linear elasticity, theory. For the mechanical description of anisotropic geologic materials capable of de- forming beyond the limit of purely elastic strains, a plasticity theory is required.

Jan 1, 1972

We did install one 100% brick bottom in our #33 furnace which is basically the same design as Inland's furnace. We had previously embarked on a program of replacing all bottoms in our 300 ton furnaces every 2nd campaign which would be about every 2000 - 2300 heats. This had been necessitated by the effect of our rather high oxygen blowing rates and our desire to maintain a minimum bottom interval level. This meant that we were able to compare bottom performance of various types of materials on a realistic bas is. Since furnace availability is critical to our operation, we are organized to employ every piece of equipment and all the necessary man power to complete a rebuild in the shortest possible time. A 300 ton furnace requires 7.5 days to rebuild. If a new bottom is to be installed an additional 2.5 days is added - 24 hours for tear out and 36 hours for bricklaying - making a total of 10 days.

Jan 1, 1972

By S. F. Willey

The difficulties encountered in justifying replacements for over-age mobile mine equipment at the Gay Mine are common to most mining operations. More critical management reviews, resulting from ever rising capital expenses, increased such difficulties. These increased difficulties are especially apparent to those who are primarily operators and are not statisticians, mathematicians, or computer oriented. The Gay Mine is located 17 miles east of the town of Fort Hall in southern Idaho. This open pit operation annually supplies the J. R. Simplot Company and the FMC Corporation with 1.5 MM - 2.0 MM tons of phosphate ore. Stripping ratios average approximately three bank cubic yards of waste per ton of ore mined. The mobile mine equipment fleet consists of ten 24 yard scrapers; twenty-one 30-50 ton end dump trucks; four 32 42 yard shovels; fifteen dozers in the D-8 and D-9 classes; and three road patrols. Equipment replacement is based on the results of evaluations made on individual units. Authorization of capital expenditures for equipment replacement is dependent upon a favorable profitability index (true rate of return on investment) plus a favorable payout time. The system is based on cash flows and requires the determination of (1) the net cash outflows in the form of capital expenses plus (2) the expected cash inflows resulting from reduced expenses and depreciation tax credits. After adjustments for taxes and the time value of money, the net amounts are used to calculate the required indices. The basic elements for the system related to the replacement of mobile mine equipment include: (1) the determination of dollar penalties to be expected from the continued use of aging equipment; (2) the selection of equipment that will provide the greatest return on the investment dollars; (3) the quantification of the expected savings; and (4) the calculations of the prescribed indices. Inadequacies inherent in previous evaluating methods led to the search for more

Jan 1, 1972

By Samuel A. Goldberg

The Federal Coal Mine Health and Safety Act of 1969 delegated to the Bureau of Mines a yearly program of health inspections. Respirable coal mine dust concentrations are measured by Bureau inspectors. Samples of respirable coal mine dust are weighed to determine dust concentration and then analyzed for ash and quartz content. This paper describes the laboratory procedure for determining the percent quartz in the respirable coal mine dust samples.

Jan 1, 1972

Horizontal holes are drilled underground into coalbeds to control methane flow from ribs and active face areas and to make gas pressure measurements in coalbeds. Gas pressure measurements are made by drilling the same hole incrementally. After each increment, the hole is filled with some type of packers and allowed to reach equilibrium before a gas pressure reading is taken. As the length of hole increases, more packers are required to effect a seal and obtain a reliable pressure measurement. Problems have been encountered in obtaining satisfactory packer seals due to the friable nature of the coalbed. New methods of packing the holes must be used. Therefore, this project was established to evaluate materials and develop a new technique in which a semiliquid and/ or rigid type grout could be placed in the hole to provide satisfactory sealing.

Jan 1, 1972

By Fred N. Kissell

Methane flows and pressures were measured in mines in the Pittsburgh, Hartshorne, and Pocahontas No. 3 coalbeds. From the data, the permeability of each of these coal beds was computed. It was found to depend strongly on the type of coal and on the amount of water in the coalbed, and it was found to increase with time. All of the coalbeds had a high-permeability zone adjacent to the face or rib, and the Pittsburgh bed exhibited directional anisotropy. Surprisingly, little or no overburden effect was observed.

Jan 1, 1972

By W. E. Lamont

Flotation studies of phosphate-bearing waste pond materials, low-grade washer products, and raw ores, all from the Tennessee brown phosphate district, showed that these types of materials could be treated without des liming to recover high-grade phosphate concentrates. The investigation showed that fine grinding before flotation was a requisite for increased recovery of the phosphate values and that the optimum pH conditions were in the range of 10.0 to 10.5 when using anionic collectors. Multiple-cleaning of the rougher phosphate concentrate was required to produce high-grade concentrates. Phosphate recoveries ranged from 60 to 82 percent and were inversely related to the grade of concentrate produced.

Jan 1, 1972

The Tasman Orogenic Zone is regarded as a single metallogenic province (the Tasman Province) with four SUb-provinces corresponding with its major tectonic components: the Lachlan, New England, Hodgkinson.and North Queensland orogenic provinces. Within the Tasman Province there are four main ore-rock associations.These are1. manganese and iron with sedimentary and basic volcanic rocks,2. zinc-lead-copper and copper with intermediate-acid volcanic sequences,3. minor chromium, platinum, and osmiridium with ultramafic complexes, and4. tin, wolfram, gold, and copper with syn- and posttectonic granitic intrusions.Whereas the ores of ultramafic and volcanic associations form geographically-restricted metallogenic districts, the ubiquitous granitic ores may be subdivided into twenty-one districts that cover almost the entireOrogenic Zone. The Tasman Province is notably lacking in uranium ores and Mississippi Valley-type deposits.There is a distinct tendency for ores of each association to be progressively younger to the east and north, thus paralleling the progressive growth and stabilization of the Zone. Similar ore-rock associations are present in repeated phases of mineralization from the Cambrian to the Permian-Triassic, reflecting the essential homogeneity of the Tasman Province, and the similarity of the successive tectonic cycles.

Jan 1, 1972

Synthetic dawsonite [NaAl(OH)2C03] has been prepared with crystallinity similar to that of dawsonite found in oil shale deposits of the Piceance Creek area of Colorado. Optimum experimental conditions were as follows: Na/Al atomic ratio, 43; temperature, 175° to 200° C; pCO2, 15 psig; and reaction time 5 hr. Chemical and spectrographic analysis revealed that the synthetic dawsonite was of high purity and Has essentially stoichwmetric. Similarity of the synthetic to natural dawsonite, demonstrated by X-ray diffraction, infrared spectrophotometry, and electron microscopy, suggests its suitability as a standard.

Jan 1, 1972

[A Editor's Note: Annual Reviews of various subjects and areas are found in February issues of Mining and Metallurgy and Mining Engineering. These Annual Reviews are not listed per se in the Index. Abating Stream Pollution in Anthracite Coal Fields. ME Mar 50 Abbadia San Salvatore mine, Italy. T178, 297 Abbott, C.E.: Limestone Mine in the Birmingham District. With Discussion. T129, 62 ABC Typifies Trend to Mechanized Mining and Coal Preparation. ME Dec 50 Abel, J.F.: Statistical Analysis of Tunnel Supporting Loads. T235, 288 Sulzbach, J. F., and Walker, D.K.: Ice Tunneling in Greenland. ME Jun 59 Aberfoyle tin mines, sphalerite, chalcopyrite, stannite, as intergrowths. T214, 1147 Abnormal Behavior of Some Ore Constituents and Their Effect on Blast Furnace Operation, The. T241, 1 Abrams, C.J.: Industry's Responsibility in Postwar Economy. M&M Mar 45 and Haley, D.F.: History of Crushing and Milling at Climax. M&M Jun 46]

Jan 1, 1972

By Garland R. Dever

Extensive deposits of high-calcium limestone occur in the Upper Mississippian Warsaw and Ste. Genevieve Limestones in the region of the lower Cumberland, Tennessee, and Ohio Rivers in western Kentucky. Analyses of foot-by-foot samples from 20 quarries and cores in 8 counties show variations between the chemical composition of high-calcium deposits in the 2 formations. Knowledge of probable variations in composition should aid in prospecting for high-calcium stone for a specific use and in evaluating potential deposits. High-calcium strata in the Warsaw consist of bryozoan- and crinoid-rich bioclastic limestones, and in the Ste. Genevieve, predominantly oolitic limestones. Values used for comparison were obtained by averaging the foot-by-foot analyses of each high-calcium deposit, 10 in the Warsaw and 15 in the Ste. Genevieve. Average MgCO3 and Fe2O3 contents are generally lower in the Warsaw than in the Ste. Genevieve. Average SO2, S, and P contents are- generally higher in the Warsaw. No characteristic differences are apparent between the average CaCO3 and A1203 contents of the two formations. The higher S and P contents of the Warsaw are believed attributable to the predominance of biogenic material in these limestones. Within the Warsaw Limestone, higher average S and A1203 contents and lower average Fe2O3 contents were found in deposits in the northern half of the region. In the Ste. Genevieve, vertical variations in composition occur within individual high-calcium deposits containing oolitic and nonoolitic limestones. Lower average CaCO3 contents and higher average contents for the other constituents were found in the nonoolitic intervals.

Jan 1, 1972

By R. A. Wyman

The overall approach to nonmetallic mineral flotation practiced in the laboratories of the Mines Branch, Ottawa, Canada, is outlined. The use of floatability tests to indicate possible areas of selectivity is indicated. Selected examples of the evolution of flotation systems are presented. Reagents are briefly discussed.

Jan 1, 1972

A method is proposed for the determination of antimony in ores. Antimony is volatilized as antimony iodide by heating with ammonium iodide at a controlled temperature.The fusion mixture is extracted with hydrochloric acid and the antimony content is measured by atomic absorption spectrophotometry using an air/ acetylene flame. The time taken for analysis when comparedwith existing fusion and separation procedures is considerably reduced. Cations and anions likely to be present in antimony ores were also studied for possible interference effects but were not found to interfere.

Jan 1, 1972

By Robert L. Bates

The natural separation of one element or compound from others in the earth's crust is a rare geological phenomenon; accumulation of large quantities of a separated substance forms mineral deposits of value. Although igneous and metamorphic processes are effective at times, by far the most significant fractionation is sedimentary. High-silica sandstone, high-purity limestone and dolomite, salt, and anhydrite-gypsum occur in very large deposits and are termed first-order fractionates. The marine diatomite of California, the trona of Wyoming, and the kaolin of Georgia and South Carolina are in deposits of comparable purity but smaller size, and are designated second-order fractionates. The paper considers the various processes and environments in which such industrially valuable deposits were formed.

Jan 1, 1972

By R. C. Diehl

Coal, fly ash, and flue gas samples were analyzed for mercury (Hg) by double gold amalgamation-flameless atomic absorption spectrophotometry. The purpose of the study was to elucidate the fate of the trace mercury in the coal when the coal is burned. Samples were collected from a bench-scale 100-g/hr combustor, a 500-lb/hr combustor, and three coal-burning powerplants. In all cases mercury was found in the fly ash. The amounts ranged from about 9 to about 70 percent of the mercury in the coal that was burned.

Jan 1, 1972