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Samples of a refractory copper ore were examined to test their response to segregation roasting, flotation, and acetonitrile leaching. Recoveries in the segregation roasting stage were between 60 and 100 per cent, while flotation recoveries varied between 60 and 85 per cent in cleaner concentrates assaying 25-40 per cent copper.The fraction of the copper which could be leached from the concentrate by an acetonitrile/sulphuric acid/cupric ion leach solution varied from 16 to 97 per cent, the lower recoveries being correlated with the presence of sulphide in the concentrate.

Jan 1, 1973

By John K. Berry

The handling and disposal of mine water is a much larger problem than is apparent at first glance. Many more tons of water are removed from underground coal mines in the United States each year than tons of coal. In the old anthracite region of Pennsylvania the average was around 36 tons of water for each ton of coal produced, while bituminous mines average about 5 or 6 tons. Water encountered in the mines may come from several different sources. In mines with light cover and without a firm solid roof, rain may seep directly into the workings. This is also true of deeper mines where pillar falls have broken the roof to the surface. The top under creek beds is generally faulty and broken and water comes through the roof at this point. Deeper mines are frequently overlain by water-bearing strata and pillar breaks and faulty top can admit water, while places running to the dip often accumulate water which comes up through the bottom. In all cases, except where passing under a year-round stream, the amount of water made is usually pretty closely connected with the weather-more water during the rainy season, less in the dry, although the deeper a mine is, the longer it is before changes in rainfall are felt. Another source of water, not connected with seasonal changes, is old water, accumulated over a period of time in abandoned workings of the mine, or from flooded adjacent mines. Here the water filters through the coal, the parting, or comes up through cracks in the bottom. Similarly, core holes, drilled to prospect the property, can be a source of unexpected water and modern safety requirements for dust-allaying water at the working faces can turn a pleasant working area into a soggy mess over the weekend if the system is not properly maintained and operated. Why water must be disposed is obvious. If allowed to accumulate, sooner or later the mine will fill up, or at least it will become "roofed" in low places, blocking ventilation and traffic. But it must also be controlled long before it reaches this stage. Water standing in the working faces is unpleasant for the men who have to work there and also cuts down on the amount of work they can do, as they must watch where they step all the time. It is especially unpleasant in low coal.

Jan 1, 1973

By David A. Monaghan, Kenneth R. Maser, Adi R. Gurdar, D. Randolph Berry

APPENDIX A - PNEUMATIC TRANSPORT OF FLY ASH 1. Introduction Two types of pneumatic transport of fly ash are critical to the success of (1) Transport of fly ash from the fly ash truck to the entrance to the borehole. Depending on the surface topography, this may be horizontal, decential and ascential. (2) Vertical downflow of fly ash through the borehole. All fly ash trucks have limited pressure with which they can pump the fly ash. Thus, the pressure drop in the fly ash hose will define the maximum length for pumping and consequently the maximum distance that the fly ash truck can be parked from the auxiliary blower. The same relationships describe the flow of the dilute fly ash-air mixture produced by mixing with the auxiliary air from the blower and thus define the selection of the pipe diameter. These are im¬portant considerations in the proper selection of the location of the passages to be sealed and the type of surface preparation required. The flow characteristics of fly ash down the borehole determine the selection of the minimum borehole diameter and the blower pressure. This appendix presents theoretical analyses of these flow regimes and summarizes the limited experimental data obtained during the field tests at Grant Town, described in Section 8.4. The analysis for the borehole flow is presented first as it is of greater interest to the program. This is followed by a discussion of the horizontal flow.

Jan 1, 1973

By John Drew Ridge

Recent work by Haas has made available information on densities and vapor pressures of solutions of differing salinities at temperatures up to 330°C. From these data it is possible to predict the behavior of volcanic exhalations of various degrees of salinity as they approach the sea floor. Particular attention is devoted to solutions of 5.0 weight per cent NaCl and 20 weight per cent NaCl, two fluids that approximate quite closely the salinities of what Roedder termed: (1) normal hydrothermal fluids and (2) fluids typical of stratiform deposits of low-temperature conditions of origin. It is apparent that solutions above 220-230°C. cannot reach a sea floor on which the depth of water is 600 feet or less in the liquid state but will boil at some appreciable depth beneath the sea floor. Such boiling would result in the precipitation of all constituents of the ore fluids of significantly lower vapor pressure than water. The principal such constituent would be salt, and no sulfide deposits, the major constituent of which is salt are known. It follows, therefore, that ore fluids probably never get close to the sea floor of shallow seas at temperatures high enough to permit boiling. Ore fluids significantly above 230°C. can reach the sea floor in the fluid state only if the depth of the sea in the area. in question is well above 600 feet, for example, solutions at temperatures of ±300°C. reach the sea floor in the liquid state only if the depth of sea water is slightly over 3000 feet. Ore fluids reaching the sea floor at such depths may be the parents of such fluids as the Red and Salton Sea brines. On the basis of these data, the Cyprus and Kuroko deposits are discussed.

Jan 1, 1973

By Everett M. White

Numerous articles have been written in regard to the man who mines coal and he has been likened to brave men in all ages who have gone out to conquer some unknown hazard. Now, however, modern mining is no longer something to be avoided but is a vocation that anyone can well be proud of, with remuneration equal to or above that of almost any industry. A concerted effort is being made each day by both the operator of most mines as well as the state and Federal inspectors to see that coal mines are as safe or safer than any other industry. However, it is true that mine fires and explosions have occurred in the mining industry since its earliest inception. One of the earliest accurate references to such an occurrence is found in the transactions of the Royal Society of London. In the Colliery Managers' Handbook, 1898, Caleb Pamely writes of an explosion that occurred at Fatfield, England, which resulted in the death of 69 persons in August 1708. It is interesting to note that he states, "Three of them, viz, two men and a woman, were blown quite up from the bottom of the shaft, fifty-seven fathoms deep, into the air, to a considerable distance from the mouth of the pit." From this statement it is noted that women were employed as miners in England during that period. Numerous mine fires and explosions have occurred in mines in this and other countries. Several of them claimed more than 100 lives. Among the greatest losses was a mine explosion in West Virginia that claimed 361 and a mine fire in Illinois that claimed 259. Although no one would minimize the seriousness of a mine fire or an explosion, yet in too many cases they have been publicized out of proportion. This especially is so when compared with the accident rate of other industries or on our highways. It should be remembered that of these general classifications of hazards in mining, mine fires and explosions rank very low in the accident rate in any given year. In modern times the coal industry has completed two years or more, at various times, without a single major disaster. The

Jan 1, 1973

By Oleg Terichow

Electrophoretic mobility measurements were made on samples of Florida phosphate slimes to determine the optimum conditions of coagulation and precipitation in aluminum sulfate solutions. The addition of silica sand and other selected materials as mutual coagulants has demonstrated the practicability of coagulating two dissimilar particle systems by elimination of the repulsive double layers. By proper selection of the solution and its concentration, the reduction of the double layer to a zero point of charge causes coagulation and rapid precipitation of both particle systems. Confirmation was found in filtration tests and sedimentation tests.

Jan 1, 1973

By James W. Collins

The bucketwheel stacker/reclaimer is suited for a variety of bulk material handling systems, especially those operating with stockpiles in excess of 30,000 tons. The bucketwheel stacker/reclaimer, although relatively new in the United States (first introduced here in 1964), has been successfully used in European countries since the early 1940's. Basically the machine is the outgrowth of the bucketwheel earth excavator and the traveling tripper boom type stacker. Since their introduction here they have achieved wide acceptance, especially with coal fired power plants. (Figures 1, 2, and 3.) The stacker reclaimer has been utilized in barge and ship loading/unloading facilities, and in the material handling systems for steel mills, where it has been used to stack and reclaim iron ore at rates up to 6000 tph stacking and 4000 tph reclaiming. They have also been employed at mine mouth power plants for the handling and storing of the plant fuel supply and to help balance the mining rate with the fuel consumption rate.

Jan 1, 1973

By G. M. Ritcey

The recovery of copper from low-grade solutions res ulting from dump leaching is well known, whereas the recovery from highly concentrated copper solutions has not been practiced. This paper discusses the use of Ashland Chemical's Kelex 100, a substituted quinoline, for the recovery of copper from solutions resulting from leaching copper-nickel concentrates. A flow sheet is described, and an economic comparison shows Kelex 100 to be superior to either the LIX 64N or LIX 70 reagents of General Mills for the recovery of copper.

Jan 1, 1973

By H. W. Smith, N. Ichiyen

A convenient method for the calculation of metallurgical balances, based on statistical treatment of all available data, is presented. An error analysis is included. Examples show the advantages of the method, and also that such balances are less precise than might be supposed.

Jan 1, 1973

By Fredrick C. Kruger

We can confidently predict such obvious long-term trends affecting the minerals industry as - increasing consumption, exhaustion of easily discovered near-surface ores, and sharp limitations upon open pit mining by environmental considerations. There- fore, we must intensify the exploration for, and the development and exploitation of, deep bodies of potash and other ores. This paper examines the state of the art of the search for, and the evaluation of, potash from both a geological bias and a mining practicability. The use of indirect geological methods and geophysical techniques, followed by expensive deep drilling, are the conventional approach to evaluation and development of mining plans. The geologist and the geophysicist will have to find ways to perform both of these tasks better and cheaper.

Jan 1, 1973

By Edwin H. Bentzen

Talc, as a mineral, is rather widespread, but as an ore sultable for mining, it is rather limited. Materials sold as "talc" range from the impeccable white material from Italy to a gray-green-bluish material from Virginia. Some uses of the material called "talc" seem to be determined by the color of the material, some by the chemistry of the material, and some by the particle size of the ground material. But, there seems to be some overlapping of criteria used to judge the acceptability of a raw material. So then, any producer of talc material that is not a consumer of this raw material is faced with the age-old problems: "what do I call the stuff, and to whom should I try to sell it?" The answer to the first part is easy: if you want a high price, call it "talc"; if you want a low price, call it "soapstone". This may seem like a very simplified answer, but it is apparent that some of the products sold as "talc" have more than a minor amount of impurities in them; whereas, if they were called "soapstone", these same products would probably get a lower price.

Jan 1, 1973

By S. Fugleberg

As a result of research work done during the planning of the Kokkola zinc plant it was found that a very efficient cementation of impurities from the suspension obtained after leaching copper and cadmium cakes was achieved by adding zinc dust to the batch without filtration after the leaching. All elements nobler than cadmium are precipitated with the exception of lead, which must be removed in a separate step. Using pure zinc dust, free from noble metals, the cadmium sponge produced will only contain elements that can be re- moved from cadmium by meltrefining. The process is thus : 1. Leaching and purification 2. Removal of lead (with BaCO3) 3. Precipitation of cadmium sponge with pure zinc dust 4. Meltrefining of briquetted sponge with NaOH for removal of Zn (and others) The paper deals with the removal of the most critical elements, i.e. Co, Ni, As, Sb, Cu, Pb, T1 in the liquid phase and Zn and T1 in the melt. A survey is also given of the behaviour of most of the other elements normally found in Cd raw material, such as Ge, Te, Se, Sn, In, Ga. It is shown that in most cases the benefit of an electrolysis in Cd production is very limited. In Kokkola 99.998% Cd is achieved by this method, but in favourable cases it may be possible to come quite close to five nines.

Jan 1, 1973

By L. G. Wilson

In our comparison of California and Turkish colemanites, we should first place the discussion in context. In order to exclude technical considerations, which are not germane to this paper, we must make the manifest and basic observation that if colemanite were not acceptable for the production of glass products it would not be used, and we would not be interested in this comparison at all. Suffice it to say that the colemanites, being calcium borates, provide a necessary flux in glass manu¬facture, together with the requisite degree of physical strength and chemical durability which can be achieved only by the use in glass of a. flux substanti¬ally free from alkali; so the sodium borates are automatically excluded from the production of textile fibers. Thus we have today under consideration only California colemanite, Turkish cole mite, and, because it provides a degree of competition to both, ABA, or anhy¬drous boric acid, which, although it is a refined intermediate and of much higher cost, it is also of a much higher degree of purity, and its characteristics can easily be modified to produce a desired end product, so we must include it in any consideration of high quality borates. [Calcim Borate Pentahydrate] Colemanite is a [calcium pentahydrate,] with the formula Ca2B6011.5H20. It has a theoretical B203 content of 50.8%.

Jan 1, 1973

By E. S. Allen, P. R. Kruesi, J. L. Lake

An electrochemical process is described for converting concentrates of base-metal sulphides to the corresponding pure metals and elemental sulphur. The application of the process to chalcopyrite is discussed. The process is also of potential interest in processing copper-nickel sulphides, and laboratory data concerning this potential are presented. The process creates neither air nor water pollution.

Jan 1, 1973

By Nord L. Gale

The discovery of important new ore deposits of lead, zinc, copper and silver in 1955 in Southeastern Missouri has resulted in the development of a thriving mineral industry known as the "New Lead Belt" or "Viburnum Trend", to distinguish it from the older lead producing areas to the East. This region has recently become the world's largest lead producing district with production in 1970 reaching 432,576 tons or 74.4% of the entire United States lead mine production. The area is heavily forested with rolling hills dotted with numerous clear running streams in the Clark National Forest of the Missouri Ozarks. The location is within 70 miles of St. Louis, Missouri and has a natural abundance of water resources which provide an important recreational area for fishing, hunting, camping and other outdoor activities. Until this recent development, the area was sparsely populated and industrialization was almost unknown. The infusion of $150 million in mining capital has brought about a dramatic change in the economic structure of the area and will almost surely be accompanied by changes in its environmental picture. In an effort to maintain this bountiful national resource and to evaluate the changes occurring in surface water quality and aquatic life forms present, an inter- disciplinary research program at the University of Missouri has been undertaken with the support of the National Science Foundation. Research has been carried out to determine background values, establish natural baselines, and to evaluate the extent and causes of changes in streams effected by mine water discharges and wastewater from ore milling operations. The unique topography of the "New Lead Belt" area allows the channelization of milling and smelter wastes to separate stream systems (Figure No. 1) thus allowing measurements of the pollutional effects on an individual basis.

Jan 1, 1973

By Hemendra N. Kalia

To plan a safe and efficient coal mining operation, the design engineer should use all the available information regarding the property to be exploited. The reliability of the mining operation must be as high as possible so that the plants relying on the coal can operate at the maximum design capacity. A good design should incorporate all of the known geological characteristics of the deposit, the structural and physical properties of the coal, as well as the rock which will form the roof and floor of the mine openings. A systematic method is proposed as a guide to insure a mine design that will be safe, efficient and will minimize surface disturbances resulting from mining operations. It is anticipated that the method proposed will result in maximum extraction at perhaps minimum cost to the operator. In general, to develop a mining area, several factors are systematically reviewed: (1) determination of the economic minability of the deposit, (2) the computation of the coal reserves, (3) the marketability of the coal, and (4) the life of the property. In general, boreholes are drilled in a predetermined pattern and geophysical or geological methods are used to log the boreholes. The information so obtained is primarily used to determine the quality and the extent of the deposit and to determine to some extent such geological features as faults, barren areas, washouts, and channels.

Jan 1, 1973

By John H. Bassarear

The never ending search for lower unit costs led Pima Mining Company's management to study various alternatives shortly after Expansion III was completed. It soon became apparent that a considerable amount of ore assaying 0.35% copper had to be moved in order to maintain mill feed at the desired 0.54% copper content, which is the overall grade of the ore reserves. Detailed investigations revealed that for a period of 8 - 10 years, about 14,000 tons per day of 0.30 - 0.40% copper ore would pass by the crusher en-route to the low grade stockpile. This ore is very hard, very clean and has to be mined at a relatively uniform rate. A six month pilot plant run testing autogenous and semi-autogenous grinding gave very encouraging results. Since no mining costs need to be charged to the extra tonnage (it had to be mined anyway) the only major costs would be against milling. The decision to proceed was made in August 1970 and Fluor-Utah was retained as the prime design construction contractor. Ore was first put through the new mill on December 29, 1971. By March of 1972 design tonnage of 14,000 TPD had been attained. The first three expansions at Pima Mining Company, 20 miles south of Tucson, increased mill capacity from 3,000 TPD to 36,000 TPD. These expansions included a separate, conventional, three stage crushing plant plus additions to the existing concentrator that primarily duplicated the then current flowsheet. Expansion IV, however, consisted of an entirely new and separate primary crusher and a completely new mill building located about 2,000 feet southeast of the 01 d concentrator. The new mill, using semi-autogenous grinding, produces scavenger and rougher flotation concentrates that are pumped to the old mill for regrinding, cleaning, thickening and filtration.

Jan 1, 1973

By Donald W. Breck

Zeolites were first recognized as a new group of minerals by Cronstedt with the discovery of stilbite in 1756. The word zeolite was coined from the two Greek words meaning "to boil" and "a stone" because of the loss of water when heated in the mineralogist's blow pipe. (1) In 1845 it was discovered that certain soils have the power of retaining ammonium Salts. (2) These were the first ion exchange experiments. Later it was discovered that it was the hydrated silicates in the soil that produced this phenomenon and several years later a paper was published dealing with the action of dilute salt solutions on silicates which showed that this base exchange principal, which we now call cation exchange, is reversible. The quantitative cation exchange behavior of zeolite minerals, such as chabazite, was studied. As a result any aluminosilicate which exhibited the property of ion exchange was referred to as a "zeolite;" even today the term has been applied to clay minerals as well as synthetic organic ion exchange resins.

Jan 1, 1973

By M. Palfreyman

"Most of the minerals employed in Canadian refractory production are imported; in fact, most of the refractories consumed in Canada are imported. Whereas this situation is partly due to a definite shortage of suitable raw materials, e.g., fire clays, it is possible that the potential of certain mineral deposits which could be usefully exploited has not been recognized. There are exceptions, notably magnesite and dolomite, from which refractories are produced in Canada.In many cases, known mineral deposits are located either in inaccessible areas or in areas where transportation would be a major economic factor. This paper lists some minerals and their respective known deposits which could be employed in the production of refractories, irrespective of economics."

Jan 1, 1973

By Allan H. Caverson

Over the past nine years a means for measuring the distance between the mine roof and floor has been developed at the White Pine Mine which yields relevant information utilized in the mining operation. The technique known as "convergence!' is an efficient, low cost way for obtaining large quantities of data for predicting roof falls, caving activity, and overall mine stability. From a limited introduction in 1964 related to monitoring an experimental longwall project, the activity of convergence measurements has been expanded to become a production tool now found in all sections of the mine. Presently, the program involves four main types of activity: 1. Monthly measurements in areas known to be active, and in sample blocks scattered throughout the mine for a long-term stability study. 2. Semi-monthly measurements along vital travel roads, belt drifts and compressor sites. 3. Weekly measurements in areas where men are working. 4. Daily measurements in pillar-recovery and caving operations. Today, one field engineer and six technicians are involved full time in convergence work. Rock Mechanics technicians have installed approximately five thousand stations since the start of the program and of this number, over twenty-five hundred active stations still comprise the mine-wide network spread over the more than five square mile extent of the White Pine Mine workings.

Jan 1, 1973