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By Kenneth R. Hancock

Iron oxides are unique in that they are the only significant colored mineral found in a natural state suitable for use as a pigment after it has been pulverized to pigmentary size. The current world production of iron oxide pig¬ments is estimated by the author to be between 450,000 and 550,000 tons based on 1969 data. The fact that highly colored natural deposits of iron ore are found throughout the world ac¬counts for its use in prehistoric man's artistic cave paintings. These early artists did not realize that they had established man's first paint test fence which now has some 20,000 years of exposure. In addition to abundance, constituting about 7 % of the earth's crust, iron oxides have the advantages of low cost, permanency, and are not toxic. Through the centuries, succeeding civilizations have utilized iron oxides as a major source for decoration and protection when coloring was desired. In the last century the chemical industry has improved on nature by developing a complete range of synthetic iron oxide pigments which surpass the pigments pro¬duced from natural iron ores in uniformity, color quality, and chemical purity. In the United States alone, the combined production of natural and synthetic iron oxides produced sales of over $28,000,000 in 1970 (Stipp, 1970). Nomenclature With the increasing importance of the syn¬thetic iron oxides it is necessary to make a distinction between the natural or mineral pig¬ments and the synthetic pigments. Natural pigments are those products which are derived from selected ores and should not be confused with iron ores mined for steel production. Iron ores that are mined for steel must be capable of being mined and reduced to iron on a com¬mercial basis. These ores are selected on the basis of iron content and processing economics. It is therefore unusual when iron ores for steel production are suitable for use as mineral pig¬ments. Natural pigment ore sources are se¬lected for their special physical-chemical prop¬erties and can command a premium price. Synthetic pigments, and in this instance iron oxides, are those pigments produced from basic chemicals. Through chemical synthesis pig¬mentary sized particles are produced as opposed to comminution, the major procedure common to all natural iron oxide pigments.

Jan 1, 1975

After a short theoretical comparison of various typical large bell tops with the bell-less top for segregation and other ,ffects on the material flowing through the equipment proper, a comparative analysis between classical and the new burdening in the furnace is given, showing the theoretical effects of distribution and segregation on the horizontal pressure variations, temperature values and gas composition in the stack. Then some typical theoretical charging patterns of the bell-less top for wall and centre temperature adjusting, pressure drop corrections, dissymmetric local action for blow-in and scaffolding are described. Finally the available practical results on furnaces equipped with the bell-less top are compared with the theoretical statements made before and conclusions indicate that the new approach to burdening blast furnaces is a real improvement.

Jan 1, 1975

By Boehme PW, Gregory OR

The results presented here show quite definitely that in the system investigated the intensity of dispersion is enhanced by switching the flow entry from bottom to sides of the packed trough. Since there is no reason to suppose that this would not be true generally then it is not surprising that the blast furnace dispersion data of Standish and Polthier lie above the data for packed columns with bottom fluid entry. In fact, on the basis of the present results, blast furnace dispersion results can never equal standard packed column behaviour but must always be above these. The result that the intensity of dispersion in the trough model is higher closer to the side ports than away from them is at variance with that of Standish and Polthier blast furnace results. Aside from the obvious structural differences between these two systems, it is thought that the presence of raceways and the tortuous path of the gas flow in the furnace may provide an answer. Clearly this is an important difference in the behaviour of the two systems and further investigations designed to clarify the position would have significant practical value. This would also give an indication of how the furnace D/ud values may be decreased along the whole height - assuming of course that this result gives the best overall performance of the furnace. However, there is to date no knowledge whatsoever about this aspect of blast furnace Technology.

Jan 1, 1975

By L. D. Gent

This report reviews the current state of the art of remote control techniques for underground continuous miners. A delineation of aspects requiring additional data is presented. Also a summary and delineation are presented in overview form for the related section functions: roof control, haulage, ventilation, power supply and rock dusting. The automated remotely controlled continuous miner project is a long-range research effort. However, the program has been divided into intermediate steps resulting in incremental production increases throughout the program. Data are developed relating the impact of our proposed research and development accomplishments to potential productivity impact.

Jan 1, 1975

By Peter G. Groer

The commonly used exact methods (1-2) to determine the WL measure the total a activity or the total number of a counts during three preselected time periods. Due to the half-lives involved (TRaB = 26.8 min, TRaC = 19.7) I these methods take 3S minutes to complete the a activity Ra measurements. Methods using the total a counts, obtained at times less than about one RaB half-life after the end of sampling run into statistical 214 problems. These methods are almost blind to RaB (Pb214) as a consequence of its relatively long half period (see above) and the fact that RaB is a ß emitter. The way out of this dilema is to measure RaB directly through its ß activity. Since RaB's daughter Rae (Bi214) is also a ß emitter, the two f3 spectra have to be separated to obtain RaB alone. How this is accomplished 1s described in subsequent sections describing the theory of the IWLM and its calibration. 2.0 THEORY The IWLM samples air for two minutes and counts this airs ample for two minutes starting 3 sec after the end of the sampling period. The instrument has three channels. The lower a channel, the upper a channel, and one ß channel. The total RaA counts observed are accumulated in the lower a channel, the total RaC? counts are stored in the upper a channel. The total ß counts from RaB and RaC are recorded in the ß channel. These three quantities are functions of NA, NB, and NC, the unknown concentrations

Jan 1, 1975

By Herbert H. Fields

The Bureau of Mines has been promoting health and safety in mining since its establishment in 1910. One area of research covers methane control in coalbeds; this report describes a multipurpose borehole used for both degasification and the production of commercial-quality gas. The multipurpose borehole was drilled into a barrier pillar, and seven horizontal degasification holes and one pressure point hole were drilled radially out from its perimeter. On January 28, 1974, after 505 days of degasification, a compressor was installed to the exhaust stack of the multipurpose borehole (1), and pipeline--quality gas was introduced into a commercial pipe-line. As of February 4, 1975, over 171 million cubic feet of gas had been purchased by the gas company. The in situ pressure at a depth of 200 feet into the coalbed and the average gas flow and water flow from the degasification holes as they were completed and closed off were 203 psig, 1,200,000 cfd, and 6.8 gpm, respectively. Twenty-four hours after the seven holes were connected through individual pipes to the atmosphere, the total gas and water flows and the in situ pressure dropped, respectively, to 971,000 cfd, 1.3 gpm, and 18 psig. Five hundred days later, the corresponding values were 620,000 cfd, 0.15 gpm, and 10.5 psig. Daily flows have been as high as 800,000 cfd, and as low as 360,000 cfd, during the last 500 days. On February 4, 1975, after 882 days of degasification, 576 million cubic feet of gas had been removed from the Pittsburgh coalbed; apparently a much larger area of virgin coal is being degasified than is defined by the holes. This study indicates that horizontal boreholes drilled into a coalbed from the bottom of any shaft will effectively remove gas from the Pittsburgh coalbed,

Jan 1, 1975

By Townsend IJ

The Upper Triassic Leigh Creek Coal Measures which include a number of seams of sub-bituminous black coal are preserved in four small intramontane basins. The largest is Telford Basin, 1,000 m in thickness. The coals, of variable thickness and quality, are mined by open cast mining methods and utilised for generation of electricity at Port Augusta. The combined proven and indicated reserves are about 100 million tonnes.

Jan 1, 1975

By Lawrence E. Mannion

In southwest Wyoming lies buried the world's largest source of natural sodium carbonate, or soda ash. Perhaps a hundred billion tons of trona (sodium sesquicarbonate) are contained in ancient lake beds in the Green River basin'). There the Green River Formation encloses more than 40 extensive beds of trona. At least 25 of these exceed 3 feet (1 meter) in thickness and most of them are more than 300 square miles in extent. Five have been exposed in mines and lie between 800 and 1500 feet below the surface. Others lie at depths of from 400 to 3500 feet. Three companies have underground mines that supply trona to adjacent soda ash plants. These are the FMC Corporation, Allied Chemical Corporation, and Stauffer Chemical Company. A fourth, Texasgulf Corporation, has a mine under development. In 1974, annual soda ash capacity in the Green River area was approximately 4,300,000 tons, which requires the mining of about 7,500,000 tons of trona.

Jan 1, 1975

By Philip C. Tully

The Bureau of Mines, in a continuing effort to improve processes and methods of helium purification, has developed a differential distillation method for removing helium-3 from helium-4. Differential distillation at 4.2 to 1.6 K was used to reduce the helium-3 in helium-4 from about 200 to less than 1 part per billion. The results from four stills ranging in size from 1 to 25 liters are reported. The method has the potential to be adapted to commercial-scale separations.

Jan 1, 1975

By George J. Conroy

Types and causes of short-circuit and open-circuit faults in mine portable trailing cables are discussed, and techniques for locating these faults are described. Time domain reflectometers (TDR) , tone generator, infrared sensing, and high voltage methods are covered. The paper summarizes Bureau of Mines research, including development of a ~DR/tone generator sender with auxiliary probe.

Jan 1, 1975

By Johnson RD

The variation in coal properties and the coal seam reduced level can be analysed using partial trend-surface analysis techniques. For the area studied seam reduced level and seam thickness data from the Bulli Coal yield trend-surfaces with a high coefficient of determination, since they have relatively small systematic local and random components in their overall variation. Sulphur content appears to have no significant re.gi_onal trend, and phosphorus content has a very weak regional trend. Other analytical variables have regional trends which are of intermediate strength. The strike-directions of.the statistically significant first degree! trend-surface are similar, sug-gesting.: that the variation of the several coal properties was controlled by a set of- related causes. The relations apparent from the dip and strike of the first degree trend-surfaces are similar to- those which are apparent from the trend- surface residuals and'from the results' of canonical trend-surface analysis.'.. It is probable that differential subsidence controlled the areal

Jan 1, 1975

By Lynch AJ, Musgrove NH

The behaviour of chalcopyrite and pyrite in the rougher-scavenger and regrind-retreatment circuits in the Warrego concentrator is discussed. The effects of change in xanthate addition on the separation of chalcopyrite and pyrite is described. The effect of the regrind mill on the (flotation rate of particles containing chalcopyrite and pyrite is discussed with particular reference to the importance of removing sub-mesh particles from the feed to the regrind mill.

Jan 1, 1975

To be able to continuously monitor the noise to which underground workers are exposed as a better way to help prevent hearing damage. The Approach: The Bureau of Mines has developed a Time-Resolved Audio Dosimeter which can be worn by miners to record noise level every 30 seconds and store It in a miniature solid state memory. Figure 1 is a photo of the dosimeter. [ ] How It Works: Acoustical noise is picked up by a micro-phone and fed to a sound level meter which produces a d-c voltage proportional to the A-weighted sound pressure level. (As specified by federal regulations, the A-weighted sound pres-sure level approximates the response of the ear by discounting the higher and lower frequency components of the noise.) This d-c voltage controls an oscillator which, together with related circuitry, produces a pulse train having a frequency that's proportional to the noise level.

Jan 1, 1975

By Carl E. Williams

A computer program has been developed which will locate the economic limits of an open-pit mine and also designate which ore and waste blocks to remove per period (years or quarters) to maximize the discounted cash flow over the life of the mine. A set of operating constraints was carefully selected so that the following functions are controlled: (1) the removal of overburden by preproduction and production stripping exposes a fixed amount of ore; (2) a constant manpower and equipment usage is insured (except for trucks); (3) the tons of mill ore, concentrate, and stockpiled ore are regulated; (4) the number and extent of shovel moves are minimized; (5) the grindability of the rock is considered as well as the variable haulage cost caused by variable haulage distances and depths; and (6) the size of the shovel working area is regulated. As many as 50 alternate schedules can be produced per computer run. They are arranged in descending order starting with the best solution.

Jan 1, 1975

By Joseph W. Leonard

Seven formulas commonly used to evaluate industrial screening efficiency are investigated to determine if they are suitable for calculating the efficiency of rectangular-hole screens. Six formulas were found to be limited in application to square-hole screens. The seventh, although acceptable for evaluating rectangular-hole as well as square-hole screening efficiency, was found to be unwieldy. A new formula is developed based on the concept of misplaced sizes. This proposed formula permits the single step determination of efficiency and is applicable to all types of screening applications.

Jan 1, 1975

By Robert M. Grogan, Gill Montgomery

Fluorspar, the commercial name for fluorite, is a mineral composed of calcium fluoride, CaF,. Its valuable properties are due to its content of fluorine, and it is the principal commercial source of that element. The name is derived from the Latin word "fluere," to flow, because the mineral has a low melting point and is used in metallurgy as a flux. Cryolite is a sodium aluminum fluoride, Na,AlF,. It is a rare mineral which has been found in commercial quantities in only one place in the world, Greenland. Small amounts of it are shipped from stock in that country, and its place in industry has been taken over almost completely by synthetic cryolite. Because of the relative unimportance of cryolite, discussion of it has been relegated to a short section at the end of this chapter, which is principally concerned with fluorspar. History Fluorspar was used for ornamental purposes by the Greeks and Romans, who fashioned such things as vases, drinking cups, and table tops from it. Various peoples including the Chinese and the American Indians carved ornaments and figurines from large crystals. Its usefulness as a flux was known to Agricola (1564), who wrote about it in 1546. Mining began in England about 1775 and at various places in the United States during the period 1820 to 1840. Production became substantial following the development and widespread adoption of the basic open hearth method of making steel, in which fluorspar is used as a flux. After that, production and usage were stimulated by growth in the steel, aluminum, chemical, and ceramic industries and were accelerated by World Wars I and II. Fluorocarbons entered the picture in 193 1 and the use of anhydrous hydrogen fluoride (HF) as a catalyst in the manufacture of alkylate for high octane fuel blends began in 1942. The development of the froth flotation process in the late 1920s, a differential flotation scheme for separating fluorspar from galena, sphalerite, and common gangue minerals in the 1930s, and the application of heavy-media concentrating methods to the treatment of low grade ores in the 1940s were outstanding technological contributions that enabled increased production of fluorspar concentrates. In recent years the development of pelletizing and briquetting processes for making flotation concentrates into gravel-size particles for use in steel furnaces and the development of more efficient and selective flotation schemes for treating crude ores containing abundant dolomite and barite have been major improvements in the industry.

Jan 1, 1975

By James A. Commins

Accurate engineering predictions of energy needs for pollution control equipment used in surface mining operations is critically important to sound management selection of control alternatives. This paper will describe a procedure for evaluating two control alternatives with different energy needs. Three steps are involved: an analysis of the pertinent regulations, a determination of the size distribution of the particles being emitted, a calculation of the energy needs and costs of the candidate control systems as a function of these regulations and emission characteristics. The principal air pollutant to be controlled in surface mining operations is particulates, or dust, some of which is already on the material introduced into the primary crusher and other dust which is generated by the various steps in the subsequent processes. The requirement for control stems both from regulations concerning workers at the operating site, and the community surrounding the operations. In order to speak quantitatively about the need for control we will use regulations that pertain in Pennsylvania although it must be borne in mind that such regulations vary according to juristiction.

Jan 1, 1975

By John B. Gustavson

Gold was first discovered in Alabama in 1830. Before a decade had passed more than 20,000 people were employed in the various gold districts scattered across east-central Alabama. By 1849 most of the presently defined gold districts were known with such towns as Arbacoochee, Chulafinnee, Goldville, Pinetucky, and Idaho being the principal mining camps. The California gold rush of 1849 signaled the end of intensive prospecting in the Alabama Piedmont for the precious metal. Reactivation of many of the old gold districts has been attempted several times since 1849. Significant activity and development took place between 1874 and 1880, 1888 and 1916, and 1929 and 1936. Locally, some of the development met with moderate succes. The last productive gold mine in Alabama ceased production in 1935. The sharp increase in gold prices since 1973 has caused renewed interest in the potential values of gold of the Alabama gold districts. Most of the gold workings have been abandoned for nearly 75 years and are for the most part inaccessible for convential property evaluation. The early gold miners and prospectors in Alabama were more intent upon finding and mining the valuable metal than in recording their activities for future generations. No matter how interesting or historically significant these records might have been the miners kept no records and left behind them few maps as clues to their activities. Inasmuch as most of the old gold districts have been extensively mined and prospected during the past 150 years, there is very little chance of finding large deposits through conventional outcrop prospecting methods. Similarly, the present geologic knowledge of the various districts is insufficient to launch successful exploration programs looking for large blind lode deposits in new locations within the general gold bearing region.

Jan 1, 1975

To develop more accurate means of measuring low ventilating air velocities in underground mines to facilitate compliance with ventilation standards. The Approach: A commercially available vane anemometer which produces an electrical, rather than a mechanical, output was coupled to electronic circuitry to produce the Bureau's Digital Low Velocity Anemometer (see photo). [ ] How It Works: The experimental instrument has a vane anemometer head which produces an electrical output signal with a frequency directly proportional to the rotating speed of the vane anemometer shaft. The commercially available ABBIRKO FLOWMASTER anemometer head was used in this instrument. In the signal conditioning circuits the electrical signal from the anemometer is converted into pulses, which are counted during either 3-second or 1-minute intervals, depending on the position of the operator's control switch. (Readout is either "instantaneous" or averaged for a period of one minute.) The number of pulses counted is then translated (integrated and divided by a constant) in the logic circuits to get average speed. Average air velocity in feet per minute is displayed in illuminated digits. (See simplified diagram of circuitry.)

Jan 1, 1975

The Florida phosphate industry, which supplies about three-quarters of the domestic phosphate fertilizer, produces tremendous volumes of phosphatic clay wastes (slimes). These clays retain a high percentage of water for extended periods of time. The clays also pose an environmental hazard because the disposal technique involves aboveground storage behind earthen dams. Although much research has been undertaken by numerous organizations to dewater slime, no completely satisfactory solution has been developed. In June 1972, a cooperative effort by the Federal Bureau of Mines and the Florida phosphate mining industry was initiated to develop a solution for dewatering the Florida phosphatic slimes. This report discusses various aspects of the slimes problem, reviews past research, makes recommendations for future research, and includes a bibliography of references and patents dealing with the subject.

Jan 1, 1975