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A programme began in 1970 to eliminate the charging of fine materials into the copper blast furnace of The Electrolytic Refining and Smelting Company of Australia Ltd. at Port Kembla, N.S.W. A disc pelletiser and drying plant has been installed as part of this programme. Feed material for the plant is a blended mixture of copper concentrates, fine copper-bearing residues, and blast furnace cyclone dust. The operating parameters for the disc have been calculated by comparing the perform- ance of three other discs on the plant. Re- search work on choice of binder, feed moisture and drying conditions has led to the production of reasonably high strength pellets. A description of the pellet plant and modifications necessary to overcome the initial performance problems is given.

Jan 1, 1974

By Chester M. F. Peters

INTRODUCTION There has been considerable discussion in recent years of the strained relations between owners, engineers and contractors caused by the rapid increase in costly litigation in underground excavation due to construction claims. These time consuming claims are not to the best interests of the industry. It has been a conclusion of some of the concerned parties that there could be a substantial reduction in these claims if a mutual respect for each other's roles could be maintained along with a practical contractual arrangement for sharing the risks of the unforeseen costs inherent in the business. This paper will touch on the overall problem of these relationships, but confine the major discussion to the role of geology in claims and, in particular, changed conditions claims, since they form the base for the bulk of those involving geology. Geologists can make a major contribution to the reduction of these claims if their particular abilities are recognized and used properly. CLAIMS AND GEOLOGICAL RISKS The tunnel contractor is strictly bound by the contract he signs, and the risks he assumes thereby must be priced. The most important variable factor on which he must base his price is the geologic data provided and his interpretation of it. If this data does not give a clear picture of the conditions, making it impossible to price

Jan 1, 1974

By Harold H. Fukubayashi

The effect of various zinc electrowinning solution impurities on the surface morphology of deposited zinc was investigated. Impurities studied included Al, Ag, Cd, Co, Cr, Cu, Ge, Mn, Ni, Sb, Sn, Ti, Pb02, PbSO4, and HC1. Also, the effect of animal glue, gum arabic, and Na2SiO3 additives on the deposited zinc surface structure was studied. Results were compared with deposits from a pure electrolyte consisting of H2SO4 and Zn+2, 200 and 65 gpl, respectively. Zinc was deposited on a Al cathode, 99.9 pct pure, using Pt anodes. Time, temperature, current density, and impurity concentrations were con¬troller The bulk of the tests were conducted at 40° C and 75 A/ft2 (82 mA/cm2). A scanning electron microscope (SEM) was used to examine the surface morphology. X ray diffraction techniques were used to determine crystal orientation and nondispersive X-ray spectrometer analyses were employed in an attempt to locate impurity concentrations on the zinc deposit when pitting or re-solution occurred. The impurities were categorized by their effect on current efficiency, morphology, and apparent mechanism of H2 evolution from the cathode.

Jan 1, 1974

By Lloyd A. Morley, Robert Stefanko

In addition to explosion-proof enclosures, the IEC has published recommendations: 1. 79-2 Pressurized Enclosures, 2. 79-3 Intrinsic Safety, 3. 79-5 Sand-Filled Apparatus, 4. 79-6 Oil-Immersed Apparatus, and 5. 79-7 Increased Safety. All these are valid methods of electrical hazard reduction and find wide use in industries other than mining. Magison (52) discusses in detail each technique and, therefore, such an examination will not be repeated. Two other systems, lamina and labyrinth, are but variations of common explosion-proof enclosures and, therefore, will not be cov¬ered. (34,35,46,53,54,61) By examining other national authorities' opinion, the following will investigate each system's applicability to coal mining. Intrinsic safety applies to any system which is incapable of re¬leasing sufficient energy to be an electrical hazard. (49) Not one foreign country contacted disagreed with the concept, and they find these systems totally acceptable. Only South Africa does not accept oil-immersed apparatus, but no reasons were given. (62) Healy (27) stated that Queenlands, Austrailia would accept all techniques, yet some were still to be employed. Japan specifications allow for all but sand filled. (42,43) Increased safety or Protection Type "e" is an approach in hazard reduction in which special design considerations are applied to ensure an extremely low probability of electrical or mechanical breakdown

Jan 1, 1974

By Seymour C. A

Peak Downs Mine, a five million tonnes a year coking coal operation, strip mines a, series of Permian coal seams. Seam thickness ranges from 0.5m to 5.0m, and seams consist of multiple coal plies with intermediate shale and mudstone partings. Four 47m3 draglines strip overburden to a cover depth of up to 60m. Coal loading is by 12m3 shovels and 14m3 to 18m3 front-end loaders. Parting removal takes place where the layer of shale and mudstone between seams exceeds 0.3m in thickness. Parting has been removed by a wide variety of earthmoving equipment in order to evaluate the problem and to select the optimum method from an operational and economic standpoint. Multi-seam stripping of the thicker seams is accomplished by working draglines from spoil- pile benches. Coal seams thinner than lm are recovered by dragline and stacked in the pit for later loading.

Jan 1, 1974

By C. H. Elder

A 5-hole pattern was drilled from the surface at a site near Oak Grove, Jefferson County, Ala., to degasify the gassy Mary Lee coal bed in advance of mining. Gas and water production was monitored for 1 year, 4 months to allow gas flow to stabilize fully. A thickened water stimulation treatment was designed and applied in one hole of the pattern to evaluate this degasification technique for the Mary Lee coalbed. A gas production rate of 70,000 fts/day after stimulation treatment indicates that the use of vertical boreholes coupled with hydraulic fracturing in advance of mining the Mary Lee coalbed would provide for more rapid degasification and could provide a possible source of natural gas.

Jan 1, 1974

By W. L. Brien, O&apos

Molybdenum alloys with good strength properties at elevated temperatures were produced by the powder metallurgical internal oxidation method previously applied to tungsten and known as oxyreaction strengthening. Commercial molybdenum powders were blended with 0 to 10 pet of a reactive powder, ZrMo2. The effects of composition, blending procedure, and sintering conditions on strength properties at elevated temperatures were studied. Strengthening was attributed to zirconium in solid solution with molybdenum and to the presence of submicrometer particles of Zr02. Several alloys had tensile strength and stress-rupture properties com-parable with those of the best commercial alloys. The maximum tensile strengths obtained were 92 kpsi at 1,200° C and 53 kpsi at 1,316° C. The maximum stress-rupture life at 30 kpsi and 1,200° C was 145 hours.

Jan 1, 1974

By N. A. Frazier

The technology for using limestone or lime to scrub SO2 from power-plant flue gas has significant implications to the limestone industry. A brief status report on these processes will be made, possible process requirements on the limestone properties will be reviewed, and projections on the buildup of demand with respect to time will be reviewed. Disposal problems inherent with the use of these throwaway processes will also be summarized. Given a viable technology, relations among (1) distance of power plants from low- and high-sulfur coal and limestone deposits, (2) modes of handling and transporting immense tonnages of bulk material-coal and/or limestone, and (3) regional air-quality standards are some of the factors which will ultimately determine the demand for limestone. A discussion of these factors will be presented, with the intent of identifying geographic regions where significant increases in production can reasonably be expected.

Jan 1, 1974

By Michael P. Amsden

"THE ECSTALL CONCENTRATOR is situated adjacent to Highway 101 and the Ontario Northland Railroad, 15 miles east of Timmins, Ontario. Ore is delivered to the concentrator by rail from the mine, which is 17 miles northwest of the plant. Power and fuel are obtained from the hydro and natural gas lines which pass close to the plant site. Water is obtained from the Frederickhouse River, 6 miles east of the concentrator. The main concentrator building is a large structure 500 by 640 feet by 90 feet high and contains facilities for fine crushing, crushed ore storage, grinding, flotation, tin recovery, concentrate handling and reagent handling. Located in the same building are the machine shop, warehouse, metallurgical laboratory, pilot plant, men's change room, sample preparation area and an assay laboratory. The general concentrator layout is shown in Figure 47. Originally designed to handle 9,000 tons per day, the concentrator now treats 10,000 tons per day. Two different ore types are processed by selective flotation in three individual circuits to recover copper, lead and zinc concentrates. In 1973, another circuit was added to recover pyrite and tin concentrates from the combined zinc tailings of the three main circuits."

Jan 1, 1974

By Dennis V. D’Andrea, Robert C. Steckley, William C. Larson, Richard A. Dick

A fragmentation experiment was performed in cooperation with Duval Corporation in a porphyry copper molybdenum deposit near the Sierrita pit south of Tucson, Ariz. A 10-hole test blast was detonated to establish relationships between blasthole spacing and the resulting fragmentation. Blastholes were 9 in. in diameter and 110 ft deep. The 10 blastholes contained a total of 17,400 lb of aluminized slurry blasting agent in 50-ft columns with 60 ft of stemming. Blasthole spacings of 25, 20, and 15 ft were tested. Diamond drill core examination was the primary method used to determine the condition of the rock before and after blasting. Topographic surveys were used to measure the rock swell produced by the blast and a fragment size distribution was obtained for the rubblized material on the surface. The rubble zone at the surface was ideal for in situ leaching. Fragmentation to depths of 110 ft was excellent from the 15- to 20-ft blasthole spacing patterns. Good breakage was also produced by the 25-ft pattern although the effects of the blast were not as obvious. In situ leaching tests were not conducted. However, based on size consideration only, all three blasting patterns produced adequate breakage for successful leaching.

Jan 1, 1974

Results of laboratory studies on the flotation of marmatite (zinc sulphide) with new reagents, which were developed to avoid the use of copper sulphate, are presented.Episulphides were chosen as the basis for the reagents because of their reported special chemical affinity for zinc and cadmium. Attempts were made to solubilize and introduce functional groups to episulphides with organic and inorganic acids, ammonia, phenol, aniline, diethylamine, and pyridine. As a class of reagents, the episulphide-amine combination was generally found effective in zinc sulphide flotation to a greater or lesser degree. Best results were obtained with ethylene sulphide-aniline combination. Although anilino-ethyl mercaptan is the reported reaction product of aniline and ethylene sulphide, it was concluded that the effective zinc sulphide flotation with ethylene sulphide-aniline combination is not entirely due to the formation of the mercaptan.The economics of the possible usage of ethylene sulphide-aniline reagent are discussed.

Jan 1, 1974

By John R. Hawley

"This paper is intended as a review of the progress that has been made in the Province of Ontario in the field of acid drainage waste treatment technology.Three years ago, at the Third Annual Meeting of the Canadian Mineral Processors, we presented a paper entitled ""The Problem of Acid Mine Drainage in Ontario"". At that time I was working for the Ontario Water Resources Commission. The paper turned out to be the very beginning of the Commission's acid mine drainage control program. In the intervening three years, the Ontario Water Resources Commission has been amalgamated with other government groups and has evolved into the present Ontario Ministry of the Environment. Today the Ministry is involved in running one of the most advanced acid mine waste control programs in the world.As a part of its mining program, the Ontario Ministry of the Environment has published three major reports which deal directly and specifically with the industrial waste disposal problems that may arise at a mining operation. In order of publication, these reports are as follows:(1) ""The Problem of Acid Mine Drainage in the Province of Ontario"".This 338-page report covers all aspects of the problem of acid mine drainage and includes detailed sections on acid flow detection, acid flow chemistry and acid flow treatment.(2) ""The Use, Characteristics and Toxicity of Mine-Mill Reagents in the Province of Ontario"".This report, 244 pages in length, gives the chemistry and toxicity of nearly all of the chemicals that find common use in the Canadian mining industry. Most of the toxicity figures quoted are the result of a comprehensive bioassay program that was initiated by the Ministry."

Jan 1, 1974

Detailed studies of mineral paragenesis, isotope and trace-element geochemistry, and physical mineralogy at Mount Morgan are compatible with deductions by Geopeko Ltd geologists concerning field relationships in the mine area. Considered together, field and laboratory data suggest that the Mount Morgan deposit originated from a shallow, intrusive, acid volcanic dome similar to those which produced the Kuroko-type deposits in Japan. At Mount Morgan, however, interaction with sea water was much less, the sulphides were concentrated rather than forming a group of deposits, and only the throat of a breccia vent is pre- served, so that only the lowermost parts of Kuroko-type deposits can be compared with the Mount Morgan mine. A final difference lies in the presence at Mount Morgan of a quartz diorite adjacent to the ore. Mineralogical data are compatible with post-ore intrusion, possibly up an earlier volcanic fissure.

Jan 1, 1974

The question of earth models has repeatedly arisen in our work. An accurate representation of the seismic properties is required for three reasons: 1.To be able to determine from a set of received arrival times, the location of a seismic source in the earth, and secondly the degree of accuracy required in the model used for calculating source location from the set of arrival time differences. 2. To be able to determine the expected arrival times at an array of geophones produced in response to a hypothetical source in the earth. 3. To be able to estimate received signal strengths more accurately. The work reported here on earth models is based on information from sever- al consultants and from others who expressed an interest in the problem and supplied information to us. II. COAL MINE GEOLOGY On one of our earlier assignments for the Bureau of Mines, Earth Science Research Inc. of Cambridge, Massachusetts prepared for us a short description of the lithology to be expected at coal mine sites. This description follows, together with the ranges of compressional seismic velocities (Figure I*) associated with typical materials comprising the layered structure of a coal mine area. Coal is primarily associated with fresh water sediments including sandstones, shales, and clays, and occasionally may be metamorphased to varying degrees. In the Appalachian Basin the coal beds occur within cyclical sequences of non-marine shales, sands tones, conglomerates, limes tones, and clays. The beds range in thickness from a few inches to 60 feet, averaging between 2 feet and 10 feet. They have generally broad areal extent, occasionally up to 5,000 square miles, and have an overall tabular or lens-like shape. Within a particular lens, local changes in thickness are normal.

Jan 1, 1974

By A. Gene Collins

The Bureau of Mines conducted a research study of the geochemistry of the Smackover Formation to determine what geochemical relationships are useful in exploration for and production of oil and gas. Samples of oil, gas, brine, and rock were collected and analyzed. The oilfied brines were analyzed by methods recommended by the American Petroleum Institute and by tentative methods of the American Society for Testing and Materials. The crude oils were analyzed by Bureau of Mines methods; the gas, by Bureau of Mines methods; and the rocks, by wet-chemical, atomic absorption, and neutron activation methods. The results were correlated and interpreted, and several geochemical relationships useful in exploration and production were found. These include the type and class of brine, organic constituents in the brine, redox potential, in situ temperature and pressure of brine, degree of sulfate and carbonate saturation of brine, and halide concentrations in the brine.

Jan 1, 1974

By R. F. Chaiken

The Bureau of Mines has carried out experimental and theoretical studies with prilled and pulverized ammonium nitrate-fuel oil (AN-FO) mixtures containing varying amounts of fuel oil in an attempt to quantify the effects of stoichiometric composition, nonideal detonation behavior, and expansion volume on the production of CO, NO, and N02 fumes. Experimental fume measurements were obtained in the Bureau's large closed gallery facility (7.2 X 104 liter expansion chamber) and in the standard Crawshaw-Jones apparatus (90--liter expansion shamber) using a prepackaged charge configuration containing about 450 g of explosive.4 The theoretical calculation of toxic fumes was achieved with an equilibrium detonation code called "TIGER,," Contrary to initial expectations, the NOx (= NO + N02) fumes from the large gallery test were found to be in essential agreement with the Crawshaw-Jones results. It was also concluded that (1) "TIGER" calculations offer a good approach to the prediction of toxic fumes; (2) there is a basic problem in extrapolating laboratory measurements of CO fumes to mine conditions--this being due to postdetonation oxidation of CO to CO2; and (3) the detonation velocity decay rate of an explosive is a useful experimental parameter for correlating toxic fumes production with nonideal detonation behavior.

Jan 1, 1974

By Roy L. Wilfong

Infrared reference spectra are presented of compounds of importance in lead sulfide flotation research. Included are the spectra of several short chain alkyl xanthates of lead and zinc, the corresponding dixanthogen compounds, and the common oxidation products of lead sulfide and their sodium analogs. The spectra of several frequently used industrial flotation reagent xanthates are also presented. A thorough, well-documented discussion is given of the various corrections made to correct the as recorded absorption band data to near absolute values.

Jan 1, 1974

By R. B. Schluter

The objective of this Bureau of Mines investigation was to determine the effects of adding manganese compounds and ores to iron ore pellets. Manganese dioxide, carbonate, sulfate and chloride, plus six manganiferous ores from the Minnesota Cuyuna Range were tested as additives to increase the manganese content of iron ore pellets. One to 5 percent manganese, as a compound or ore, was added to five magnetite concentrates and one hematite concentrate. These concentrates were ballad, indurated (1,300° C), and tested for reducibility. Manganese sulfate and chloride were unsatisfactory additives causing cracking and degradation of the pellets during reduction. Manganese dioxide, carbonate, and the ores were satisfactory additives. The additives increased pellet compression strengths with a corresponding loss of reducibility, as compared to the pellets without manganese additions. The changes in compression strengths and reducibility were caused by the formation of Jacobite spinel and slag within the pellets. However, when the induration temperature was lowered from 1,300° to 1,200° C the reducibility and compression strengths were comparable to the pellets without manganese additions indurated at 1,300° C.

Jan 1, 1974

By John B. Squyres

The purpose of this paper is to describe certain features of the uranium deposits of the South San Juan Basin, and to suggest a mode of origin for the deposits which is consistent with the data. A series of photographs is included at the end of the paper to illustrate the nature of the ore bodies. Since the general geology of the Grants Region is well described in the literature, it will be only briefly reviewed, and the time will be spent instead on the morphology, spatial relations, and geochemistry of the ore deposits. Part of this material is original, but data and ideas have been taken from a variety of sources, including the literature and the personnel of the USGS, the AEC, and many of the operating companies of the South San Juan Basin. I gratefully acknowledge these sources. The accuracy of the data and the conclusions presented here are my own responsibility, however.

Jan 1, 1974

By Ian M. Thomson, Robert W. Greene

To move 7 million tons annually from their new inland coal mines at Camp Breckenridge, Ky., TVA selected a transportation package proposed by American Commercial Barge Line. The land portion includes two cable-driven conveyors covering 12.7 miles; a 260,000-ton storage area on a man-made island with a stacking-reclaiming bucket wheel; and a barge-loading system of 5500-tph capacity. The 183mile river portion will utilize three unit-tows with towboats and barges specially designed to carry the maximum tonnage allowed by locks and channel depth. The system has two noteworthy features. The first is a single-flight cable belt conveyor over nine miles long. The other is a high capacity twin belt conveyor using the principal of two separate belts supported in 60° troughing idlers. This conveyor exhibits a high carrying capacity combined with accurate tracking and lack of spillage. A description is given of the mechanical problems and solutions to the design, construction, and operation of the conveyor system which provides the link between the coal mine and the barge loading dock.

Jan 1, 1974