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By Houlihan RN, Landau J

A reciprocating plate column is described in which two sets of perforated plates are mounted alternately on two shafts and are reciprocated with a phase difference of 1800 between them. It is shown that such a column is mechanically superior to the previously proposed types: under practical operating conditions the pressure fluctuations at the base of the column are only a small fraction of the static head. Furthermore, mass transfer experiments with the system tributyl phosphate in kerosene- acid aqueous solutions of uranyl nitrate show that both high specific throughputs and reason- ably good efficiencies can be attained in this type of column. A comparison with the more conventional extraction equipment (mixer -settlers, pulsed columns) on the basis of residence time per equilibrium stage indicates the potential of reciprocating plate columns in hydrometallurg- ical application, especially in which the requirements of separation efficiency are modest while the scale of operation is large.

Jan 1, 1975

Almost one half of Canada's total land surface is underlain by permafrost. This term describes the thermal condition of earth materials when their temperature remains below 0°C continuously for a number of years. The drilling and blasting of frozen materials requires more energy than the blasting of same in its unfrozen state. The cost of comminution could double in permafrost even with adequate organization, drilling equipment and proper explosives.

Jan 1, 1975

Coal washing practice can be improved not only by critical examination of the plant being operated but also by studying plants operated in other areas. The developments at the Australian Iron & Steel Pty. Ltd. plants are discussed in relation to experiences there as well as developments which have taken place in Queensland in recent years. Early A.I.S. problems involved small coal cleaning in heavy medium cyclones and flotation. A proposed future plant flowsheet for A.I.S. is considered in the light of these experiences. Reference is made to plants operated by the Thiess, Peabody, Mitsui Coal Company Pty. Ltd. at Moura and the Utah Development Company's plants at Blackwater and Goonyella in the development of coal washing prac- tice in Australia.

Jan 1, 1975

By E. M. Watkin

"Although Canada has achieved one of the highest living standards in the world, people and organizations have, over the past decade, begun to question the cost and means of this achievement. Concern has been expressed about the degree of environmental disturbance arising from industrial activities which have greatly contributed to our increased living standards. These industries include hardrock mining, pit and quarry operations, hydro-electric schemes, various agricultural enterprises and urban land developments.In the construction and operation of the above industries many environmental problems arise because the natural vegetative land cover is destroyed or drastically disturbed. Disturbance may occur to such a degree that revegetation is di ffi cult, often it appears impossible. Portions of the environment around such industries remain aesthetically unacceptable and appear to offer little or no potential for future resource use in wildlife, recreation or agriculture.The general public cannot dissociate itself from the activities of the aforementioned industries. It has, over many years, accepted the benefits and conveniences arising from those activities. Despite this, the increasing level of public concern imposes upon industry a need to alleviate or repair past, present and future environmental disturbance. Therefore it is incumbent upon industry to modify present technology or develop new techniques which would allow the disturbed environment to be easily and rapidly repaired."

Jan 1, 1975

By John F. Slonaker, Joseph W. Leonard

This note is a review of current research intended to increase the utilization of coal ash. Due to the magnitude of the fly-ash research program, some projects may be inadvertently omitted. Field research on fly-ash for use as an agricultural fertilizer is being monitored at Virginia Polytechnic Institute and State University. This research is directed at determining the plant nutrients that are available in fly ash as well as the quantities of fly ash that can be applied to agricultural soil.

Jan 1, 1975

By Lawrence W. Hallanger

Anaheim Bay, located at Seal Beach, California, is the site of the Huntington Harbor development of waterfront homes and marine facilities. The main entrance to Anaheim Bay is a relatively narrow channel connecting the bay with the Pacific Ocean which runs under California State Highway One. During the development of Huntington Harbor the old highway bridge was replaced with a new, higher bridge to allow for boat passage through the channel. At that time only the main span decking of the old bridge was removed, leaving the support pillars and the approach ramps in place (see Figure 1). The narrowness of this channel, plus the increasing boat traffic created a situation in which public demand for the removal of the old bridge became significant. Because the bridge was located within the boundaries of the Seal Beach Naval Weapons Station (see Figure 2) the Navy became involved in the bridge removal. Eventually the task was assigned to the Naval Amphibious Construction Battalion One and work began in early 1974.

Jan 1, 1975

By G. J. S. Govett

Dwindling near-surface mineral reserves emphasize the need for the development of exploration techniques capable of greater depth penetration; geochemical techniques tradition- ally have been restricted to the search for deposits having at least a sub-outcrop expression. Rock geochemical techniques developed in Cyprus in 1967-1968 recognized anomalous conditions in volcanic rocks up to one mile from an ore de- posit. Research by the Exploration Geochemistry Group at the University of New Brunswick has shown that some massive sulphide deposits in New Brunswick have well-defined halos of major, minor, and trace elements in the host rocks extending up to 1,200 metres (4,000 feet) laterally along the same stratigraphic horizon, and up to 450 metres (1,500 feet) vertically in hanging wall rocks which apparently post-date mineralization; well-defined halos have also been found in foot- wall rocks. Some of these halos are readily identified as individual elements or as element pairs; others are so subtle as to be recognizable only through computer-calculated multivariate analysis. Research continues to extend the dimension of rock geochemical halos for regional exploration and for identification of more restrictive anomalous conditions which may closely define the location and extent of buried sulphide deposits.

Jan 1, 1975

To improve a miner's chance of survival during an emergency by providing immediately avail-able breathable air and protection from toxic gases until a longer-duration breathing apparatus, stored nearby, can be reached. Approach: A belt-carried apparatus which can provide a closed-circuit atmosphere for ten minutes breathing has been developed under a Bureau of Mines contract. How It Works: Water vapor and carbon dioxide in the user's exhaled breath are removed, and oxygen is supplied, by chemical reactions. When the user exhales into the mouthpiece, water vapor in his breath reacts with potassium superoxide (KO2) stored In the canister to produce oxygen. The other product of this reaction (KOH) reacts with carbon dioxide and removes it from the air. The oxygen-enriched air then flows from the canister into two breathing bags. When user inhales through the mouth, that air is drawn out of the bags, makes a second pass through the chemical-containing canister, and flows into the mouthpiece tube. A nose clip is worn to seal off the nasal passages.

Jan 1, 1975

By D. L. Leach

This report covers laboratory experiments simulating in situ copper recovery from primary sulfide ores in sulfuric acid systems pressurized with oxygen. Copper extraction and acid consumption data are correlated with temperature in the range 50-150°C and quenched pH in the range 0.25-2. Adverse changes in the chemical composition of the leach solution and the formation of gangue-mineral alteration products and secondary sulfides can severely limit the extraction of copper above 90°C. Keeping the pH below the self-buffered value of about 2 and the temperature below about 110°C produces the maximum extraction rates. Forcing the pH too low not only results in excessively high acid consumption but may also limit the extraction of copper at temperatures above 100°C.

Jan 1, 1975

By Edward T. Koch

With the dramatic increase in world demand for basic raw materials, open pit mining is proceeding at an unprecedented rate. A viable demand is the ever tempting Siren's song for increased production or new facilities. When the Siren's lure is viewed against the panorama of today's world economic milieu the concomitant Scylla and Charybdis are seen in the form of high capital cost and high operating cost. If the economic realities of present day open pit mining are to show a proper return on investment, a clear and penetrating eye must be cast upon the area of mine planning. This paper deals with the problem of overburden removal. In almost every open pit mining operation overburden removal is a significant part of the capital cost and operating cost of the total operation. This paper deals with a new and unique method to affect economical overburden removal. Well known to all are the parameters surrounding draglines, shovels, and bucket wheel excavators. All of these machines require a reasonably stable soil to support them and the shovel and bucket wheel excavator require a reasonably stable bank in which to operate. Their reliability, portability and rate of production per dollar of invested capital are good.

Jan 1, 1975

The history of black coal as a fuel dates back in Europe more than 2,300 years, and possibly longer in China. Originally the mining of coal was done by underprivileged people, but with the industrial revolution and the dawn of mechanisation, the status of the coal miner improved. The improvement continued to the present day. Coal miners now take an important role in industrialised countries and enjoy a high standard of living. The miner is amongst the highest paid and best technologically served in any industrial activity. The abundance of coal relative to alternative fuels and its widespread occurrence, brings with it a prosperity much valued in those countries with significant resources such as Australia. Coal will play a major role in easing the world energy shortage. In addition to the conventional usage, throughout the world coal gasification plants are in various stages of development. Coal liquefaction plants are beyond the drawing board stage. Slurry pipelines to supply coal for direct burning in electric generating and other plants are planned. In the current atmosphere of environment consciousness, Australia has to contend with people with only marginal interest trying to influence coal mining activities to the detriment of the overall prosperity of Australia. Fortunately enlightened legislation is the greatest protector of the environment and in many instances great improvement to the environment ensues after mining has passed. With its vast resources of black coal Australia can look forward to a significant role in future supply of fuel. As a result of the trade and industry involved, Australia can become an even more influential country in world politics, trade, and the setting of high living standards.

Jan 1, 1975

By C. J. Milam

Oil shale may not produce the same excitement of the gold rush days, but presently there is an "oil shale fever" among mining men. Such exotic equipment as 800-ton haul units, 75 ft. boring machines, and huge fully automatic multi-purpose jumbo drill units are only a few of the topics of conversation in the oil shale groups. I am dreaming, perhaps, but this type of exotic thinking will exuberate the advancement in mining technology and will only be tempered by the practicality and the availability of today's equipment.

Jan 1, 1975

By D. H. Desy

The Bureau of Mines has conducted research on the ignition of methane-air mixtures by sparks caused by frictional impact of aluminum alloys on rusted steel at typical coal mine fan speeds. The objectives were to establish the incendivity of aluminum alloys under these conditions, to investigate differences between aluminum alloys, and to evaluate substitute materials for the aluminum-steel combination. With a specially designed apparatus, three commercial aluminum casting alloys and a number of experimental aluminum alloys were tested for incendivity of the frictional impact against rusted steel in flammable methane-air mixtures. All aluminum alloys tested produced some ignitions. Of the experimental alloys, the harder alloys and those containing silicon tended to be more incendive than the others. With the normal experimental conditions, constructional steel, stainless steel, brass, and plastic did not cause ignition of methane-air mixtures in frictional impact against rusted steel. Some ignitions occurred with constructional steel at high speed in more flammable gas mixtures enriched with oxygen. From these findings, it is suggested that constructional material combinations other than the aluminum-steel combustion would minimize this inc endive hazard. A detailed description is given of previous research, and comparison is made with present results where appropriate.

Jan 1, 1975

By W. G. Miller

A series of computer programs for the analysis and mapping of coal-related data has been developed at the Illinois State Geological Survey; these programs, known collectively as the Coal Data System, represent the latest achievements in computer processing of geologic data at the Survey. Building upon programs previously developed in the Survey's Computer Services Unit, they expand the scope of the computerized data base that the Survey has been using for analyzing coal-related data. The System was partially developed during a joint study by the Illinois State Water Survey and the Geological Survey entitled, ?Coal and Water Resources for Coal Conversion in Illinois.? 2 In that study the available coal reserves more than 42 inches thick in the two principal coal seams throughout the state were mapped. The System was used to calculate the coal reserves and to report the average number of tons of coal in place per square mile in each township (Figures 1 and 2). It also produced maps of the coal features of sufficient quality to be printed on material that was scribed as master copy for the printing of full-color 1:500,000 scale maps (see Figures 3 and 4).

Jan 1, 1975

By L. B. Gittinger

Sulfur is a nonmetallic element widely distributed in nature. It constitutes 0.06% of the earth's crust but only a very small portion occurs in sufficiently concentrated amounts to justify mining. Sulfur occurs in practically all animal and plant life. It constitutes approximately 0.09% of the elements in the oceans; it has been found in meteorites. Sulfur was known and used by man before recorded history. The American Chemical Society approved spelling for the element is sulfur. The English spelling sulphur is used commercially in the United States. In ancient times, sulfur was called brimstone, literally "burning stone." Today the term brimstone is used interchangeably with the term elemental sulfur. Sulfur is found naturally in the elemental form in subsurface deposits associated with gypsum and anhydrite in salt domes and sedimentary formations in evaporite basins and in solfatara-type deposits associated with volcanoes and mineral springs. Sulfur occurs also in molecular combination in ferrous sulfides (pyrites and pyrrhotite) and nonferrous sulfides (copper, lead, zinc, and nickel), and in mineral sulfates (gypsum and anhydrite); as hydrogen sulfide contaminant in natural gas; as organic compounds in crude oil and tar sands; and as pyrite and organic compounds in coal and oil shales. Sulfur resources are abundant and exist throughout the world but the extent to which they can be classified as reserves is greatly circumscribed by prevailing prices and technology. Estimates of world sulfur reserves are compiled by the U.S. Bureau of Mines. A compilation of reserves by area and source of sulfur published in 1970 and presented here as [Table 1] totaled 2.47 billion tons (Lewis, 1970). The effect of the decline in prices which has occurred since the earlier estimate is dramatically illustrated by the 1972 estimate of the U.S. Dept. of the Interior which shows world sulfur reserves of only 1.2 billion tons (Anon., 1972d). Sulfur is produced commercially from one or more sources in nearly 70 countries of the world. World production of sulfur in all forms totaled 41.6 million tons in 1971. (Sulfur statistics given in this chapter are long tons.) Native deposits, sulfides and oil and gas contributed, respectively, 31, 41, and 25% of world production (Table 2). Of the sulfur produced from native deposits, salt domes accounted for 54% and evaporite basin deposits, 44%. Volcanic deposits are of little significance except for local consumption. The past two decades have seen important shifts in the world's sulfur sources. In 1950, native deposits and sulfides each supplied about one-half of the world's production. During the 1950s, sulfur recovered from oil and natural gas grew rapidly, representing about 10% of the total by 1960. Since then, the petroleum industry has continued to increase its relative importance as a source of sulfur, representing more than 30% at 1972 year-end. Sulfur is generally classified as elemental or nonelemental for statistical purposes. Elemental sulfur is sulfur produced in the pure, uncombined form. It includes production from native deposits, as well as that recovered in the elemental form from oil and natural gas or other sulfur-bearing materials. When produced from other than native deposits, it is generally referred to as recovered elemental sulfur. Nonelemental sulfur is that which is utilized commercially in molecular combination with other elements, such as sulfides or sulfates. Elemental sulfur is being produced from salt dome deposits in the Gulf Coast region of the United States and the Isthmus of Tehuantepec in Mexico, and from evaporite basin deposits in west Texas, Poland, Sicily,

Jan 1, 1975

By William G. Pariseau

The purpose of this paper is to present a design procedure for the quantitative estimation of support load requirements in underground mines. Emphasis is upon the basic features of support behavior common to a large variety of support systems-bolts, timber sets, stope fill, steel arches, concrete liners and so forth. A strong reliance is placed upon fundamental principles and modern computing techniques for their quantitative implementation. Example problems illustrate the approach. Where artificial support is required, the ground in the vicinity of the face usually stands unsupported long enough for the support to be installed. At the time of installation, the load transferred to the support from the adjacent rock is essentially zero, although in some cases there may be an initial set load, for example, from timber blocking. With the passage of time and advance of the face, ground motion loads the supports. If the support system is properly designed, then the additional loading poses no threat to the safety and productivity of operations. If not, then difficulties may arise including high maintenance costs, hazardous work conditions and reduced productivity. Of course, over-design can be equally wasteful. Quantitative estimation of support loads is therefore essential to overall efficiency in mining.

Jan 1, 1975

By Richard H. Jahns

Gem materials, comprising those minerals and closely allied natural substances used for personal adornment, for the fashioning of ornamental objects, or for other decorative purposes, have been valued in human commerce for thousands of years. Amber, jet, natural glasses, and at least 15 mineral species were sought and used by primitive man, and most of the materials in common use today were known well before the time of Christ. Their variety is remarkably great, and the traceable relationships among their respective sources, modes of occurrence, properties, and histories of production, preparation, and valuation are extremely complex. Their uses have been affected by numerous shifts in fashion, and from time to time by superstition, by decrees of church and state, by personal interpretations of religious significance, and by various presumptions concerning medicinal value and influence on human behavior (Ball, 1935, 1950; Kunz, 1913; Pogue, 1915, Whitlock, 1946). Thanks to their durability, portability, and relative scarcity, some gem stones have been employed as media of exchange, and the investment value of the more precious stones has long been recognized and exploited, especially in Asiatic and European countries. Demands for gem materials have stimulated trade among various peoples for centuries, and they also were responsible for much early geographic exploration. During more recent times they have prompted numerous geological studies and a considerable amount of research on the growth and properties of crystals. Apart from decorative uses, some naturally occurring gem materials also are employed directly in numerous fields of industry. Substances that are manufactured for gem or industrial uses are termed synthetic gem materials; most of these correspond in composition and crystal structure to certain minerals found in nature. Imitation materials are those whose use is based upon their resemblance to substances of different composition and greater intrinsic value. Gem stone is a designation commonly restricted to those materials suitable for personal adornment, and the complementary term ornamental stone is applied to the remaining materials not used industrially. This distinction is arbitrary and somewhat inconsistent, owing to numerous geographic differences and historical shifts in end uses. Further, there is a complete gradation between the category of ornamental stones and that of dimension stone. Substances that lose their identity in use are excluded from the gem category; thus a transparent crystal of beryl would not be classified as a gem stone if it were processed as a source of beryllium metal. The adjectives precious and semiprecious have been employed as a means for distinguishing different gem materials on the basis of recognized value. Diamond, emerald, ruby, and sapphire consistently have been regarded as precious stones, and in cut form they commonly are referred to as the noble gems. Opal, pearl, turquoise, and chrysoberyl also have been classed as precious at various times. In recent years, however, it has been increasingly recognized that no satisfactory distinction can be based upon assessed value or any group of specific properties, and now all gem stones normally are referred to as precious. Indeed, the tendency is to extend this term to include many of the so-called ornamental stones, and the designation semi- precious has been essentially discontinued. Unlike most mineral commodities of economic value, gem materials are little altered in processing for end uses. Some stones are used in essentially their natural form, and most are reshaped and polished without significant changes in their fundamental properties. Thus the preparation of gem and ornamental stones is intended chiefly to emphasize or enhance

Jan 1, 1975

By Pierre J. Goossens

Since Guild 1 and Snelgrove 2 attracted our attention to the relationships between certain endogenic ore deposits and plate boundaries, an abundant flow of papers appeared in the metallogenic literature concerned with this problem and its application to mineral exploration. Some of the papers only speculate with the formation of specific type of ore deposit 3, 4, 5, 6, 7, 8, 9, 10, 11, 12 Other papers are more concerned with genetic and structural relationships between plate tectonics and mineralization 13, 14, 15, 16, 17, 18, 19, 20 They are philosophical, in that they are generalized and refer to no specific area. Yet it is true that a large part of the world mineral potential is concentrated at the convergence of oceanic and continental plates, for example, around the Pacific. Therefore, the interaction of two plates by either subduction, obduction or slippage likely has an important role for the genesis and/or the (structural) control of these "orogenic" ore deposits. If subduction is the driving mechanism for the generation of igneous rocks 21, 22 and endogenic ore deposits 18, volcanic activity and the nature of volcanic products certainly are the major geologic processes and events to be tested. Fonteilles 23 and Alsac 24 have already emphasized the important relationship between mineralization and the talc-alkaline affinity of the volcanics. The Andean orogen is one of the best areas for testing such genetic relationships. Rich and varied endogenic and volcanogenic ore deposits occur there and plate interaction is still active.

Jan 1, 1975

By T. Peters, W. C. Ferguson

"Shebandowan is about 600 miles west of Sudbury and 50 miles west of Thunderbay close to the trans Canada highway. Shebandowan Lake is about 38 miles long. The ore body is located between No. 1 and No. 2 shafts at the lower end of the lake. The economic mineralization lies between 200 and 2000 feet below. Years ago development of this ore body would probably have entailed draining the lake and using the open pit method to mine the ore.The water of Gold Creek which flows into Lake Shebandowan is representative of all local waters and is very close to rain water in purity. It is obvious that any industrial water discharged would have a measurable impact on the local water. The dissolved solids content is low and consistent with what is normally found in northern Ontario.A Koepe headframe is the only visible evidence of the mine from the lake. The Koepe headframe is esthetically pleasing and quiet in operation. The structure is of concrete to control noise. Noise from ore dumping is controlled by dumping underground to an ore pocket 400 feet below the surface. A 3600 foot conveyor belt carries the ore underground to the mill and is out of sight of the lake and the cottagers. The main objective to all our environmental efforts has been to preserve the natural beauty of the region. The mill is housed in a conventional metal-clad-siding building painted in esthetically pleasing colours. A single service building houses warehouse, dry storage and offices. The area surrounding the mill and service building is paved or grassed and drainage from this area is collected and pumped to the tailings area. Air intake silencers are installed on the compressors which are mounted at the back of the mill. Sound measurements taken on the lake indicate that noise suppression is excellent."

Jan 1, 1975

The major incentives for developing continuous processes for the production of formcoke are to achieve a wider range of coals which can be used, greater operating flexibility enabling the production of various coke qualities, and environmental improvements. The characteristics of a formcoke which must be considered when assessing its performance in the blast furnace are compressive strength, abrasion resistance, volatile matter, reac- tivity, porosity, density, size, shape, ash yield and sulphur content. Lurgi's development work in attempting to pro- duce a formcoke which meets the specified requirements has resulted in most current efforts being concentrated on the Bergbauforschung/Lurgi hot briquetting process. This process blends hot char produced from a non-caking coal with small quantities of caking coal in a special mixer in the plastic range of the caking coal. The material is subsequently briquetted hot, then subjected to a thermal after-treatment to produce a strong abrasion resistant formcoke. A 650 tonne per day plant for British Steel Corporation is now under construction. A study of the equipment requirements and the operating costs indicate that the economics of large scale formcoke plants compare favourably with those of conventional coke-making plants.

Jan 1, 1975